公开(公告)号：US07598409B2

公开(公告)日：2009-10-06

申请号：US10583553

申请日：2004-10-21

申请人： Eckhard Just ,  Sabine Giessler ,  Peter Jenkner

发明人： Eckhard Just ,  Sabine Giessler ,  Peter Jenkner

IPC分类号： C07F7/04

CPC分类号： C07F7/14

摘要： The present invention relates to a process for preparing silicon compounds bearing fluoroalkyl groups by hydrosilylation of a fluoroolefin in the presence of a hydrosilylation catalyst, which comprises initially charging and heating a hydrogenchlorosilane, then metering in the fluoroolefin and reacting the reaction mixture and subsequently isolating the hydrosilylation product.

摘要翻译： 本发明涉及一种在氢化硅烷化催化剂存在下通过氟代烯烃的氢化硅烷化制备含氟烷基的硅化合物的方法，该方法包括首先加入和加热氢氯硅烷，然后计量氟代烯烃并使反应混合物反应， 氢化硅烷化产物。

公开(公告)号：US20070112213A1

公开(公告)日：2007-05-17

申请号：US10583553

申请日：2004-10-21

申请人： Eckhard Just ,  Sabine Giessler ,  Peter Jenkner

发明人： Eckhard Just ,  Sabine Giessler ,  Peter Jenkner

IPC分类号： C07F7/00

CPC分类号： C07F7/14

摘要： The present invention relates to a process for preparing silicon compounds bearing fluoroalkyl groups by hydrosilylation of a fluoroolefin in the presence of a hydrosilylation catalyst, which comprises initially charging and heating a hydrogenchlorosilane, then metering in the fluoroolefin and reacting the reaction mixture and subsequently isolating the hydrosilylation product.

摘要翻译： 本发明涉及一种在氢化硅烷化催化剂存在下通过氟代烯烃的氢化硅烷化制备含氟烷基的硅化合物的方法，该方法包括首先加入和加热氢氯硅烷，然后计量氟代烯烃并使反应混合物反应， 氢化硅烷化产物。

公开(公告)号：US20090011246A1

公开(公告)日：2009-01-08

申请号：US12096647

申请日：2006-11-15

申请人： Sabine Giessler-Blank ,  Eckhard Just

发明人： Sabine Giessler-Blank ,  Eckhard Just

IPC分类号： B32B27/36 ,  C04B24/42 ,  B32B17/06 ,  B32B27/40 ,  B32B27/00 ,  B32B15/04

CPC分类号： C09D183/08 ,  Y10T428/31507 ,  Y10T428/31598 ,  Y10T428/31612 ,  Y10T428/31663

摘要： The present invention relates to a special coating composition based on components a) at least one hydrolyzable fluoroalkylsilane of the formula (I) CF3(CF2)n(CH2)2Si(CH3)yX3-y (I), in which X is a group from the series chlorine, methoxy, ethoxy, isopropoxy, and n-propoxy and n is a number from the series 3, 4, 5, 6, 7, 8, and 9, and y is 0 or 1, b) HCl, c) water, d) isopropanol, and e) dodecane, and on a silane component (a): water molar ratio of 1:4.5 to 1:9. The invention further relates to a process for preparing such a composition and also to its use for providing smooth, inorganic substrate surfaces with an abrasion-resistant and weathering-stable easy-to-clean coating.

摘要翻译： 本发明涉及基于组分a）至少一种式（I）CF 3（CF 2）n（CH 2）2 Si（CH 3）y X 3-y（I）的可水解氟烷基硅烷的特殊涂料组合物，其中X是基团 来自系列氯，甲氧基，乙氧基，异丙氧基和正丙氧基，n是序列3,4,5,6,7,8和9的数，y是0或1，b）HCl，c ）水，d）异丙醇和e）十二烷，以及硅烷组分（a）：水摩尔比为1:4.5至1:9。 本发明还涉及一种制备这种组合物的方法，还涉及其用于提供具有耐磨和耐风化稳定的易于清洁的涂层的光滑无机基材表面的用途。

公开(公告)号：US07670422B2

公开(公告)日：2010-03-02

申请号：US12096647

申请日：2006-11-15

申请人： Sabine Giessler-Blank ,  Eckhard Just

发明人： Sabine Giessler-Blank ,  Eckhard Just

IPC分类号： C09D4/00

CPC分类号： C09D183/08 ,  Y10T428/31507 ,  Y10T428/31598 ,  Y10T428/31612 ,  Y10T428/31663

摘要： The present invention relates to a special coating composition based on components a) at least one hydrolyzable fluoroalkylsilane of the formula (I) CF3(CF2)n(CH2)2Si(CH3)yX3-y (I), in which X is a group from the series chlorine, methoxy, ethoxy, isopropoxy, and n-propoxy and n is a number from the series 3, 4, 5, 6, 7, 8, and 9, and y is 0 or 1, b) HC1, c) water, d) isopropanol, and e) dodecane, and on a silane component (a): water molar ratio of 1:4.5 to 1:9. The invention further relates to a process for preparing such a composition and also to its use for providing smooth, inorganic substrate surfaces with an abrasion-resistant and weathering-stable easy-to-clean coating.

摘要翻译： 本发明涉及基于组分a）至少一种式（I）CF 3（CF 2）n（CH 2）2 Si（CH 3）y X 3-y（I）的可水解氟烷基硅烷的特殊涂料组合物，其中X是基团 来自系列氯，甲氧基，乙氧基，异丙氧基和正丙氧基，n是序列3,4,5,6,7,8和9的数，y是0或1，b）HC1，c ）水，d）异丙醇和e）十二烷，以及硅烷组分（a）：水摩尔比为1:4.5至1:9。 本发明还涉及一种制备这种组合物的方法，还涉及其用于提供具有耐磨和耐风化稳定的易于清洁的涂层的光滑无机基材表面的用途。

公开(公告)号：US07666257B2

公开(公告)日：2010-02-23

申请号：US12090327

申请日：2006-11-15

申请人： Sabine Giessler-Blank ,  Eckhard Just

发明人： Sabine Giessler-Blank ,  Eckhard Just

IPC分类号： C09D4/00

CPC分类号： C09D4/00 ,  C03C17/25 ,  C03C2217/213 ,  C03C2217/241 ,  C03C2217/75 ,  C03C2217/76 ,  C03C2218/113 ,  C04B41/009 ,  C04B41/4933 ,  C04B41/52 ,  C04B41/84 ,  C04B41/89 ,  C04B2111/2069 ,  C09D183/08 ,  C04B41/463 ,  C04B41/502 ,  C04B41/5022 ,  C04B33/00 ,  C08G77/24 ,  C08L2666/34

摘要： The present invention relates to a special coating composition based on components a) at least one hydrolysable fluoroalkylsilane of the formula (I) CF3(CF2)n(CH2)2Si(CH3)yX3-y, in which X is a group from the series chlorine, methoxy, ethoxy, isopropoxy, and n-propoxy and n is a number from the series 3, 4, 5, 6, 7, 8, and 9, and y is 0 or 1, b) HCl, c) water, d) isopropanol, and e) at least one further solvent and/or diluent from the series of the alcohols, glycols, glycol ethers, ethers, esters, ketones, and aliphatic and aromatic hydrocarbons, wherein the silane component (a):water molar ratio of 1:4.5 to 1:9. The invention further relates to a process for preparing such a composition and also to its use for providing smooth, inorganic substrate surfaces with an abrasion-resistant and weathering-stable easy-to-clean coating.

摘要翻译： 本发明涉及基于组分a）至少一种式（I）CF 3（CF 2）n（CH 2）2 Si（CH 3）y X 3-y的可水解氟代烷基硅烷的特殊涂料组合物，其中X是一系列 氯，甲氧基，乙氧基，异丙氧基和正丙氧基，n是序列3,4,5,6,7,8和9的数，y是0或1，b）HCl，c）水， d）异丙醇，和e）来自该醇，二醇，二醇醚，醚，酯，酮和脂族和芳族烃系列的至少一种其它溶剂和/或稀释剂，其中所述硅烷组分（a）：水摩尔 比例为1:4.5〜1:9。 本发明还涉及一种制备这种组合物的方法，还涉及其用于提供具有耐磨和耐风化稳定的易于清洁的涂层的光滑无机基材表面的用途。

公开(公告)号：US20090005518A1

公开(公告)日：2009-01-01

申请号：US11572555

申请日：2005-06-03

申请人： Eckhard Just ,  Sabine Giessler-Blank ,  Burkhard Standke

发明人： Eckhard Just ,  Sabine Giessler-Blank ,  Burkhard Standke

IPC分类号： C09D183/04 ,  B05D3/10

CPC分类号： C08G77/24 ,  C08G77/26 ,  C09D183/08

摘要： The present invention relates to a composition which comprises (i) at least one block condensate of organofunctional siloxanes of the general formula (I) [F]e[QcPb]d (I) and/or (ii) at least one mixture composed of e[F] and d(c[Q]+b[P]) and, where appropriate d[QcPb]. These compositions or block condensates are obtainable via reaction of block units F with block units Q, P, and/or QP, by one of the following methods:—c1) diluting block unit F optionally with an alcohol, adding an organic or inorganic acid and from 0.5 to 150 mol of water per mole of Si of the siloxane used, whereupon at least partial hydrolysis of the block units used takes place, then adding block unit Q and block unit P, and allowing the mixture to react, or—c2) diluting block unit F optionally with an alcohol, mixing with Q, P, and/or block unit QP, then adding an organic or inorganic acid and, using from 0.5 to 150 mol of water per mole of Si of the siloxanes used, carrying out partial hydrolysis and block-condensation, or—c3) diluting block unit F optionally with an alcohol, adding an organic or inorganic acid and from 0.5 to 150 mol of water per mole of Si of the siloxane used, with at least partial hydrolysis, adding block unit QP, and allowing the mixture to react, or—c4) diluting block units Q, P, and/or QP, optionally with an alcohol, adding an organic or inorganic acid and from 0.5 to 1.5 mol of water per mole of Si of the siloxanes used, and at least partially hydrolyzing, then adding block unit F and also from 0 to 148.5 mol of water per mole of Si of the siloxanes used, and allowing the mixture to react, or—c5) diluting block unit F optionally with an alcohol, mixing with from 0.5 to 150 mol of water per mole of Si of the siloxanes used, and with an organic or inorganic acid, and then adding a tetraalkoxysiloxane, and allowing the mixture to react. The present invention further relates to a process for the preparation of these compositions or block condensates, and to their use and to items thus obtainable: abrasion-resistant easy-clean coatings and items equipped with this type of coating.

公开(公告)号：US20080210130A1

公开(公告)日：2008-09-04

申请号：US12090327

申请日：2006-11-15

申请人： Sabine Giessler-Blank ,  Eckhard Just

发明人： Sabine Giessler-Blank ,  Eckhard Just

IPC分类号： C07F7/18

CPC分类号： C09D4/00 ,  C03C17/25 ,  C03C2217/213 ,  C03C2217/241 ,  C03C2217/75 ,  C03C2217/76 ,  C03C2218/113 ,  C04B41/009 ,  C04B41/4933 ,  C04B41/52 ,  C04B41/84 ,  C04B41/89 ,  C04B2111/2069 ,  C09D183/08 ,  C04B41/463 ,  C04B41/502 ,  C04B41/5022 ,  C04B33/00 ,  C08G77/24 ,  C08L2666/34

摘要： The present invention relates to a special coating composition based on components a) at least one hydrolysable fluoroalkylsilane of the formula (I) CF3(CF2)n(CH2)2Si(CH3)yX3−y, in which X is a group from the series chlorine, methoxy, ethoxy, isopropoxy, and n-propoxy and n is a number from the series 3, 4, 5, 6, 7, 8, and 9, and y is 0 or 1, b) HCl, c) water, d) isopropanol, and e) at least one further solvent and/or diluent from the series of the alcohols, glycols, glycol ethers, ethers, esters, ketones, and aliphatic and aromatic hydrocarbons, and on a silane component (a):water molar ratio of 1:4.5 to 1:9. The invention further relates to a process for preparing such a composition and also to its use for providing smooth, inorganic substrate surfaces with an abrasion-resistant and weathering-stable easy-to-clean coating.

摘要翻译： 本发明涉及一种基于组分的特殊涂料组合物a）至少一种式（I）CF 3 3（CF 2）n的可水解氟烷基硅烷， （CH 2）2 Si（CH 3 3）y X 3-y（CH 3） / SUB，其中X是一系列氯，甲氧基，乙氧基，异丙氧基和正丙氧基，n是序列3,4,5,6,7,8和9的数，y 是0或1，b）HCl，c）水，d）异丙醇，和e）至少一种其它溶剂和/或稀释剂，该系列醇，二醇，二醇醚，醚，酯，酮和脂族和 芳族烃和硅烷组分（a）：水摩尔比为1:4.5至1:9。 本发明还涉及一种制备这种组合物的方法，还涉及其用于提供具有耐磨和耐风化稳定的易于清洁的涂层的光滑无机基材表面的用途。

公开(公告)号：US07578877B2

公开(公告)日：2009-08-25

申请号：US10567023

申请日：2004-06-09

申请人： Sabine Giessler ,  Eckhard Just

发明人： Sabine Giessler ,  Eckhard Just

IPC分类号： C09D183/04 ,  C09D183/06 ,  C09D183/08

CPC分类号： C09D183/04 ,  B05D5/08 ,  C03C17/30 ,  C03C2217/76 ,  C09D4/00 ,  C09D5/20 ,  C09D183/08 ,  C09K3/18 ,  C08G77/24 ,  C08G77/04 ,  C08L2666/44 ,  C08L83/00

摘要： The present invention relates to a two-component system for equipping surfaces with an oil, water, and dirt repellent coating, the two-component system being composed of a formulation 1 and a formulation 2, and both formulations being mixed together shortly before application. The invention further relates to a method of applying the two-component system to surfaces. The invention additionally relates to the use of the two-component system.

摘要翻译： 本发明涉及一种双组分系统，用于将表面装备有油，水和防污涂层，该双组分体系由制剂1和制剂2组成，两种制剂在施用前不久混合在一起。 本发明还涉及将双组分系统应用于表面的方法。 本发明还涉及双组分系统的用途。

公开(公告)号：US20110118496A1

公开(公告)日：2011-05-19

申请号：US12995852

申请日：2009-04-17

申请人： Eckhard Just ,  Philipp Albert ,  Peter Jenkner

发明人： Eckhard Just ,  Philipp Albert ,  Peter Jenkner

IPC分类号： C07F7/20

CPC分类号： C07F7/1892 ,  Y02P20/582

摘要： A process for preparing an alkylaminoalkylalkoxysilane of formula (I) R—(NR′)—Y—Si(R1)n(OR2)3-n (I) in which R is a linear, branched or cyclic alkyl group having 1 to 12 carbon atoms, R′ is a hydrogen (H) or is a linear, branched or cyclic alkyl group having 1 to 12 carbon atoms, Y is a bivalent alkyl group from the group of —CH2—, —(CH2)2—, —(CH2)3—, —(CH2)(CH(CH3))(CH2)— and —(CH2)4—, R1 and R2 groups are the same or different and are each a linear or branched alkyl group having 1 to 4 carbon atoms, and n is 0 or 1 or 2, by reacting an alkylamine, used in excess, with a haloalkylalkoxysilane, distilling off excess free alkylamine, treating the remaining product mixture with the alkylaminoalkylalkoxysilane and working up.

摘要翻译： 制备式（I）所示的烷基氨基烷基烷氧基烷氧基硅烷的方法R-（NR'）-Y-Si（R 1）n（OR 2）3-n（I）其中R是具有1至12个直链，支链或环状的烷基 碳原子，R'是氢（H）或是具有1至12个碳原子的直链，支链或环状烷基，Y是来自-CH 2 - ， - （CH 2）2 - ， - （CH 2）3 - ， - （CH 2）（CH（CH 3））（CH 2） - 和 - （CH 2）4 - ，R 1和R 2相同或不同，各自为具有1-4个 碳原子，n为0或1或2，通过使过量使用的烷基胺与卤代烷基烷氧基硅烷反应，蒸馏掉过量的游离烷基胺，用烷基氨基烷基烷氧基硅烷处理剩余的产物混合物并加工。

公开(公告)号：US20110259240A1

公开(公告)日：2011-10-27

申请号：US12674601

申请日：2008-07-04

申请人： Peter Jenkner ,  Christoph Batz-Sohn ,  Heinz Lach ,  Stefan Scharfe ,  Philipp Albert ,  Eckhard Just

发明人： Peter Jenkner ,  Christoph Batz-Sohn ,  Heinz Lach ,  Stefan Scharfe ,  Philipp Albert ,  Eckhard Just

IPC分类号： C09D7/00

CPC分类号： C08G77/54 ,  B41M5/52 ,  B41M5/5218 ,  B41M5/529 ,  C08L83/14 ,  C09D183/14

摘要： The present invention relates to the use of a composition in coating agents, which is poor in volatile organic compounds (VOC) or essentially free of VOC, wherein the composition is at least partially based on one or more partially or fully hydrolyzed and optionally condensed or co-condensed aminoalkyl- and oligosilylated-aminoalkyl-, alkoxy- or hydroxy-functional silicon compounds and the alcohol is at least partially removed from the composition. The invention also relates to a composition containing aminoalkyl- or oligosilylated-aminoalkyl-, hydroxy- and optionally alkoxy-functional silicon compounds and to a method for producing such a composition.

摘要翻译： 本发明涉及组合物在包衣剂中的用途，其在挥发性有机化合物（VOC）中较差或基本上不含VOC，其中该组合物至少部分基于一种或多种部分或全部水解并任选地缩合或 共缩合氨基烷基 - 和寡甲硅烷基化 - 氨基烷基 - ，烷氧基 - 或羟基官能的硅化合物和醇至少部分地从组合物中除去。 本发明还涉及包含氨基烷基 - 或寡甲硅烷基化的 - 氨基烷基 - 羟基 - 和任选的烷氧基官能的硅化合物的组合物以及用于制备这种组合物的方法。