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1.发明授权Electrode modification using surface associated lithium salts and an associated process for fabrication of an electrode 有权使用表面相关的锂盐进行电极改性和用于制造电极的相关工艺公开(公告)号：US06228531B1
公开(公告)日：2001-05-08
申请号：US09166013
申请日：1998-10-02
申请人： Eric S. Kolb , Martin Van Buren , Denis G. Fauteux
发明人： Eric S. Kolb , Martin Van Buren , Denis G. Fauteux
IPC分类号： H01M448
CPC分类号： H01M4/131 , H01M4/04 , H01M4/366 , H01M4/485 , H01M4/525 , H01M4/62 , H01M10/052 , Y10T29/49115
摘要： The present invention is directed to an electrode, and associated fabrication process, for use in an electrochemical cell. The electrode has an active material comprising a transition metal oxide. A lithium salt having an organic component is associated with the surface of the transition metal oxide so as to increase compatibility with an associated electrolyte. In another embodiment, a lithium salt of saccharin may be adsorbed onto the surface of the transition metal oxide.
摘要翻译： 本发明涉及用于电化学电池中的电极和相关的制造工艺。 电极具有包含过渡金属氧化物的活性材料。 具有有机成分的锂盐与过渡金属氧化物的表面相关联，以增加与相关电解质的相容性。 在另一个实施方案中，糖精的锂盐可以被吸附到过渡金属氧化物的表面上。
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2.发明授权Electrochemical cell having a controlled electrode surface and associated fabrication and chemical process 有权具有受控电极表面和相关制造和化学过程的电化学电池公开(公告)号：US06168878A
公开(公告)日：2001-01-02
申请号：US09208895
申请日：1998-12-10
申请人： Denis G. Fauteux , Martin Van Buren , Eric S. Kolb
发明人： Denis G. Fauteux , Martin Van Buren , Eric S. Kolb
IPC分类号： H01M1034
CPC分类号： H01M4/0442 , H01M4/0438 , H01M4/66 , H01M4/661
摘要： An electrochemical cell, and an associated process, wherein the cell includes a controlled electrode surface comprising an electrode with a metallic current collector having a surface, an electrolyte and a reduced additive. The invention further includes a passivating layer at the interface between the metallic current collector and the electrolyte. The passivating layer includes the reduced additive. This passivating layer substantially precludes contact between electrolyte solvent and surface of the metallic current collector to, in turn, substantially prevent gas formation within the cell, which would otherwise result from decomposition of the solvent upon contact with the surface of the metallic current collector. Also, the reduced additive will likewise be substantially precluded from generating a gas upon its decomposition.
摘要翻译： 电化学电池和相关联的方法，其中所述电池包括受控电极表面，其包括具有带有表面的金属集流体的电极，电解质和还原性添加剂。 本发明还包括在金属集流体和电解质之间的界面处的钝化层。 钝化层包括还原添加剂。 该钝化层基本上排除了电解质溶剂和金属集流体表面之间的接触，从而基本上防止了电池内的气体形成，否则这些气体在与金属集流体的表面接触时分解溶剂会导致。 此外，还原添加剂同样基本上不会在其分解时产生气体。
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3.发明授权Electrochemical cell having a controlled electrode surface and associated fabrication and chemical process 有权具有受控电极表面和相关制造和化学过程的电化学电池
公开(公告)号：US6045937A
公开(公告)日：2000-04-04
申请号：US178846
申请日：1998-10-26
申请人： Eric S. Kolb , Martin Van Buren , Denis G. Fauteux
发明人： Eric S. Kolb , Martin Van Buren , Denis G. Fauteux
IPC分类号： H01M4/02 , H01M2/02 , H01M4/04 , H01M4/62 , H01M4/66 , H01M6/16 , H01M10/38 , H01M10/40 , H01M10/42 , H01M10/44 , H01M10/52 , H01M10/34
CPC分类号： H01M4/62 , H01M10/0525 , H01M10/058 , H01M4/0442 , H01M4/66 , H01M4/661 , H01M10/4235 , H01M10/446 , H01M10/52 , H01M2/0275 , H01M2002/0205 , H01M6/168
摘要： An electrochemical cell, and an associated process, wherein the cell includes a controlled electrode surface comprising an electrode with a carbonaceous surface, an electrolyte and a reduced additive. The reduced additive is formulated from an additive which is either soluble or insoluble in the solvated electrolyte prior to reduction. The invention further includes a passivating layer at the carbonaceous electrode/electrolyte interface. The passivating layer includes the additive and/or the reduced additive. This passivating layer substantially precludes contact between electrolyte solvent and the carbonaceous surface of the electrode to, in turn, substantially prevent gas formation within the cell, which would otherwise result from decomposition of the solvent upon contact with the carbonaceous surface. Also, the additive and/or the reduced additive will likewise be substantially precluded from generating a gas upon its decomposition.
摘要翻译： 电化学电池和相关联的方法，其中所述电池包括受控电极表面，其包括具有碳质表面的电极，电解质和还原性添加剂。 还原的添加剂由在还原之前可溶或不溶于溶剂化电解质的添加剂配制。 本发明还包括在碳质电极/电解质界面处的钝化层。 钝化层包括添加剂和/或还原添加剂。 该钝化层基本上排除了电解质溶剂和电极的碳质表面之间的接触，从而基本上防止了电池内的气体形成，否则这些气体在与碳质表面接触时会由溶剂分解而产生。 此外，添加剂和/或还原添加剂同样基本上不会在其分解时产生气体。
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4.发明授权
公开(公告)号：US5846267A
公开(公告)日：1998-12-08
申请号：US893387
申请日：1997-07-11
申请人： Denis G. Fauteux , Martin Van Buren
发明人： Denis G. Fauteux , Martin Van Buren
IPC分类号： H01M4/60 , H01M6/10 , H01M6/18 , H01M6/22 , H01M10/052 , H01M10/0565 , H01M10/38
CPC分类号： H01M10/052 , H01M10/0565 , H01M6/18 , H01M6/188 , H01M6/10 , H01M6/181 , Y10T29/49108 , Y10T29/49112
摘要： The present invention is directed to an electrolytic cell and associated process for fabrication, wherein the cell utilizes an intermediate sub-component connecting layer. This layer comprises an electrolyte which, in an at least partially cured state, is at least partially sandwiched between an electrolyte on a first sub-component and an electrolyte on a second sub-component. Prior to full curing of the intermediate sub-component connecting layer, the cell is oriented into a desired product configuration. Once such a configuration is obtained, the intermediate sub-component connecting layer is fully cured to, in turn, maintain the cell in the desired product configuration without concern of misalignment or mechanical degradation between the various sub-components and/or the cell.
摘要翻译： 本发明涉及一种电解池及其制造方法，其中电池利用中间子部件连接层。 该层包括电解质，其至少部分固化的状态至少部分地夹在第一子组分上的电解质和第二子组分上的电解质之间。 在完全固化中间子部件连接层之前，将电池定向成所需的产品配置。 一旦获得了这样的配置，中间子部件连接层就被完全固化，从而将电池保持在所需的产品结构中，而不考虑各种子部件和/或电池之间的不对准或机械劣化。
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5.发明授权Electrode materials having an elastomer binder and associated electrochemical and fabrication process 有权电极材料具有弹性体粘合剂和相关的电化学和制造工艺公开(公告)号：US06225003B1
公开(公告)日：2001-05-01
申请号：US09178844
申请日：1998-10-26
IPC分类号： H01M462
摘要： An electrode for use in an electrochemical cell comprising a current collecting substrate, an electrode active material cluster having at least one particle wherein the particle includes at least one inclusion, an elastomer binder surrounding at least a portion of the at least one particle, and means associated with the elastomer binder for precluding mechanical degradation of the electrode active material cluster and, in turn, loss of electrical continuity between the at least one particle therein.
摘要翻译： 一种用于电化学电池的电极，包括集电衬底，具有至少一个颗粒的电极活性材料簇，其中所述颗粒包括至少一种夹杂物，围绕所述至少一个颗粒的至少一部分的弹性体粘合剂， 与弹性体粘合剂相关联，用于排除电极活性材料簇的机械降解，从而损失其中的至少一个颗粒之间的电连续性。
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公开(公告)号：US5434021A
公开(公告)日：1995-07-18
申请号：US290017
申请日：1994-08-12
申请人： Denis G. Fauteux , Martin Van Buren , Jie Shi , Mehmet Rona
发明人： Denis G. Fauteux , Martin Van Buren , Jie Shi , Mehmet Rona
摘要： An electrolytic cell and electrolytic process wherein the cell includes a metal anode (such as a lithium anode), a cathode and an electrolyte. A surface layer which is applied to the metal anode enables transfer of ions from the metal anode to the electrolyte and thus allows the ions to pass back into contact with the metal anode. The surface layer is also electronically conductive so that the ions will be uniformally attracted back onto the metal anode during electrodeposition to, in turn, substantially suppress dendrite growth and, in turn, substantially increase the cycle life of the cell.
摘要翻译： 一种电解槽和电解工艺，其中电池包括金属阳极（例如锂阳极），阴极和电解质。 施加到金属阳极的表面层能够将离子从金属阳极转移到电解质，从而允许离子返回与金属阳极接触。 表面层也是电子导电的，使得在电沉积期间离子将均匀地吸引回到金属阳极上，从而基本上抑制枝晶生长，并且进而显着增加电池的循环寿命。
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公开(公告)号：US5547778A
公开(公告)日：1996-08-20
申请号：US502109
申请日：1995-07-13
申请人： Denis G. Fauteux , Martin Van Buren , Jie Shi
发明人： Denis G. Fauteux , Martin Van Buren , Jie Shi
CPC分类号： H01M10/0567 , H01M10/05 , H01M4/02 , H01M4/381 , H01M10/24
摘要： An electrolytic cell, such as a rechargeable lithium battery, having cavitands associated with a metal ion source-electrode and an electrolyte. The cavitands, which are anchored to the electrode by a polymer leash, are capable of releasably attracting particular ions, such as lithium ions, which are migrating from the electrolyte, toward the surface of the electrode during electrodeposition. The polymer leash serves to continuously maintain the cavitands at a predetermined distance away from the surface of the electrode, regardless of surface area fluctuations, typically caused during deposition and dissolution of the particular ions. Accordingly, the cavitands facilitate substantially uniform electrodeposition of the particular ions, which, in turn, substantially suppresses and/or controls the formation and growth of a passive film or layer, on the electrode surface, which may otherwise promote the formation of dendrites.
摘要翻译： 具有与金属离子源电极和电解质相关联的空穴的诸如可再充电锂电池的电解池。 通过聚合物皮带锚定到电极的空穴能够在电沉积期间释放地吸引从电解质迁移到电极表面的特定离子，例如锂离子。 聚合物带用于将空穴连续地保持在离电极表面预定距离处，而不管通常在特定离子的沉积和溶解期间引起的表面积波动。 因此，空穴促进了特定离子的基本上均匀的电沉积，其进而基本上抑制和/或控制在电极表面上的钝化膜或层的形成和生长，否则可能促进枝晶的形成。
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公开(公告)号：US5776209A
公开(公告)日：1998-07-07
申请号：US451911
申请日：1995-05-26
CPC分类号： H01M4/0416 , H01M4/04 , H01M4/0402 , H01M4/0404 , H01M4/16 , Y02P70/54 , Y10T29/49115 , Y10T29/53135
摘要： An apparatus and process for applying an electrode paste onto a substrate for use in an electrolytic cell. The apparatus includes a mixing device which mixes, and then dispenses, predetermined amounts of an electrode paste and a polymerization initiator onto a substrate. The mixing device is constructed so as to substantially preclude polymerization of the electrode paste during such mixing, as well as to preclude polymerization prior to application of the mixture onto the substrate.
摘要翻译： 一种用于将电极浆料涂敷在用于电解槽中的基板上的装置和方法。 该装置包括混合装置，然后将预定量的电极浆料和聚合引发剂分配到基材上。 混合装置被构造成基本上排除了在这种混合期间电极浆料的聚合，以及在将混合物施加到基材之前阻止聚合。
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公开(公告)号：US5746782A
公开(公告)日：1998-05-05
申请号：US679442
申请日：1996-07-08
CPC分类号： H01M4/0416 , H01M4/04 , H01M4/0402 , H01M4/0404 , H01M4/16 , Y02P70/54 , Y10T29/49115 , Y10T29/53135
摘要： An apparatus and process for applying an electrode paste onto a substrate for use in an electrolytic cell. The apparatus includes a mixing device which mixes, and then dispenses, predetermined amounts of an electrode paste and a polymerization initiator onto a substrate. The mixing device is constructed so as to substantially preclude polymerization of the electrode paste during such mixing, as well as to preclude polymerization prior to application of the mixture onto the substrate.
摘要翻译： 一种用于将电极浆料涂敷在用于电解槽中的基板上的装置和方法。 该装置包括混合装置，然后将预定量的电极浆料和聚合引发剂分配到基材上。 混合装置被构造成基本上排除了在这种混合期间电极浆料的聚合，以及在将混合物施加到基材之前阻止聚合。
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公开(公告)号：US5724721A
公开(公告)日：1998-03-10
申请号：US757229
申请日：1996-11-27
申请人： Denis G. Fauteux , Martin Van Buren
发明人： Denis G. Fauteux , Martin Van Buren
CPC分类号： H01M2/08 , H01M10/0436 , H01M6/188 , H01M6/40 , H01M6/181 , H01M8/0271 , Y02P70/56 , Y10T29/49108 , Y10T29/49115
摘要： The present invention is directed to an electrode mask for use in an electrolytic cell, and an associated process for fabricating such a cell with an electrode mask. The electrode mask is applied to a limited portion of the active material of at least one of the first and second electrodes so that the peripheral edge of the electrode mask and associated electrodes are in planer relationship with each other. In addition, the electrode mask can be applied in a manner which enables a fully fabricated electrolytic cell to be manufactured with any desired geometric configuration, merely by altering the electrode mask application pattern, and a die-cutter to cut an assembled cell in conformance with the applied pattern of the electrode mask.
摘要翻译： 本发明涉及一种用于电解池的电极掩模，以及用于制造具有电极掩模的电池的相关工艺。 将电极掩模施加到第一和第二电极中的至少一个电极的活性材料的有限部分，使得电极掩模和相关电极的周边彼此成平面关系。 此外，电极掩模可以以使得完全制造的电解池能够通过改变电极掩模施加图案而以任何期望的几何构造制造的方式被施加，并且模切机以符合以下步骤的方式切割组装的电池 电极掩模的应用图案。
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