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    Melt-processable block copolyesterimide and method for manufacturing it
    1.
    发明授权
    Melt-processable block copolyesterimide and method for manufacturing it 失效
    熔融加工性嵌段共聚酯酰亚胺及其制造方法

    公开(公告)号：US5677394A

    公开(公告)日：1997-10-14

    申请号：US406859

    申请日：1995-04-28

    申请人： Frank Bohme ,  Doris Pospiech ,  Manfred Ratzsch ,  Christer Bergstrom ,  Mika Harkonen ,  Heli Alanko ,  Pentti Passiniemi

    发明人： Frank Bohme ,  Doris Pospiech ,  Manfred Ratzsch ,  Christer Bergstrom ,  Mika Harkonen ,  Heli Alanko ,  Pentti Passiniemi

    IPC分类号： C08J5/18 ,  B29C45/00 ,  B29C47/00 ,  B29C49/00 ,  B29D22/00 ,  B29D23/00 ,  B29D99/00 ,  B29K79/00 ,  C08G63/685 ,  C08G73/16 ,  C08L79/08

    CPC分类号： C08G73/16 ,  C08G63/685 ,  C08L79/08

    摘要： A melt-processable block copolyesterimide comprising the repeating units (I), (II) and (III) and, optionally, a repeating unit (IV), wherein (I) is a repeating unit of the formula ##STR1## wherein R is an aliphatic polyether chain and/or a polysiloxane chain; (II) and (III) are repeating units of the formulas ##STR2## wherein Z is hydrogen, alkyl, alkoxy, aryl, halogen and w is zero or one; and (IV) is a repeating unit of the formula ##STR3## wherein Z' is hydrogen, alkyl, alkoxy, aryl or halogen and the phenylene ring is substituted in by Z' in the m- or p-positions. The repeating unit of formula (I) is present in an amount of 5 to 50 mole-%, the repeating unit of formula (II) is present in an amount of 10 to 80 mole-%, the repeating unit of formula (III) is present in an mount of 5 to 50 mole-% and the repeating unit of formula (IV) is present in an amount of 0 to 45 mole-% of the block copolyesterimide. The polymer according to the invention has liquid crystalline properties and it can be used as thermoplastic elastomer component of polymer compounds.

    摘要翻译： PCT No.PCT / FI93 / 00374 Sec。 371日期：1995年4月28日 102（e）1995年4月28日PCT PCT 1993年9月17日PCT公布。 公开号WO94 / 06846 日期1994年3月31日包含重复单元（I），（II）和（III）的可熔融加工的嵌段共聚酯酰亚胺和任选的重复单元（IV），其中（I）是下式的重复单元：IMAGE >（I）其中R是脂族聚醚链和/或聚硅氧烷链; （II）和（III）是式（III）的重复单元，其中Z是氢，烷基，烷氧基，芳基，卤素，w是0或1; 和（IV）是式（IV）的重复单元，其中Z'是氢，烷基，烷氧基，芳基或卤素，并且亚苯基环被m'或p-位上的Z'取代。 式（I）的重复单元以5至50摩尔％的量存在，式（II）的重复单元的存在量为10至80摩尔％，式（III）的重复单元 以5至50摩尔％的含量存在，并且式（IV）的重复单元以嵌段共聚酯酰亚胺的0至45摩尔％的量存在。 根据本发明的聚合物具有液晶性质，并且可以用作聚合物化合物的热塑性弹性体组分。

    Amorphous polyesterimides which can be processed as thermoplastics
    3.
    发明授权
    Amorphous polyesterimides which can be processed as thermoplastics 失效
    可以加工成热塑性塑料的无定形聚酯酰亚胺

    公开(公告)号：US5369209A

    公开(公告)日：1994-11-29

    申请号：US101186

    申请日：1993-08-03

    申请人： Horst-Tore Land ,  Michaela Gedan ,  Manfred Ratzsch ,  Frank Bohme

    发明人： Horst-Tore Land ,  Michaela Gedan ,  Manfred Ratzsch ,  Frank Bohme

    IPC分类号： C08G73/16 ,  C08K3/00 ,  C08L79/08 ,  C08G73/00

    CPC分类号： C08G73/16 ,  C08L79/08

    摘要： The invention relates to amorphous polyesterimides which comprises 50 to 100 mole-% of units of formula II ##STR1## and from 0 to 50 mole-% of units of formula ##STR2## in which units R.sub.1 and R.sub.2, independentlyof one another, are H, branched or unbranched alkyl radicals having 1 to 6 carbon atoms, branched or unbranched alkoxy radicals having 1 to 6 carbon atoms, or F, Cl or Br.The polyesterimides according to the invention are suitable for the production of molding compositions, moldings, fibers and films.

    摘要翻译： 本发明涉及无定形聚酯酰亚胺，其包含50至100摩尔％的式II式II的单元和0至50摩尔％的式I的单元，其中单元R1和R2独立地为一个 另一个是具有1至6个碳原子的H，支链或非支链烷基，具有1至6个碳原子的支链或非支链烷氧基，或F，Cl或Br。 根据本发明的聚酯酰亚胺适用于生产模塑组合物，模制品，纤维和薄膜。

    Direct synthesis method for the production of etherified melamine resin condensates, melemine resin condensates, and use thereof
    4.
    发明申请
    Direct synthesis method for the production of etherified melamine resin condensates, melemine resin condensates, and use thereof 审中-公开
    用于生产醚化三聚氰胺树脂缩合物，美甲树脂缩合物的直接合成方法及其用途

    公开(公告)号：US20060252909A1

    公开(公告)日：2006-11-09

    申请号：US10539789

    申请日：2003-12-18

    申请人： Steffen Pfeiffer ,  Manfred Ratzsch ,  Hartmut Bucka ,  Günter Tappeiner

    发明人： Steffen Pfeiffer ,  Manfred Ratzsch ,  Hartmut Bucka ,  Günter Tappeiner

    IPC分类号： C08G69/10

    CPC分类号： C08G12/427

    摘要： The invention relates to a direct synthesis method for producing etherified melamine resin condensates having average molar masses of 500 to 50,000. The method is characterized by the fact that a) an etherified melamine resin precondensate is produced in an alcoholic solution in a first reaction step; b) the etherified melamine resin precondensate is concentrated in an alcoholic solution in at least one condensation step, C4 to C18 alcohols, diols of type HO—R—OH, and/or tetravalent alcohols that are based on erythritol being added to the melamine resin precondensate during and/or following the concentration process; c) the concentrated melamine resin precondensate is reacted by means of a mixer, especially a kneader, in a second reaction step.

    摘要翻译： 本发明涉及平均摩尔质量为500〜50000的醚化三聚氰胺树脂缩合物的制造方法。 该方法的特征在于a）在第一反应步骤中在醇溶液中产生醚化的三聚氰胺树脂预缩合物; b）将醚化的三聚氰胺树脂预缩合物在至少一个缩合步骤，C 4〜C 18醇，HO-R-OH型二醇， 和/或基于赤藓糖醇的四价醇在浓缩过程中和/或之后加入到三聚氰胺树脂中预缩合; c）浓缩的三聚氰胺树脂预缩合物在第二反应步骤中通过混合器，特别是捏合机反应。

    Products, especially moulding materials of polymers containing triazine segments, method for the production thereof and uses of the same
    5.
    发明申请
    Products, especially moulding materials of polymers containing triazine segments, method for the production thereof and uses of the same 有权
    产品，特别是含有三嗪片段的聚合物的成型材料，其制备方法和用途

    公开(公告)号：US20050038226A1

    公开(公告)日：2005-02-17

    申请号：US10495903

    申请日：2002-11-19

    申请人： Manfred Ratzsch ,  Hartmut Bucka ,  Rene Dicke ,  Martin Burger ,  Steffen Pfeiffer ,  Christian Furst

    发明人： Manfred Ratzsch ,  Hartmut Bucka ,  Rene Dicke ,  Martin Burger ,  Steffen Pfeiffer ,  Christian Furst

    IPC分类号： C08G73/06 ,  C08G63/44

    CPC分类号： C08G73/0644

    摘要： The invention relates to products, especially moulding materials of polymers containing triazine segments and consisting of mixtures of meltable 4-18 ring oligotriazine ethers which are soluble in highly polar solvents, and in which the triazine rings are predominantly linked by alkylene diamiino groups. Said moulding materials can contain up to 50 mass % of other reactive polymers such as ethylene copolymers, maleic acid anhydride copolymers, modified maleic acid anhydride copolymers, poly(meth)acrylates, polyamides, polyester and/or polyurethanes, up to 75 mass % of filling materials and/or reinforcing fibres, and up to 2 mass % of stabilisers, UV absorbers and/or auxiliary agents. The moulding materials of polymers containing triazine segments can be processed by means of conventional fusion methods and can be used as hot-melt adhesives and for producing plates, tubes, profiles, injection moulded parts, fibres, coatings and foamed material.

    摘要翻译： 本发明涉及产品，特别是包含三嗪链段的聚合物的成型材料，由可溶于高极性溶剂的可熔性4-18环低聚三嗪醚的混合物组成，其中三嗪环主要由亚烷基二胺基团连接。 所述成型材料可以含有至多50质量％的其它反应性聚合物，例如乙烯共聚物，马来酸酐共聚物，改性马来酸酐共聚物，聚（甲基）丙烯酸酯，聚酰胺，聚酯和/或聚氨酯，高达75质量％ 填充材料和/或增强纤维，以及至多2质量％的稳定剂，UV吸收剂和/或辅助剂。 含有三嗪片段的聚合物的成型材料可以通过常规的熔融方法加工，并且可以用作热熔胶和用于制造板，管，型材，注模部件，纤维，涂层和发泡材料。

    Plastic products with high strength and flexibility
    7.
    发明申请
    Plastic products with high strength and flexibility 审中-公开
    塑料制品具有高强度和柔韧性

    公开(公告)号：US20060276581A1

    公开(公告)日：2006-12-07

    申请号：US10565354

    申请日：2004-07-21

    申请人： Manfred Ratzsch ,  Andreas Haider ,  Uwe Muller ,  Andrea Gosweiner

    发明人： Manfred Ratzsch ,  Andreas Haider ,  Uwe Muller ,  Andrea Gosweiner

    IPC分类号： C08G18/42

    CPC分类号： C08J3/246 ,  C08K5/005 ,  C08K5/14 ,  C08L23/08 ,  C08L61/28 ,  C08L2666/02

    摘要： The invention relates to plastic products with high strength and flexibility, having 10 to 50 mass % of at least one crosslinked thermoplast and 90 to 50 mass % of at least one crosslinked melamine resin ether. The invention further relates to a method for production of such a plastic product. The aim of the invention is the production of plastic objects in thermoplastics and duroplastics which can be produced by thermoplastic methodology and which have improved material properties.

    摘要翻译： 本发明涉及具有高强度和柔韧性的塑料制品，具有10至50质量％的至少一种交联热塑性塑料和90至50质量％的至少一种交联的三聚氰胺树脂醚。 本发明还涉及这种塑料制品的生产方法。 本发明的目的是在热塑性塑料和塑料制品中生产塑料，其可以通过热塑性方法制造并具有改善的材料性能。

    Method for curing aminoplasts
    8.
    发明申请
    Method for curing aminoplasts 审中-公开
    固化氨基塑料的方法

    公开(公告)号：US20060084007A1

    公开(公告)日：2006-04-20

    申请号：US10517963

    申请日：2003-06-12

    申请人： Manfred Ratzsch ,  Hartmut Bucka ,  Martin Burger ,  Uwe Muller

    发明人： Manfred Ratzsch ,  Hartmut Bucka ,  Martin Burger ,  Uwe Muller

    IPC分类号： G03C1/76 ,  D02G3/00 ,  F16J15/20

    CPC分类号： D01F6/76 ,  C08K5/18 ,  C08K5/3492 ,  C08K5/42 ,  C08L61/28 ,  C09D161/28 ,  Y10T428/2913 ,  Y10T428/2915 ,  C08L61/00

    摘要： A method for curing aminoplasts, during which layers having layer thicknesses of up to 300 um or filaments and fiber fibrids having a diameter of up to 300 um, which consist of: i) 95 to 99.95% by mass of solvent-free meltable aminoplast polycondensates with molar masses ranging from 1000 to 300000; j) 5 to 0.05% by mass of curing agents, which can be activated by actinic light and which are comprised of acidifiers of the blocked sulfonic acid and/or halogen-substituted triazine derivative and/or onium salt type, and optionally; k) 1 to 20% by mass, with regard to the meltable aminoplast polycondensates, of unmodified and/or modified maleic anhydride copolymers, and/or; i) 0.1 to 5% by mass, with regard to the meltable aminoplast polycondensates, of nanoparticles. The aminoplasts are cured by irradiating them with actinic light at a temperature between the melting point of the aminoplast polycondensate and the thermoinduced decomposition temperature of the light-activatable curing agents. This method enables the production of, preferably, textile fabrics or coatings.

    摘要翻译： 一种用于固化氨基塑料的方法，其中具有高达300μm的层厚度或直径高达300μm的长丝和纤维纤维素，其由以下组成：i）95至99.95质量％的无溶剂的可熔化氨基塑料缩聚物 摩尔质量范围为1000〜300000; j）5〜0.05质量％的固化剂，其可以通过光化剂活化，并且其由阻断的磺酸和/或卤素取代的三嗪衍生物和/或鎓盐型的酸化剂和任选的; k）1〜20质量％，相对于可熔融的氨基塑料缩聚物，未改性和/或改性的马来酸酐共聚物，和/或; i）相对于可熔化氨基塑料缩聚物，为0.1〜5质量％的纳米粒子。 通过在氨基塑料缩聚物的熔点和可光活化的固化剂的热分解温度之间的温度下用光化光照射氨基塑料来固化。 该方法能够生产优选的织物或涂层。

    Synthetic material dispersions
    10.
    发明申请
    Synthetic material dispersions 审中-公开
    合成材料分散体

    公开(公告)号：US20060173102A1

    公开(公告)日：2006-08-03

    申请号：US10539935

    申请日：2003-12-18

    申请人： Daniel Jocham ,  Manfred Ratzsch

    发明人： Daniel Jocham ,  Manfred Ratzsch

    IPC分类号： B22F1/00

    CPC分类号： B32B29/06 ,  B32B7/12 ,  B32B27/10 ,  B32B27/20 ,  B32B27/42 ,  B32B2307/3065 ,  B32B2307/4026 ,  B32B2307/712 ,  B32B2307/73 ,  B32B2317/12 ,  B32B2317/16 ,  B32B2331/04 ,  B32B2367/00 ,  B32B2377/00 ,  B32B2419/00 ,  B44C5/0461 ,  C08G12/32 ,  C08G12/427 ,  D06M15/423 ,  D21H17/51 ,  D21H27/26

    摘要： The invention relates to synthetic material dispersions consisting of (a) an aqueous phase of solutions of hydrophilic melamine resin precondensates and a latent hardening catalyst in water or in mixtures of water and alcohols C1-C6, (b) an organic nanophase in the form of nanometric droplets and/or nanoparticles derived from 70-99% of the melamine resin precondensates which are insoluble in water and etherifieds and contain hardening acid catalysts and acid impermeability agents, (c) dispersion agents at a concentration of 1-10 mass % in relation to the total mass of the melamine resin precondensates. The synthetic material dispersions are used for producing flat coated products which are externally used in the form of laminates, of coated flat carrying materials or moulded coated bodies for construction or for sports and recreation.

    摘要翻译： 本发明涉及由（a）亲水性三聚氰胺树脂预缩合物的溶液的水相和水中或水和醇的混合物中的潜在硬化催化剂组成的合成材料分散体C 1 -C 3 - （b）纳米微滴形式的有机纳米相和/或衍生自70-99％三聚氰胺树脂预缩合物的纳米相，其不溶于水和醚化并含有硬化酸催化剂和酸不渗透剂， （c）相对于三聚氰胺树脂预缩合物的总质量为1-10质量％的分散剂。 合成材料分散体用于生产平面涂层产品，其外部以层压材料的形式，涂覆的平面携带材料或用于建造或用于运动和娱乐的模制涂层体。