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    Liquid crystal display device provided with a liquid crystalline compensating film having a positive uniaxiality in a nematic hybrid orientation
    1.
    发明授权
    Liquid crystal display device provided with a liquid crystalline compensating film having a positive uniaxiality in a nematic hybrid orientation 失效
    具有向列混合取向具有正单轴性的液晶补偿膜的液晶显示装置

    公开(公告)号：US5943110A

    公开(公告)日：1999-08-24

    申请号：US88598

    申请日：1998-06-01

    申请人： Eiji Yoda ,  Takehiro Toyooka ,  Tadahiro Kaminade ,  Takuya Matsumoto

    发明人： Eiji Yoda ,  Takehiro Toyooka ,  Tadahiro Kaminade ,  Takuya Matsumoto

    IPC分类号： G02F1/13 ,  C09K19/38 ,  G02F1/1335 ,  G02F1/13363 ,  G02F1/139 ,  G02F1/141

    CPC分类号： G02F1/133632 ,  G02F1/1396 ,  G02F2413/105

    摘要： A liquid crystal display device having improved and broadened viewing angle characteristics. The device includes a liquid crystal cell of the twisted nematic type for driving sandwiched by a pair of upper and lower polarizing plates in which at least one compensating film is inserted between the liquid crystal cell and the upper polarizing plate or between the liquid crystal cell and the lower polarizing plate. Alternatively, two compensating films are respectively inserted between the liquid crystal cell and the upper polarizing plate and between the liquid crystal cell and the lower polarizing plate. The compensating film consists essentially of a liquid crystalline polymer showing optically a positive uniaxiality, the liquid crystalline polymer being fixed in a nematic hybrid orientational order. The device is further characterized by an angle between a tilt direction of the compensating film and a pretilt direction on a liquid crystal cell substrate opposed to a substrate for the liquid crystal cell for driving closest to the compensating film in the range of 165.degree. and 195.degree. C.

    摘要翻译： 一种液晶显示装置，其具有改进的和加宽的视角特性。 该装置包括扭转向列型的液晶单元，用于驱动夹在一对上下偏振板之间，其中至少一个补偿膜插入在液晶单元和上偏振板之间或液晶单元与 下偏振片。 或者，两个补偿膜分别插入在液晶单元和上偏振板之间以及液晶单元和下偏振板之间。 补偿膜基本上由液晶聚合物基本上由光学上显示正单轴性组成，液晶聚合物以向列混合取向顺序固定。 该装置的特征还在于，补偿膜的倾斜方向与液晶单元基板的与用于最靠近补偿膜驱动的液晶单元的基板相对的165°和195°范围内的倾斜方向之间的角度 DEG C.

    Optical film
    2.
    发明授权
    Optical film 失效
    光学胶片

    公开(公告)号：US06261649B1

    公开(公告)日：2001-07-17

    申请号：US09008007

    申请日：1998-01-16

    申请人： Akira Takagi ,  Tadahiro Kaminade ,  Takuya Matsumoto ,  Yosuke Numao ,  Takayuki Hirayama ,  Masato Sone

    发明人： Akira Takagi ,  Tadahiro Kaminade ,  Takuya Matsumoto ,  Yosuke Numao ,  Takayuki Hirayama ,  Masato Sone

    IPC分类号： C09K1938

    CPC分类号： G02F1/133632 ,  G02B5/3016 ,  G02F1/133365 ,  G02F2413/105 ,  Y10T428/10 ,  Y10T428/1036

    摘要： A high-quality optical compensator for use in liquid crystal display elements can be prepared from a film comprising an end unit modified liquid crystalline polymer which has a monofunctional structural unit and which exhibits an optically positive uniaxiality, and, as needed, a liquid crystalline polymer which has a logarithmic viscosity at least 0.01 dl/g higher than that of the end unit modified liquid crystalline polymer and a glass transition point at least 5° C. higher than that of the end unit modified liquid crystalline polymer and which exhibits an optically positive uniaxiality, wherein a nematic hybrid orientation which is formed in the liquid crystal state is immobilized.

    摘要翻译： 用于液晶显示元件的高质量光学补偿器可以由包含端单元改性液晶聚合物的膜制备，所述端单元改性液晶聚合物具有单官能结构单元并且显示出光学上的单轴性，并且根据需要可以制备液晶聚合物 其对数粘度比末端单元改性液晶聚合物的对数粘度至少为0.01dl / g，玻璃化转变点比末端单元改性液晶聚合物高至少5℃，并且具有光学阳性 单轴性，其中固定有以液晶状态形成的向列混合取向。

    METHOD FOR PRODUCING NORBORNENE DERIVATIVE
    5.
    发明申请
    METHOD FOR PRODUCING NORBORNENE DERIVATIVE 失效
    生产诺贝恩衍生物的方法

    公开(公告)号：US20100197970A1

    公开(公告)日：2010-08-05

    申请号：US12669954

    申请日：2008-07-29

    申请人： Shinichi Komatsu ,  Toshikatsu Shoko ,  Tadahiro Kaminade

    发明人： Shinichi Komatsu ,  Toshikatsu Shoko ,  Tadahiro Kaminade

    IPC分类号： C07F9/28 ,  C07C4/24

    CPC分类号： C07C13/605 ,  C07C2/86 ,  C07C2/861 ,  C07C17/266 ,  C07C2531/24 ,  C07C2602/42 ,  C07C2603/86 ,  C07C2603/90 ,  C07C13/42 ,  C07C13/68 ,  C07C13/64 ,  C07C25/24

    摘要： A method for producing a norbornene derivative wherein, in the presence of palladium and at least one selected from phosphorus compounds represented by the following General Formulae (1) and (2): [in Formula (1), R1, R2, R3 and R4 each independently represent a hydrogen atom or the like, and R5 and R6 each independently represent a branched chain saturated hydrocarbon group having 3 to 10 carbon atoms or the like], and [in Formula (2), R7 represents a branched chain saturated hydrocarbon group having 3 to 10 carbon atoms], a norbornadiene derivative represented by the following General Formula (3): [in Formula (3), R8, R9, R10, R11 and R12 each independently represent a hydrogen atom or the like, l represents an integer of 0 or 1, m represents an integer of 0 or 1, and n represents an integer of 0 or 1], and a bromine compound represented by the following General Formula (4): [Chemical Formula 4] Br—Z—R13  (4) [in Formula (4), Z represents a phenylene group or the like, and R13 represents a hydrogen atom or the like] are reacted with each other, to thereby obtain a norbornene derivative represented by the following General Formula (5): [in Formula (5), R14, R15, R16, R17 and R18 each independently represent a hydrogen atom or the like, Z represents a phenylene group or the like, R19 represents a hydrogen atom or the like, l represents an integer of 0 or 1, m represents an integer of 0 or 1, and n represents an integer of 0 or 1], the norbornene derivative having a configuration of a substituent represented by Z in General Formula (5) that is an exo configuration.

    摘要翻译： 一种降冰片烯衍生物的制备方法，其中在钯和选自由以下通式（1）和（2）表示的磷化合物中的至少一种的存在下，[式（1）中，R 1，R 2，R 3和R 4 各自独立地表示氢原子等，R5和R6各自独立地表示碳原子数3〜10的支链饱和烃基等]，[式（2）中，R7表示支链饱和烃基 具有3至10个碳原子]，由以下通式（3）表示的降冰片二烯衍生物：[式（3）中，R 8，R 9，R 10，R 11和R 12各自独立地表示氢原子等，l表示 0或1的整数，m表示0或1的整数，n表示0或1的整数]和由以下通式（4）表示的溴化合物：[化学式4] Br-Z-R13 （4）[式（4）中，Z表示亚苯基等，R 13表示亚苯基等 代表氢原子等]彼此反应，从而得到由以下通式（5）表示的降冰片烯衍生物：[式（5）中，R 14，R 15，R 16，R 17和R 18各自独立地表示 氢原子等，Z表示亚苯基等，R 19表示氢原子等，l表示0或1的整数，m表示0或1的整数，n表示0以上的整数， 1]表示的通式（5）中由Z表示的取代基的降冰片烯衍生物为外部构型。

    REVERSE DISPERSION RETARDATION FILM AND LIQUID CRYSTAL DISPLAY DEVICE USING THE SAME
    7.
    发明申请
    REVERSE DISPERSION RETARDATION FILM AND LIQUID CRYSTAL DISPLAY DEVICE USING THE SAME 失效
    反向分散延迟膜和使用其的液晶显示装置

    公开(公告)号：US20110313121A1

    公开(公告)日：2011-12-22

    申请号：US13145826

    申请日：2009-12-24

    申请人： Tadahiro Kaminade ,  Shinichi Komatsu ,  Hisashi Sone ,  Takeshi Koike ,  Sayako Kawahama

    发明人： Tadahiro Kaminade ,  Shinichi Komatsu ,  Hisashi Sone ,  Takeshi Koike ,  Sayako Kawahama

    IPC分类号： C08F232/08

    CPC分类号： G02B5/3083 ,  C08G61/08 ,  C08G2261/3324 ,  C08G2261/418 ,  Y10T428/10

    摘要： A reverse dispersion retardation film, formed by stretching a film comprising a norbornene-based ring-opening copolymer containing a structural unit (A) represented by the following general formula (1): [in the formula (1), m represents an integer of any one of 0 and 1, R1 represents a hydrogen atom or the like, X1 represents a group represented by a formula: —CH2CH2— or the like, a and b each independently represent an integer of 0 to 6, Y represents a methylene group or the like, and represents a methylene group or the like] and a structural unit (B) represented by the following general formula (2): [in the formula (2), n represents an integer of any one of 0 and 1, X2 represents a group represented by a formula: —CH2CH2— or the like, R2, R3, R4, and R5 each represent a hydrogen atom or the like, wavy lines d and e each represent a configuration of any one of an endo and an exo, and a wavy line f represents a configuration of any one of an endo and an exo], wherein a total amount of the structural unit (A) and an exo-form structural unit, in which the wavy line f represents the exo configuration, among the structural units (B) is not less than 20 mol % but not more than 65 mol % of all the structural units.

    摘要翻译： 通过拉伸含有由以下通式（1）表示的结构单元（A）的降冰片烯系开环共聚物的膜形成的反色散相位差膜：[式（1）中，m表示 0和1中的任一个，R 1表示氢原子等，X 1表示由式-CH 2 CH 2 - 等表示的基团，a和b各自独立地表示0〜6的整数，Y表示亚甲基 并且表示亚甲基等]和由以下通式（2）表示的结构单元（B）：[式（2）中，n表示0和1中任一项的整数， X 2表示由式-CH 2 CH 2 - 等表示的基团，R 2，R 3，R 4和R 5各自表示氢原子等，波浪线d和e分别表示内酯和 exo，波浪线f表示endo和exo]中任何一个的构型，其中总数为am 结构单元（A）的结构单元（B）中的波浪线f表示外部构型的外部结构单元，其结构单元（B）中的结构单元（B）不小于20mol％但不大于65mol％ 结构单位。

    Optical film
    10.
    发明授权
    Optical film 有权
    光学胶片

    公开(公告)号：US06210872B1

    公开(公告)日：2001-04-03

    申请号：US09554780

    申请日：2000-05-18

    申请人： Kenji Hosaki ,  Yoshihiro Kumagai ,  Tadahiro Kaminade

    发明人： Kenji Hosaki ,  Yoshihiro Kumagai ,  Tadahiro Kaminade

    IPC分类号： G03C1005

    CPC分类号： C09K19/3809 ,  C08G63/06 ,  C08G63/19 ,  C08G63/60 ,  C08G63/605 ,  C08G63/6824 ,  G02B5/3016

    摘要： A novel optical film capable of readily vitrifying the tendency and state of liquid crystal alignment, excellent in the ability to retain the alignment state, and suitable for the application to optical elements. The film is produced from a liquid-crystal material containing as the essential ingredient a liquid-crystal polyester having structural units (A) and (B) as the essential unit, exhibiting a vitrified state at a temperature lower than the liquid-crystal transition point, and having a logarithmic viscosity number (&eegr;) of 0.04-0.4 dl/g as measured at 30° C. in a phenol/tetrachloroethane solvent (60/40 by weight), wherein each X represents independently O or C═O; each Y represents independently a group selected from among F, Cl, Br and 1-4C alkyls; and n is 0 or 1.

    摘要翻译： 一种能够容易地玻璃化液晶取向的趋势和状态的新型光学膜，保持取向状态的能力优异，并且适用于光学元件。 该膜由含有结构单元（A）和（B）作为必须单元的液晶聚酯作为必需成分的液晶材料制成，在低于液晶转变点的温度下显示玻璃化状态 并且在苯酚/四氯乙烷溶剂（60/40重量比）中在30℃下测得的对数粘度数（η）为0.04-0.4dl / g，其中每个X独立地表示O或C = O; 每个Y独立地表示选自F，Cl，Br和1-4C烷基的基团; n为0或1。