摘要:
Thermoplastic molding materials contain, as essential components,(A) from 10 to 89% by weight of a blend of(A.sub.1) from 20 to 98% by weight, based on (A.sub.1)+(A.sub.2), of a polyester of an aromatic dicarboxylic acid and an aliphatic dihydroxy compound and(A.sub.2) from 2 to 80% by weight, based on (A.sub.1)+(A.sub.2), of a polyester of an aromatic dicarboxylic acid and an aromatic dihydroxy compound of the formula I ##STR1## or its C.sub.1 -C.sub.6 -alkyl or halogen derivative substituted in the nucleus, where Z is an alkylene or cycloalkylene group of not more than 8 carbon atoms, an arylene group of not more than 12 carbon atoms, --O--, --S--, ##STR2## or a chemical bond and m is 0 or 1, (B) from 10 to 89% by weight of a polycarbonate and(C) from 1 to 30% by weight of a rubber toughener having a glass transition temperature of less than -30.degree. C.
摘要:
Thermoplastic molding materials contain, as essential components,(A) from 10 to 89.99% by weight of a polyester,(B) from 10 to 89.99% by weight of a polycarbonate and(C.sub.1) from 0.01 to 1% by weight of a low molecular weight organic compound of not more than 70 carbon atoms which contains (--SO.sub.3).sub.m Q groups where Q is hydrogen, NH.sub.4 or an alkali or alkaline earth metal and m is an integer equal to the valency of Q, and/or(C.sub.2) from 0.01 to 30% by weight of a polymer containing sulfo groups and having a weight average molecular weight of not less than 1000,and, as a further component,(D) from 0 to 30% by weight of a rubber impact modifier.
摘要:
Thermoplastic molding materials containA) not less than 5% by weight of a polymer component consisting of from 50 to 100% by weight of polyphenylene ethers and from 0 to 50% by weight of a styrene polymer differing from component C),B) not less than 5% by weight of a polyester,C) not less than 0.1% by weight of a copolymer consisting ofC.sub.1) not less than 20% by weight of .alpha.-olefins of 2 to 8 carbon atoms, styrene or substituted styrenes of the general formula I ##STR1## where R and R.sup.1 is alkyl of 1 to 8 carbon atoms, hydrogen and/or halogen and n is 0, 1 or 2, or a mixture of these monomers,C.sub.2) not less than 0.5% by weight of a polymerizable monomer containing epoxide groups, and/orC.sub.3) not less than 0.05% by weight of a halobenzyl-containing polymerizable monomer having the structural unit (II) ##STR2## where X is halogen and R.sup.2 and R.sup.3 are each alkyl of 1 to 8 carbon atoms or hydrogen and n is 1, 2 or 3, and/orC.sub.4) not less than 0.05% by weight of a polymerizable monomer containing oxazoline groups, andC.sub.5) from 0 to 65% by weight of acrylonitrile, methacrylonitrile and further nonionic comonomers, andD) from 0 to 40% by weight of a rubber impact modifier.
摘要:
Thermoplastic molding materials contain(A) not less than 5% by weight of a polymer component consisting of from 50 to 10 % by weight by polyphenylene ethers and from 0 to 50% by weight of a styrene polymer differing from component (C),(B) not less than 5% by weight of a polyester,(C) not less than 0.1% by weight of a copolymer consisting of(C.sub.1) not less than 20% by weight of .alpha.-olefins of 2 to 8 carbon atoms, styrene or substituted styrenes of the general formula I ##STR1## where R and R.sup.1 is alkyl of 1 to 8 carbon atoms, hydrogen and/or halogen and n is 0, 1 or 2, or a mixture of these monomers,(C.sub.2) not less than 0.5% by weight of a polymerizable monomer containing epoxide groups,and/or(C.sub.3) not less than 0.05% by weight of a halobenzyl-containing polymerizable monomer having the structural unit (II) ##STR2## where X is halogen and R.sup.2 and R.sup.3 are each alkyl of 1 to 8 carbon atoms or hydrogen and n is 1, 2 or 3,and/or(C.sub.4) not less than 0.05% by weight of a polymerizable monomer containing oxazoline groups,and(C.sub.5) from 0 to 65% by weight of acrylonitrile, methacrylonitrile and further nonionic comonomers, and(D) from 0 to 40% by weight of a rubber impact modifier.
摘要:
Thermoplastic molding materials based on(A) polycarbonates and(B) polyesters containing from 1 to 30% by weight, based on (A)+(B)+(C),(C) of a graft copolymer based on(C.sub.1) from 60 to 99% by weight of an elastomeric component based on acrylic acid esters, methacrylic acid esters and/or conjugated dienes as well as, if desired, further comonomers, as graft base and(C.sub.2) from 1 to 40% by weight of an expoxy-containing monomer as applied graft.
摘要:
Thermoplastic molding materials which consist of polyesters and polycarbonates and have good low-temperature impact strength contain(A) from 5 to 94 parts by weight of one or more aliphatic polyesters of an aromatic dicarboxylic acid,(B) from 5 to 94 parts by weight of one or more aromatic polycarbonates,(C) from 1 to 40 parts by weight of one or more olefin polymers which contain epoxide groups,the amounts of components A, B and C summing to 100 parts by weight, and, if required,(D) additives in effective amounts.
摘要:
A process for the preparation of imidazoles which are substituted with p-nitrophenyl in the 2- and/or 4- and/or 5-position and may carry additional substituents, by reacting imidazoles which are substituted by phenyl in the 2- and/or 4- and/or 5-position and may carry additional substituents with mixtures of sulfuric acid and nitric acid, wherein the reaction is carried out in the presence of urea.
摘要:
Self-extinguishing, thermoplastic polyphenylene ether/polyamide molding materials contain, as essential components,(A) from 10 to 90% by weight of component (A), which consists of(A.sub.1) from 70 to 99% by weight of a modified polyphenylene ether,(A.sub.2) from 1 to 30% by weight of a compound containing bound phosphorus, the percentages by weight being based on the total weight of component (A), and(B) from 90 to 10% by weight of component (B), which consists of(B.sub.1) from 80 to 99% by weight of one or more polyamides and(B.sub.2) from 1 to 20% by weight of one or more compounds containing a bound triazine radical and from the group consisting of cyanuric acid and its derivatives.
摘要:
Graft polymers of(A) a polyphenylene ether as a base polymer and(B) a half ester of an unsaturated dicarboxylic acid of the general formula ##STR1## as a graft monomer, where R.sup.1 is C.sub.1 -C.sub.25 -alkyl, C.sub.2 -C.sub.25 -alkylene or aryl, R.sup.2 and R.sup.3 are each H, Br, Cl or one of the radicals R.sup.1, and Q is H or an alkali metal, an alkaline earth metal or an ammonium cation,with or without(C) further olefinically unsaturated monomers,and their preparation.
摘要:
A sheet-like structure is produced from a vinyl alcohol polymer by a method wherein, in a self-cleaning multi-screw extruder, the polymer is mixed with a small amount of water, the mixture is melted, homogenized, devolatilized and finally extruded as a melt, and the extrudate is shaped in a conventional manner into the sheet-like structure.