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1.发明授权Process for the synthesis of zeolites and mesoporous solids from a homogeneous solution in a semi-open system 失效在半开放系统中从均相溶液合成沸石和介孔固体的方法
公开(公告)号：US5695735A
公开(公告)日：1997-12-09
申请号：US565399
申请日：1995-11-30
IPC分类号： C01B37/02 , C01B39/02 , C01B39/04 , C01B39/24 , C01B39/30 , C01B39/38 , C01B39/40 , C01B39/48
CPC分类号： C01B39/02 , C01B37/02 , C01B39/04 , C01B39/24 , C01B39/305 , C01B39/40 , C01B39/48 , Y10S423/21 , Y10S423/22 , Y10S423/27 , Y10S423/32 , Y10S423/38
摘要： The invention concerns a process for the synthesis of zeolites based on element(s) T and mesoporous solids based on element(s) T, T being silicon and/or aluminium, comprising the following sequence of steps: i) synthesizing a reaction medium which is a homogeneous source of element(s) T containing: a) at least one source of element(s) T selected from the group formed by aqueous basic solutions of silica or silica and alumina and alcoholic solutions of alkyl tetraorthosilicate and trialkoxyaluminium; b) optionally, at least one structuring agent; c) optionally, seeds of the desired crystalline phase; ii) heating the reaction medium to a temperature in the range 20.degree. C. to 220.degree. C. for a period in the range several minutes and several days; iii) injecting at least one chemical agent at a controlled rate to generate polycondensable species in said medium.
摘要翻译： 本发明涉及一种基于元素T和介孔固体的基于元素T，T为硅和/或铝的合成沸石的方法，其包括以下步骤顺序：i）合成反应介质，其中 是元素T的均匀源，其含有：a）选自由二氧化硅或二氧化硅和氧化铝的碱性水溶液形成的基团中的至少一种元素T，以及四原硅酸烷基酯和三烷氧基铝的烷基醇溶液; b）任选地，至少一种结构剂; c）任选地，所需结晶相的种子; ii）将反应介质加热至20℃至220℃的温度，持续数分钟和数天的时间; iii）以受控的速率注射至少一种化学试剂以在所述介质中产生可缩聚物质。
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公开(公告)号：US5171556A
公开(公告)日：1992-12-15
申请号：US743967
申请日：1991-08-12
申请人： Philippe Caullet , Jean-Louis Guth , Anne-Catherine Faust , Francis Raatz , Jean-Francois Joly , Jean-Marie Deves
发明人： Philippe Caullet , Jean-Louis Guth , Anne-Catherine Faust , Francis Raatz , Jean-Francois Joly , Jean-Marie Deves
CPC分类号： B01J29/7007 , C01B39/48 , B01J2229/26 , B01J2229/42
摘要： The object of the invention is a synthetic crystalline zeolite of the beta type characterized by:a) the following approximate general formula:M.sub.2/n O, Al.sub.2 O.sub.3, xSiO.sub.2where M represents a proton and/or a metallic cationn is the valence of Mx is a number ranging from 5 to 800,b) an X-ray diffraction diagram represented in table I of the description, andc) a fluorine content ranging from about 0.005 to 2.0% by weight, said zeolite having been furthermore synthetized in a fluoride medium.
摘要翻译： 本发明的目的是一种β型合成结晶沸石，其特征在于：a）以下近似通式：M 2 / nO，Al 2 O 3，xSiO 2，其中M表示质子和/或金属阳离子n是M x的化合价 是5〜800的数，b）说明书的表I所示的X射线衍射图，c）氟含量为0.005〜2.0重量％左右，所述沸石进一步在氟化物中合成 中。
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公开(公告)号：US5215736A
公开(公告)日：1993-06-01
申请号：US860557
申请日：1992-03-30
申请人： Philippe Caullet , Jean-Louis Guth , Anne-Catherine Faust , Jean-Francois Joly , Christine Travers , Francis Raatz
发明人： Philippe Caullet , Jean-Louis Guth , Anne-Catherine Faust , Jean-Francois Joly , Christine Travers , Francis Raatz
CPC分类号： C01B33/2861 , B01J29/18 , C07C5/2724 , Y10S423/25
摘要： The object of the invention is a synthetic crystalline zeolite of the mordenite type characterized by:a) the following approximate general formula:Na.sub.2 O, Al.sub.2 O.sub.3, xSiO.sub.2 where x is a number ranging from 9 to 30, andb) an X-ray diffraction diagram represented in table I of the description,c) a fluorine content ranging from about 0.005 to 2.0% by weight,and in that it has been synthetized in a fluoride medium.The invention also relates to a process for preparing said zeolite.This zeolite can notably be utilized in adsorption and in catalysis.
摘要翻译： 本发明的目的是丝光沸石的合成结晶沸石，其特征在于：a）以下近似通式：Na 2 O，Al 2 O 3，xSiO 2，其中x为9至30的数，以及b）X射线衍射图 表示在说明书的表I中，c）氟含量范围为约0.005-2.0重量％，并且其在氟化物介质中合成。 本发明还涉及制备所述沸石的方法。 该沸石可以显着地用于吸附和催化。
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公开(公告)号：US5350722A
公开(公告)日：1994-09-27
申请号：US920487
申请日：1992-08-20
CPC分类号： B01J29/7034 , C01B39/42 , B01J2229/26 , B01J2229/42 , Y10S423/33
摘要： The invention relates to a synthetic crystalline zeolite of the MTW type, characterized by:a) the following approximate general formula:M.sub.2/n O, Al.sub.2 O.sub.3, xSiO.sub.2 in which M represents a metal cation and/or proton, n is the valency of M and x is a number between 14 and 800,b) a X-ray diagram shown in table I of the description,c) a fluorine content between approximately 0.005 and 2% by weight, said zeolite having been synthesized in a fluoride medium and accompanied by stirring.
摘要翻译： PCT No.PCT / FR91 / 01029 Sec。 371日期：1992年8月20日 102（e）日期1992年8月20日PCT 1991年12月18日PCT PCT。 出版物WO92 / 11203 本发明涉及MTW型合成结晶沸石，其特征在于：a）以下近似通式：M 2 / nO，Al 2 O 3，xSiO 2，其中M表示金属阳离子和/或质子， n是M的化合价，x是14和800之间的数字，b）描述表I所示的X射线图，c）约0.005-2重量％的氟含量，所述沸石已被合成 在氟化物介质中并伴随搅拌。
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公开(公告)号：US5338525A
公开(公告)日：1994-08-16
申请号：US923880
申请日：1992-10-16
申请人： Jean-Francois Joly , Philippe Caullet , Jean-Louis Guth , Anne-Catherine Faust , Nathalie Brunard , Frederic Kolenda
发明人： Jean-Francois Joly , Philippe Caullet , Jean-Louis Guth , Anne-Catherine Faust , Nathalie Brunard , Frederic Kolenda
IPC分类号： B01J29/40 , B01J29/70 , B01J29/86 , B01J29/87 , B01J29/88 , C01B39/06 , C01B39/08 , C01B39/38 , C01B33/26 , B01J29/06
CPC分类号： C01B39/065 , B01J29/40 , B01J29/87 , C01B39/082 , C01B39/38 , B01J2229/26 , B01J2229/42
摘要： Synthetic crystalline zeolite of the MFI type and its preparation process, said zeolite being characterized by:a) the following approximate general formula:M.sup.+.sub.(x+y) [Si.sub.(96-(x+y)) Al.sub.x Ga.sub.y 0.sub.192 ].sup.(x+y).sup.- in which M represents an alkaline cation and/or ammonium cation and/or a proton, x is a number between 0 and 24, y is a number between 0 and 24, (x+y) is a number between 0.64 and 24 and preferably between 1.88 and 19.2,b) a X-ray diagram of its ammonium form shown in Table I of the description andc) a fluorine content of its ammonium form between approximately 0.01 and 2.0% by weight, said zeolite having been synthesized in a fluoride medium and in the absence of an organic agent.
摘要翻译： PCT No.PCT / FR91 / 01068 Sec。 371日期：1992年10月16日 102（e）日期1992年10月16日PCT 1991年12月24日PCT公布。 出版物WO92 / 12096 日本1992年7月23日。MFI型合成结晶沸石及其制备方法，所述沸石的特征在于：a）以下近似通式：M +（x + y）[Si（96-（x + y）） （x + y） - 其中M表示碱性阳离子和/或铵阳离子和/或质子，x为0至24之间的数，y为0至24之间的数，（x + y）为 数字在0.64和24之间，优选在1.88和19.2之间，b）其描述的表I所示的铵形式的X射线图，c）其铵形式的氟含量在约0.01和2.0重量％之间， 所述沸石已经在氟化物介质中合成，并且在不存在有机试剂的情况下。
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6.发明授权公开(公告)号：US06558647B2
公开(公告)日：2003-05-06
申请号：US09736048
申请日：2000-12-14
申请人： Sylvie Lacombe , David Marseault , Philippe Caullet , Henri Kessler , Eric Benazzi , Alexandre Jouve
发明人： Sylvie Lacombe , David Marseault , Philippe Caullet , Henri Kessler , Eric Benazzi , Alexandre Jouve
IPC分类号： C01B3904
CPC分类号： B01J29/005 , B01J29/0308 , B01J29/041 , B01J29/7007 , B01J29/7415 , B01J2229/42 , C01B39/023 , C10G47/20 , Y10S423/27
摘要： The invention relates to an acidic silicoaluminate solid that has a microporous zeolitic phase that is characterized by at least one infrared band between 400-1600 cm−1, an organized mesoporosity that is characterized by the presence of at least one X-diffraction line between 20-100 Å, a silica/alumina molar ratio of between 5-250 and an acidity that is measured by infrared analysis via an area of the band at about 1545 cm−1 at least equal to 50 g of dry solid. The invention also relates to a process for the preparation of the solid, a substrate that consists of solid and at least one matrix, and a catalyst that comprises said solid. The catalyst can be used for the conversion of hydrocarbons and in particular hydrocracking.
摘要翻译： 本发明涉及一种酸性硅铝酸盐固体，其具有微孔沸石相，其特征在于至少一个在400-1600cm -1之间的红外波段，有组织的介孔密度，其特征在于存在至少一个X射线在20 -100埃，二氧化硅/氧化铝摩尔比在5-250之间，并且通过红外分析通过在约1545cm -1至少等于50g干固体的带的面积测量的酸度。 本发明还涉及制备固体的方法，由固体和至少一种基质组成的底物和包含所述固体的催化剂。 催化剂可用于转化烃，特别是加氢裂化。
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公开(公告)号：US08444952B2
公开(公告)日：2013-05-21
申请号：US13140501
申请日：2009-11-26
申请人： Mathias Dodin , Yannick Lorgouilloux , Jean-Louis Paillaud , Philippe Caullet , Joel Patarin , Nicolas Bats
发明人： Mathias Dodin , Yannick Lorgouilloux , Jean-Louis Paillaud , Philippe Caullet , Joel Patarin , Nicolas Bats
摘要： The invention concerns a crystalline solid designated IM-20 which has the X-ray diffraction diagram given below. Said solid has a chemical composition expressed by the empirical formula: mXO2: nGeO2: pZ2O3: qR: sF: wH2O, in which R represents one or more organic species, X represents one or more tetravalent element(s) other than germanium, Z represents at least one trivalent element and F is fluorine.
摘要翻译： 本发明涉及一种称为IM-20的结晶固体，其具有以下给出的X射线衍射图。 所述固体具有由以下经验式表示的化学组成：mXO2：nGeO2：pZ2O3：qR：sF：wH2O，其中R表示一种或多种有机物质，X表示一种或多种除锗以外的四价元素，Z表示 至少一个三价元素，F是氟。
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公开(公告)号：US08372376B2
公开(公告)日：2013-02-12
申请号：US12301889
申请日：2007-05-10
CPC分类号： C01B39/06 , C01B37/00 , C01B37/005
摘要： The invention relates to a crystallized solid, referred to by the name IM-13, which has an X-ray diffraction diagram as provided below. Said solid has a chemical composition that is expressed according to the general formula mXO2: nYO2: pZ2O3: qR: sF: wH2O, where R represents one or more organic radical(s), X represents one or more tetravalent element(s) different from germanium, Y represents germanium, Z represents at least one trivalent element, and F is fluorine.
摘要翻译： 本发明涉及名称为IM-13的结晶固体，其具有如下提供的X射线衍射图。 所述固体具有根据通式mXO 2：n YO 2：pZ 2 O 3：qR：sF：wH 2 O表示的化学组成，其中R表示一个或多个有机基团，X表示一个或多个与以下不同的四价元素： 锗，Y表示锗，Z表示至少一种三价元素，F表示氟。
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9.发明申请Process for separation by selective adsorption on a solid containing a zeolite with a crystalline structure analogous to IM-12 审中-公开通过选择性吸附在含有类似于IM-12的晶体结构的沸石的固体上分离的方法公开(公告)号：US20060115421A1
公开(公告)日：2006-06-01
申请号：US11256271
申请日：2005-10-24
申请人： Philibert Leflaive , Anne-Claire Dubreuil , Philippe Caullet , Joel Patarin , Jean-Louis Paillaud
发明人： Philibert Leflaive , Anne-Claire Dubreuil , Philippe Caullet , Joel Patarin , Jean-Louis Paillaud
CPC分类号： C07C7/12 , B01D15/00 , B01D15/08 , B01D15/1821 , B01D53/02 , B01D2253/108 , B01J20/18 , B01J2220/54 , C07C7/13 , C10G25/03 , C10G25/05 , C10G2300/1025 , C10G2300/1096 , C10G2300/202 , C10G2300/4006 , C10G2300/4012 , C10G2400/30 , C10L3/10
摘要： A process for adsorption separation uses a solid IM-12 type adsorbent to separate a molecular species from any feed.
摘要翻译： 吸附分离方法使用固体IM-12型吸附剂将分子种类与任何进料分离。
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公开(公告)号：US20100324320A1
公开(公告)日：2010-12-23
申请号：US12301889
申请日：2007-05-10
IPC分类号： C07F7/02
CPC分类号： C01B39/06 , C01B37/00 , C01B37/005
摘要： The invention relates to a crystallized solid, referred to by the name IM-13, which has an X-ray diffraction diagram as provided below. Said solid has a chemical composition that is expressed according to the general formula mXO2: nYO2: pZ2O3: qR : sF : wH2O, where R represents one or more organic radical(s), X represents one or more tetravalent element(s) different from germanium, Y represents germanium, Z represents at least one trivalent element, and F is fluorine.
摘要翻译： 本发明涉及名称为IM-13的结晶固体，其具有如下提供的X射线衍射图。 所述固体具有根据通式mXO 2：n YO 2：pZ 2 O 3：qR：sF：wH 2 O表示的化学组成，其中R表示一个或多个有机基团，X表示一个或多个与以下不同的四价元素： 锗，Y表示锗，Z表示至少一种三价元素，F表示氟。
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