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    Method and system for providing remote portal service modules
    1.
    发明申请
    Method and system for providing remote portal service modules 审中-公开
    提供远程门户服务模块的方法和系统

    公开(公告)号：US20060047781A1

    公开(公告)日：2006-03-02

    申请号：US11226936

    申请日：2005-09-15

    申请人： Ed Anuff ,  Miles Chaston ,  Peter Leiser ,  Jean Tessier ,  John Taylor

    发明人： Ed Anuff ,  Miles Chaston ,  Peter Leiser ,  Jean Tessier ,  John Taylor

    IPC分类号： G06F15/16

    CPC分类号： H04L67/02 ,  H04L67/28 ,  H04L67/2838

    摘要： The present invention is a method for providing Remote Portal Services (RPS). RPS is a system for easily and quickly incorporating remote applications (RPS Services) into a portal. RPS Services may be enabled making the RPS Service available for incorporation onto a server implementing a portal. Enabled RPS Services may be disabled discontinuing the availability of the RPS Service for incorporation onto a server implementing a portal. RPS Services may be incorporated onto and removed from a server implementing a portal server. RPS Services may be added to and removed from a portal implemented on a server. RPS Services are exposed in the portal as modules, without installing, on the server implementing the portal, any software specific to a RPS Service. Enabled RPS Services may be listed on a directory that may be searched and browsed. The present invention may protect the exposure of data stored on servers during communication between servers.

    摘要翻译： 本发明是提供远程门户服务（RPS）的方法。 RPS是一种用于将远程应用程序（RPS Services）轻松快速地并入门户的系统。 可以启用RPS服务，使RPS服务可用于实现门户的服务器。 启用的RPS服务可能会禁用RPS服务的可用性，以将其并入实施门户的服务器。 RPS服务可以并入到实现门户服务器的服务器的服务器上并从其中移除。 可以将RPS服务添加到服务器上实施的门户网站或从其中删除。 RPS服务作为模块在门户中暴露出来，而无需在实现门户的服务器上安装任何特定于RPS服务的软件。 启用的RPS服务可能列在可能搜索和浏览的目录中。 本发明可以在服务器之间的通信期间保护存储在服务器上的数据的曝光。

    Pyrroles possessing insecticidal activity
    6.
    发明授权
    Pyrroles possessing insecticidal activity 失效
    PYRROLES POSSESSING INSECTICIDAL活动

    公开(公告)号：US5164409A

    公开(公告)日：1992-11-17

    申请号：US661399

    申请日：1991-02-26

    申请人： Marc Benoit ,  Jacques Demassey ,  Jean-Pierre Demoute ,  Jean Tessier

    发明人： Marc Benoit ,  Jacques Demassey ,  Jean-Pierre Demoute ,  Jean Tessier

    IPC分类号： A01N53/00 ,  A01N53/04 ,  C07D207/32 ,  C07D207/333

    CPC分类号： C07D207/333 ,  A01N53/00

    摘要： All possible stereoisomers and mixtures of a compound of the formula ##STR1## wherein X and Y are different and are selected from the group consisting of hydrogen, halogen, --CN, alkyl and haloalkyl of 1 to 8 carbon atoms and phenyl optionally substituted by at least one member of the group consisting of halogen and alkyl and alkoxy of 1 to 8 carbon atoms, R.sub.1 is selected from the group consisting of hydrogen, methyl, --CN and ethynyl, ##STR2## A and B are individually selected from the group consisting of hydrogen, halogen, alkyl of 1 to 8 carbon atoms and aryl of 6 to 14 carbon atoms and the --CF.sub.3 is in the 2-, 4- or 5-position of the pyrrole ring having pesticidal activity.

    摘要翻译： 式（I）化合物的所有可能的立体异构体和混合物，其中X和Y不同，并且选自氢，卤素，-CN，具有1至8个碳原子的烷基和卤代烷基，以及任选的苯基 被至少一个由卤素和1至8个碳原子的烷基和烷氧基组成的组取代，R 1选自氢，甲基，-CN和乙炔基，A和B分别选自 由氢，卤素，碳原子数1〜8的烷基和碳原子数为6〜14的芳基构成的基团，在具有杀虫活性的吡咯环的2-，4-或5-位。

    Process for the preparation of 1.R, cis cyclopropane di-carboxylic acid derivatives
    7.
    发明授权
    Process for the preparation of 1.R, cis cyclopropane di-carboxylic acid derivatives 失效
    制备1.R，顺式环丙烷二羧酸衍生物的方法

    公开(公告)号：US5026862A

    公开(公告)日：1991-06-25

    申请号：US416718

    申请日：1989-10-03

    申请人： Jean Tessier ,  Jean-Pierre Demoute

    发明人： Jean Tessier ,  Jean-Pierre Demoute

    IPC分类号： C07C69/743 ,  A01N53/10 ,  C07C67/00 ,  C07C67/343 ,  C07C67/44 ,  C07C69/608 ,  C07C69/747 ,  C07C253/30 ,  C07C255/39 ,  C07C325/00 ,  C07C327/12 ,  C07C327/22 ,  C07F9/6571

    CPC分类号： C07F9/657181

    摘要： A novel process for the preparation of compounds in all their possible isomeric forms of the formula ##STR1## wherein R is selected from the group consisting of hydrogen, alkyl of 1 to 18 carbon atoms, an easily cleavable derivative of the alcohol R-OH and a residue of an alcohol used in the pyrethrinoid series and when Y is --COOR' or --COSR', W is hydrogen and W is halogen when Y is --COOR' and R' is selected from the group consisting of hydrogen, optionally unsaturated alkyl of 1 to 18 carbon atoms and optionally substituted with at least one functional group, aryl optionally substituted with at least one functional group and heterocycle optionally substituted with at least one functional group and when W is hydrogen, the double bond has Z configuration and when W is halogen, the double bond has the E configuration comprising reacting a compound of the formula ##STR2## wherein R has the above definition with a compound of the formula ##STR3## wherein W and Y have the above definitions and A is alkylene of 1 to 18 carbon atoms attached to the two oxygen atoms fixed on the phosphorus atom to obtain a compound of formula I with the double bond having the Z configuration when W is hydrogen and having the E configuration when W is halogen, the cyclopropane and the carboxyl of Y being in both cases in the cis position with respect to the double bond and novel intermediates.

    摘要翻译： 一种用于制备其所有可能的式I化合物的化合物的新方法，其中R选自氢，1至18个碳原子的烷基，醇的易裂解衍生物R-OH 和在拟除虫菊酯类中使用的醇的残基，当Y是-COOR'或-COSR'时，W是氢，当Y是-COOR'时W是卤素，R'选自氢，任选不饱和的 任选被至少一个官能团取代的芳基和任选被至少一个官能团取代的杂环，当W是氢时，该双键具有Z构型，并且当 W是卤素，双键具有E构型，其包括使式II的化合物其中R具有上述定义与式III的化合物反应，其中W和Y具有上述定义 并且A是与固定在磷原子上的两个氧原子连接的1至18个碳原子的亚烷基，以便当W是氢时具有Z构型的双键并且当W是卤素时具有E构型的式I化合物 在两种情况下，Y的环丙烷和羧基在双键的顺式位置和新的中间体。

    Intermediates for (1,5) 6,6-Dimethyl-4-Hydroxy-3-oxabicyclo (3,1,0) Hexan-2-one and its ethers
    9.
    发明授权
    Intermediates for (1,5) 6,6-Dimethyl-4-Hydroxy-3-oxabicyclo (3,1,0) Hexan-2-one and its ethers 失效
    （1,5）6,6-二甲基-4-羟基-3-氧杂双环（3,1,0）己酮-2-酮及其醚的中间体

    公开(公告)号：US4801723A

    公开(公告)日：1989-01-31

    申请号：US36890

    申请日：1987-04-10

    申请人： Jacques Martel ,  Jean Tessier ,  Jean-Pierre DeMoute

    发明人： Jacques Martel ,  Jean Tessier ,  Jean-Pierre DeMoute

    IPC分类号： C07D307/33 ,  C07D307/60 ,  C07D307/93 ,  C07D307/58

    CPC分类号： C07D307/60 ,  C07D307/93

    摘要： A process for the preparation of compounds of the (1RS, 4RS, 5SR), (1R, 4R, 5S) or (1S, 4S, 5R) configuration having the formula ##STR1## wherein Y is selected from the group consisting of hydrogen and the organic residue Z of an optionally chiral alcohol of the formula ZOH comprising reacting in the presence of an acid agent 5RS-hydroxy-2,5-dihydrofuran-2-one having the formula ##STR2## either (a) with an achiral alcohol of the formula ZOH to obtain the resulting ether and reacting the latter in an anhydrous medium with an isopropylidene sulfurane of the formula ##STR3## wherein R.sub.1 and R.sub.2 are individually selected from the group consisting of optionally substituted monocyclic aromatic groups, isopropyl, groups and tertiary alkyl groups, to obtain a compound of formula I of the (1RS, 4RS, 5SR) configuration and Y is Z and optionally hydrolyzing the latter in acid medium to obtain the compound of formula I wherein Y is hydrogen or (b) with an optically active chiral alcohol of the formula ZOH to obtain a mixture of stereoisomeric ether due to the asymetrical carbon in the 5-position which mixture is rich in one of the two diastereoisomers, separating the diastereoisomeric ethers by physical means and reacting the separated diastereoisomers with the compound of formula II in anhydrous medium to obtain the compound of formula I with (1R, 4R, 5S) or (1S, 4S, 5R) configuration wherein Y is Z and optionally hydrolyzing the latter in an acid media to obtain the compound of formula I wherein Y is hydrogen and novel intermediates. The compounds of formula I where Y is hydrogen are described in French Pat. No. 1,580,474 and are interemediates for diversely substituted cyclopropane carboxylic acids whose esters are may active insecticides.

    摘要翻译： 制备具有下式的（1RS，4RS，5SR），（1R，4R，5S）或（1S，4S，5R）构型的化合物的方法，其中Y选自氢 和式ZOH的任选手性醇的有机残基Z包括在酸式试剂5RS-羟基-2,5-二氢呋喃-2-酮的存在下反应，式（II）与（a）与非手性 醇，得到所得的醚，并使其在无水介质中与式III的异丙叉硫烷反应，其中R 1和R 2分别选自任选取代的单环芳基，异丙基，基团 和叔烷基，得到（1RS，4RS，5SR）构型的式I化合物，Y为Z，并任选地在酸性介质中水解后者，得到其中Y为氢的式I化合物或（b）与 一种光学活性的手性醇 由于五位不对称碳在5位上得到立体异构体醚的混合物，该混合物富含两种非对映异构体之一，通过物理方法分离非对映异构体醚，并将分离的非对映异构体与式II化合物在无水 （1R，4R，5S）或（1S，4S，5R）构型的式I化合物，其中Y是Z，并任选地在酸性介质中水解后者，得到其中Y是氢的式I化合物， 新颖的中间体。 其中Y是氢的式I化合物描述于French Pat。 为1,580,474，并且是用于各种可取代的环丙烷羧酸的中间体，其酯可以是活性杀虫剂。

    Resolution of hemiacetals and alcohols
    10.
    发明授权
    Resolution of hemiacetals and alcohols 失效
    半缩醛和醇的分辨率

    公开(公告)号：US4701542A

    公开(公告)日：1987-10-20

    申请号：US846570

    申请日：1986-03-31

    申请人： Jean Tessier ,  Jean-Pierre Demoute

    发明人： Jean Tessier ,  Jean-Pierre Demoute

    IPC分类号： C07D307/00 ,  C07B31/00 ,  C07B57/00 ,  C07C31/125 ,  C07C45/67 ,  C07C49/743 ,  C07C62/02 ,  C07C67/00 ,  C07D213/64 ,  C07D307/77 ,  C07D307/87 ,  C07D307/93 ,  C07D307/935 ,  C07D405/12

    CPC分类号： C07D307/77 ,  C07C255/00 ,  C07C45/673 ,  C07C62/02 ,  C07D213/64 ,  C07D307/93

    摘要： A process for the resolution of hemiacetal compounds of the formula ##STR1## wherein A is a hydrocarbon chain containing 1 to 16 groups, the said chain optionally containing at least one heteroatom, at least one unsaturation, the assembly of the group constituting the chain may be a mono- or polycyclic system including a spiro or endosystem and the assembly of chain A and the carbon atoms attached thereto can contain at least one chiral atom or the hemiacetal moiety thereto which can present a chirality due to the dissymetric spatial configuration of the molecule and Y is selected from the group consisting of hydrogen, alkyl of 1 to 18 carbon atoms optionally substituted, --CY.sub.3 ' and the .beta.,.gamma.bond together with Y can be part of A and Y' is bromine or chlorine and the resolution of alcohols of the formulaR--OH IVwherein R is selected from the group consisting of primary, secondary or tertiary alcohol moiety having at least one asymmetric carbon or the remainder of a substituted alcohol with a chirality due to the dissymetric spatial configuration of the entire molecule comprising reacting in an organic solvent diisobutyl aluminum hydride and a racemate or optical isomer of a compound of the formula ##STR2## wherein A and Y have the above definition to obtain a compound of the formula ##STR3## and reacting the latter with a racemate or optical isomer of a compound of the formulaR--OH IVwherein R has the above definition to obtain a compound of the formula ##STR4## wherein Y, A and R have the above definitions, separating the diastereoisomers and cleaving the latter to obtain the enantiomers of the hemiacetal of formula III if the racemate was used above or the alcohol of formula IV if the racemate was used above and novel compounds.

    摘要翻译： 一种用于拆分式III的半缩醛化合物的方法，其中A是含有1至16个基团的烃链，所述链任选地含有至少一个杂原子，至少一个不饱和键，构成链的基团的组装 可以是包括螺或体系的单环或多环体系，并且链A的组合和与其连接的碳原子可以含有至少一个手性原子或其半缩醛部分，其可以由于不均匀空间结构而呈现手性 分子，Y选自氢，任选取代的1至18个碳原子的烷基，-CY 3'和β，γ键与Y一起可以是A的一部分，Y'是溴或氯，分解度 式R-OHIV的醇，其中R选自具有至少一个不对称碳的伯，仲或叔醇部分或其余的取代的 醇由于整个分子的不均匀空间构型而具有手性，包括在有机溶剂二异丁基氢化铝和式II化合物的外消旋物或旋光异构体中反应，其中A和Y具有上述定义，以获得 式III的化合物，并使其与式R-OHIV化合物的外消旋物或旋光异构体反应，其中R具有上述定义，得到下式的化合物其中Y，A和R 具有上述定义，分离非对映异构体并切割后者，如果外消旋物在上面使用或得到式IV的醇，如果上述使用外消旋物和新化合物，则获得式III的半缩醛的对映异构体。