公开(公告)号：US09919303B2

公开(公告)日：2018-03-20

申请号：US14419580

申请日：2013-07-24

Applicant: Frank Erhardt ,  Lukas Falke ,  Ralf Kelle ,  Harald Haeger ,  Thomas Haas ,  Hans-Georg Hennemann ,  Oliver Thum ,  Martin Roos ,  Markus Poetter

Inventor： Frank Erhardt ,  Lukas Falke ,  Ralf Kelle ,  Harald Haeger ,  Thomas Haas ,  Hans-Georg Hennemann ,  Oliver Thum ,  Martin Roos ,  Markus Poetter

IPC: B01J39/04 ,  C07C209/90 ,  B01J39/16 ,  C02F1/42 ,  C02F1/26 ,  C07C227/40 ,  C07C209/84 ,  C02F101/30 ,  C02F101/38 ,  C02F103/36

CPC classification number: B01J39/04 ,  B01J39/16 ,  C02F1/26 ,  C02F1/42 ,  C02F2001/425 ,  C02F2101/30 ,  C02F2101/38 ,  C02F2103/36 ,  C07C209/84 ,  C07C209/90 ,  C07C227/40 ,  C07C2601/14

Abstract: The present invention relates to a method for removing an organic compound from an aqueous solution, comprising the steps of providing the aqueous solution which contains the organic compound, and a hydrophobic organic solution, where the latter comprises a liquid hydrophobic cation exchanger, contacting the aqueous solution and the hydrophobic organic solution, and separating off the hydrophobic organic solution from the aqueous solution, wherein the liquid hydrophobic cation exchanger is a saturated alkanoic acid having at least one alkyl substituent, where the organic compound is an organic compound having at least one positive charge and a neutral or positive total charge.

公开(公告)号：US09524807B2

公开(公告)日：2016-12-20

申请号：US13882799

申请日：2011-10-31

Applicant: Sylvia Anita Hermasch ,  Roland Wursche ,  Harald Haeger ,  Petra Poetschke ,  Beate Krause ,  Robert Socher

Inventor： Sylvia Anita Hermasch ,  Roland Wursche ,  Harald Haeger ,  Petra Poetschke ,  Beate Krause ,  Robert Socher

IPC: H01B1/24 ,  C09D5/24 ,  H01B3/02 ,  C08L77/02 ,  C08K5/098 ,  C08K5/3445 ,  C08K7/24

CPC classification number: H01B3/025 ,  C08K3/041 ,  C08K5/098 ,  C08K5/17 ,  C08K5/3445 ,  C08K7/06 ,  C08K7/24 ,  C08L33/08 ,  C08L71/02 ,  C08L77/02 ,  C08L77/12 ,  C09D5/24 ,  H01B1/24

Abstract: A polyamide composition contains the following components: (a) at least 40 parts by weight PA12; (b) 0.1-15 parts by weight of at least one salt with a non-metallic cation; (c) 0.1-25% by weight of at least one dispersant based on esters or amides; (d) a quantity of carbon nanotubes that produces in the molding compound a specific surface resistance according to IEC standard 60167 of maximum 10−1-1010Ω; (e) 0-5 parts by weight of at least one metal salt; and optionally (f) conventional auxiliary substances and additives, the sum of the parts by weight of components (a) to (f) amounting to 100. The polyamide composition can be used for manufacturing moldings with improved electrical conductivity and improved surface quality.

Abstract translation: 聚酰胺组合物含有以下成分：（a）至少40重量份PA12; （b）0.1-15重量份的至少一种与非金属阳离子的盐; （c）基于酯或酰胺的0.1-25重量％的至少一种分散剂; （d）一定数量的碳纳米管在模塑料中产生符合IEC标准60167最高10-1-1010Ω的比表面电阻; （e）0-5重量份的至少一种金属盐; 和任选的（f）常规辅助物质和添加剂，组分（a）至（f）的重量份数合计为100。聚酰胺组合物可用于制造具有改善的导电性和改进的表面质量的模制品。

公开(公告)号：US20140141478A1

公开(公告)日：2014-05-22

申请号：US14077750

申请日：2013-11-12

Applicant: Steffen SCHAFFER ,  Heiko Andrea ,  Mirja Wessel ,  Hans-Georg Hennemann ,  Harald Haeger

Inventor： Steffen SCHAFFER ,  Heiko Andrea ,  Mirja Wessel ,  Hans-Georg Hennemann ,  Harald Haeger

IPC: C12P7/62

Abstract: The invention provides a process for reacting a carboxylic acid ester of the formula (I) R1-A-COOR2   (I), wherein R1 is hydrogen, —CH2OH, —CHO, —COOR3, —CH2SH, —CH2OR3 or —CH2NH2, R2 is an alkyl group,R3 is hydrogen or an alkyl group, and A is a substituted, unsubstituted, linear, branched and/or cyclic alkylene, alkenylene, arylene or aralkylene radical having at least 4 carbons,in the presence of a cell. The process comprises a) contacting the cell with said carboxylic acid ester in an aqueous solution,wherein the cell is a recombinant cell which has reduced activity of a polypeptide comprising SEQ ID NO: 2 or a variant thereof over the wild-type cell.

Abstract translation: 本发明提供使式（I）R1-A-COOR2（Ⅰ）的羧酸酯与式（Ⅰ）中R1为氢，-CH2OH，-CHO，-COOR3，-CH2SH，-CH2OR3或-CH2NH2，R2 在烷基存在下，R 3是氢或烷基，A是具有至少4个碳的取代的，未被取代的，直链的，支链的和/或环状的亚烷基，亚烯基，亚芳基或亚芳基。 该方法包括a）使细胞与所述羧酸酯在水溶液中接触，其中所述细胞是包含SEQ ID NO：2或其变体的多肽在野生型细胞上的活性降低的重组细胞。

公开(公告)号：US20140039210A1

公开(公告)日：2014-02-06

申请号：US14000067

申请日：2011-12-01

Applicant: Frank Erhardt ,  Thomas Haas ,  Martin Roos ,  Daniel Demicoli ,  Markus Poetter ,  Anja Schubert ,  Jan Christoph ,  Thomas Tacke ,  Harald Haeger ,  Andreas Pfennig ,  Marie-Dominique Przybylski-Freund

Inventor： Frank Erhardt ,  Thomas Haas ,  Martin Roos ,  Daniel Demicoli ,  Markus Poetter ,  Anja Schubert ,  Jan Christoph ,  Thomas Tacke ,  Harald Haeger ,  Andreas Pfennig ,  Marie-Dominique Przybylski-Freund

IPC: C07C67/62

CPC classification number: C07C67/62 ,  B01D11/0492 ,  B01J39/04 ,  B01J39/16 ,  C02F1/26 ,  C02F2001/425 ,  C02F2101/34 ,  C07C227/40 ,  C07C229/08

Abstract: The invention relates to a method for removing an organic compound having one or more positive charges from an aqueous solution. Said method consists of the following steps a) the aqueous solution containing the organic compound, and a hydrophobic organic solution which contains a hydrophobic liquid cation exchanger having one or more negative charges and a negative total charge, are provided, b) the aqueous solution and the organic solution are brought into contact with each other and c) the organic solution is separated from the aqueous solution.

Abstract translation: 本发明涉及从水溶液中除去具有一个或多个正电荷的有机化合物的方法。 所述方法包括以下步骤a）含有有机化合物的水溶液和含有具有一个或多个负电荷和负总电荷的疏水液体阳离子交换剂的疏水性有机溶液，b）水溶液和 使有机溶液彼此接触并且c）将有机溶液与水溶液分离。

公开(公告)号：US08642811B2

公开(公告)日：2014-02-04

申请号：US13364493

申请日：2012-02-02

Applicant: Franz-Erich Baumann ,  Matthias Ullrich ,  Martin Roos ,  Peter Hannen ,  Frank-Martin Petrat ,  Harald Haeger ,  Angela Koeckritz ,  Guido Walther ,  Jens Deutsch ,  Andreas Martin

Inventor： Franz-Erich Baumann ,  Matthias Ullrich ,  Martin Roos ,  Peter Hannen ,  Frank-Martin Petrat ,  Harald Haeger ,  Angela Koeckritz ,  Guido Walther ,  Jens Deutsch ,  Andreas Martin

IPC: C07C209/16

CPC classification number: C07C209/16 ,  Y02P20/544 ,  C07C211/09

Abstract: The invention provides a method to produce primary diamines by catalytic conversion of diols having a linear main chain of from 4 to 31 carbon atoms into the corresponding diamines. The reaction is conducted in a liquid or supercritical phase and is catalyzed by a homogeneous ruthenium-containing complex. The primary diamines obtained may be suitable for polyamide syntheses.

Abstract translation: 本发明提供了通过将具有4至31个碳原子的直链主链的二醇催化转化成相应的二胺来生产伯胺的方法。 该反应在液相或超临界相中进行，并由均匀的含钌络合物催化。 所得到的伯胺可适用于聚酰胺合成。

公开(公告)号：US20130287981A1

公开(公告)日：2013-10-31

申请号：US13872226

申请日：2013-04-29

Applicant: Jan BERGER ,  Klaus GAHLMANN ,  Harald HAEGER ,  Markus HARTMANN ,  Jasmin NITSCHE

Inventor： Jan BERGER ,  Klaus GAHLMANN ,  Harald HAEGER ,  Markus HARTMANN ,  Jasmin NITSCHE

IPC: C09D177/06

CPC classification number: C09D177/06 ,  C08G61/08 ,  C08G2261/135 ,  C08G2261/3322 ,  C08G2261/418 ,  C08G2261/58 ,  C08G2261/76 ,  C09D5/08 ,  C09D177/02 ,  F16L58/109 ,  Y10T428/1355 ,  Y10T428/31529 ,  Y10T428/3154 ,  Y10T428/31605 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31699 ,  C08L65/00

Abstract: A method for coating of a metallic article is provided. According to the method, the metal surface is coated with a composition which comprises a polymer or comprises a two-component system that reacts to form a polymer following application to the metal surface. The composition comprises 70-2700 meq/kg olefinic double bonds which leads to stronger adhesion and to increased corrosion resistance.

Abstract translation: 提供了金属制品的涂覆方法。 根据该方法，金属表面涂覆有包含聚合物的组合物或包含在施加到金属表面之后反应形成聚合物的双组分体系。 该组合物包含70-2700meq / kg烯属双键，这导致更强的粘附性和增加的耐腐蚀性。

公开(公告)号：US20130092233A1

公开(公告)日：2013-04-18

申请号：US13649616

申请日：2012-10-11

Applicant: Andreas PAWLIK ,  Martin Wielpuetz ,  Harald Haeger

Inventor： Andreas PAWLIK ,  Martin Wielpuetz ,  Harald Haeger

IPC: B32B27/08 ,  H01L31/0203 ,  H01L31/04 ,  B32B7/02

CPC classification number: B32B27/36 ,  B32B7/12 ,  B32B27/08 ,  B32B27/34 ,  B32B2250/24 ,  B32B2270/00 ,  B32B2457/12 ,  H01L31/049 ,  Y02E10/50 ,  Y10T428/24975 ,  Y10T428/269 ,  Y10T428/31725 ,  Y10T428/31736

Abstract: A multilayer film containing layers of polyamide and polyester, suitable as a back cover for a photovoltaic module is provided. The film comprises, in the order listed: a) a layer which comprises at least 35% by weight of polyamide; c) a layer which comprises at least 35% by weight, of a thermoplastic polyester; and e) a layer which comprises at least 35% by weightof polyamide; wherein the layers a) and e) further comprise 0.1 to 60% by weight, of a polyamine-polyamide graft copolymer, or the layer c) further comprises 0.1 to 30% by weight of polyamine-polyamide graft copolymer. The polyamine-polyamide graft copolymer comprises as copolymerized monomers: a polyamine having at least 4 nitrogen atoms and at least one polyamide-forming unit selected from the group consisting of a lactam, an ω-aminocarboxylic acid and an equimolar combinations of a diamine and a dicarboxylic acid. In another embodiment, adhesion promoting layers are placed between the layers.

Abstract translation: 提供了适合作为光伏组件的后盖的聚酰胺和聚酯层的多层膜。 所述膜包括：a）包含至少35重量％聚酰胺的层; c）包含至少35重量％的热塑性聚酯的层; 和e）包含至少35重量％聚酰胺的层; 其中层a）和e）还包含0.1至60重量％的聚胺 - 聚酰胺接枝共聚物，或者c）还包含0.1-30重量％的聚胺 - 聚酰胺接枝共聚物。 多胺 - 聚酰胺接枝共聚物包含共聚单体：具有至少4个氮原子的多胺和至少一种选自内酰胺，ω-氨基羧酸和二胺和等摩尔组合的聚酰胺形成单元 二羧酸。 在另一个实施方案中，粘附促进层位于层之间。

公开(公告)号：US08221890B2

公开(公告)日：2012-07-17

申请号：US11240493

申请日：2005-10-03

Applicant: Guido Schmitz ,  Harald Haeger ,  Hans Ries

Inventor： Guido Schmitz ,  Harald Haeger ,  Hans Ries

IPC: B32B1/08 ,  B32B27/06 ,  B32B25/16 ,  B32B27/00 ,  B32B27/04 ,  B32B27/08 ,  B32B27/28 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B37/00 ,  B29C47/06 ,  B29C45/00

CPC classification number: C08L77/00 ,  A22C13/0013 ,  A22C2013/0053 ,  A22C2013/0059 ,  B32B1/08 ,  B32B27/08 ,  B32B27/18 ,  B32B27/304 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B2250/24 ,  B32B2307/718 ,  B32B2307/7242 ,  B32B2307/7265 ,  B32B2597/00 ,  B32B2605/08 ,  C08L67/02 ,  C08L77/06 ,  Y10T428/1321 ,  Y10T428/1334 ,  Y10T428/1352 ,  Y10T428/1372 ,  Y10T428/1386 ,  Y10T428/1393 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31736 ,  Y10T428/31739 ,  Y10T428/31743 ,  Y10T428/31746 ,  Y10T428/31786 ,  Y10T428/31938 ,  C08L2666/02 ,  C08L2666/06

Abstract: A multilayer composite which has improved adhesion between the layers, with the following layers: I. an inner layer I selected from among a fluoropolymer molding composition and a polyolefin molding composition; II. a bonding layer II which has the following composition: a) from 2 to 80 parts by weight of a polyamine-polyamide graft copolymer, b) from 0 to 85 parts by weight of a polyester, c) from 0 to 85 parts by weight of a polymer selected from among polyamides, fluoropolymers and polyolefins, where the sum of the parts by weight of a), b) and c) is 100; d) not more than 50 parts by weight of additives; III. a layer III of a polyester molding composition.

Abstract translation: 具有改进的层之间的粘合性的多层复合材料，具有以下层：I.选自氟聚合物模塑组合物和聚烯烃模塑组合物的内层I; 二， 具有以下组成的粘合层II：a）2至80重量份的聚胺 - 聚酰胺接枝共聚物，b）0至85重量份的聚酯，c）0至85重量份的 选自聚酰胺，含氟聚合物和聚烯烃的聚合物，其中a），b）和c）的重量份之和为100; d）不超过50重量份的添加剂; 三， 聚酯模塑组合物的层III。

公开(公告)号：US20100312012A1

公开(公告)日：2010-12-09

申请号：US12865018

申请日：2009-04-17

Applicant: Peter Hannen ,  Martin Roos ,  Harald Haeger

Inventor： Peter Hannen ,  Martin Roos ,  Harald Haeger

IPC: C07C51/36 ,  C07C55/02

CPC classification number: C07C51/43 ,  C07C51/353 ,  C07C51/44 ,  C07C57/13

Abstract: The invention relates to a method for producing α/β-unsaturated dicarboxylic acids and the corresponding saturated dicarboxylic acids, whereby the corresponding cycloalkene and acrylic acid are reacted with a ruthenium catalyst by way of a metathesis reaction at high substrate concentrations until the reaction takes place in substance, the resulting dicarboxylic acid being precipitated.

Abstract translation: 本发明涉及一种生产α/β-不饱和二羧酸和相应的饱和二羧酸的方法，其中相应的环烯烃和丙烯酸通过在高底物浓度下的复分解反应与钌催化剂反应，直到反应 置于物质中，所得二羧酸沉淀。

公开(公告)号：US06783821B2

公开(公告)日：2004-08-31

申请号：US10024379

申请日：2001-12-21

Applicant: Hans Ries ,  Guido Schmitz ,  Harald Haeger

Inventor： Hans Ries ,  Guido Schmitz ,  Harald Haeger

IPC: B32B102

CPC classification number: C08L77/00 ,  B32B27/34 ,  C08L77/02 ,  C08L77/06 ,  Y10T428/13 ,  Y10T428/1352 ,  Y10T428/1386 ,  Y10T428/139 ,  Y10T428/1393 ,  Y10T428/31562 ,  Y10T428/31728 ,  Y10T428/31732

Abstract: A good layer adhesion can be achieved in a composite having two or more layers wherein a layer I is obtained from a molding composition which has the following components: a) from 0 to 80 parts by weight of a polyamide selected from the group consisting of PA6, PA66, PA6/66 and a mixture thereof; b) from 0.05 to 100 parts by weight of a polyamine-polyamide copolymer; and c) from 0 to 80 parts by weight of a polyamide selected from the group consisting of PA11, PA12, PA612, PA1012, PA1212 and a mixture thereof; wherein a total of the parts by weight of components a), b) and c) is 100; wherein at least 20 parts by weight of components a) and b) is a monomer unit which is obtained from caprolactam and/or from a combination of hexamethylenediamine/adipic acid; and wherein at least 20 parts by weight of components b) and c) is a monomer unit which is obtained from &ohgr;-aminoundecanoic acid, laurolactam, a mixture of hexamethylenediamine and 1,12-dodecanedioic acid, a mixture of 1,10-decanediamine and 1,12-dodecanedioic acid, and/or a mixture of 1,12-dodecanediamine and 1,12-dodecanedioic acid.

Abstract translation: 在具有两层或更多层的复合材料中可以实现良好的层粘合性，其中层I由具有以下组分的模塑组合物获得：a）0至80重量份选自PA6， PA66，PA6 / 66及其混合物; b）0.05-100重量份的聚胺 - 聚酰胺共聚物; 和c）0至80重量份选自PA11，PA12，PA612，PA1012，PA1212的聚酰胺及其混合物;其中组分a），b）和c）的总重量份， 为100;其中至少20重量份的组分a）和b）是由己内酰胺和/或六亚甲基二胺/己二酸的组合获得的单体单元; 并且其中至少20重量份的组分b）和c）是由ω-氨基十一烷酸，月桂内酰胺，六亚甲基二胺和1,12-十二烷二酸的混合物得到的单体单元，1,10-癸二胺和 1,12-十二烷二酸和/或1,12-十二烷二胺和1,12-十二烷二酸的混合物。