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1.发明授权
公开(公告)号：US3990866A
公开(公告)日：1976-11-09
申请号：US521881
申请日：1974-11-07
IPC分类号： B01J23/755 , C10G11/02 , C10G11/28
CPC分类号： B01J23/755
摘要： The compound Ni.sub.5 MgAl.sub.2 (OH).sub.16.sup.. CO.sub.3.sup.. 4H.sub.2 O is precipitated from an aqueous solution containing salts of nickel, magnesium and aluminum with a carbonate or bicarbonate of an alkali metal. After this catalyst precursor has been dried, calcined and reduced with hydrogen a catalyst can be prepared which is suitable for the cracking of hydrocarbons in the presence of steam. In the steam cracking of hydrocarbons the hydrocarbon and the steam may be reacted to form a gas rich in methane in contact with this catalyst at a preheating temperature of less than 300.degree. C.
摘要翻译： 化合物Ni5MgAl2（OH）16.CO3·4H2O从含有镍，镁和铝的盐的水溶液中与碱金属的碳酸盐或碳酸氢盐沉淀。 在该催化剂前体已经干燥，煅烧并用氢还原之后，可以制备适合于在蒸汽存在下裂解烃的催化剂。 在烃的蒸汽裂化中，烃和蒸汽可在低于300℃的预热温度下反应形成富含甲烷的气体与该催化剂接触。
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公开(公告)号：US3950368A
公开(公告)日：1976-04-13
申请号：US415416
申请日：1973-11-13
申请人： Franz Josef Broecker , Guenter Zirker , Bruno Triebskorn , Laszlo Marosi , Matthias Schwarzmann , Winfried Dethlefsen , Knut Kaempfer
发明人： Franz Josef Broecker , Guenter Zirker , Bruno Triebskorn , Laszlo Marosi , Matthias Schwarzmann , Winfried Dethlefsen , Knut Kaempfer
IPC分类号： C10G11/20 , B01J23/00 , B01J23/755 , C07B61/00 , C07C1/00 , C07C1/02 , C07C4/00 , C07C4/06 , C07C9/04 , C07C67/00 , C07C27/06
CPC分类号： C07C1/02 , B01J23/755 , C07C4/00 , C10G11/02 , C10G11/10 , C07C2527/236
摘要： A two-stage process for the manufacture of methane from hydrocarbons is described. In the first stage, the hydrocarbons are converted into methane-rich gases, using the nickel catalyst described below. The cracked gases thus obtained are cooled and converted into methane-rich gases in a further catalytic process stage, using a methanization catalyst or the nickel catalyst mentioned below. To produce the nickel catalyst, the compound Ni.sub.6 Al.sub.2 (OH).sub.16.CO.sub.3.4H.sub.2 O is prepared in aqueous solution. The catalyst is obtained from this compound by drying, calcination and subsequent reduction in a stream of hydrogen whilst maintaining very specific temperature gradients between the drying stage and the calcination stage.
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公开(公告)号：US3941721A
公开(公告)日：1976-03-02
申请号：US415407
申请日：1973-11-13
申请人： Franz Josef Broecker , Guenter Zirker , Bruno Triebskorn , Laszlo Marosi , Matthias Schwarzmann , Winfried Dethlefsen , Knut Kaempfer
发明人： Franz Josef Broecker , Guenter Zirker , Bruno Triebskorn , Laszlo Marosi , Matthias Schwarzmann , Winfried Dethlefsen , Knut Kaempfer
IPC分类号： B01J23/755 , B01J37/08 , C07B61/00 , C07C1/00 , C07C4/00 , C07C4/06 , C07C9/04 , C07C67/00 , B01J21/04 , B01J23/74
CPC分类号： C07C4/06 , B01J23/755 , B01J37/08 , C07C4/00 , C10G11/02 , C07C2527/236
摘要： The compound Ni.sub.6 Al.sub.2 (OH).sub.16. CO.sub.3. 4H.sub.2 O is isolated from aqueous solution. The catalyst is obtained from this compound by drying, calcination and subsequent reduction in a stream of hydrogen, whilst maintaining very specific temperature gradients between the drying stage and the calcination stage. A process for the manufacture of gases containing methane from hydrocarbons by steam cracking, in which the abovementioned catalyst is employed, is also described.
摘要翻译： 化合物Ni6Al2（OH）16。 CO3。 4H2O与水溶液分离。 通过干燥，煅烧和随后在氢气流中还原从该化合物获得催化剂，同时在干燥阶段和煅烧阶段保持非常特定的温度梯度。 还描述了使用上述催化剂通过蒸汽裂化从烃制造含甲烷的气体的方法。
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公开(公告)号：US06340713B1
公开(公告)日：2002-01-22
申请号：US09423613
申请日：1999-11-15
申请人： Guiscard Glück , Klaus Hahn , Knut Kaempfer , Dieter Naegele , Frank Braun
发明人： Guiscard Glück , Klaus Hahn , Knut Kaempfer , Dieter Naegele , Frank Braun
IPC分类号： C08J900
CPC分类号： C04B16/08 , C04B18/027 , C04B2111/28 , C08J9/0023 , C08J9/0066 , C08J9/141 , C08J9/16 , C08J2325/04 , Y10S521/907 , C04B14/024 , C04B2103/63
摘要： Particulate expandable styrene polymers contain homogeneously distributed graphite particles and can be processed to give self-extinguishing foams having a density of ≦35 g/l.
摘要翻译： 颗粒状可发性苯乙烯聚合物含有均匀分布的石墨颗粒，可以加工成具有<35g / l密度的自熄泡沫体。
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5.发明授权
公开(公告)号：US5258415A
公开(公告)日：1993-11-02
申请号：US10316
申请日：1993-01-28
申请人： Klaus Hahn , Knut Kaempfer , Hans Hintz , Anthony Schaefer , Michael Riethues , Michael Witt
发明人： Klaus Hahn , Knut Kaempfer , Hans Hintz , Anthony Schaefer , Michael Riethues , Michael Witt
CPC分类号： C08J9/0061 , C08J9/18 , C08K5/0008 , C08K5/17 , C08L25/04 , C08J2325/04 , C08J2471/00 , C08L71/02
摘要： The invention relates to expandable styrene polymers containinga) a styrene polymer,b) and at least one carbon dioxide absorber, mixed or copolymerized with the above, in an amount of from 0.01 to 50% by weight, based on the sum of a) and b), andc) a blowing agent or blowing agent mixture in an amount of from 0.5 to 12% by weight,where the blowing agent or blowing agent mixture comprisesc.sub.1) from 10 to 100% by weight of carbon dioxide andc.sub.2) from 0 to 90% by weight of at least one further blowing agent.The invention furthermore relates to the styrene polymers containing a carbon dioxide absorber, to the styrene polymer foams obtainable from the expandable styrene polymers, and to an improved process for impregnating styrene polymers with carbon dioxide-containing blowing agents or blowing agent mixtures.
摘要翻译： 本发明涉及含有a）苯乙烯聚合物，b）和至少一种与上述混合或共聚的二氧化碳吸收剂的可发性苯乙烯聚合物，其量为0.01至50重量％，基于a） 和b），和c）发泡剂或发泡剂混合物的量为0.5至12重量％，其中发泡剂或发泡剂混合物包含c1）10至100重量％的二氧化碳和c2） 0至90重量％的至少一种其它发泡剂。 本发明还涉及含有二氧化碳吸收剂的苯乙烯聚合物，可从可发性苯乙烯聚合物获得的苯乙烯聚合物泡沫，以及用含二氧化碳的发泡剂或发泡剂混合物浸渍苯乙烯聚合物的改进方法。
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公开(公告)号：US5905096A
公开(公告)日：1999-05-18
申请号：US391
申请日：1998-01-29
申请人： Peter Nikolaus Lay , Swen Ruck , Michael Schiessl , Michael Witt , Hans Dieter Zettler , Michael Baumgartel , Gerhard Dembek , Klaus Hahn , Jan Holoch , Wolfram Husemann , Knut Kaempfer
发明人： Peter Nikolaus Lay , Swen Ruck , Michael Schiessl , Michael Witt , Hans Dieter Zettler , Michael Baumgartel , Gerhard Dembek , Klaus Hahn , Jan Holoch , Wolfram Husemann , Knut Kaempfer
CPC分类号： C08F12/08
摘要： A continuous process for preparing bead-form expandable styrene polymers in which the styrene is prepolymerized in bulk to a conversion of 10 to 80%, the prepolymer is dispersed in liquid form in an aqueous phase in the presence of suspension stabilizers, and the polymerization of the prepolymer is completed in an aqueous suspension to a residual styrene content of less than 2000 ppm.
摘要翻译： PCT No.PCT / EP96 / 03633 371日期1998年1月29日 102（e）1998年1月29日PCT PCT 1996年8月19日PCT公布。 公开号WO97 / 08231 日期1997年3月6日一种用于制备珠粒可发性苯乙烯聚合物的连续方法，其中将苯乙烯本体预聚合至10至80％的转化率，预聚物在悬浮稳定剂存在下以液态分散在水相中 ，并且预聚物的聚合在水悬浮液中完成至小于2000ppm的残余苯乙烯含量。
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7.发明授权
公开(公告)号：US5229429A
公开(公告)日：1993-07-20
申请号：US973822
申请日：1992-11-09
申请人： Klaus Hahn , Knut Kaempfer , Hans Hintz , Anthony Schaefer , Michael Riethues , Michael Witt
发明人： Klaus Hahn , Knut Kaempfer , Hans Hintz , Anthony Schaefer , Michael Riethues , Michael Witt
IPC分类号： C08J9/12 , C08J9/00 , C08J9/16 , C08J9/18 , C08K5/00 , C08K5/05 , C08K5/06 , C08K5/17 , C08L25/04 , C08L71/00 , C08L71/02
CPC分类号： C08J9/0061 , C08J9/18 , C08K5/0008 , C08K5/17 , C08L25/04 , C08J2325/04 , C08J2471/00 , C08L71/02
摘要： The invention relates to expandable styrene polymers containinga) a styrene polymer,b) and at least one carbon dioxide absorber, mixed or copolymerized with the above, in an amount of from 0.01 to 50% by weight, based on the sum of a) and b), andc) a blowing agent or blowing agent mixture in an amount of from 0.5 to 12% by weight,where the blowing agent or blowing agent mixture comprisesc.sub.1) from 10 to 100% by weight of carbon dioxide andc.sub.2) from 0 to 90% by weight of at least one further blowing agent.The invention furthermore relates to the styrene polymers containing a carbon dioxide absorber, to the styrene polymer foams obtainable from the expandable styrene polymers, and to an improved process for impregnating styrene polymers with carbon dioxide-containing blowing agents or blowing agent mixtures.
摘要翻译： 本发明涉及含有a）苯乙烯聚合物，b）和至少一种与上述混合或共聚的二氧化碳吸收剂的可发性苯乙烯聚合物，其量为0.01至50重量％，基于a） 和b），和c）发泡剂或发泡剂混合物的量为0.5至12重量％，其中发泡剂或发泡剂混合物包含c1）10至100重量％的二氧化碳和c2） 0至90重量％的至少一种其它发泡剂。 本发明还涉及含有二氧化碳吸收剂的苯乙烯聚合物，可从可发性苯乙烯聚合物获得的苯乙烯聚合物泡沫，以及用含二氧化碳的发泡剂或发泡剂混合物浸渍苯乙烯聚合物的改进方法。
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公开(公告)号：US4623533A
公开(公告)日：1986-11-18
申请号：US825626
申请日：1986-02-03
申请人： Franz J. Broecker , Hans Gettert , Knut Kaempfer
发明人： Franz J. Broecker , Hans Gettert , Knut Kaempfer
CPC分类号： C01B17/0465 , B01D53/8612 , B01J23/755
摘要： H.sub.2 S-containing gases are desulfurized by direct catalytic oxidation of the H.sub.2 S to elemental sulfur with an oxygen-containing gas at elevated temperatures by a method in which the catalyst used is a supported titanium dioxide catalyst containing from 0.1 to 25% by weight of nickel oxide and from 0 to 10% by weight of aluminum oxide, the percentages being based on the supported catalyst.
摘要翻译： 通过使用的催化剂是含有0.1〜25重量％的氧化镍的负载型二氧化钛催化剂的方法，通过在升高的温度下用含氧气体将H 2 S直接催化氧化成元素硫而将含H2S的气体脱硫 和0至10重量％的氧化铝，所述百分比基于负载型催化剂。
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公开(公告)号：US4521387A
公开(公告)日：1985-06-04
申请号：US552930
申请日：1983-11-18
申请人： Franz J. Broecker , Hans Gettert , Knut Kaempfer
发明人： Franz J. Broecker , Hans Gettert , Knut Kaempfer
CPC分类号： B01J23/80 , B01D53/8603 , C01B3/58 , C01B31/20 , C10K1/20 , C10K1/34 , C01B2203/045 , C01B2203/0465 , C01B2203/0485
摘要： Gases containing CO and/or CO.sub.2 are purified by removing sulfur compounds and other impurities by catalytic reaction at elevated temperatures by a process in which the gases to be purified are passed directly through a catalyst charge containing a Cu/ZnO catalyst prepared by thermal decomposition of a mixed crystalline compound of zinc hydroxide carbonate, and the space velocity is set at 500-5,000 m.sup.3 (S.T.P.) per m.sup.3 of catalyst per hour. Preferably, the catalyst used is a Cu/ZnO catalyst which is prepared by thermal decomposition of a catalyst precursor of the general formulaCu.sub.x Zn.sub.y (OH).sub.6 (CO.sub.3).sub.2.
摘要翻译： 含有CO和/或CO2的气体通过在高温下通过催化反应除去硫化合物和其它杂质而被纯化，其中待纯化气体直接通过含有通过热分解制备的Cu / ZnO催化剂的催化剂装料 氢氧化锌碳酸盐的混合结晶化合物，空速为每小时每立方米催化剂500-5,000立方米（STP）。 优选地，所用的催化剂是通过热分解通式CuxZny（OH）6（CO 3）2的催化剂前体制备的Cu / ZnO催化剂。
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公开(公告)号：US4728437A
公开(公告)日：1988-03-01
申请号：US894808
申请日：1986-08-08
CPC分类号： B01D37/03 , C02F1/54 , C02F11/008 , C02F11/12 , C02F2101/20 , C02F2101/30 , C02F2103/34 , Y10S210/912
摘要： Wastewaters which contain carbon black and ash and originate from high temperature processes and in which the carbon black is present in a very finely divided state and partially in a colloidal state are treated and disposed of by a process in which the wastewater is treated with calcium carbonate or calcium hydroxide and an organic flocculant and subjected to a two-stage filtration and the resulting filter cake containing carbon black and ash is subjected to an aftertreatment with an aqueous iron salt solution.
摘要翻译： 含有炭黑和灰分并且源于高温过程并且其中炭黑以非常细分的状态存在且部分为胶体状态的废水通过其中用碳酸钙处理废水的方法进行处理和处理 或氢氧化钙和有机絮凝剂进行两级过滤，并将所得到的含有炭黑和灰分的滤饼用铁盐水溶液进行后处理。
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