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    Metallic monolith catalyst support for selective gas phase reactions in tubular fixed bed reactors
    1.
    发明授权
    Metallic monolith catalyst support for selective gas phase reactions in tubular fixed bed reactors 有权
    用于管式固定床反应器中选择性气相反应的金属整料催化剂载体

    公开(公告)号：US07678343B2

    公开(公告)日：2010-03-16

    申请号：US09746219

    申请日：2000-12-22

    申请人： Diego Carmello ,  Andrea Marsella ,  Pio Forzatti ,  Enrico Tronconi ,  Gianpiero Groppi

    发明人： Diego Carmello ,  Andrea Marsella ,  Pio Forzatti ,  Enrico Tronconi ,  Gianpiero Groppi

    IPC分类号： B01D50/00 ,  B01D53/34

    CPC分类号： B01J35/04 ,  B01J19/2485 ,  B01J37/0225 ,  B01J2219/2404 ,  B01J2219/2407 ,  B01J2219/2408 ,  B01J2219/2428 ,  B01J2219/2434 ,  B01J2219/2445 ,  B01J2219/2446

    摘要： There is disclosed a catalyst support for selective gas phase reactions in a tubular fixed bed reactor comprising a metallic monolith having channels the walls of which are adapted to receive a catalytically active phase or an intermediate layer acting as a carrier for a catalytically active phase. The monoliths are coated with catalytically active material and loaded lengthwise into tubular reactors, the channels being parallel to the length of the reactors. The catalysts are particularly useful in the chlorination/oxychlorination of alkenes and alkanes, and the oxidation of alkenes. Compared with the use of conventional catalysts in pellet form or in the form of ceramic monoliths the catalysts of the invention offer greater yields and selectivity, the avoidance of hot spots, greater catalyst life and flexibility in use.

    摘要翻译： 公开了一种用于管式固定床反应器中的选择性气相反应的催化剂载体，其包括具有通道的金属整料，其通道适于接收催化活性相或作为催化活性相载体的中间层。 整料用催化活性材料涂覆并纵向加载到管式反应器中，通道平行于反应器的长度。 催化剂特别适用于烯烃和烷烃的氯化/氧氯化和烯烃的氧化。 与使用颗粒形式的常规催化剂或以陶瓷整料的形式相比，本发明的催化剂提供更高的产率和选择性，避免热点，更大的催化剂寿命和使用的灵活性。

    Process for preparing an oxidation catalyst
    4.
    发明授权
    Process for preparing an oxidation catalyst 失效
    制备氧化催化剂的方法

    公开(公告)号：US4563440A

    公开(公告)日：1986-01-07

    申请号：US577756

    申请日：1984-02-07

    申请人： Pio Forzatti ,  Ferruccio Trifiro ,  Pierluigi Villa

    发明人： Pio Forzatti ,  Ferruccio Trifiro ,  Pierluigi Villa

    IPC分类号： C07C5/333 ,  B01J23/84 ,  B01J23/843 ,  B01J23/88 ,  B01J27/057 ,  C07B61/00 ,  C07C1/00 ,  C07C11/12 ,  C07C45/35 ,  C07C47/22 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  B01J21/06

    CPC分类号： C07C253/26 ,  B01J23/84 ,  B01J23/8435 ,  B01J27/0576 ,  C07C45/35 ,  B01J2523/00 ,  Y02P20/52

    摘要： This invention provides a catalyst composition suitable for the gas phase oxidation, ammoxidation and oxidative dehydrogenation of olefins to unsaturated aldehydes, unsaturated nitriles and dienes respectively. The catalyst composition comprises, as active catalyst component, a solid solution of Fe, Sb and Ti oxides which has a rutile type crystal structure which is present in the composition in an amount of at least 80 wt. %, and which is represented by the empirical formula Fe.sub.x Sb.sub.y Ti.sub.z O.sub.w, wherein, for x=1, y is in the range of 0.5 to 10, z is in the range of 0.16 to 209 and w represents the number of oxygen atoms corresponding to the oxides of the above elements. The catalyst component is prepared by co-precipitating metal oxides from solutions of corresponding metal salts followed by calcination at 600.degree.-1000.degree. C. of the washed and dried precipitate.

    摘要翻译： 本发明提供一种催化剂组合物，其适用于分别将烯烃氧化，氨氧化和氧化脱氢成不饱和醛，不饱和腈和二烯烃。 作为活性催化剂组分，催化剂组合物包含Fe，Sb和Ti氧化物的固溶体，其具有金红石型晶体结构，其组合物中存在至少80wt。 ％，并且由经验式FexSbyTizOw表示，其中，对于x = 1，y在0.5至10的范围内，z在0.16至209的范围内，w表示对应于氧化物的氧原子数 的上述要素。 催化剂组分通过将相应金属盐溶液中的金属氧化物共沉淀，然后在600-1000℃煅烧洗涤和干燥的沉淀物来制备。