公开(公告)号：US10195600B2

公开(公告)日：2019-02-05

申请号：US15179032

申请日：2016-06-10

Applicant: ExxonMobil Research and Engineering Company

Inventor： Paul Podsiadlo ,  Quanchang Li ,  David C. Calabro ,  Kiara M. Benitez ,  Machteld M. W. Mertens ,  Scott J. Weigel ,  Doron Levin ,  Randall D. Partridge

IPC: B01J31/26 ,  B01J29/70 ,  B01J31/12 ,  B01J35/00 ,  B01J37/00 ,  C10G45/54 ,  C10G45/64 ,  C10G47/16 ,  B01J29/40 ,  B01J29/44 ,  B01J29/74 ,  C07C5/10

Abstract: Catalysts including at least one microporous material (e.g., zeolite), an organosilica material binder, and at least one catalyst metal are provided herein. Methods of making the catalysts, preferably without surfactants and processes of using the catalysts, e.g., for aromatic hydrogenation, are also provided herein.

公开(公告)号：US20170354961A1

公开(公告)日：2017-12-14

申请号：US15179032

申请日：2016-06-10

Applicant: ExxonMobil Research and Engineering Company

Inventor： Paul Podsiadlo ,  Quanchang Li ,  David C. Calabro ,  Kiara M. Benitez ,  Machteld M.W. Mertens ,  Scott J. Weigel ,  Doron Levin ,  Randall D. Partridge

IPC: B01J31/26 ,  C10G47/16 ,  C10G45/54 ,  B01J29/70 ,  B01J31/12 ,  B01J35/00 ,  B01J37/00 ,  C10G45/64

CPC classification number: B01J31/26 ,  B01J29/40 ,  B01J29/44 ,  B01J29/70 ,  B01J29/703 ,  B01J29/7038 ,  B01J29/7461 ,  B01J29/7476 ,  B01J31/125 ,  B01J31/127 ,  B01J35/0006 ,  B01J37/0009 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/42 ,  B01J2231/641 ,  B01J2231/646 ,  C10G45/54 ,  C10G45/64 ,  C10G47/16

Abstract: Catalysts including at least one microporous material (e.g., zeolite), an organosilica material binder, and at least one catalyst metal are provided herein. Methods of making the catalysts, preferably without surfactants and processes of using the catalysts, e.g., for aromatic hydrogenation, are also provided herein.

公开(公告)号：US10661262B2

公开(公告)日：2020-05-26

申请号：US16031449

申请日：2018-07-10

Applicant: ExxonMobil Research and Engineering Company

Inventor： Paul Podsiadlo ,  Quanchang Li ,  David Charles Calabro ,  Jean Willem Lodewijk Beeckman ,  Lei Zhang ,  Kiara M. Benitez ,  Matthew Scott Ide ,  Stephen John McCarthy ,  Mobae Afeworki ,  Simon Christopher Weston ,  Preeti Kamakoti ,  Matu J. Shah ,  Wenyih Frank Lai ,  Meghan Kochersperger ,  David A. Griffin ,  Ivy D. Johnson

IPC: B01J37/02 ,  B01D15/00 ,  C01B37/00 ,  C08F2/10 ,  C08G77/60 ,  C10G25/00 ,  C10G45/44 ,  C07F7/08 ,  C10G45/46 ,  C01B39/00 ,  B01J37/03 ,  B01J23/42 ,  B01J31/12 ,  B01J37/04 ,  B01J23/44 ,  B01J31/02 ,  B01J35/10 ,  C10G45/52 ,  C10M101/02 ,  B01J20/06 ,  B01J20/08 ,  B01J20/10 ,  B01J20/26 ,  B01J20/28 ,  B01J20/286 ,  B01J20/30 ,  B01J20/32 ,  B01J20/22

Abstract: Hydrogenation catalysts for aromatic hydrogenation including an organosilica material support, which is a polymer comprising independent units of a monomer of Formula [Z1OZ2OSiCH2]3 (I), wherein each Z1 and Z2 independently represent a hydrogen atom, a C1-C4 alkyl group or a bond to a silicon atom of another monomer; and at least one catalyst metal are provided herein. Methods of making the hydrogenation catalysts and processes of using, e.g., aromatic hydrogenation, the hydrogenation catalyst are also provided herein.

公开(公告)号：US10183272B2

公开(公告)日：2019-01-22

申请号：US14966534

申请日：2015-12-11

Applicant: ExxonMobil Research and Engineering Company

Inventor： Paul Podsiadlo ,  Jianxin Wu ,  Kiara M. Benitez ,  Quanchang Li ,  David Charles Calabro

IPC: B01J20/22 ,  C07F7/08 ,  B01D15/00 ,  B01J20/06 ,  B01J20/08 ,  B01J20/10 ,  B01J20/18 ,  B01J20/26 ,  B01D53/04 ,  B01J20/28 ,  B01J20/286 ,  B01J20/30 ,  B01J20/32 ,  B01J29/03 ,  C01B37/00 ,  C08F36/04 ,  C08F36/20 ,  C08G77/60 ,  C08F2/00 ,  C08F2/42 ,  C10G25/00 ,  C10G45/44 ,  B01J20/02 ,  B01J20/16 ,  B01D53/02 ,  B01D53/047 ,  B01J23/44 ,  B01J31/02 ,  B01J37/02 ,  C10G45/52 ,  B01J35/10 ,  C08G77/26 ,  C10M101/02 ,  B01D67/00 ,  B01D69/10 ,  B01D71/70 ,  C10G31/09 ,  C23C16/56 ,  C08F2/10 ,  C08F4/659 ,  C08F4/6592

Abstract: Adsorbent materials including a porous material support and about 0.5 wt. % to about 30 wt. % of a Group 8 metal ion are provide herein. Methods of making the adsorbent material and processes of using the adsorbent material, e.g., for heteroatom species separation, are also provided herein.

公开(公告)号：US10011780B2

公开(公告)日：2018-07-03

申请号：US15582825

申请日：2017-05-01

Applicant: ExxonMobil Research and Engineering Company

Inventor： Paul Podsiadlo ,  Lei Zhang ,  Kiara M. Benitez ,  Himanshu Gupta ,  Darryl D. Lacy ,  Scott J. Weigel ,  Xiaochun Xu

IPC: C10G25/00

CPC classification number: C10G25/003 ,  C10G2300/202 ,  C10G2400/04

Abstract: Methods for reducing impurities and improving color in liquid hydrocarbon products (e.g., diesel fuel) are provided herein.

公开(公告)号：US11325111B2

公开(公告)日：2022-05-10

申请号：US16212922

申请日：2018-12-07

Applicant: ExxonMobil Research and Engineering Company

Inventor： Paul Podsiadlo ,  Quanchang Li ,  David C. Calabro ,  Kiara M. Benitez ,  Machteld M. W. Mertens ,  Scott J. Weigel ,  Doron Levin ,  Randall D. Partridge

IPC: B01J31/00 ,  B01J31/26 ,  B01J29/40 ,  B01J29/44 ,  B01J29/70 ,  B01J29/74 ,  B01J31/12 ,  C07C5/10 ,  B01J35/00 ,  B01J37/00 ,  C10G45/54 ,  C10G45/64 ,  C10G47/16

Abstract: Catalysts including at least one microporous material (e.g., zeolite), an organosilica material binder, and at least one catalyst metal are provided herein. Methods of making the catalysts, preferably without surfactants and processes of using the catalysts, e.g., for aromatic hydrogenation, are also provided herein.

公开(公告)号：US20190105647A1

公开(公告)日：2019-04-11

申请号：US16212922

申请日：2018-12-07

Applicant: ExxonMobil Research and Engineering Company

Inventor： Paul Podsiadlo ,  Quanchang Li ,  David C. Calabro ,  Kiara M. Benitez ,  Machteld M.W. Mertens ,  Scott J. Weigel ,  Doron Levin ,  Randall D. Partridge

IPC: B01J31/26 ,  B01J29/70 ,  C07C5/10 ,  B01J31/12 ,  B01J29/74 ,  B01J29/44 ,  B01J29/40 ,  B01J35/00 ,  C10G47/16 ,  B01J37/00 ,  C10G45/54 ,  C10G45/64

Abstract: Catalysts including at least one microporous material (e.g., zeolite), an organosilica material binder, and at least one catalyst metal are provided herein. Methods of making the catalysts, preferably without surfactants and processes of using the catalysts, e.g., for aromatic hydrogenation, are also provided herein.

公开(公告)号：US20180318790A1

公开(公告)日：2018-11-08

申请号：US16031449

申请日：2018-07-10

Applicant: ExxonMobil Research and Engineering Company

Inventor： Paul Podsiadlo ,  Quanchang Li ,  David Charles Calabro ,  Jean Willem Lodewijk Beeckman ,  Lei Zhang ,  Kiara M. Benitez ,  Matthew Scott Ide ,  Stephen John McCarthy ,  Mobae Afeworki ,  Simon Christopher Weston ,  Preeti Kamakoti ,  Matu J. Shah ,  Wenyih Frank Lai ,  Meghan Kochersperger ,  David A. Griffin ,  Ivy D. Johnson

IPC: B01J20/22 ,  C07F7/08 ,  C23C16/56 ,  C10M101/02 ,  C10G45/52 ,  C10G45/44 ,  C10G31/09 ,  C10G25/00 ,  C08G77/60 ,  C08G77/26 ,  C08F210/02 ,  C08F36/20 ,  C08F36/04 ,  C08F4/64 ,  C08F4/02 ,  C08F2/42 ,  C08F2/10 ,  C08F2/00 ,  C01B37/00 ,  B01J37/02 ,  B01J35/10 ,  B01J31/02 ,  B01J29/03 ,  B01J23/44 ,  B01J20/32 ,  B01J20/30 ,  B01J20/286 ,  B01J20/28 ,  B01J20/26 ,  B01J20/18 ,  B01J20/16 ,  B01J20/10 ,  B01J20/08 ,  B01J20/06 ,  B01J20/02 ,  B01D71/70 ,  B01D69/10 ,  B01D67/00 ,  B01D53/047 ,  B01D53/04 ,  B01D53/02 ,  B01D15/00

CPC classification number: B01J20/223 ,  B01D15/00 ,  B01D53/02 ,  B01D53/04 ,  B01D53/0462 ,  B01D53/047 ,  B01D67/0088 ,  B01D69/10 ,  B01D71/70 ,  B01D2253/20 ,  B01D2253/25 ,  B01D2256/245 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/40 ,  B01D2257/504 ,  B01D2257/80 ,  B01J20/0229 ,  B01J20/0237 ,  B01J20/06 ,  B01J20/08 ,  B01J20/10 ,  B01J20/103 ,  B01J20/16 ,  B01J20/18 ,  B01J20/22 ,  B01J20/226 ,  B01J20/262 ,  B01J20/264 ,  B01J20/28011 ,  B01J20/28057 ,  B01J20/28061 ,  B01J20/28064 ,  B01J20/28066 ,  B01J20/28069 ,  B01J20/28071 ,  B01J20/28073 ,  B01J20/28076 ,  B01J20/28078 ,  B01J20/28083 ,  B01J20/286 ,  B01J20/3042 ,  B01J20/3204 ,  B01J20/3212 ,  B01J20/3236 ,  B01J20/3238 ,  B01J20/3272 ,  B01J23/42 ,  B01J23/44 ,  B01J29/0308 ,  B01J31/0274 ,  B01J31/125 ,  B01J31/127 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1061 ,  B01J37/0213 ,  B01J37/0236 ,  B01J37/036 ,  B01J2220/86 ,  B01J2231/641 ,  B01J2231/646 ,  C01B37/00 ,  C01B39/00 ,  C07F7/08 ,  C07F7/0807 ,  C07F7/081 ,  C07F7/0818 ,  C08F2/00 ,  C08F2/10 ,  C08F2/42 ,  C08F4/027 ,  C08F4/64089 ,  C08F4/64148 ,  C08F4/64158 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F36/04 ,  C08F36/20 ,  C08F210/02 ,  C08G77/26 ,  C08G77/60 ,  C10G25/003 ,  C10G31/09 ,  C10G45/44 ,  C10G45/46 ,  C10G45/52 ,  C10M101/02 ,  C23C16/56 ,  Y02C20/20 ,  C08F210/14 ,  C08F4/64048 ,  C08F4/64013 ,  C08F4/64189 ,  C08F4/64193

Abstract: Hydrogenation catalysts for aromatic hydrogenation including an organosilica material support, which is a polymer comprising independent units of a monomer of Formula [Z1OZ2OSiCH2]3 (I), wherein each Z1 and Z2 independently represent a hydrogen atom, a C1-C4 alkyl group or a bond to a silicon atom of another monomer; and at least one catalyst metal are provided herein. Methods of making the hydrogenation catalysts and processes of using, e.g., aromatic hydrogenation, the hydrogenation catalyst are also provided herein.

公开(公告)号：US10022700B2

公开(公告)日：2018-07-17

申请号：US14966284

申请日：2015-12-11

Applicant: ExxonMobil Research and Engineering Company

Inventor： Paul Podsiadlo ,  Quanchang Li ,  David Charles Calabro ,  Lei Zhang ,  Kiara M. Benitez ,  Himanshu Gupta ,  Xiaochun Xu ,  Scott J. Weigel ,  Darryl Donald Lacy ,  Bal Kaul ,  James William Gleeson ,  Wenyih Frank Lai ,  Mobae Afeworki ,  Simon Christopher Weston ,  David A. Griffin ,  Meghan Nines

IPC: B01J20/22 ,  B01D15/00 ,  B01J20/06 ,  B01J20/08 ,  B01J20/10 ,  B01J20/18 ,  B01J20/26 ,  B01D53/04 ,  B01J20/28 ,  B01J20/286 ,  B01J20/30 ,  B01J20/32 ,  B01J29/03 ,  C01B37/00 ,  C08F36/04 ,  C08F36/20 ,  C08G77/60 ,  C08F2/00 ,  C08F2/42 ,  C10G25/00 ,  C10G45/44 ,  B01J20/02 ,  B01J20/16 ,  B01D53/02 ,  B01D53/047 ,  B01J23/44 ,  B01J31/02 ,  B01J37/02 ,  C10G45/52 ,  B01J35/10 ,  C07F7/08 ,  C08G77/26 ,  C10M101/02 ,  B01D67/00 ,  B01D69/10 ,  B01D71/70 ,  C10G31/09 ,  C23C16/56 ,  C08F2/10 ,  C08F4/659 ,  C08F4/6592

Abstract: Methods of preparing organosilica materials, which are a polymer comprising of at least one independent cyclic polyurea monomer of Formula wherein each R1 is a Z1OZ2Z3SiZ4 group, wherein each Z1 represents a hydrogen atom, a C1-C4 alkyl group, or a bond to a silicon atom of another monomer unit; each Z2 and Z3 independently represent a hydroxyl group, a C1-C4 alkyl group, a C1-C4 alkoxy group or an oxygen atom bonded to a silicon atom of another monomer unit; and each Z4 represents a C1-C8 alkylene group bonded to a nitrogen atom of the cyclic polyurea are provided herein. Methods of preparing and processes of using the organosilica materials, e.g., for gas separation, color removal, etc., are also provided herein.