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公开(公告)号：US09677011B2
公开(公告)日：2017-06-13
申请号：US13382823
申请日：2010-07-02
申请人： Pekka Knuuttila , Jaakko Nousiainen
发明人： Pekka Knuuttila , Jaakko Nousiainen
CPC分类号： C10G65/00 , A61K8/31 , A61K47/06 , C10G3/46 , C10G3/50 , C10G45/02 , C10G45/58 , C10G2300/1014 , C10G2300/202 , C10G2300/207 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/04 , Y02P30/20
摘要： The invention relates to a process and an apparatus for producing hydrocarbon components in the presence of a hydrodesulphurization catalyst. The components obtained by the process are suitable for use as fuel composition as such or as an additive in fuel compositions, and in cosmetics or pharmaceutical products.
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2.发明申请公开(公告)号：US20110203277A1
公开(公告)日：2011-08-25
申请号：US13126789
申请日：2009-10-30
申请人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
发明人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
CPC分类号： C10K3/04 , C10G2/30 , C10J3/482 , C10J2300/0906 , C10J2300/0909 , C10J2300/0916 , C10J2300/092 , C10J2300/0946 , C10J2300/0959 , C10J2300/0976 , C10J2300/1659 , C10J2300/1675 , C10K1/004 , C10K1/024 , C10K1/08 , C10K1/165 , C10K3/023 , C10L1/06 , C10L1/08 , Y02E50/13 , Y02E50/32 , Y02P20/124 , Y02P20/145
摘要： The invention relates to producing liquid hydro carbonaceous product (1) from solid biomass (2). In the invention solid biomass (2) is gasified in a gasifier (6) to produce raw synthesis gas (3). The raw synthesis gas (3) is conditioned to purify the raw synthesis gas (3) to obtain purified synthesis gas (4), the conditioning comprising lowering the temperature of the raw synthesis gas (3) in a cooler (19) producing saturated steam (51). Then the purified gas (4) is subjected to a Fischer-Tropsch synthesis in a Fischer-Tropsch reactor (5) to produce liquid hydro carbonaceous product (1). In the invention the saturated steam (51) produced by the cooler (19) is further superheated in a superheating boiler (50) for producing superheated steam (52).
摘要翻译： 本发明涉及从固体生物质（2）生产液体含碳产物（1）。 在本发明中，固体生物质（2）在气化器（6）中气化以产生原始合成气（3）。 对原料合成气（3）进行调节以净化原料合成气（3）以获得纯化的合成气（4），该调理包括降低生产饱和蒸汽的冷却器（19）中的原料合成气（3）的温度 （51）。 然后，将经纯化的气体（4）在费 - 托反应器（5）中进行费 - 托合成以制备液体含碳产物（1）。 在本发明中，由冷却器（19）产生的饱和蒸汽（51）在用于制造过热蒸汽（52）的过热锅炉（50）中进一步过热。
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公开(公告)号：US20100305220A1
公开(公告)日：2010-12-02
申请号：US12669769
申请日：2008-07-18
申请人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
发明人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
CPC分类号： C01B3/48 , B01D53/526 , B01D53/8618 , B01D2252/2026 , B01D2252/204 , B01D2253/1124 , B01D2255/20792 , B01D2257/304 , B01D2257/504 , C01B3/38 , C01B3/52 , C01B2203/0233 , C01B2203/0283 , C01B2203/0415 , C01B2203/0475 , C01B2203/1235 , C10G2/32 , C10G2300/1011 , C10G2300/202 , C10G2300/4081 , C10G2300/44 , C10G2300/807 , C10J3/503 , C10J3/721 , C10J3/84 , C10J2300/0903 , C10J2300/0916 , C10J2300/0959 , C10J2300/0973 , C10J2300/1618 , C10J2300/1659 , C10J2300/1807 , C10J2300/1838 , C10J2300/1884 , C10K1/002 , C10K1/005 , C10K1/006 , C10K1/101 , C10K1/143 , C10K3/023 , C10K3/04 , Y02E50/32 , Y02P20/145 , Y02P20/152 , Y02P30/20
摘要： The invention relates to a method and apparatus for producing liquid hydro carbonaceous product (1) such as biofuel from solid biomass (2). The method comprises a gasifying step for gasifying solid biomass (2) in a gasifier (6) to produce raw synthesis gas (3), conditioning of the raw synthesis gas (3) to purify the raw synthesis gas (3) to obtain purified synthesis gas (4) having a molar ratio of hydrogen to carbon monoxide between 2.5 to 1 and 0.5 to 1, preferably to between 2.1 to 1 and 1.8 to 1, more preferably about 2 to 1, and subjecting purified synthesis gas (4) to a Fischer-Tropsch synthesis in a Fischer-Tropsch reactor (5) to produce liquid hydro carbonaceous product (1).
摘要翻译： 本发明涉及一种用于生产液体含碳物质（1）如固体生物质（2）的生物燃料的方法和装置。 该方法包括在气化器（6）中气化固体生物质（2）以产生原料合成气（3）的气化步骤，原料合成气（3）的调理以净化原料合成气（3）以获得纯化合成 将氢与一氧化碳的摩尔比在2.5至1和0.5至1之间，优选为2.1至1至1.8至1，更优选约2至1的气体（4）和将纯化的合成气（4） 费 - 托反应器（5）中的费 - 托合成，生产液态含碳产物（1）。
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公开(公告)号：US5177291A
公开(公告)日：1993-01-05
申请号：US798508
申请日：1991-11-26
申请人： Pekka Knuuttila , Jukka Hietala , Anja Linna
发明人： Pekka Knuuttila , Jukka Hietala , Anja Linna
CPC分类号： B01J23/30 , C07C6/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/14 , C07C2523/30 , C07C2527/224
摘要： A metathesis process of the conversion of olefines, in which at least one olefine is brought into contact with a solid catalyst system comprising on a solid silica carrier 0.1-40% by weight of a tungsten compound under reaction conditions such that the catalyst system converts the olefine into olefines having a different molecular weight. In the process a magnesium oxide or titanium oxide containing co-gel prepared by means of a co-gelling system is used as the silica carrier.
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公开(公告)号：US09790439B2
公开(公告)日：2017-10-17
申请号：US13699328
申请日：2011-05-23
CPC分类号： C10G45/60 , C10G3/46 , C10G3/48 , C10G3/49 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/1022 , C10G2300/202 , C10G2300/4018 , C10G2300/4081 , C10G2300/802 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/04 , C10L1/06 , C10L1/08 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要： The present invention relates to a process for producing mixture of fuel components, which process comprises providing a feed of biological origin; subjecting said feed of biological origin and a hydrogen gas feed to a single step of hydroprocessing in the presence of a catalyst system comprising dewaxing catalyst to form a mixture of fuel components. The present invention relates also to an apparatus for producing a mixture of fuel components from a feed of biological origin. The invention relates also to the use of the fuel components.
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公开(公告)号：US09120982B2
公开(公告)日：2015-09-01
申请号：US13450260
申请日：2012-04-18
申请人： Jaakko Nousiainen , Arto Rissanen , Andrea Gutierrez , Teemu Lindberg , Heli Laumola , Pekka Knuuttila
发明人： Jaakko Nousiainen , Arto Rissanen , Andrea Gutierrez , Teemu Lindberg , Heli Laumola , Pekka Knuuttila
CPC分类号： C10G3/50 , B01J8/0453 , B01J8/0492 , B01J2208/00274 , B01J2208/025 , C10G3/46 , C10G3/48 , C10G3/49 , C10G3/54 , C10G2300/1014 , C10G2300/1018 , C10G2300/4018 , C10G2400/02 , C10G2400/04 , C10L1/08 , Y02P30/20
摘要： The present invention relates to a process for catalytically converting material of biological origin into hydrocarbons useful as fuel components. The process includes hydrodeoxygenation and isomerization of the material. The present invention relates also to a reactor and an apparatus suitable for use in the process.
摘要翻译： 本发明涉及将生物来源的材料催化转化成可用作燃料组分的烃的方法。 该方法包括加氢脱氧和异构化的材料。 本发明还涉及适用于该方法的反应器和装置。
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7.发明申请PROCESS AND APPARATUS FOR PRODUCING FUEL FROM A BIOLOGICAL ORIGIN THROUGH A SINGLE HYDROPROCESSING STEP IN THE PRESENCE OF A NIW CATALYST 有权通过NIW催化剂存在下的单一加氢步骤从生物原产生燃料的工艺和装置公开(公告)号：US20130067801A1
公开(公告)日：2013-03-21
申请号：US13699328
申请日：2011-05-23
CPC分类号： C10G45/60 , C10G3/46 , C10G3/48 , C10G3/49 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/1022 , C10G2300/202 , C10G2300/4018 , C10G2300/4081 , C10G2300/802 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/04 , C10L1/06 , C10L1/08 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要： The present invention relates to a process for producing mixture of fuel components, which process comprises providing a feed of biological origin; subjecting said feed of biological origin and a hydrogen gas feed to a single step of hydroprocessing in the presence of a catalyst system comprising dewaxing catalyst to form a mixture of fuel components. The present invention relates also to an apparatus for producing a mixture of fuel components from a feed of biological origin. The invention relates also to the use of the fuel components.
摘要翻译： 本发明涉及生产燃料组分混合物的方法，该方法包括提供生物来源的饲料; 在包含脱蜡催化剂的催化剂体系的存在下，将所述生物来源的饲料和氢气进料进行加氢处理的一个步骤以形成燃料组分的混合物。 本发明还涉及一种用于生产来自生物来源的饲料的燃料成分的混合物的装置。 本发明还涉及燃料组分的使用。
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公开(公告)号：US20120260565A1
公开(公告)日：2012-10-18
申请号：US13450260
申请日：2012-04-18
申请人： Jaakko NOUSIAINEN , Arto RISSANEN , Andrea GUTIERREZ , Teemu LINDBERG , Heli LAUMOLA , Pekka KNUUTTILA
发明人： Jaakko NOUSIAINEN , Arto RISSANEN , Andrea GUTIERREZ , Teemu LINDBERG , Heli LAUMOLA , Pekka KNUUTTILA
CPC分类号： C10G3/50 , B01J8/0453 , B01J8/0492 , B01J2208/00274 , B01J2208/025 , C10G3/46 , C10G3/48 , C10G3/49 , C10G3/54 , C10G2300/1014 , C10G2300/1018 , C10G2300/4018 , C10G2400/02 , C10G2400/04 , C10L1/08 , Y02P30/20
摘要： The present invention relates to a process for catalytically converting material of biological origin into hydrocarbons useful as fuel components. The process includes hydrodeoxygenation and isomerisation of the material. The present invention relates also to a reactor and an apparatus suitable for use in the process.
摘要翻译： 本发明涉及将生物来源的材料催化转化成可用作燃料组分的烃的方法。 该方法包括加氢脱氧和异构化的材料。 本发明还涉及适用于该方法的反应器和装置。
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9.发明申请Use of Methanol in the Production of Hydrogen and Fuel, Processes and Plants for the Production of Hydrogen and Fuel 审中-公开在生产氢气和燃料中使用甲醇，生产氢和燃料的方法和工艺公开(公告)号：US20100317905A1
公开(公告)日：2010-12-16
申请号：US12742213
申请日：2008-10-29
申请人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
发明人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
CPC分类号： C01B3/323 , C01B3/382 , C01B3/48 , C01B3/52 , C01B13/0248 , C01B2203/0233 , C01B2203/0244 , C01B2203/0283 , C01B2203/0415 , C01B2203/043 , C01B2203/0465 , C01B2203/048 , C01B2203/049 , C01B2203/1223 , C01B2210/0046 , C02F1/00 , C02F3/00 , C02F2101/34 , C02F2103/023 , C02F2103/16 , C02F2103/28 , C02F2103/365 , C10G2/30 , C10G2/32 , C10G3/00 , C10G3/50 , C10G45/58 , C10G2300/1003 , C10G2300/1011 , C10J3/00 , C10J2300/0916 , C10J2300/0959 , C10J2300/16 , C10J2300/1659 , C10J2300/1678 , C10J2300/169 , C10K1/101 , C10K3/04 , C10L1/04 , C10L2200/0469 , C10L2290/42 , C10L2290/54 , D21C11/0007 , D21C11/06 , Y02E20/16 , Y02E20/18 , Y02E50/32 , Y02P20/145 , Y02P30/20
摘要： The invention relates to the use of biomethanol from the pulp industry in the production of biohydrogen. The preferred biomethanol comprises purified biomethanol derived from black liquor. The invention also relates to a process for the production of biohydrogen from crude biomethanol recovered from black liquor and to a process for producing hydrocarbon biofuel using such biohydrogen as a hydrogen source. The invention further relates to a biofuel production facility for producing fuel from biohydrogen and biohydrocarbon, and to biofuel so produced. The invention makes it possible to produce a biofuel, wherein 100% of the raw material stems from non-fossil sources.
摘要翻译： 本发明涉及来自纸浆工业的生物甲醇在生物氢生产中的应用。 优选的生物甲醇包含来自黑液的纯化生物甲醇。 本发明还涉及从从黑液中回收的粗生物甲醇生产生物氢的方法，以及使用这种生物氢作为氢源生产烃生物燃料的方法。 本发明还涉及用于从生物氢和生物烃生产燃料的生物燃料生产设备以及如此生产的生物燃料。 本发明使得可以生产生物燃料，其中100％的原料源自非化石源。
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10.发明申请Integrated Process for Producing Diesel Fuel from Biological Material and Products, Uses and Equipment Relating to Said Process 审中-公开生物材料和产品生产柴油的综合工艺，与所述方法相关的用途和设备公开(公告)号：US20100317903A1
公开(公告)日：2010-12-16
申请号：US12742209
申请日：2008-10-31
申请人： Pekka Knuuttila
发明人： Pekka Knuuttila
CPC分类号： C01B3/32 , C01B3/382 , C01B3/48 , C01B3/501 , C01B3/56 , C01B2203/0244 , C01B2203/0283 , C01B2203/0405 , C01B2203/043 , C01B2203/0465 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/062 , C01B2203/1217 , C01B2203/1223 , C01B2203/1235 , C10G1/00 , C10G2/32 , C10G3/46 , C10G3/50 , C10G45/58 , C10G65/16 , C10G2300/1014 , C10G2300/1018 , C10G2300/1022 , C10G2300/304 , C10G2300/307 , C10G2400/04 , C10J3/00 , C10J2300/0916 , C10J2300/1659 , C10K3/00 , C10K3/04 , Y02E50/13 , Y02E50/14 , Y02E50/32 , Y02P20/125 , Y02P20/145 , Y02P30/20
摘要： The present invention relates to an integrated process for producing diesel fuel or fuel additive from biological material by producing paraffins by a Fischer-Tropsch reaction on one hand and by a catalytic hydrodeoxygenation of bio oils and fats on the other hand. The two hydrocarbon streams are combined and distilled together. The invention also relates to the use of lignocellulosic material, such as by-products of the wood-processing industry for producing diesel fuel and to a method for narrowing the chain length distribution of Fischer-Tropsch derived diesel fuel. The invention provides a high-quality middle distillate fraction from various biological sources and most preferably from by-products of the wood-processing industry. The invention also relates to equipment for producing fuel form biological material, which comprises a hydrodeoxygenation reactor (3) for hydrocarbons, a cracking/isomerization reactor (11) for FT paraffins and a separation unit (12) for the combined hydrocarbons. Hydrogen is separated from light fractions in a separation unit (9) and reformed in the process. The equipment is advantageously integrated with a pulp and paper mill, which provides biological material and receives waste and energy.
摘要翻译： 本发明涉及通过一方面通过费 - 托反应和另一方面通过生物油和脂肪的催化加氢脱氧来生产石蜡从生物材料生产柴油燃料或燃料添加剂的综合方法。 将两个烃流合并并蒸馏。 本发明还涉及木质纤维素材料（例如木材加工工业的副产物）用于生产柴油的用途以及缩短费 - 托衍生的柴油燃料的链长度分布的方法。 本发明提供了来自各种生物来源的高品质中间馏分馏分，最优选由木材加工工业的副产物提供。 本发明还涉及用于生产燃料形式生物材料的设备，其包括用于烃的加氢脱氧反应器（3），用于FT石蜡的裂化/异构化反应器（11）和用于组合烃的分离单元（12）。 在分离单元（9）中将氢与轻馏分分离，并在该过程中重整。 该设备有利地与纸浆和造纸厂结合，纸浆和造纸厂提供生物材料并且接收废物和能量。
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