CATALYSIS OF NATURAL OIL BASED FLEXIBLE POLYURETHANE FOAMS WITH BISMUTH COMPOUNDS
    1.
    发明申请
    CATALYSIS OF NATURAL OIL BASED FLEXIBLE POLYURETHANE FOAMS WITH BISMUTH COMPOUNDS 审中-公开
    用双酚化合物催化天然油基柔性聚氨酯

    公开(公告)号:US20110190408A1

    公开(公告)日:2011-08-04

    申请号:US12675088

    申请日:2008-08-26

    IPC分类号: C08J9/04 C08G18/66

    摘要: A process for producing a polyurethane product comprises steps of (a) supplying at least one polyisocyanate (b) supplying at least one polyol composition comprising at least about 5 weight percent based on total weight of polyols of at least one natural oil based polyol (b1) having a hydroxyl number of at most about 300 and a viscosity below about 10000 mPa·os; and (c) exposing the polyisocyanate and the polyol composition to reaction conditions such that urethane bonds are formed, wherein reaction conditions include the presence of at least one bismuth catalyst. Use of bismuth catalysts is particularly applicable to preparation of open celled, flexible polyurethane foams using polyols made from renewable resources, optionally with other polyols. The invention includes foams made by the process, including viscoelastic foams, preferably having a velvet feel.

    摘要翻译: 一种制备聚氨酯产品的方法包括以下步骤:(a)提供至少一种多异氰酸酯(b),其供应至少一种多元醇组合物,所述多元醇组合物包含至少一种天然油基多元醇(b1)的多元醇的总重量的至少约5重量% ),羟值至多约300,粘度低于约10000mPa·os; 和(c)将多异氰酸酯和多元醇组合物暴露于形成氨基甲酸酯键的反应条件,其中反应条件包括至少一种铋催化剂的存在。 使用铋催化剂特别适用于使用由可再生资源制备的多元醇,任选与其它多元醇制备开孔,柔性聚氨酯泡沫体。 本发明包括通过该方法制造的泡沫,包括粘弹性泡沫,优选具有天鹅绒感。

    COPOLYMER POLYOLS AND A PROCESS FOR THE PRODUCTION THEREOF
    2.
    发明申请
    COPOLYMER POLYOLS AND A PROCESS FOR THE PRODUCTION THEREOF 审中-公开
    共聚聚合物及其生产方法

    公开(公告)号:US20090281206A1

    公开(公告)日:2009-11-12

    申请号:US12305538

    申请日:2007-06-22

    IPC分类号: C08L75/04 C08G18/42 C08G18/10

    摘要: The present inventions disclosed copolymer polyol composition which have a polymer content of 40 to 75 weight percent, based on total weight, and product stability such that essentially 100 percent passes through a 150 mesh screen produced by a free radical polymerization of the composition comprising: (a) a feedstock polyol; (b) at least one ethylenically unsaturated monomer; (c) a free radical polymerization initiator; (d) a chain transfer agent; (e) optionally a preformed stabilizer; and (f) optionally a macromer; with the proviso that at least one of e) or f) is present; wherein the feedstock has a nominal average functionality of 1.5 to 2.7, an equivalent weight of 400 to 2000. Such copolymer polyols can be used for the production of polyurethane products.

    摘要翻译: 本发明公开了共聚物多元醇组合物,其聚合物含量基于总重量为40至75重量%,并且产品稳定性使得基本上100%通过包含以下组分的组合物的自由基聚合产生的150目筛网:( a)原料多元醇; (b)至少一种烯属不饱和单体; (c)自由基聚合引发剂; (d)链转移剂; (e)任选的预成型稳定剂; 和(f)任选的大分子单体; 条件是存在e)或f)中的至少一个; 其中原料的标称平均官能度为1.5至2.7,当量为400至2000.这种共聚物多元醇可用于生产聚氨酯产品。

    NATURAL OIL BASED POLYOL BLENDS
    4.
    发明申请
    NATURAL OIL BASED POLYOL BLENDS 审中-公开
    天然油基多酚共混

    公开(公告)号:US20110054060A1

    公开(公告)日:2011-03-03

    申请号:US12990609

    申请日:2009-05-07

    IPC分类号: C08G18/36 C09K3/00

    摘要: A natural oil based polyol blend is provided. The blend includes a first natural oil based polyol comprising is the reaction product of a first monomer and a first initiator, and where the first monomer is derived from at least one first fatty acid methyl ester. The blend also includes a second natural oil based polyol comprising the reaction product of a second monomer and a second initiator. The second monomer is derived from at least one second fatty acid methyl ester, and at least one of the second monomer and the second initiator is different from the first monomer and the first initiator, respectively. The natural oil based polyol blend may be reacted with an isocyanate to form a foam.

    摘要翻译: 提供天然油基多元醇共混物。 共混物包括第一天然油基多元醇,其包含第一单体和第一引发剂的反应产物,其中第一单体衍生自至少一种第一脂肪酸甲酯。 共混物还包括第二天然油基多元醇,其包含第二单体和第二引发剂的反应产物。 第二单体衍生自至少一种第二脂肪酸甲酯,第二单体和第二引发剂中的至少一种分别与第一单体和第一引发剂不同。 天然油基多元醇共混物可以与异氰酸酯反应以形成泡沫。

    High resilience foams
    5.
    发明授权
    High resilience foams 有权
    高弹性泡沫

    公开(公告)号:US08236866B2

    公开(公告)日:2012-08-07

    申请号:US12599998

    申请日:2008-05-07

    IPC分类号: C08G18/28

    摘要: A high resilience (HR) polyurethane foam comprising the reaction product of (1) at least one polyisocyanate comprising at least about 5 weight percent of at least one methylene diphenyl diisocyanate isomer, derivative or a combination thereof and (2) an admixture of at least one natural oil based polyol and at least one additional polyol which is not a natural oil based polyol, wherein the admixture comprises at least about 10 weight percent natural oil based polyol and at least about 40 weight percent additional polyol having an equivalent weight of at least about 1700 Daltons; and the foam has a resiliency indicated by a ball rebound of at least 40 percent as measured according to the procedures of ASTM D 3574, Test H.

    摘要翻译: 高弹性(HR)聚氨酯泡沫,其包含(1)至少一种包含至少约5重量%的至少一种亚甲基二苯基二异氰酸酯异构体,衍生物或其组合的至少一种多异氰酸酯的反应产物和(2)至少 一种天然油基多元醇和至少一种不是天然油基多元醇的另外的多元醇,其中所述混合物包含至少约10重量%的天然油基多元醇和至少约40重量%的额外的多元醇,其当量重量至少为 约1700道尔顿; 并且根据ASTM D 3574测试H的程序,泡沫具有由至少40%的球回弹所示的弹性。

    HIGH RESILIENCE FOAMS
    6.
    发明申请
    HIGH RESILIENCE FOAMS 有权
    高可靠性

    公开(公告)号:US20100249260A1

    公开(公告)日:2010-09-30

    申请号:US12599998

    申请日:2008-05-07

    IPC分类号: C08G18/76

    摘要: A high resilience (HR) polyurethane foam comprising the reaction product of (1) at least one polyisocyanate comprising at least about 5 weight percent of at least one methylene diphenyl diisocyanate isomer, derivative or a combination thereof and (2) an admixture of at least one natural oil based polyol and at least one additional polyol which is not a natural oil based polyol, wherein the admixture comprises at least about 10 weight percent natural oil based polyol and at least about 40 weight percent additional polyol having an equivalent weight of at least about 1700 Daltons; and the foam has a resiliency indicated by a ball rebound of at least 40 percent as measured according to the procedures of ASTM D 3574, Test H. An HR foam is made according to a process comprising steps of (a) forming a natural oil based polyol composition comprising at least about 10 weight percent of at least one natural oil based polyol having an OH functionality of at least about 2.2 and an equivalent weight of at least about 500 Dalton (Da) and at least about 40 weight percent of at least one conventional polyol having an equivalent weight of at least about 1700 Da and water; (b) admixing at least one catalyst with the natural oil based polyol composition to form a catalyst polyol admixture; (c) supplying a poly isocyanate comprising at least about 5 weight percent of at least one methylene diphenyl diisocyanate isomer, derivative or combination thereof in an amount corresponding to an isocyanate index of at least about 55 and at most about 105 and (c) admixing the isocyanate with the catalyst polyol admixture. The foams are useful in such applications as comfort, sound absorption including noise dampening, harshness dampening, protection, packaging, medical equipment, safety equipment and combinations thereof.

    摘要翻译: 高弹性(HR)聚氨酯泡沫,其包含(1)至少一种包含至少约5重量%的至少一种亚甲基二苯基二异氰酸酯异构体,衍生物或其组合的至少一种多异氰酸酯的反应产物和(2)至少 一种天然油基多元醇和至少一种不是天然油基多元醇的另外的多元醇,其中所述混合物包含至少约10重量%的天然油基多元醇和至少约40重量%的额外的多元醇,其当量重量至少为 约1700道尔顿; 并且根据ASTM D 3574,试验H的程序,泡沫具有至少40%的球回弹所示的弹性。根据包括以下步骤的方法制备HR泡沫:(a)形成天然油基 多元醇组合物,其包含至少约10重量%的OH官能度为至少约2.2且至少约500道尔顿(Da)至少约40重量%的至少一种天然油基多元醇至少一种 具有至少约1700Da当量的常规多元醇和水; (b)将至少一种催化剂与天然油基多元醇组合物混合以形成催化剂多元醇混合物; (c)提供聚异氰酸酯,其包含至少约5重量%的至少一种亚甲基二苯基二异氰酸酯异构体,衍生物或其组合,其量对应于异氰酸酯指数为至少约55至最多约105,和(c)混合 异氰酸酯与催化剂多元醇混合物。 泡沫在诸如舒适性,吸声性,包括噪音抑制,粗糙度衰减,保护,包装,医疗设备,安全设备及其组合的应用中是有用的。

    Low emission polyurethane polymers made with autocatalytic polyols
    8.
    发明申请
    Low emission polyurethane polymers made with autocatalytic polyols 审中-公开
    用自催化多元醇制成的低排放聚氨酯聚合物

    公开(公告)号:US20050020707A1

    公开(公告)日:2005-01-27

    申请号:US10861594

    申请日:2004-06-04

    摘要: The present invention discloses a process for producing a polyurethane product with autocatalytic polyols. These auto-catalytic polyols are based on an initiator of the formula (I): HmA-(CH2)n—N(R)—(CH2)p-AHm where n and p are independently integers from 2 to 6, A at each occurrence is independently oxygen, nitrogen or hydrogen, with the proviso that only one of A can be hydrogen at one time, R is a C1 to C3 alkyl group, m is equal to 0 when A is hydrogen, is 1 when A B is oxygen and is 2 when A is nitrogen; or are polyols which contain an alkyl amine of within the polyol chain or a dialkylylamino group pendant to the polyol chain wherein the polyol chain is obtained by copolymerization of at least one monomer containing an alkyl aziridine or N,N-dialkyl glycidylamine with at least one alkylene oxide. These auto-catalytic polyols are reacted with a polyisocyanate in the presence of other additives and/or auxiliary agents known per se to produce polyurethane products.

    摘要翻译: 本发明公开了一种用自催化多元醇制备聚氨酯产品的方法。 这些自催化多元醇基于式(I)的引发剂:HmA-(CH2)nN(R) - (CH2)p-AHm,其中n和p独立地为2至6的整数,每次出现A 独立地是氧,氮或氢,条件是A中只有一个可以同时为氢,R为C1至C3烷基,当A为氢时,m等于0,当AB为氧时为1,当AB为氧时为2 当A是氮时; 或者是含有多元醇链中的烷基胺或多元醇链侧基的二烷基氨基的多元醇,其中所述多元醇链通过至少一种含烷基氮丙啶或N,N-二烷基缩水甘油胺与至少一种 环氧烷。 在本身已知的其它添加剂和/或辅助剂的存在下,这些自动催化多元醇与多异氰酸酯反应以生产聚氨酯产品。