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    Polypropylene silicate nanocomposites
    1.
    发明申请
    Polypropylene silicate nanocomposites 审中-公开
    聚丙烯硅酸盐纳米复合材料

    公开(公告)号：US20060260677A1

    公开(公告)日：2006-11-23

    申请号：US11435867

    申请日：2006-05-18

    申请人： Dotsevi Sogah ,  Xiao-Ping Chen ,  Hyuk Lee ,  Geoffrey Coates

    发明人： Dotsevi Sogah ,  Xiao-Ping Chen ,  Hyuk Lee ,  Geoffrey Coates

    IPC分类号： H01L31/00

    CPC分类号： C08L23/10 ,  C08L23/145 ,  C08L51/06 ,  C08L2666/24

    摘要： Nanoadditive is constituted of organophilic polymer or copolymer covalently bonded by linking group to silicate and is blended with polypropylene to produce nanocomposite which is useful in all cases where polypropylene is used and resists breakage and is not flammable and has improved barrier properties compared to neat polypropylene.

    摘要翻译： 纳米添加剂由有机聚合物或共聚物共聚而成，其通过连接基团与硅酸酯共价键合并与聚丙烯共混以制备纳米复合材料，其可用于所有使用聚丙烯且不易燃并且与纯聚丙烯相比具有改善的阻隔性的所有情况。

    Polycarbonates made using highly selective catalysts
    2.
    发明申请
    Polycarbonates made using highly selective catalysts 有权
    使用高选择性催化剂制备的聚碳酸酯

    公开(公告)号：US20070255039A1

    公开(公告)日：2007-11-01

    申请号：US11812106

    申请日：2007-06-15

    申请人： Geoffrey Coates ,  Zengquan Qin ,  Claire Cohen

    发明人： Geoffrey Coates ,  Zengquan Qin ,  Claire Cohen

    IPC分类号： B01J31/00 ,  C08G67/02

    CPC分类号： C07F15/065 ,  B01J31/1805 ,  B01J2231/14 ,  B01J2531/0252 ,  B01J2531/845

    摘要： Poly(propylene carbonates) are prepared from propylene oxide and CO2 with less than 10% cyclic propylene carbonate by product using cobalt based catalysts of structure preferably in combination with salt cocatalyst, very preferably cocatalyst where the cation is PPN+ and the anion is Cl− or OBzF5−. Novel products include poly(propylene carbonates) having a stereoregularity greater than 90% and/or a regioregularity of greater than 90%.

    摘要翻译： 聚（丙烯碳酸酯）由环氧丙烷和CO 2与小于10％的环状碳酸亚丙酯制成，使用优选结合盐助催化剂的钴基催化剂，非常优选助催化剂，其中阳离子为 PPN + +和 - 阴离子是Cl - O - 或 - O - Z - 。 新产品包括立构规整度大于90％和/或大于90％的区域规整度的聚（丙烯碳酸酯）。

    FUNCTIONALIZED POLY (ETHYLENE-CO-SYNDIOTACTIC PROPYLENE)
    4.
    发明申请
    FUNCTIONALIZED POLY (ETHYLENE-CO-SYNDIOTACTIC PROPYLENE) 失效
    功能性聚（乙烯 - 共聚丙烯）

    公开(公告)号：US20060041070A1

    公开(公告)日：2006-02-23

    申请号：US10921207

    申请日：2004-08-19

    申请人： Lewis Fetters ,  Geoffrey Coates

    发明人： Lewis Fetters ,  Geoffrey Coates

    IPC分类号： C08L9/00 ,  C08L23/04

    CPC分类号： C08F210/18 ,  C08F210/06 ,  C08F236/20 ,  C08F2500/16 ,  C08F2500/03

    摘要： Poly(ethylene-co-syndiotactic propylene) functionalized with group(s), that enable crosslinking, e.g., vinyl or anhydride group(s), in admixture with crosslinking agent and filler is subjected to crosslinking reaction to provide filled copolymer. The presence of propylene in syndiotactic sequences provides lower entanglement molecular weight compared to other propylene placement and therefore allows more filler to be present than for other propylene placement. Crosslinking provides filled materials with good elastomeric properties.

    摘要翻译： 通过与交联剂和填料的混合使得能够与乙烯基或酸酐基团交联的基团官能化的聚（乙烯 - 共间同立构丙烯）进行交联反应以提供填充的共聚物。 间同立构序列中丙烯的存在与其他丙烯放置相比提供较低的缠结分子量，因此与其它丙烯放置相比，允许存在更多的填料。 交联提供具有良好弹性体性能的填充材料。

    Ethylene-C4-C20-alkene copolymers
    5.
    发明申请
    Ethylene-C4-C20-alkene copolymers 审中-公开
    乙烯-C4-C20烯烃共聚物

    公开(公告)号：US20050107559A1

    公开(公告)日：2005-05-19

    申请号：US10983680

    申请日：2004-11-09

    申请人： Geoffrey Coates ,  Masayuki Fujita

    发明人： Geoffrey Coates ,  Masayuki Fujita

    IPC分类号： C08F210/02 ,  C08F20/06

    CPC分类号： C08F210/02 ,  C08F232/00 ,  C08F2500/03

    摘要： Poly (ethylene-co-C4-C20-alkene) copolymers or segments with polydispersities less than 1.3 and/or predominantly enchainment in a cis-1,2 fashion and/or poly(ethylene-co-C4-C20 monocyclic alkene) copolymers or segments provide in some cases substitutes for ultra high molecular weight polyethylenes and in some cases substitutes for polypropylenes and in some cases utility as gas barrier coatings.

    摘要翻译： 聚（乙烯 - 共-C 4 -C 20 - 烯烃）共聚物或多分散性小于1.3的链段和/或主要以顺式-1,1的方式链接， /或聚（乙烯 - 共-C 4 -C 20 -C 20单环烯烃）共聚物或链段在某些情况下提供了替代超高分子量聚乙烯，并且在某些情况下代替 聚丙烯，在某些情况下用作阻气涂层。

    Polycarbonates made using highly selective catalysts
    6.
    发明申请
    Polycarbonates made using highly selective catalysts 有权
    使用高选择性催化剂制备的聚碳酸酯

    公开(公告)号：US20080108499A1

    公开(公告)日：2008-05-08

    申请号：US11976800

    申请日：2007-10-29

    申请人： Geoffrey Coates ,  Zengquan Qin ,  Claire Cohen

    发明人： Geoffrey Coates ,  Zengquan Qin ,  Claire Cohen

    IPC分类号： B01J31/18

    CPC分类号： C07F15/065 ,  B01J31/1805 ,  B01J2231/14 ,  B01J2531/0252 ,  B01J2531/845

    摘要： Poly(propylene carbonates) are prepared from propylene oxide and CO2 with less than 10% cyclic propylene carbonate by product using cobalt based catalysts of structure preferably in combination with salt cocatalyst, very preferably cocatalyst where the cation is PPN+ and the anion is Cl− or OBzF5−. Novel products include poly(propylene carbonates) having a stereoregularity greater than 90% and/or a regioregularity of greater than 90%.

    摘要翻译： 聚（丙烯碳酸酯）由环氧丙烷和CO 2与小于10％的环状碳酸亚丙酯制成，使用优选结合盐助催化剂的钴基催化剂，非常优选助催化剂，其中阳离子为 PPN + +和 - 阴离子是Cl - O - 或 - O - Z - 。 新产品包括立构规整度大于90％和/或大于90％的区域规整度的聚（丙烯碳酸酯）。

    Polycarbonates made using highly selective catalysts
    7.
    发明申请
    Polycarbonates made using highly selective catalysts 有权
    使用高选择性催化剂制备的聚碳酸酯

    公开(公告)号：US20060089252A1

    公开(公告)日：2006-04-27

    申请号：US11244231

    申请日：2005-10-06

    申请人： Geoffrey Coates ,  Zengquan Qin ,  Claire Cohen

    发明人： Geoffrey Coates ,  Zengquan Qin ,  Claire Cohen

    IPC分类号： B01J31/00

    CPC分类号： C07F15/065 ,  B01J31/1805 ,  B01J2231/14 ,  B01J2531/0252 ,  B01J2531/845

    摘要： Poly(propylene carbonates) are prepared from propylene oxide and CO2 with less than 10% cyclic propylene carbonate by product using cobalt based catalysts of structure preferably in combination with salt cocatalyst, very preferably cocatalyst where the cation is PPN+ and the anion is Cl− or OBzF5−. Novel products include poly(propylene carbonates) having a stereoregularity greater than 90% and/or a regioregularity of greater than 90%.

    摘要翻译： 聚（丙烯碳酸酯）由环氧丙烷和CO 2与小于10％的环状碳酸亚丙酯制成，使用优选结合盐助催化剂的钴基催化剂，非常优选助催化剂，其中阳离子为 PPN + +和 - 阴离子是Cl - O - 或 - O - Z - 。 新产品包括立构规整度大于90％和/或大于90％的区域规整度的聚（丙烯碳酸酯）。

    Polyolefins having reduced crystallinity
    9.
    发明授权
    Polyolefins having reduced crystallinity 有权
    具有降低的结晶度的聚烯烃

    公开(公告)号：US08389660B1

    公开(公告)日：2013-03-05

    申请号：US13012402

    申请日：2011-01-24

    申请人： Rufina Alamo ,  Geoffrey Coates ,  Carolina Ruiz-Orta

    发明人： Rufina Alamo ,  Geoffrey Coates ,  Carolina Ruiz-Orta

    IPC分类号： C08F110/06 ,  C08F210/00

    CPC分类号： C08F8/00 ,  C08F110/06 ,  C08F4/7006 ,  C08F2500/15 ,  C08F2500/16

    摘要： The invention is a novel family of polyolefins characterized by chain-walking defects of the type that add extra backbone carbons per monomer. These polyolefins display a large decrease in crystallinity relative to polyolefins known in the art. Specifically, the reduction in crystallinity is much greater than for earlier polypropylenes with a matched content of stereo or 1-alkene type defects. The claimed polyolefins can be made by a late metal Ni(II) catalyst. The defects in the polyolefin backbone are generated by a chain waling mechanism in which three or more carbons per monomer are added to the polymer backbone instead of two, as in conventional polymerization or copolymerization methods of alpha olefins. The novel polyolefins can be used in applications such as plastic wrapping, thin films, co-extrusion layers or molded parts in the absence of polymer blending or copolymerization. The cost of materials production can be reduced.

    摘要翻译： 本发明是一种新型的聚烯烃系列，其特征在于每单体添加额外的骨架碳的类型的链步行缺陷。 这些聚烯烃相对于本领域已知的聚烯烃显示出大的结晶度降低。 具体来说，结晶度的降低远远大于具有匹配的立体或1-烯烃型缺陷的早先聚丙烯。 所要求保护的聚烯烃可以由晚期金属Ni（II）催化剂制成。 聚烯烃主链中的缺陷是通过链式漂浮机理产生的，其中每个单体的三个或更多个碳被加入聚合物主链而不是两个，如在α-烯烃的常规聚合或共聚方法中。 在不存在聚合物共混或共聚的情况下，新型聚烯烃可用于塑料包装，薄膜，共挤出层或模制部件等应用中。 可以降低材料生产的成本。