Synthesis of phenyl-substituted polyfluoroanthenes and the use thereof
    1.
    发明授权
    Synthesis of phenyl-substituted polyfluoroanthenes and the use thereof 有权
    苯基取代的多氟代苯的合成及其用途

    公开(公告)号:US08137822B2

    公开(公告)日:2012-03-20

    申请号:US11912998

    申请日:2006-04-03

    IPC分类号: H01L51/54 C09K11/06

    摘要: The invention relates to a method for producing polyfluoroanthenes containing repeat units of general formula (I), said method consisting of the following steps: a) a monomer fluoroanthene derivative of formula IIa is produced; b) optionally the monomer fluoroanthene derivative of formula IIa is converted into another monomer fluoroanthene derivative of formula IIb; and c) the monomer fluoroanthene derivative of formula IIa or IIb is polymerised, optionally together with at least one other comonomer. The invention also relates to polyfluoroanthenes that can be produced according to the inventive method, films, a light-emitting layer containing or consisting of at least one inventive polyfluoroanthene, OLEDs containing at least one inventive polyfluoroanthene, OLEDs containing an inventive light-emitting layer, a device containing an inventive OLED, and the use of the inventive polyfluoroanthene emitter substances in OLEDs.

    摘要翻译: 本发明涉及一种含有通式(I)重复单元的多氟代a的制备方法,所述方法包括以下步骤:a)制备式Ⅱa的单体氟代蒽衍生物; b)任选地,式IIa的单体氟代蒽衍生物转化成式IIb的另一单体氟代蒽衍生物; 和c)式IIa或IIb的单体氟代蒽衍生物聚合,任选与至少一种其它共聚单体一起聚合。 本发明还涉及可根据本发明方法制备的多氟代苯,膜,含有或由至少一种本发明的多氟代烯烃组成的发光层,含有至少一种本发明的多氟蒽的OLED,含有本发明的发光层的OLED, 含有本发明OLED的器件,以及本发明的多氟蒽发光物质在OLED中的用途。

    Synthesis of Polynaphthalenes and Their Use
    2.
    发明申请
    Synthesis of Polynaphthalenes and Their Use 审中-公开
    聚萘的合成及其用途

    公开(公告)号:US20070287821A1

    公开(公告)日:2007-12-13

    申请号:US11574546

    申请日:2005-09-05

    IPC分类号: C08G61/10 H01B1/12

    CPC分类号: H01B1/128 C08G61/02 C08G61/10

    摘要: The present invention relates to a process for preparing polynaphthalene derivatives comprising repeating units of the general formula Ia and/or Ib where R1, R2, R1′, R2′ are as defined in the description. The present invention further relates to polynaphthalene derivatives which can be prepared by the process of the invention, films comprising or consisting of at least one polynaphthalene derivative according to the invention, organic light-emitting diodes (OLEDs) comprising at least one polynaphthalene derivative according to the invention, a light-emitting layer comprising or consisting of at least one polynaphthalene derivative according to the invention, an OLED comprising the light-emitting layer of the invention, devices comprising an OLED according to the invention and the use of the polynaphthalene derivatives of the invention as emitter substances in OLEDs.

    摘要翻译: 本发明涉及一种制备聚萘衍生物的方法,其包含通式Ia和/或Ib的重复单元,其中R 1,R 2,R 1, ,R“2”如说明书中所定义。 本发明还涉及可以通过本发明的方法制备的聚萘衍生物,包含或由至少一种根据本发明的聚萘衍生物的膜组成的有机发光二极管(OLED)包含至少一种根据本发明的聚萘衍生物 本发明包括由至少一种根据本发明的聚萘衍生物或由本发明的至少一种聚萘衍生物构成的发光层,包含本发明的发光层的OLED,包含根据本发明的OLED的器件和使用 本发明作为OLED中的发射物质。

    Synthesis Of Phenyl-Substituted Polyfluoroanthenes and the Use Thereof
    3.
    发明申请
    Synthesis Of Phenyl-Substituted Polyfluoroanthenes and the Use Thereof 有权
    苯基取代的聚四氟乙烯的合成及其用途

    公开(公告)号:US20080213623A1

    公开(公告)日:2008-09-04

    申请号:US11912998

    申请日:2006-04-03

    IPC分类号: B32B27/00 C08G2/16 C08G79/08

    摘要: The invention relates to a method for producing polyfluoroanthenes containing repeat units of general formula (I), said method consisting of the following steps: a) a monomer fluoroanthene derivative of formula IIa is produced; b) optionally the monomer fluoroanthene derivative of formula IIa is converted into another monomer fluoroanthene derivative of formula IIb; and c) the monomer fluoroanthene derivative of formula IIa or IIb is polymerised, optionally together with at least one other comonomer. The invention also relates to polyfluoroanthenes that can be produced according to the inventive method, films, a light-emitting layer containing or consisting of at least one inventive polyfluoroanthene, OLEDs containing at least one inventive polyfluoroanthene, OLEDs containing an inventive light-emitting layer, a device containing an inventive OLED, and the use of the inventive polyfluoroanthene emitter substances in OLEDs.

    摘要翻译: 本发明涉及一种含有通式(I)重复单元的多氟代a的制备方法,所述方法包括以下步骤:a)制备式Ⅱa的单体氟代蒽衍生物; b)任选地,式IIa的单体氟代蒽衍生物转化成式IIb的另一单体氟代蒽衍生物; 和c)式IIa或IIb的单体氟代蒽衍生物聚合,任选与至少一种其它共聚单体一起聚合。 本发明还涉及可根据本发明方法制备的多氟代苯,膜,含有或由至少一种本发明的多氟代烯烃组成的发光层,含有至少一种本发明的多氟蒽的OLED,含有本发明的发光层的OLED, 含有本发明OLED的器件,以及本发明的多氟蒽发光物质在OLED中的用途。

    Polymers based on fluoranthene and their use
    5.
    发明申请
    Polymers based on fluoranthene and their use 有权
    基于荧蒽的聚合物及其用途

    公开(公告)号:US20050159582A1

    公开(公告)日:2005-07-21

    申请号:US11077199

    申请日:2005-03-11

    摘要: Polymers comprising repeating units of the formula I where the variables are defined as follows: a is an integer from 0 to 3, R1, R2, R3 are identical or different and are selected independently from among hydrogen, C1-C20-alkyl, C1-C20-alkyl containing one or more Si, N, P, O or S atoms, C6-C30-aryl, preferably C6-C14-aryl, C4-C14-heteroaryl, —N(C6-C14-aryl)2, and Y1, where Y1 may be identical or different and are selected from among —CH═CH2, trans- or cis-CH═CH—C6H5, acryloyl, methacryloyl, methylstyryl, O—CH═CH2 and glycidyl, where Y2 is selected from among —CH═CH2, trans- or cis-CH═CH—C6H5, acryloyl, methacryloyl, methylstyryl, —O—CH═CH2 and glycidyl, and one or more groups Y1 or Y2 may be crosslinked to one another.

    摘要翻译: 包含式I重复单元的聚合物,其中变量定义如下:a是0-3的整数,R 1,R 2,R 3, 独立地选自氢,C 1 -C 20 - C 20 - 烷基,C 1 -C 3 - 烷基, 含有一个或多个Si,N,P,O或S原子的C 20 -C 20烷基,C 6 -C 30 - 芳基,优选C 或 Y 2可以彼此交联。

    Continuous press and method of operating same
    7.
    发明授权
    Continuous press and method of operating same 有权
    连续按压和操作方法相同

    公开(公告)号:US6098532A

    公开(公告)日:2000-08-08

    申请号:US152941

    申请日:1998-09-14

    IPC分类号: B27N3/24 B30B5/06 B30B15/34

    CPC分类号: B30B5/06 B27N3/24

    摘要: A continuous press for pressing a thick mat into a thin panel has a press frame, upper and lower press belts having confronting lower and upper stretches defining a press gap extending in a horizontal transport direction, upper and lower flexible intake plates juxtaposed respectively above and below upstream ends of the lower and upper stretches of the belts and defining therewith an intake mouth flaring upstream, and a plurality of hydraulic actuators braced between at least one of the intake plates and the frame and operable to deform the one intake plate and thereby change the spacing of the belts at the mouth. A desired shape of the one intake plate at the mouth is established in accordance with the thickness of the mat, the density of the mat, and the thickness of the panel. Then an actual shape of the one intake plate is detected by the use of an array of position sensors, the detected actual shape of the one intake plate is compared to the desired shape, any variation between the actual shape and the desired shape is determined, and the actuators are pressurized to impart the desired shape to the one intake plate.

    摘要翻译: 用于将厚垫压入薄板的连续压机具有压机框架,上下压榨带具有限定在水平输送方向上延伸的压隙的上下延伸,上下柔性进料板分别并列在上方和下方 带的下部和上部延伸段的上游端和限定上游的进气口,以及支撑在至少一个进气板和框架之间的多个液压致动器,可操作以使一个进气板变形,从而改变 口袋的间距。 根据垫子的厚度,垫子的密度和面板的厚度,建立在口处的一个进气板的期望形状。 然后通过使用位置传感器阵列检测一个进气板的实际形状,将检测到的一个进气板的实际形状与期望的形状进行比较,确定实际形状和期望形状之间的任何变化, 并且致动器被加压以赋予所述一个进气板所需的形状。

    Cycle press
    9.
    发明授权

    公开(公告)号:US10011084B2

    公开(公告)日:2018-07-03

    申请号:US14117051

    申请日:2012-05-22

    摘要: The invention relates to a cycle press, in particular a short-cycle press, for producing and/or coating board-shaped materials, in particular engineered wood boards, comprising a press body having several press frames arranged next to one another in the longitudinal press direction, and further comprising an upper press plate and a lower press plate, wherein pressing cylinders supported on the press frames act on the upper press plate or the lower press plate. According to the invention, said cycle press is characterized in that the pressing cylinders are attached to the press frames by means of frame pins, wherein said frame pins engage in cut-outs of the press frames. Thus, the pressing cylinders can be prestressed against the press frames.

    Method for the emulsion polymerization of olefins
    10.
    发明授权
    Method for the emulsion polymerization of olefins 失效
    烯烃乳液聚合方法

    公开(公告)号:US07683145B2

    公开(公告)日:2010-03-23

    申请号:US10521117

    申请日:2003-07-16

    IPC分类号: C08F4/00 C08F2/00

    摘要: A method for the emulsion polymerization of one or more olefins by reacting a ligand of general formulae Ia and Ib or a mixture of at least two ligands Ia or Ib, wherein R respectively represents one or several of the following radicals; hydrogen, halogen, nitrile, C1-C12-alkyl groups, C1-C12-alkoxy groups, C7-C13-aralkyl groups, C6-C14-aryl groups, and wherein identical or different compounds of general formulae Ia and Ib can, optionally, be concatenated by one or several bridges, with a phosphine compound PR3′ and a metal compound of general formula M(L2)2 or M(L2)2 (L1)z, wherein the variables are defined as follows: M is a transition metal of groups 7-10 in the periodic system of the elements; L1 represents phosphanes (R5)xPH3-x or amines (R5)xNH3-x with identical or different radicals R5, ether (R5)2O, H2O, alkohols (R5)OH, pyridine, pyridine derivatives of formula C5H5-x(R5)xN, CO, C1-C12-alkylnitriles, C6-C14-arylnitriles or ethylenically unsaturated double bond systems, wherein x is a whole number ranging from 0-3, L2 represents halogenide ions R6xNH3-x, wherein x is a whole number ranging from 0 3 and R6 represents C1-C12-alkyl, and C1-C6-alkylane ions, allylane ions, benzylane ions or arylane ions, wherein L1 and L2 can be concatenated with each other by one or several covalent bonds, z is a number ranging from 0 4. The invention also relates to the immediate use of the reaction product in the polymerization or copolymerization of olefins in water or in a solvent mixture containing at least 50 vol. % water in the presence of an emulsifier and, optionally, in the presence of an activator.

    摘要翻译: 通过使通式Ia和Ib的配体或至少两种配体Ia或Ib的混合物反应来使一种或多种烯烃乳液聚合的方法,其中R分别表示一个或几个以下基团; 氢,卤素,腈,C 1 -C 12 - 烷基,C 1 -C 12 - 烷氧基,C 7 -C 13 - 芳烷基,C 6 -C 14 - 芳基,并且其中相同或不同的通式Ia和Ib化合物可以任选地, 通过一个或几个桥连,与膦化合物PR3'和通式M(L2)2或M(L2)2(L1)z的金属化合物连接,其中变量定义如下:M是过渡金属 在元素周期性系统中的第7-10组; L1代表具有相同或不同基团的磷烷(R5)xPH3-x或具有相同或不同基团的胺(R5)xNH3-x5,醚(R5)2O,H2O,烷醇(R5)OH,吡啶,式C5H5-x(R5) xN,CO,C 1 -C 12烷基腈,C 6 -C 14 - 芳基腈或烯属不饱和双键体系,其中x为0-3的整数,L 2表示卤化物离子R 6 x N H 3-x,其中x为 O 3和R 6表示C 1 -C 12 - 烷基和C 1 -C 6 - 烷基离子,烯丙基离子,苯甲烷离子或芳基烷基离子,其中L1和L2可以通过一个或几个共价键彼此连接,z是数字范围 本发明还涉及立即使用反应产物在烯烃在水中或在含有至少50体积%的溶剂混合物中的聚合或共聚中。 在乳化剂存在下,和任选地,在活化剂存在下,水分。