Purification of bis(beta-hydroxyethyl) terephthalate
    2.
    发明授权
    Purification of bis(beta-hydroxyethyl) terephthalate 失效
    BIS(β-羟基乙基)三苯甲酸酯的纯化

    公开(公告)号:US3663600A

    公开(公告)日:1972-05-16

    申请号:US3663600D

    申请日:1969-12-15

    申请人: EASTMAN KODAK CO

    IPC分类号: C07C69/82

    CPC分类号: C07C67/60 C07C69/82

    摘要: A PROCESS FOR THE PURIFICATION OF BIS(B-HYDROXYETHYL) TEREPHTHALATE, AND PARTICULARLY THAT PREPARED BY THE ESTERIFICATION OF TEREPHTHALIC ACID WITH ETHYLENE GLYCOL, WHICH COMPRISES DISSOLVING ONE PART OF CRUDE BIS(B-HYDROXYETHYL) TEREPHTHALATE IN A HOT SOLVENT, TREATING THE SOLUTION WITH FROM ABOUT 0.005 TO ABOUT 0.5 PART, BASED ON THE BIS(B-HYDROXYETHYL) TEREPHTHALATE, OF A PHOSPHORUS CONTAINING COMPONENT SELECTED FROM PHOSPHORIC ACID, PHOSPHOROUS ACID, AND PHOSPHATE ESTERS HAVING THE GENERAL FORMULA

    O=P(-O-R1)(-O-R2)-O-R3

    WHEREIN EACH OF R1, R2 AND R3 ARE SELECTED FROM HYDROGEN OR STRAIGHT OR BRANCHED CHAIN ALKYL RADICALS HAVING FROM 1 TO 10 CARBON ATOMS, AND WHEREIN THE ESTER CONTAINS AT LEAST AN AVERAGE OF 0.5 ACIDIC HYDROGEN ATOMS FOR EACH PHOSPHORUS ATOM, FILTERING THE HOT SOLUTION AND COOLING THE FILTRATE TO CAUSE PURE BIS(B-HYDROXYETHYL) TEREPHTHALATE TO CRYSTALLIZE THEREFROM.

    Process and catalyst-inhibitor system for preparing synthetic linear polyester
    4.
    发明授权
    Process and catalyst-inhibitor system for preparing synthetic linear polyester 失效
    制备合成线性聚酯的工艺和催化剂抑制剂体系

    公开(公告)号:US3907754A

    公开(公告)日:1975-09-23

    申请号:US48077674

    申请日:1974-06-19

    申请人: EASTMAN KODAK CO

    摘要: Catalyst-inhibitor system for the polymerization of poly(ethylene terephthalate) having excellent properties for fabrication of fibers and films. The catalyst-inhibitor system comprises a combination of organic or inorganic salts of manganese and cobalt with acetyl triisopropyl titanate and a phosphate ester. This invention also is directed to an improved method of preparing synthetic linear polyesters utilizing the new catalyst-inhibitor system.

    摘要翻译: 聚对苯二甲酸乙二醇酯的催化剂抑制剂体系具有优异的纤维和薄膜制造性能。 催化剂抑制剂体系包括锰和钴与乙酰基三异丙基钛酸酯和磷酸酯的有机或无机盐的组合。 本发明还涉及利用新的催化剂抑制剂体系制备合成线性聚酯的改进方法。

    Copolyester melt adhesive
    5.
    发明授权
    Copolyester melt adhesive 失效
    聚酯胶粘剂

    公开(公告)号:US3669921A

    公开(公告)日:1972-06-13

    申请号:US3669921D

    申请日:1971-02-08

    申请人: EASTMAN KODAK CO

    摘要: Copolyesters useful as melt adhesives in the bonding of fabrics, metal, glass, wood, rubber, plastic sheets and other products to produce a bond which will resist the action of heat, steam, dry cleaning solvents and the like, said copolyester being derived from (1) terephthalic acid, (2) adipic acid, (3) ethylene glycol, and (4) 1,4-butanediol or derivatives of these four components. These copolyesters are advantageously improved by the incorporation therein of specific amounts of either sodium stearate or titanium dioxide.

    摘要翻译: 共聚酯可用作粘合织物,金属,玻璃,木材,橡胶,塑料片和其它产品中的熔融粘合剂,以产生将抵抗热,蒸汽,干洗溶剂等的作用的粘合剂,所述共聚酯衍生自 (1)对苯二甲酸,(2)己二酸,(3)乙二醇和(4)1,4-丁二醇或这四种组分的衍生物。 这些共聚酯有利地通过在其中加入特定量的硬脂酸钠或二氧化钛来改善。