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公开(公告)号：US06255541B1
公开(公告)日：2001-07-03
申请号：US09319572
申请日：1999-06-09
申请人： Erkki Paatero , Esa Nummi , Lars Peter Lindfors , Hannu Nousiainen , Jukka Hietala , Leila Lahtinen , Rami Haakana
发明人： Erkki Paatero , Esa Nummi , Lars Peter Lindfors , Hannu Nousiainen , Jukka Hietala , Leila Lahtinen , Rami Haakana
IPC分类号： C07C2704
摘要： The invention relates to a process for the preparation of polyvalent alcohols by hydrogenation of an aldehyde. According to the invention said aldehyde is obtained by aldolisation reaction of an aldehyde containing an &agr; hydrogen atom and having the formula R1CHO, or the mixture of said aldehyde with a second different aldehyde having the formula or R2CHO, wherein R1 is selected from alkyl having 1-12 carbon atoms, cycloalkyl, aryl and aralkyl having 1-14 carbon atoms, and R2 is selected from H, alkyl having 1-12 carbon atoms, cycloalkyl, aryl and aralkyl having 1-14 carbon atoms, said aldolisation being carried out in the presence of a weak base anion exchange resin, and the hydrogenation being carried out in the presence of a solvent and a hydrogenation catalyst.
摘要翻译： 本发明涉及通过醛的氢化制备多元醇的方法。 根据本发明，所述醛是通过含有α氢原子并具有式R 1 CHO的醛的醛缩合反应或所述醛与具有下式的R 2 CHO的第二种不同的醛的混合物获得的，其中R 1选自具有1 -12个碳原子，环烷基，芳基和具有1-14个碳原子的芳烷基，R2选自H，具有1-12个碳原子的烷基，具有1-14个碳原子的环烷基，芳基和芳烷基，所述醛醇化在 存在弱碱性阴离子交换树脂，并且在溶剂和氢化催化剂存在下进行氢化。
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公开(公告)号：US06500780B1
公开(公告)日：2002-12-31
申请号：US08840274
申请日：1997-04-14
申请人： Tuomo Suntola , Suvi Haukka , Arla Kytökivi , Eeva-Liisa Lakomaa , Marina Lindblad , Jukka Hietala , Harri Hokkanen , Hilkka Knuuttila , Pekka Knuuttila , Outi Krause , Lars Peter Lindfors
发明人： Tuomo Suntola , Suvi Haukka , Arla Kytökivi , Eeva-Liisa Lakomaa , Marina Lindblad , Jukka Hietala , Harri Hokkanen , Hilkka Knuuttila , Pekka Knuuttila , Outi Krause , Lars Peter Lindfors
IPC分类号： B01J3702
CPC分类号： B01J37/0238 , B01J21/063 , B01J23/26 , B01J23/30
摘要： The present invention concerns a method for preparing heterogeneous catalysts. According to the method, preparation is carried out under such process conditions in which the bonding of compounds from the gas phase onto the surface of a support material is primarily determined by the properties of the support surface. The constituents contained in the reagent are then selectively bonded to the bonding sites of the support material surface, thus forming stable surface bonds. According to the invention, the number of surface-bond sites available for preparing a stable product with surface bonds is controlled by varying the reaction temperature and/or selecting a suitable reagent. The invention makes it possible to control the metal content of the end product at a predetermined level.
摘要翻译： 本发明涉及一种制备非均相催化剂的方法。 根据该方法，在这样的工艺条件下进行制备，其中化合物从气相到载体材料的表面上的键合主要由支撑体表面的性质决定。 然后将包含在试剂中的组分选择性地结合到载体材料表面的结合位点，从而形成稳定的表面键。 根据本发明，通过改变反应温度和/或选择合适的试剂来控制可用于制备具有表面键的稳定产物的表面键合位点的数目。 本发明使得能够将最终产品的金属含量控制在预定水平。
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公开(公告)号：US5372982A
公开(公告)日：1994-12-13
申请号：US913723
申请日：1992-07-16
申请人： Jukka Hietala , Pekka Knuuttila , Arla Kytokivi
发明人： Jukka Hietala , Pekka Knuuttila , Arla Kytokivi
IPC分类号： B01J27/10 , B01J23/30 , B01J37/02 , C07B61/00 , C07C6/04 , C07C11/02 , B01J27/138 , B01J21/08 , B01J27/135
CPC分类号： B01J23/30 , B01J37/0238 , C07C6/04 , C07C2521/08 , C07C2521/14 , C07C2523/30
摘要： The present invention concerns a heterogeneous catalyst particularly suited to the metathetic reactions of olefins in liquid or gas phase. Such a catalyst generally includes catalytically active species of tungsten on an inorganic support. The catalyst in accordance with the invention is prepared by vaporizing a precursor of tungsten, such as tungsten oxychloride or hexachloride and then routing the vapor of the tungsten-containing reagent into a reaction space, where the vapor is brought to interaction with the support material at approximately 160.degree. to 500.degree. C. The vapor pressure of the tungsten-containing reagent is kept sufficiently high, and the duration of interaction with the support sufficiently long, to keep the amount of the reagent at least equal to the number of available bonding sites of the support, whereby the bonding of the tungsten-containing reagent to the support surface is determined by the surface properties of the support. The catalyst can be posttreated after its preparation to modify its catalytic activity. The specific activity of the catalytic metal species of the catalyst according to the invention is high.
摘要翻译： 本发明涉及一种特别适用于液相或气相中烯烃的互变异构反应的非均相催化剂。 这种催化剂通常包括无机载体上的钨的催化活性物质。 根据本发明的催化剂通过将钨的前体如氯化氧化铈或六氯化碳蒸发，然后将含钨试剂的蒸气导入反应空间来制备，其中蒸气与载体材料相互作用 约160℃至500℃。含钨试剂的蒸汽压力保持足够高，并且与载体的相互作用持续时间足够长，以保持试剂的量至少等于可用结合位点的数量 由此通过载体的表面性质来确定含钨试剂与载体表面的结合。 催化剂在其制备后可以进行后处理以改变其催化活性。 根据本发明的催化剂的催化金属种类的比活性很高。
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公开(公告)号：US20090039310A1
公开(公告)日：2009-02-12
申请号：US11884236
申请日：2006-02-06
申请人： Jukka Hietala
发明人： Jukka Hietala
IPC分类号： C09K3/18
摘要： Disclosed is a novel deicing composition having improved corrosion inhibition and being obtained by mixing 89-99.98% by weight of an alkali metal formate 0.01-6% by weight of an alkali metal silicate and 0.01-5% by weight of a C4-C19 alkyl carboxylic acid, said weight percentages being calculated on dry substances.
摘要翻译： 公开了一种具有改进的腐蚀抑制作用的新型除冰组合物，其通过将89-99.98重量％的0.01-6重量％的碱金属甲酸盐和0.01-5重量％的C 4 -C 19烷基 羧酸，所述重量百分比是根据干物质计算的。
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公开(公告)号：US07628934B2
公开(公告)日：2009-12-08
申请号：US11884236
申请日：2006-02-06
申请人： Jukka Hietala
发明人： Jukka Hietala
IPC分类号： C09K3/18
摘要： Disclosed is a novel deicing composition having improved corrosion inhibition and being obtained by mixing 89-99.98% by weight of an alkali metal formate 0.01-6% by weight of an alkali metal silicate and 0.01-5% by weight of a C4-C19 alkyl carboxylic acid, said weight percentages being calculated on dry substances.
摘要翻译： 公开了一种具有改进的腐蚀抑制作用的新型除冰组合物，其通过将89-99.98重量％的0.01-6重量％的碱金属甲酸盐和0.01-5重量％的C 4 -C 19烷基 羧酸，所述重量百分比是根据干物质计算的。
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公开(公告)号：US5177291A
公开(公告)日：1993-01-05
申请号：US798508
申请日：1991-11-26
申请人： Pekka Knuuttila , Jukka Hietala , Anja Linna
发明人： Pekka Knuuttila , Jukka Hietala , Anja Linna
CPC分类号： B01J23/30 , C07C6/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/14 , C07C2523/30 , C07C2527/224
摘要： A metathesis process of the conversion of olefines, in which at least one olefine is brought into contact with a solid catalyst system comprising on a solid silica carrier 0.1-40% by weight of a tungsten compound under reaction conditions such that the catalyst system converts the olefine into olefines having a different molecular weight. In the process a magnesium oxide or titanium oxide containing co-gel prepared by means of a co-gelling system is used as the silica carrier.
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7.发明授权Catalyst for metathesis reactions of olefines and a method for preparing it as well as the metathesis reaction concerned 失效烯烃复分解反应的催化剂及其制备方法以及相关的复分解反应
公开(公告)号：US5296437A
公开(公告)日：1994-03-22
申请号：US915098
申请日：1992-07-16
CPC分类号： C07C6/04 , B01J23/30 , C07C2521/08 , C07C2531/16
摘要： The invention relates to a catalyst to be utilized in the metathesis reactions of olefines, the catalyst comprising an after-treated tungsten complex containing diol ligands and hydrocarbon ligands, which are benzenes substituted with a lower alkyl group. The invention also relates to a method for preparing a heterogenous catalyst to be used in the metathesis reaction of olefines as well as to a metathesis process for the conversion of olefines.
摘要翻译： 本发明涉及用于烯烃的复分解反应中的催化剂，该催化剂包含含有二醇配体的后处理钨络合物和烃配体，其为被低级烷基取代的苯。 本发明还涉及一种用于制备用于烯烃的复分解反应的异质催化剂的方法以及用于烯烃转化的复分解方法。
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公开(公告)号：US20130331601A1
公开(公告)日：2013-12-12
申请号：US13992343
申请日：2011-12-09
申请人： Esko Tirronen , Jukka Hietala , Reijo Aksela
发明人： Esko Tirronen , Jukka Hietala , Reijo Aksela
IPC分类号： C07C51/493
CPC分类号： C07C51/493 , B01D11/043 , B01D11/0434 , B01D11/0492 , C07C53/02 , C07C53/08
摘要： The present invention relates to a method and an arrangement for recovery of at least one organic acid from a dilute aqueous solution thereof. In this method a complex between said organic acid and an extractant is formed by contacting the solution with a reactive extractant and dissolving the formed complex into said extractant thus forming an extractant phase. The organic acid is removed from the formed complex by esterification using an alcohol.
摘要翻译： 本发明涉及一种从其稀水溶液中回收至少一种有机酸的方法和装置。 在该方法中，通过使溶液与反应性提取剂接触并将形成的络合物溶解在所述萃取剂中形成萃取相，形成所述有机酸和萃取剂之间的络合物。 使用醇通过酯化从形成的络合物中除去有机酸。
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