Thermoplastic molding materials of polyester and polycarbonate
    1.
    发明授权
    Thermoplastic molding materials of polyester and polycarbonate 失效
    聚酯和聚碳酸酯的热塑性成型材料

    公开(公告)号:US4764556A

    公开(公告)日:1988-08-16

    申请号:US47132

    申请日:1987-05-08

    CPC分类号: C08L67/02 C08L67/03 C08L69/00

    摘要: Thermoplastic molding materials contain, as essential components,(A) from 10 to 89% by weight of a blend of(A.sub.1) from 20 to 98% by weight, based on (A.sub.1)+(A.sub.2), of a polyester of an aromatic dicarboxylic acid and an aliphatic dihydroxy compound and(A.sub.2) from 2 to 80% by weight, based on (A.sub.1)+(A.sub.2), of a polyester of an aromatic dicarboxylic acid and an aromatic dihydroxy compound of the formula I ##STR1## or its C.sub.1 -C.sub.6 -alkyl or halogen derivative substituted in the nucleus, where Z is an alkylene or cycloalkylene group of not more than 8 carbon atoms, an arylene group of not more than 12 carbon atoms, --O--, --S--, ##STR2## or a chemical bond and m is 0 or 1, (B) from 10 to 89% by weight of a polycarbonate and(C) from 1 to 30% by weight of a rubber toughener having a glass transition temperature of less than -30.degree. C.

    摘要翻译: 热塑性成型材料含有作为必要组分的(A)10至89重量%的(A1)20至98重量%(A1)+(A2)的芳族聚酯的共混物 二羧酸和脂族二羟基化合物,和(A2)基于(A1)+(A2)的2-80重量%的芳族二羧酸的聚酯和式I的芳族二羟基化合物(IMAGE)( I)或其在核中被取代的C 1 -C 6 - 烷基或卤素衍生物,其中Z是不大于8个碳原子的亚烷基或亚环烷基,不超过12个碳原子的亚芳基,-O - , - S - ,或化学键,m为0或1,(B)10至89重量%的聚碳酸酯和(C)1至30重量%的橡胶增韧剂,其玻璃化转变温度为 小于-30℃

    Thermoplastic molding materials containing a polyester and a
polycarbonate
    2.
    发明授权
    Thermoplastic molding materials containing a polyester and a polycarbonate 失效
    含有聚酯和聚碳酸酯的热塑性成型材料

    公开(公告)号:US4791158A

    公开(公告)日:1988-12-13

    申请号:US72031

    申请日:1987-07-10

    CPC分类号: C08K5/42 C08L67/02 C08L69/00

    摘要: Thermoplastic molding materials contain, as essential components,(A) from 10 to 89.99% by weight of a polyester,(B) from 10 to 89.99% by weight of a polycarbonate and(C.sub.1) from 0.01 to 1% by weight of a low molecular weight organic compound of not more than 70 carbon atoms which contains (--SO.sub.3).sub.m Q groups where Q is hydrogen, NH.sub.4 or an alkali or alkaline earth metal and m is an integer equal to the valency of Q, and/or(C.sub.2) from 0.01 to 30% by weight of a polymer containing sulfo groups and having a weight average molecular weight of not less than 1000,and, as a further component,(D) from 0 to 30% by weight of a rubber impact modifier.

    摘要翻译: 热塑性成型材料作为必要成分含有(A)10〜89.99重量%的聚酯,(B)10〜89.99重量%的聚碳酸酯和(C1)0.01〜1重量%的低聚物 含有(-SO 3)m Q基团的不超过70个碳原子的分子量有机化合物,其中Q是氢,NH4或碱金属或碱土金属,m是等于Q的化合价的整数,和/或(C2) 0.01〜30重量%的含有磺基且重均分子量为1000以上的聚合物,作为其他成分,(D)0〜30重量%的橡胶抗冲改性剂。

    Thermoplastic molding materials based on polyphenylene ethers and
polyesters
    3.
    发明授权
    Thermoplastic molding materials based on polyphenylene ethers and polyesters 失效
    基于聚苯醚和聚酯的热塑性成型材料

    公开(公告)号:US5180778A

    公开(公告)日:1993-01-19

    申请号:US574073

    申请日:1990-08-29

    IPC分类号: C08L67/00 C08L67/02 C08L71/12

    摘要: Thermoplastic molding materials containA) not less than 5% by weight of a polymer component consisting of from 50 to 100% by weight of polyphenylene ethers and from 0 to 50% by weight of a styrene polymer differing from component C),B) not less than 5% by weight of a polyester,C) not less than 0.1% by weight of a copolymer consisting ofC.sub.1) not less than 20% by weight of .alpha.-olefins of 2 to 8 carbon atoms, styrene or substituted styrenes of the general formula I ##STR1## where R and R.sup.1 is alkyl of 1 to 8 carbon atoms, hydrogen and/or halogen and n is 0, 1 or 2, or a mixture of these monomers,C.sub.2) not less than 0.5% by weight of a polymerizable monomer containing epoxide groups, and/orC.sub.3) not less than 0.05% by weight of a halobenzyl-containing polymerizable monomer having the structural unit (II) ##STR2## where X is halogen and R.sup.2 and R.sup.3 are each alkyl of 1 to 8 carbon atoms or hydrogen and n is 1, 2 or 3, and/orC.sub.4) not less than 0.05% by weight of a polymerizable monomer containing oxazoline groups, andC.sub.5) from 0 to 65% by weight of acrylonitrile, methacrylonitrile and further nonionic comonomers, andD) from 0 to 40% by weight of a rubber impact modifier.

    摘要翻译: 热塑性成型材料包含A)不小于5重量%的由50至100重量%的聚苯醚和0至50重量%的不同于组分C)的苯乙烯聚合物组成的聚合物组分,B)不 小于5重量%的聚酯,C)不小于0.1重量%的由C1组成的共聚物,不少于20重量%的碳原子数2〜8的α-烯烃,苯乙烯或苯乙烯的取代苯乙烯 通式I其中R和R 1是1至8个碳原子的烷基,氢和/或卤素,n是0,1或2,或这些单体的混合物,C2)不小于0.5% 重量的含有环氧基的可聚合单体和/或C3)不少于0.05重量%的具有结构单元(II)的卤代苄基的可聚合单体(II),其中X是卤素,R 2和R 3 各自为1至8个碳原子的烷基或氢,n为1,2或3,和/或C 4)不小于0.05重量%的可聚合单体 r为0〜65重量%的丙烯腈,甲基丙烯腈和其它非离子共聚单体,和D)0〜40重量%的橡胶抗冲改性剂。

    Thermoplastics molding materials based on polyphenylene ethers and
polyesters
    4.
    发明授权
    Thermoplastics molding materials based on polyphenylene ethers and polyesters 失效
    基于聚苯醚和聚酯的热塑性塑料成型材料

    公开(公告)号:US4962157A

    公开(公告)日:1990-10-09

    申请号:US209210

    申请日:1988-06-20

    IPC分类号: C08L67/00 C08L67/02 C08L71/12

    摘要: Thermoplastic molding materials contain(A) not less than 5% by weight of a polymer component consisting of from 50 to 10 % by weight by polyphenylene ethers and from 0 to 50% by weight of a styrene polymer differing from component (C),(B) not less than 5% by weight of a polyester,(C) not less than 0.1% by weight of a copolymer consisting of(C.sub.1) not less than 20% by weight of .alpha.-olefins of 2 to 8 carbon atoms, styrene or substituted styrenes of the general formula I ##STR1## where R and R.sup.1 is alkyl of 1 to 8 carbon atoms, hydrogen and/or halogen and n is 0, 1 or 2, or a mixture of these monomers,(C.sub.2) not less than 0.5% by weight of a polymerizable monomer containing epoxide groups,and/or(C.sub.3) not less than 0.05% by weight of a halobenzyl-containing polymerizable monomer having the structural unit (II) ##STR2## where X is halogen and R.sup.2 and R.sup.3 are each alkyl of 1 to 8 carbon atoms or hydrogen and n is 1, 2 or 3,and/or(C.sub.4) not less than 0.05% by weight of a polymerizable monomer containing oxazoline groups,and(C.sub.5) from 0 to 65% by weight of acrylonitrile, methacrylonitrile and further nonionic comonomers, and(D) from 0 to 40% by weight of a rubber impact modifier.

    摘要翻译: 热塑性成型材料含有(A)不少于5重量%的由聚苯醚组成的聚合物组分50至10重量%和0至50重量%不同于组分(C)的苯乙烯聚合物,(C) B)不小于5重量%的聚酯,(C)不小于0.1重量%的由(C1)不低于20重量%的2-8个碳原子的α-烯烃组成的共聚物,苯乙烯 或通式I的取代苯乙烯(I)其中R和R 1是1至8个碳原子的烷基,氢和/或卤素和n是0,1或2,或这些单体的混合物(C2 )不小于0.5重量%的含有环氧基的可聚合单体,和/或(C3)不小于0.05重量%的具有结构单元(II)的卤代苄基的可聚合单体(II)其中 X是卤素,R 2和R 3各自是1至8个碳原子的烷基或氢,n是1,2或3,和/或(C 4)不小于0.05重量%的聚合物 包含恶唑啉基的单体,和(C5)0至65重量%的丙烯腈,甲基丙烯腈和其它非离子共聚单体,和(D)0至40重量%的橡胶抗冲改性剂。

    Preparation of p-nitrophenyl-imidazoles
    7.
    发明授权
    Preparation of p-nitrophenyl-imidazoles 失效
    对硝基苯基咪唑的制备

    公开(公告)号:US5008398A

    公开(公告)日:1991-04-16

    申请号:US416027

    申请日:1989-10-02

    IPC分类号: C07D233/54 C07D233/64

    CPC分类号: C07D233/64

    摘要: A process for the preparation of imidazoles which are substituted with p-nitrophenyl in the 2- and/or 4- and/or 5-position and may carry additional substituents, by reacting imidazoles which are substituted by phenyl in the 2- and/or 4- and/or 5-position and may carry additional substituents with mixtures of sulfuric acid and nitric acid, wherein the reaction is carried out in the presence of urea.

    摘要翻译: 在2-和/或4-和/或5-位上用对硝基苯取代的咪唑制备方法,可以通过在2-和/或 4-和/或5-位,并且可以用硫酸和硝酸的混合物携带另外的取代基,其中反应在尿素存在下进行。

    Self-extinguishing, thermoplastic polyphenylene ether/polyamide molding
materials and their use for the production of moldings
    8.
    发明授权
    Self-extinguishing, thermoplastic polyphenylene ether/polyamide molding materials and their use for the production of moldings 失效
    自熄性,热塑性聚苯醚/聚酰胺成型材料及其用于生产模塑品

    公开(公告)号:US4866114A

    公开(公告)日:1989-09-12

    申请号:US250170

    申请日:1988-09-28

    摘要: Self-extinguishing, thermoplastic polyphenylene ether/polyamide molding materials contain, as essential components,(A) from 10 to 90% by weight of component (A), which consists of(A.sub.1) from 70 to 99% by weight of a modified polyphenylene ether,(A.sub.2) from 1 to 30% by weight of a compound containing bound phosphorus, the percentages by weight being based on the total weight of component (A), and(B) from 90 to 10% by weight of component (B), which consists of(B.sub.1) from 80 to 99% by weight of one or more polyamides and(B.sub.2) from 1 to 20% by weight of one or more compounds containing a bound triazine radical and from the group consisting of cyanuric acid and its derivatives.

    摘要翻译: 自熄性热塑性聚苯醚/聚酰胺成型材料含有作为必要成分的(A)10〜90重量%的成分(A),(A1)70〜99重量%的改性聚亚苯基 乙醚,(A2)1〜30重量%的含有结合磷的化合物,其重量百分比以组分(A)的总重量计,和(B)90至10重量%的组分(B ),其由(B1)80至99重量%的一种或多种聚酰胺和(B2)1至20重量%的一种或多种含有结合的三嗪基的化合物和由以下组成的组:(a)氰尿酸和 其衍生物。

    Graft polymers of polyphenylene ethers
    9.
    发明授权
    Graft polymers of polyphenylene ethers 失效
    聚苯醚接枝聚合物

    公开(公告)号:US4797453A

    公开(公告)日:1989-01-10

    申请号:US63687

    申请日:1987-06-19

    CPC分类号: C09D151/08 C08F283/08

    摘要: Graft polymers of(A) a polyphenylene ether as a base polymer and(B) a half ester of an unsaturated dicarboxylic acid of the general formula ##STR1## as a graft monomer, where R.sup.1 is C.sub.1 -C.sub.25 -alkyl, C.sub.2 -C.sub.25 -alkylene or aryl, R.sup.2 and R.sup.3 are each H, Br, Cl or one of the radicals R.sup.1, and Q is H or an alkali metal, an alkaline earth metal or an ammonium cation,with or without(C) further olefinically unsaturated monomers,and their preparation.

    摘要翻译: (A)聚苯醚作为基础聚合物的接枝聚合物和(B)作为接枝单体的通式为不饱和二羧酸的半酯,其中R 1是C 1 -C 25烷基,C 2 -C 25 - 亚烷基或芳基,R 2和R 3各自为H,Br,Cl或基团R 1中的一个,Q为H或碱金属,碱土金属或铵阳离子,具有或不具有(C)另外的烯属不饱和单体 ,及其准备。