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公开(公告)号:US12084558B2
公开(公告)日:2024-09-10
申请号:US17713346
申请日:2022-04-05
发明人: Mridula Nair , Ellen M. Pyszczek
CPC分类号: C08J9/365 , C08J3/03 , C08J3/24 , C08J9/0066 , C08J2201/026 , C08J2205/052
摘要: An aqueous non-foamed functional composition formulation is disposed on a foamed opacifying layer in light-blocking, foamed opacifying elements. This non-foamed functional composition formulation has 0.5-15% solids and essential (i) and (iv) components and optional (ii), (v), (vi), and (vii) components. The components (i) untreated synthetic silica (fumed silica or precipitated silica) at 0.5-10 weight %; and a (iv) water-soluble or water-dispersible organic polymeric binder having a glass transition temperature (Tg) below 25° C. The weight ratio of the (i) untreated synthetic silica to the (iv) water-soluble or water-dispersible organic polymeric binder is 10:1 to 1:1. The optional components include: a (ii) solid or non-solid lubricant; a (v) crosslinking agent; a (vi) thickener; and a (vii) coating aid. Glass particles can also be present. The presence of the (i) untreated synthetic silica provides improved brightness, e.g. an L* value of at least 80, and uniform coatings in the resulting, foamed opacifying element.
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公开(公告)号:US20240026112A1
公开(公告)日:2024-01-25
申请号:US18476824
申请日:2023-09-28
发明人: Mridula Nair , Ellen M. Pyszczek
CPC分类号: C08J9/365 , C08J9/0066 , C08J3/24 , C08J3/03 , C08J2205/052 , C08J2201/026
摘要: An aqueous non-foamed functional composition formulation is disposed on a foamed opacifying layer in light-blocking, foamed opacifying elements. This non-foamed functional composition formulation has 0.5-15% solids and essential (i) and (iv) components and optional (ii), (v), (vi), and (vii) components. The components (i) untreated synthetic silica (fumed silica or precipitated silica) at 0.5-10 weight %; and a (iv) water-soluble or water-dispersible organic polymeric binder having a glass transition temperature (Tg) below 25° C. The weight ratio of the (i) untreated synthetic silica to the (iv) water-soluble or water-dispersible organic polymeric binder is 10:1 to 1:1. The optional components include: a (ii) solid or non-solid lubricant; a (v) crosslinking agent; a (vi) thickener; and a (vii) coating aid. Glass particles can also be present. The presence of the (i) untreated synthetic silica provides improved brightness, e.g. an L* value of at least 80, and uniform coatings in the resulting, foamed opacifying element.
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公开(公告)号:US11370924B2
公开(公告)日:2022-06-28
申请号:US16907393
申请日:2020-06-22
发明人: Mridula Nair , Ellen M. Pyszczek , Stephen Swanton
IPC分类号: C09D4/06 , C09D133/06 , C09D133/26 , C09D175/04 , C09D7/65 , C09D7/61 , C09D7/40 , C09D7/43 , C09D5/02
摘要: An aqueous functional composition formulation is used to provide a top layer or pattern in light-blocking opacifying elements. This functional composition formulation has 0.5-15% solids and the essential (i) and (iv) components and any optional (ii), (v), (vi), and (vii) components. The essential components are (i) fumed silica particles at 0.5-10 weight %; and a (iv) water-soluble or water-dispersible organic polymeric binder having a glass transition temperature (Tg) below 25° C. The weight ratio of the (i) fumed silica particles to the (iv) water-soluble or water-dispersible organic polymeric binder is 10:1 to 1:5. The optional components include: a (ii) solid or non-solid lubricant; a (v) crosslinking agent; a (vi) thickener; and a (vii) coating aid. Glass particles can also be present. The presence of the (i) fumed silica provides improved brightness, e.g. an L* value of at least 80, and uniform coatings in the opacifying element.
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公开(公告)号:US20210189640A1
公开(公告)日:2021-06-24
申请号:US16720025
申请日:2019-12-19
发明人: Mridula Nair , Diane Marie Herrick
摘要: Laminate precursors are prepared by applying an aqueous foamed opacifying composition to a non-woven fabric, drying, optionally applying an anti-blocking material to the dried aqueous foamed opacifying composition, and densifying the dry foamed opacifying layer so that it will have a thickness that is at least 20% less than its thickness before densifying. Each laminate precursor is rolled up for immediate or later use to make laminate decorative articles when the unrolled laminate precursor is laminated with back side of a decorative fabric. The applied aqueous foamed opacifying composition has 35%-70% solids and a foam density of 0.1-0.5 g/cm3. It is composed of (a) porous particles, (b) a binder material, (c) two or more additives comprising at least one foaming surfactant and at least one foam stabilizer, (d) an aqueous medium, and (e) an opacifying colorant that absorbs electromagnetic radiation having a wavelength of 380-800 nm.
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公开(公告)号:US10920032B2
公开(公告)日:2021-02-16
申请号:US16203737
申请日:2018-11-29
摘要: A foamed, opacifying element useful as a light-blocking article has a substrate; an opacifying layer disposed on the substrate, and a functional composition disposed over the opacifying layer. The functional composition comprises: (i) glass particles such as hollow glass particles. The presence of the glass particles provides additional heat absorption for the foamed, opacifying elements that can be formed into light-blocking materials.
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公开(公告)号:US10696814B2
公开(公告)日:2020-06-30
申请号:US16018367
申请日:2018-06-26
摘要: Foamed, opacifying elements are prepared using a foamable aqueous composition containing porous particles and an opacifying colorant. This composition is aerated, disposed onto a substrate, and dried. The dry foamed composition is densified, and cured in either order. At some point after the drying feature, a functional composition is disposed onto either the dry foamed composition or the opacifying layer, and dried. This functional composition has either or both of: (i) inorganic or organic spacer particles having a mode particle size of 1 to 100 μm, and which inorganic or organic spacer particles resist melt flow at a pressure of up to and including 100 psi (689.5 kPa) and a temperature of up to and including 220° C.; and (iii) a tinting material comprising a pigment, dye, or a combination thereof. The (i) inorganic or organic spacer particles and the (iii) tinting material are different materials.
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公开(公告)号:US20200173099A1
公开(公告)日:2020-06-04
申请号:US16203708
申请日:2018-11-29
IPC分类号: D06M15/263 , C09D127/06 , C09D133/04 , C09D7/65 , C09D7/40 , C09D7/61 , C09D5/18 , D06M15/248 , D06M13/224 , D06M11/51
摘要: A coated yarn has a yarn core and a coating disposed coaxially on the yarn core. This coating contains: (i) porous particles present in an amount of at least 4 weight % and up to and including 20 weight %, each porous particle comprising a continuous polymeric phase and discrete pores dispersed within the continuous polymeric phase, having a mode particle size of 2-50 μm and up to and including 50 μm; (ii) a film-forming binder material having a Tg of less than or equal to 25° C., which is present in an amount of 40-90 weight %; and (iii) an inorganic filler material having a value of less than 5 on the MOHS scale of mineral hardness, which inorganic filler material is present in an amount of 4 weight % and up to and including 30 weight %.
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公开(公告)号:US20200173067A1
公开(公告)日:2020-06-04
申请号:US16203722
申请日:2018-11-29
IPC分类号: D03D15/00 , C09D127/06 , C09D133/04 , C09D7/65 , C09D7/40 , C09D7/61 , C09D5/18 , D06M13/224 , D06M11/51 , D06M15/248 , D06M15/263
摘要: A fabric substrate is prepared from woven coated yarns. Each coated yarn has a yarn core and a coating disposed coaxially on the yarn core. This coating contains: (i) porous particles in an amount of 4-20 weight %, each porous particle comprising a continuous polymeric phase and discrete pores dispersed within the continuous polymeric phase, a mode particle size of 2-50 μm; (ii) a film-forming binder material having a Tg of less than or equal to 25° C., in an amount of 40-90 weight %; and (iii) an inorganic filler material having a value of less than 5 on the MOHS scale of mineral hardness, which inorganic filler material is present in an amount of 4-30 weight %.
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公开(公告)号:US20200088915A1
公开(公告)日:2020-03-19
申请号:US16131351
申请日:2018-09-14
发明人: Mridula Nair , Mary Christine Brick
摘要: An opacifying article can be made using a (i) fabric having a face side and a back side and an (ii) opacifying element having a substrate that has first and second opposing surfaces; and a dry opacifying layer that has an inner surface and an outer surface. The dry opacifying layer is disposed with its inner surface in contact with the first opposing surface of the substrate. The dry opacifying layer has (a) 40-90 weight % of porous particles, each having a continuous polymeric phase and discrete pores dispersed within the continuous polymeric phase. The porous particles have a mode particle size of 2-50 μm and a porosity of 20-70 volume %. The dry opacifying layer also contains (b) 10-60 weight % of a binder material. The (ii) opacifying element is laminated to the back side of the fabric to provide the opacifying article.
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公开(公告)号:US10138342B2
公开(公告)日:2018-11-27
申请号:US15239915
申请日:2016-08-18
摘要: Foamable aqueous compositions can be foamed and applied to porous substrates to make light-blocking dry opacifying elements. Such compositions have 0.05-15 weight % of porous particles; at least 20 weight % of a binder; at least 0.0001 weight % of additives (including a surfactant); water; and at least 0.001 weight % of an opacifying colorant. Each porous particle includes a continuous polymeric phase and discrete pores; a mode particle size of 2-50 μm; and a porosity of 20-70 volume %. The continuous polymeric phase Tg is >80° C. and has a polymer viscosity of 80-500 centipoises at an ethyl acetate shear rate of 100 sec−1 at a concentration of 20 weight % at 25° C. The dry opacifying element light blocking value is at least 4 and has a luminous reflectance >40% as measured by the Y tristimulus value. The foamed aqueous composition has a foam density of 0.1-0.5 g/cm3.
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