Pesticidally active phosphoric (phosphonic) acid ester amides
    1.
    发明授权
    Pesticidally active phosphoric (phosphonic) acid ester amides 失效
    杀虫活性磷酸(膦酸)酸酯酰胺

    公开(公告)号:US4386082A

    公开(公告)日:1983-05-31

    申请号:US352687

    申请日:1982-02-26

    摘要: The invention relates to new phosphoric (phosphonic) acid ester amides of the general formula ##STR1## wherein R.sup.1 represents a hydrogen atom or an optionally substituted alkyl radical,R.sup.2 represents an optionally substituted alkyl or optionally substituted alkoxy radical,R.sup.3 represents an optionally substituted alkyl or optionally substituted aryl radical andHal represents a halogen atom,which are obtained by the reaction of phosphoric (phosphonic) acid ester amides of the general formula ##STR2## wherein R.sup.1, R.sup.2 and Hal have the meaning given above, with sulphenyl chlorides of the general formulaClSR.sup.3 (III)wherein R.sup.3 has the meaning given above, in the presence of an acid acceptor and, if appropriate, in the presence of a solvent, and which can be used for combating pests (such as insects, acaricids and nematodes) or for combating microbes (especially fungi).

    摘要翻译: 本发明涉及通式为(I)的新的磷酸(膦酸)酯酰胺,其中R 1表示氢原子或任选取代的烷基,R 2表示任选取代的烷基或任选取代的烷氧基,R 3表示 任选取代的烷基或任选取代的芳基,Hal表示卤素原子,其通过使通式(II)的磷酸(膦酸)酯酯酰胺(其中R1,R2和Hal具有上述含义) ,其中R3具有上述含义的通式为ClSR 3(III)的磺酰氯,在酸受体存在下,如果合适的话,在溶剂存在下,可用于防治害虫(如 昆虫,螨类和线虫)或用于对抗微生物(特别是真菌)。

    Pesticidally active novel phosphoric (phosphonic) acid ester amides
    5.
    发明授权
    Pesticidally active novel phosphoric (phosphonic) acid ester amides 失效
    杀虫活性新型磷酸(膦酸)酸酯酰胺

    公开(公告)号:US4389530A

    公开(公告)日:1983-06-21

    申请号:US352723

    申请日:1982-02-26

    摘要: Pesticidally active novel phosphoric (phosphonic) acid ester amides have the general formula ##STR1## wherein R.sup.1 represents hydrogen or optionally substituted alkyl,R.sup.2 represents optionally substituted alkyl or optionally substituted alkoxy,R.sup.3 represents optionally substituted alkyl andHal represents halogen,and are obtained if phosphoric (phosphonic) acid ester amides of the formula ##STR2## wherein R.sup.1, R.sup.2 and Hal have the meanings given above, are reacted with trialkyl-chlorosilanes of the formulaClSi(R.sup.3).sub.3 (III)whereinR.sup.3 has the meaning given above, in the presence of an acid acceptor and, if appropriate, in the presence of a solvent. The compounds (I) can be used as pest-combating agents, particularly as insecticides and acaricides.

    摘要翻译: 杀虫活性的新型磷酸(膦酸)酸酯酰胺具有通式(I)其中R 1表示氢或任选取代的烷基,R 2表示任选取代的烷基或任选取代的烷氧基,R 3表示任选取代的烷基,Hal表示卤素, 其中R 1,R 2和Hal具有上面给出的含义的式(II)的磷酸(膦酸)酸酯酰胺与式ClSi(R3)3(III)的三烷基氯硅烷反应,其中R3 具有上述含义,在酸受体存在下,如果合适的话,在溶剂存在下。 化合物(I)可以用作防虫剂,特别是杀虫剂和杀螨剂。

    Combating pests with novel phenoxypyridylmethyl esters
    8.
    发明授权
    Combating pests with novel phenoxypyridylmethyl esters 失效
    用新的苯氧基吡啶甲基酯来防治害虫

    公开(公告)号:US4491585A

    公开(公告)日:1985-01-01

    申请号:US355044

    申请日:1982-03-05

    摘要: New phenoxypyridylmethyl esters of the general formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 have the meaning given in the description andR represents the radical ##STR2## wherein R.sup.4 and R.sup.5 have the meaning given in the description, and represents the radical ##STR3## wherein R.sup.6 and R.sup.7 have the meaning given in the description, are obtained by a process in which carboxylic acids of the general formulaR--COOH (II)wherein R has the meaning given previously, or reactive derivatives of these acids, are reacted with phenoxypyridyl alcohols of the general formula ##STR4## wherein R.sup.1, R.sup.2 and R.sup.3 have the meaning given above, or with reactive derivatives of these alcohols, if appropriate in the presence of acid acceptors, if appropriate in the presence of catalysts and if appropriate in the presence of diluents. The new phenoxypyridylmethyl esters of the formula (I) are distinguished by a high pesticidal, particularly insecticidal and acardicidal activity.

    摘要翻译: 新颖的通式(I)的苯氧基吡啶甲基酯其中R1,R2和R3具有说明书中给出的含义,R代表基团,其中R4和R5具有说明书中给出的含义,并且表示基团 其中R6和R7具有说明书中给出的含义,通过其中R具有以前给出的含义或这些酸的反应性衍生物的通式为R-COOH(II)的羧酸为 与式(III)的苯氧基吡啶醇反应,其中R 1,R 2和R 3具有上述含义,或与这些醇的活性衍生物反应,如果合适,在酸受体存在下,如果合适的话,在催化剂存在下 并在适当的情况下在稀释剂存在下进行。 式(I)的新的苯氧基吡啶基甲基酯的特征在于高杀虫性,特别是杀虫和杀虫活性。

    Combating pests with novel pyrazol-4-yl N-alkylcarbamates
    10.
    发明授权
    Combating pests with novel pyrazol-4-yl N-alkylcarbamates 失效
    用新的吡唑-4-基N-烷基氨基甲酸酯抗虫

    公开(公告)号:US4423058A

    公开(公告)日:1983-12-27

    申请号:US360138

    申请日:1982-03-22

    IPC分类号: A01N47/18 C07D231/18

    CPC分类号: C07D231/18 A01N47/18

    摘要: New pyrazol-4-yl N-alkylcarbamates of the general formula ##STR1## in which R.sup.1 represents an optionally substituted alkyl group having more than one carbon atom or an alkenyl, alkinyl or cycloalkyl group, andR.sup.2 represents an optionally substituted alkyl,alkenyl, alkinyl, cycloalkyl, aralkyl or aryl group, can be obtained if a 4-hydroxypyrazole of the general formula ##STR2## is reacted with an isocyanate of the general formulaR.sup.1 --N.dbd.C.dbd.O (III)or with a carbamoyl halide of the general formulaR.sup.1 --NH--CO--Hal (IV).The new compounds are distinguished by a high degree of activity as pest-combating agents, in particular by their insecticidal and nematicidal activity.

    摘要翻译: 新的吡唑-4-基N-烷基氨基甲酸酯,其中R 1表示任选取代的具有多于一个碳原子的烷基或烯基,炔基或环烷基,R 2表示任选取代的烷基 如果通式为(II)的4-羟基吡唑与通式为R 1 -N = C = O(III)的异氰酸酯反应,则可以得到,烯基,炔基,环烷基,芳烷基或芳基, 与通式为R 1 -NH-CO-Hal(IV)的氨基甲酰卤反应。 新化合物的特征在于作为防虫剂的高度活性,特别是其杀虫和杀线虫活性。