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1.发明授权Methods of refining and producing isomerized fatty acid esters and fatty acids from natural oil feedstocks 有权从天然油原料精制和生产异构化脂肪酸酯和脂肪酸的方法公开(公告)号：US09382502B2
公开(公告)日：2016-07-05
申请号：US13827798
申请日：2013-03-14
发明人： Thomas E. Snead , Steven A. Cohen , Demond L. Gildon , Leslie V. Beltran , Linda A. Kunz , Tessa M. Pals , Jordan R. Quinn , Raymond T. Behrends, Jr. , Randal J. Bernhardt
IPC分类号： C11C3/14 , C10L1/00 , C10L1/02 , C11B3/00 , C10G3/00 , C10G65/04 , C10G69/12 , C11C3/00 , C10G45/00 , C10G29/20 , C10G50/00 , C10L1/08 , C10G45/58
CPC分类号： C11C3/14 , C10G3/42 , C10G29/205 , C10G45/00 , C10G45/58 , C10G50/00 , C10G65/043 , C10G69/123 , C10G2300/1014 , C10G2300/1018 , C10G2300/1088 , C10G2300/30 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/22 , C10L1/00 , C10L1/02 , C10L1/026 , C10L1/08 , C10L2200/0469 , C10L2200/0476 , C11B3/00 , C11C3/003 , Y02E50/13 , Y02P30/20
摘要： Methods are provided for refining natural oil feedstocks and producing isomerized esters and acids. The methods comprise providing a C4-C18 unsaturated fatty ester or acid, and isomerizing the fatty acid ester or acid in the presence of heat or an isomerization catalyst to form an isomerized fatty ester or acid. In some embodiments, the methods comprise forming a dibasic ester or dibasic acid prior to the isomerizing step. In certain embodiments, the methods further comprise hydrolyzing the dibasic ester to form a dibasic acid. In certain embodiments, the olefin is formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having unsaturated esters.
摘要翻译： 提供了用于精制天然油原料并生产异构化酯和酸的方法。 该方法包括提供C4-C18不饱和脂肪酸酯或酸，并在热或异构化催化剂存在下异构化脂肪酸酯或酸以形成异构化的脂肪酸酯或酸。 在一些实施方案中，所述方法包括在异构化步骤之前形成二元酯或二元酸。 在某些实施方案中，所述方法还包括水解二元酯以形成二元酸。 在某些实施方案中，烯烃是通过在复分解催化剂存在下，在足以形成包含烯烃和酯的复分解产物的条件下进行反应而形成的，将烯烃与复分解产物中的酯分离，并在存在下酯交换酯 的醇形成具有不饱和酯的酯交换产物。
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2.发明申请Methods of Refining and Producing Dibasic Esters and Acids from Natural Oil Feedstocks 有权从天然油原料精制和生产二元酯和酸的方法公开(公告)号：US20150299613A1
公开(公告)日：2015-10-22
申请号：US14628467
申请日：2015-02-23
IPC分类号： C11B3/02
CPC分类号： C11B3/02 , C07C67/03 , C07C67/333 , C07C67/475 , C10G3/42 , C10G45/00 , C10G45/58 , C10G50/00 , C10G65/043 , C10G2300/1014 , C10G2300/1018 , C10G2300/1088 , C10G2300/30 , C10G2300/301 , C10G2300/307 , C10G2300/308 , C10G2300/44 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/22 , C10L1/026 , C10L1/08 , C10L2200/0469 , C10L2200/0476 , C11B3/00 , C11C3/00 , C11C3/003 , Y02P20/582 , Y02P30/20 , C07C69/533 , C07C69/593
摘要： Methods are provided for refining natural oil feedstocks and producing dibasic esters and/or dibasic acids. The methods comprise reacting a terminal olefin with an internal olefin in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In certain embodiments, the olefin esters are formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having olefin esters.
摘要翻译： 提供了用于精制天然油原料和生产二元酯和/或二元酸的方法。 所述方法包括在复分解催化剂存在下使末端烯烃与内烯烃反应以形成二元酯和/或二元酸。 在某些实施方案中，所述烯烃酯通过在复分解催化剂存在下在足以形成包含烯烃和酯的复分解产物的条件下进行反应而形成，将烯烃与复分解产物中的酯进行酯交换， 存在醇以形成具有烯烃酯的酯交换产物。
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公开(公告)号：US09738853B2
公开(公告)日：2017-08-22
申请号：US14639864
申请日：2015-03-05
摘要： Methods for making specialty chemical products and chemical intermediates using hydroformylation are generally disclosed. Further, compositions and compounds formed using such methods are also disclosed. In some embodiments, methods are disclosed for refining a renewably sourced material, such as a natural oil, to form compositions, which can be further reacted employing the methods disclosed herein to form certain specialty chemical products or chemical intermediates.
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公开(公告)号：US20170096383A1
公开(公告)日：2017-04-06
申请号：US15287986
申请日：2016-10-07
发明人： Alpeshkumar K. Patel , Brian Pease , Bradon J. Dreyer , Yenamandra Viswanath , Brian Albert , Steven A. Cohen , Thomas E. Snead , Demond L. Gildon
IPC分类号： C07C51/43
CPC分类号： C07C51/43 , C07C51/09 , C07C67/303 , C07C67/475 , C07C55/02 , C07C69/593 , C07C69/34
摘要： High-purity dibasic acid compositions are generally disclosed. In some embodiments, the dibasic acid compositions are solutions or suspensions. In some other embodiments, the compositions are solid-state compositions. In some such embodiments, the solid-state compositions include a dibasic acid as a crystalline solid and further include a low quantity of certain impurities, such as monobasic acids, various esters, and the like. Methods and systems for making such high-purity dibasic acid compositions are also disclosed.
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公开(公告)号：US20150119602A1
公开(公告)日：2015-04-30
申请号：US14502382
申请日：2014-09-30
发明人： Alpeshkumar K. Patel , Brian Pease , Bradon J. Dreyer , Brian Albert , Colin Huie , Yenamandra Viswanath , Purvi Kapasi , Chander Balakrishnan , Steven A. Cohen , Thomas E. Snead , Demond L. Gildon
IPC分类号： C07C51/09
CPC分类号： C07C51/43 , C07C51/09 , C07C67/303 , C07C67/475 , C07C55/02 , C07C69/593 , C07C69/34
摘要： High-purity dibasic acid compositions are generally disclosed. In some embodiments, the dibasic acid compositions are solutions or suspensions. In some other embodiments, the compositions are solid-state compositions. In some such embodiments, the solid-state compositions include a dibasic acid as a crystalline solid and further include a low quantity of certain impurities, such as monobasic acids, various esters, and the like. Methods and systems for making such high-purity dibasic acid compositions are also disclosed.
摘要翻译： 通常公开了高纯度二元酸组合物。 在一些实施方案中，二元酸组合物是溶液或悬浮液。 在一些其它实施方案中，组合物是固体组合物。 在一些这样的实施方案中，固态组合物包括作为结晶固体的二元酸，并且还包括少量某些杂质，例如一元酸，各种酯等。 还公开了制备这种高纯度二元酸组合物的方法和系统。
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公开(公告)号：US10472588B2
公开(公告)日：2019-11-12
申请号：US15633760
申请日：2017-06-27
摘要： Methods for making specialty chemical products and chemical intermediates using hydroformylation are generally disclosed. Further, compositions and compounds formed using such methods are also disclosed. In some embodiments, methods are disclosed for refining a renewably sourced material, such as a natural oil, to form compositions, which can be further reacted employing the methods disclosed herein to form certain specialty chemical products or chemical intermediates.
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公开(公告)号：US20180016519A1
公开(公告)日：2018-01-18
申请号：US15633760
申请日：2017-06-27
摘要： Methods for making specialty chemical products and chemical intermediates using hydroformylation are generally disclosed. Further, compositions and compounds formed using such methods are also disclosed. In some embodiments, methods are disclosed for refining a renewably sourced material, such as a natural oil, to form compositions, which can be further reacted employing the methods disclosed herein to form certain specialty chemical products or chemical intermediates.
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8.发明授权Methods of refining and producing dibasic esters and acids from natural oil feedstocks 有权从天然油原料精制和生产二元酯和酸的方法公开(公告)号：US09365487B2
公开(公告)日：2016-06-14
申请号：US14048673
申请日：2013-10-08
IPC分类号： C07C1/00 , C07C1/20 , C07C5/03 , C07C67/343 , C10G29/20 , C10G45/00 , C10G45/58 , C10G50/00 , C10G65/04 , C10G69/12 , C11B3/00 , C10L1/02 , C10L1/08 , C11C3/00 , C10G3/00 , C07C67/475
CPC分类号： C07C67/343 , C07C67/475 , C10G3/42 , C10G29/205 , C10G45/00 , C10G45/58 , C10G50/00 , C10G65/043 , C10G69/123 , C10G2300/1014 , C10G2300/1018 , C10G2300/1088 , C10G2300/30 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/22 , C10L1/02 , C10L1/026 , C10L1/08 , C10L2200/0469 , C11B3/00 , C11C3/003 , Y02E50/13 , Y02P20/582 , Y02P30/20 , C07C69/533 , C07C69/593
摘要： Methods and systems for making dibasic esters and/or dibasic acids using metathesis are generally disclosed. In some embodiments, the methods comprise reacting a terminal olefin ester with an internal olefin ester in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In some embodiments, the terminal olefin ester or the internal olefin ester are derived from a renewable feedstock, such as a natural oil feedstock. In some such embodiments, the natural oil feedstock, or a transesterified derivative thereof, is metathesized to make the terminal olefin ester or the internal olefin ester.
摘要翻译： 通常公开了使用复分解来制备二元酯和/或二元酸的方法和系统。 在一些实施方案中，所述方法包括在复分解催化剂存在下使末端烯烃酯与内烯烃酯反应以形成二元酯和/或二元酸。 在一些实施方案中，末端烯烃酯或内烯烃酯衍生自可再生原料，例如天然油原料。 在一些这样的实施方案中，将天然油原料或其酯交换的衍生物复分解以制备末端烯烃酯或内烯烃酯。
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公开(公告)号：US09284512B2
公开(公告)日：2016-03-15
申请号：US14628467
申请日：2015-02-23
IPC分类号： C07C1/213 , C07C1/36 , C07C67/475 , C11B3/02 , C11C3/00 , C10G45/00 , C10G45/58 , C10G50/00 , C10G65/04 , C11B3/00 , C10L1/02 , C10L1/08 , C10G3/00 , C07C67/03 , C07C67/333
CPC分类号： C11B3/02 , C07C67/03 , C07C67/333 , C07C67/475 , C10G3/42 , C10G45/00 , C10G45/58 , C10G50/00 , C10G65/043 , C10G2300/1014 , C10G2300/1018 , C10G2300/1088 , C10G2300/30 , C10G2300/301 , C10G2300/307 , C10G2300/308 , C10G2300/44 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/22 , C10L1/026 , C10L1/08 , C10L2200/0469 , C10L2200/0476 , C11B3/00 , C11C3/00 , C11C3/003 , Y02P20/582 , Y02P30/20 , C07C69/533 , C07C69/593
摘要： Methods are provided for refining natural oil feedstocks and producing dibasic esters and/or dibasic acids. The methods comprise reacting a terminal olefin with an internal olefin in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In certain embodiments, the olefin esters are formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having olefin esters.
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公开(公告)号：US20150252290A1
公开(公告)日：2015-09-10
申请号：US14639864
申请日：2015-03-05
IPC分类号： C11B3/02
摘要： Methods for making specialty chemical products and chemical intermediates using hydroformylation are generally disclosed. Further, compositions and compounds formed using such methods are also disclosed. In some embodiments, methods are disclosed for refining a renewably sourced material, such as a natural oil, to form compositions, which can be further reacted employing the methods disclosed herein to form certain specialty chemical products or chemical intermediates.
摘要翻译： 通常公开了使用加氢甲酰化制备特种化学产品和化学中间体的方法。 此外，还公开了使用这些方法形成的组合物和化合物。 在一些实施方案中，公开了用于精制可再生来源的材料（例如天然油）以形成组合物的方法，其可以使用本文公开的方法进一步反应以形成某些特殊化学产品或化学中间体。
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