公开(公告)号：US20160318829A1

公开(公告)日：2016-11-03

申请号：US15106084

申请日：2014-12-04

申请人： Felix GAERTNER ,  Guido STOCHNIOL ,  Joerg SCHALLENBERG ,  Horst-Werner ZANTHOFF ,  Oliver Markus BUSCH ,  Stephan PEITZ ,  Frank GEILEN ,  Arne REINSDORF ,  Natalya PRODAN

发明人： Felix GAERTNER ,  Guido STOCHNIOL ,  Joerg SCHALLENBERG ,  Horst-Werner ZANTHOFF ,  Oliver Markus BUSCH ,  Stephan PEITZ ,  Frank GEILEN ,  Arne REINSDORF ,  Natalya PRODAN

IPC分类号： C07C5/48 ,  B01J38/12 ,  B01J23/887 ,  C07C5/25 ,  B01J23/02

CPC分类号： C07C5/48 ,  B01J23/02 ,  B01J23/8876 ,  B01J23/92 ,  B01J38/12 ,  B01J2523/00 ,  C07C5/2512 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2521/12 ,  C07C2523/02 ,  C07C2523/18 ,  C07C2523/28 ,  C07C2523/887 ,  Y02P20/584 ,  C07C11/167 ,  C07C11/08 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/847

摘要： The invention relates to a process for preparing 1,3-butadiene by heterogeneously catalysed oxidative dehydrogenation of n-butene, in which a butene mixture comprising at least 2-butene is provided. The problem that it addresses is that of specifying a process for economically viable preparation of 1,3-butadiene on the industrial scale, which is provided with a butene mixture as raw material, wherein the 1-butene content is comparatively low compared to the 2-butene content thereof, and in which the ratio of 1-butene to 2-butene is subject to variation. This problem is solved by a two-stage process in which, in a first stage, the butene mixture provided is subjected to a heterogeneously catalysed isomerization to obtain an at least partly isomerized butene mixture, and in which the at least partly isomerized butene mixture obtained in the first stage is then subjected, in a second stage, to oxidative dehydrogenation. The two-stage process leads to higher butadiene yields compared to the one-stage process.

摘要翻译： 本发明涉及一种通过异丁烯催化的正丁烯的氧化脱氢制备1,3-丁二烯的方法，其中提供包含至少2-丁烯的丁烯混合物。 其所涉及的问题是指定以工业规模经济上可行的制备1,3-丁二烯的方法，其中提供了丁烯混合物作为原料，其中1-丁烯含量相对于2 丁烯含量，其中1-丁烯与2-丁烯的比例发生变化。 该问题通过两阶段方法解决，其中在第一阶段中，所提供的丁烯混合物经历非均相催化的异构化以获得至少部分异构化的丁烯混合物，并且其中获得至少部分异构化的丁烯混合物 然后在第一阶段中，在第二阶段进行氧化脱氢。 与一级方法相比，两阶段方法导致更高的丁二烯产率。

公开(公告)号：US20160207848A1

公开(公告)日：2016-07-21

申请号：US15000807

申请日：2016-01-19

申请人： Guido STOCHNIOL ,  Helene REEKER ,  Stephan PEITZ ,  Dietrich MASCHMEYER ,  Joerg SCHALLENBERG ,  Horst-Werner ZANTHOFF ,  Harald HAEGER

发明人： Guido STOCHNIOL ,  Helene REEKER ,  Stephan PEITZ ,  Dietrich MASCHMEYER ,  Joerg SCHALLENBERG ,  Horst-Werner ZANTHOFF ,  Harald HAEGER

IPC分类号： C07C2/24

CPC分类号： C07C7/04 ,  C07C2/10 ,  C07C2521/12 ,  C07C2523/755 ,  Y02P20/52 ,  Y02P20/582 ,  C07C11/08 ,  C07C11/107 ,  C07C11/02

摘要： A process for the combined preparation of a butene and an octene from ethene, proceeds by: a) providing a solvent having a boiling point or boiling range above the boiling points of the butenes and below the boiling points of the octenes and wherein the solvent is an inert solvent or is hexene alone or is hexene admixed with pentane or hexane or heptane or is a mixture of pentane, hexane, and heptane; b) providing a first feed mixture containing at least the solvent and ethene dissolved therein; c) providing a second feed mixture containing at least hexene, the solvent and also ethene dissolved in the solvent and/or in the hexene; d) transferring the first feed mixture into a first synthesis and the second feed mixture into a second synthesis, wherein the first and second syntheses are physically separated from one another; e) oligomerising of at least part of the ethene present in the first feed mixture in the presence of a first heterogeneous catalyst and in the presence of the solvent in the first synthesis to give a first reaction mixture comprising at least the solvent, butene and hexene; f) separating a butene-containing low boiler fraction from the first reaction mixture or from a stream based on the first reaction mixture; g) separating an intermediate boiler fraction containing hexene and the solvent from the first reaction mixture or from a stream based on the first reaction mixture; h) using at least part of the intermediate boiler fraction in the course of providing the second feed mixture; and i) reacting at least part of the ethene present in the second feed mixture with at least part of the hexene present in the second feed mixture in the presence of a second heterogeneous catalyst and in the presence of the solvent in the second synthesis to give a second reaction mixture comprising at least octene and the solvent.

摘要翻译： 从乙烯组合制备丁烯和辛烯的方法是通过以下方式进行的：a）提供沸点或沸点范围高于丁烯沸点并低于辛烯沸点的溶剂，其中溶剂是 惰性溶剂或己烯或己烯与戊烷或己烷或庚烷混合，或是戊烷，己烷和庚烷的混合物; b）提供至少含有溶解在其中的溶剂和乙烯的第一进料混合物; c）提供至少含有己烯，溶剂和溶解在溶剂和/或己烯中的乙烯的第二进料混合物; d）将第一进料混合物转移到第一合成物中，将第二进料混合物转移到第二合成物中，其中第一和第二合成物在物理上彼此分离; e）在第一种非均相催化剂的存在下和在第一种合成中的溶剂存在下，存在于第一进料混合物中的至少部分乙烯的低聚反应，得到至少包含溶剂，丁烯和己烯的第一反应混合物 ; f）从第一反应混合物或基于第一反应混合物的物流中分离含丁烯的低沸点馏分; g）从第一反应混合物或基于第一反应混合物的流中分离含有己烯和溶剂的中间锅炉馏分; h）在提供第二进料混合物的过程中使用至少部分中间锅炉馏分; 和i）使第二进料混合物中存在的乙烯的至少一部分与第二进料混合物中存在的第二进料混合物中的至少部分己烯在第二种非均相催化剂的存在下反应，并在第二次合成中在溶剂存在下反应，得到 至少包含辛烯和溶剂的第二反应混合物。

公开(公告)号：US20160207849A1

公开(公告)日：2016-07-21

申请号：US15000837

申请日：2016-01-19

申请人： Guido STOCHNIOL ,  Stephan PEITZ ,  Dietrich MASCHMEYER ,  Helene REEKER ,  Joerg SCHALLENBERG

发明人： Guido STOCHNIOL ,  Stephan PEITZ ,  Dietrich MASCHMEYER ,  Helene REEKER ,  Joerg SCHALLENBERG

IPC分类号： C07C2/24

CPC分类号： C07C2/24 ,  C07C2/10 ,  C07C7/04 ,  C07C2521/12 ,  C07C2523/755 ,  C07C11/08 ,  C07C11/107 ,  C07C11/02

摘要： A process for the combined preparation of at least butene and octene from ethane, proceeds by a) providing an inert solvent having a boiling point or boiling range below the boiling point of butene; b) providing a first feed mixture comprising at least the inert solvent and ethene dissolved therein; c) converting the first feed mixture in a first synthesis; d) in the first synthesis, oligomerizing at least a portion of the ethene present in the first feed mixture in the presence of a first heterogeneous catalyst and in the presence of the inert solvent to obtain a first reaction mixture comprising at least the inert solvent, butene, hexene and octene; e) working-up of the first reaction mixture and/or a substance stream based thereon into a low boiler fraction comprising the inert solvent, at least one C4-fraction comprising butenes, a C6-fraction comprising hexenes, a C8-fraction comprising octenes and into a C8+-fraction comprising hydrocarbons having more than eight carbon atoms; f) using at least a portion of the low boiler fraction for providing the first feed mixture; g) providing a second feed mixture comprising at least hexene and ethene dissolved in the hexene using at least a portion of the C6-fraction; h) converting the second feed mixture in a second synthesis, wherein the second synthesis is spatially separated from the first synthesis; i) in the second synthesis, reacting at least a portion of the ethene present in the second feed mixture with at least a portion of the hexene present in the second feed mixture in the presence of a second heterogeneous catalyst to obtain a second reaction mixture comprising at least octene; and k) joint working-up of the second reaction mixture with the first reaction mixture or with the substance stream based thereon.

摘要翻译： 从乙烷中至少组合制备丁烯和辛烯的方法是：a）提供沸点或沸点低于丁烯沸点的惰性溶剂; b）提供至少包含溶解在其中的惰性溶剂和乙烯的第一进料混合物; c）在第一合成中转化第一进料混合物; d）在第一种合成中，在存在第一种非均相催化剂的情况下和在惰性溶剂存在下使存在于第一进料混合物中的至少一部分乙烯低聚，得到包含至少惰性溶剂的第一反应混合物， 丁烯，己烯和辛烯; e）将第一反应混合物和/或基于其的物质流加工到包含惰性溶剂的低沸点馏分中，至少一种包含丁烯的C 4馏分，包含己烯的C 6馏分，包含辛烯的C 8馏分 并进入包含具有多于8个碳原子的烃的C8 +分馏; f）使用低沸点馏分的至少一部分来提供第一进料混合物; g）使用C 6馏分的至少一部分提供包含至少己烯和溶解在己烯中的乙烯的第二进料混合物; h）在第二合成中转化所述第二进料混合物，其中所述第二合成在空间上与所述第一合成分离; i）在第二合成中，使第二进料混合物中存在的乙烯的至少一部分与存在于第二进料混合物中的至少一部分己烯存在于第二种非均相催化剂中，以获得第二反应混合物， 至少辛烯; 和k）第二反应混合物与第一反应混合物或其上的物质流的联合处理。

公开(公告)号：US20120232305A2

公开(公告)日：2012-09-13

申请号：US13131462

申请日：2009-10-29

申请人： Alexander MAY ,  Martin KOESTNER ,  Joerg BECKER ,  Joerg SCHALLENBERG ,  Hermann SIEGERT ,  Bernd VOGEL

发明人： Alexander MAY ,  Martin KOESTNER ,  Joerg BECKER ,  Joerg SCHALLENBERG ,  Hermann SIEGERT ,  Bernd VOGEL

IPC分类号： C07C67/20 ,  C07C231/24

CPC分类号： C07C231/06 ,  C07C231/065 ,  C07C231/14 ,  C07C253/00 ,  C07C233/09 ,  C07C255/16

摘要： The invention relates to a method for producing a carboxylic acid amide from a carbonyl compound and hydrocyanic acid, comprising the steps of A) reacting a carbonyl compound with hydrocyanic acid to produce a hydroxycarboxylic acid nitrile, B) hydrolysis of the hydroxycarboxylic acid nitrile obtained in step A) in the presence of a catalyst comprising manganese dioxide, wherein a molar excess of carbonyl compound is used in relation to the hydrocyanic acid to react the carbonyl compound with hydrocyanic acid according to step A), and the reaction mixture obtained in step A) is not purified by distillation before the hydrolysis according to step B) is carried out. The invention furthermore relates to a method for producing alkyl(meth)acrylates from polymers, moulding compounds and moulded bodies, wherein a method for producing a carboxylic acid amide from a carbonyl compound and hydrocyanic acid is carried out in accordance with the method described above.

摘要翻译： 本发明涉及一种由羰基化合物和氢氰酸制备羧酸酰胺的方法，包括以下步骤：a）使羰基化合物与氢氰酸反应生成羟基羧酸腈，B）水解得到的羟基羧酸腈 步骤A）在包含二氧化锰的催化剂存在下，其中相对于氢氰酸使用摩尔过量的羰基化合物以使羰基化合物与氢氰酸根据步骤A）反应，并将步骤A中获得的反应混合物 ）在根据步骤B）进行水解之前未经蒸馏纯化。 本发明还涉及从聚合物，成型化合物和成型体制备（甲基）丙烯酸烷基酯的方法，其中根据上述方法由羰基化合物和氢氰酸制备羧酸酰胺的方法。