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公开(公告)号：US4386153A
公开(公告)日：1983-05-31
申请号：US240433
申请日：1981-03-04
IPC分类号： C08F2/00 , C08F2/50 , G03F7/031 , H01L21/027 , G03C1/68
CPC分类号： G03F7/031 , Y10S430/12 , Y10S430/124
摘要： A light-sensitive composition comprising addition polymerizable ethylenically unsaturated double bond-containing compounds and a photopolymerization initiator comprising (1) at least one compound selected from the group consisting of benzanthrone, substituted benzanthrones (the substituents of which include halogen atoms, alkyl groups having 1 to 5 carbon atoms and alkoxy groups having 1 to 5 carbon atoms), 1,2-benzanthraquinone and substituted benzanthraquinones (substituents of which include halogen atoms, alkyl groups having 1 to 5 carbon atoms and alkoxy groups having 1 to 5 carbon atoms) and (2) at least one compound selected from the group consisting of 4,4'-di-substituted amino-benzophenones represented by the following general formula (a), p-substituted amino-benzaldehyde derivatives represented by the following general formula (b), 2-(p-substituted amino-phenyl)-1,3-dioxolanes represented by the following general formula (c), 4,4'-bis(substituted amino)-N-benzylideneanilines represented by the following general formula (d) and 2-[4-(substituted amino)cinnamoyl]naphthalenes represented by the following general formula (e): ##STR1## wherein R and R', which may be the same or different, each represents a methyl group or an ethyl group, and R.sup.0 represents a hydrogen atom, a hydroxy group, a --CR.sup.1 R.sup.2 R.sup.3 group, where R.sup.1, R.sup.2 and R.sup.3, which may be the same or different, each represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, or an --OR.sup.4 group, where R.sup.4 represents an alkyl group having 1 to 5 carbon atoms.
摘要翻译： 一种包含可加成聚合的烯属不饱和双键的化合物和光聚合引发剂的感光性组合物，其包含（1）选自由以下的化合物组成的组中的至少一种化合物：苯并蒽酮，取代的苯并蒽酮（其取代基包括卤素原子， 至5个碳原子和具有1至5个碳原子的烷氧基），1,2-苯并蒽醌和取代的苯并蒽醌（其取代基包括卤素原子，具有1至5个碳原子的烷基和具有1至5个碳原子的烷氧基）和 （2）选自由以下通式（a）表示的4,4'-二取代氨基 - 二苯甲酮，由以下通式（b）表示的对取代氨基 - 苯甲醛衍生物， ，由以下通式（c）表示的2-（对取代氨基 - 苯基）-1,3-二氧戊环，4,4'-双（取代氨基）-N-亚苄基苯胺r （d）和由下列通式（e）表示的2- [4-（取代氨基）肉桂酰基]萘表示：（a）图像（c）（c） （e）其中R和R'可以相同或不同，表示甲基或乙基，R 0表示氢原子，羟基，-CR 1 R 2 R 3 基团，其中可以相同或不同的R 1，R 2和R 3各自表示氢原子或具有1至3个碳原子的烷基或-OR 4基团，其中R 4表示具有1至5个碳原子的烷基 原子
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2.发明授权Light-sensitive ethylenically unsaturated materials containing benzanthrones and novel sensitizers 失效含有苯并蒽和新型敏化剂的光敏烯属不饱和物质
公开(公告)号：US4439515A
公开(公告)日：1984-03-27
申请号：US484818
申请日：1983-04-14
IPC分类号： C08F2/00 , C08F2/50 , G03F7/031 , H01L21/027 , G03C1/68
CPC分类号： G03F7/031 , Y10S430/12 , Y10S430/124
摘要： A light-sensitive composition comprising addition polymerizable ethylenically unsaturated double bond-containing compounds and a photopolymerization initiator comprising (1) at least one compound selected from the group consisting of benzanthrone, substituted benzanthrones (the substituents of which include halogen atoms, alkyl groups having 1 to 5 carbon atoms and alkoxy groups having 1 to 5 carbon atoms), 1,2-benzanthraquinone and substituted benzanthraquinones (substituents of which include halogen atoms, alkyl groups having 1 to 5 carbon atoms and alkoxy groups having 1 to 5 carbon atoms) and (2) at least one compound selected from the group consisting of 4,4'-di-substituted amino-benzophenones represented by the following general formula (a), p-substituted amino-benzaldehyde derivatives represented by the following general formula (b), 2-(p-substituted amino-phenyl)-1,3-dioxolanes represented by the following general formula (c), 4,4'-bis(substituted amino)-N-benzylideneanilines represented by the following general formula (d) and 2-[4-(substituted amino)cinnamoyl]naphthalenes represented by the following general formula (e): ##STR1## wherein R and R', which may be the same or different, each represents a methyl group or an ethyl group, and R.sup.0 represents a hydrogen atom, a hydroxy group, a --CR.sup.1 R.sup.2 R.sup.3 group, where R.sup.1, R.sup.2 and R.sup.3, which may be the same or different, each represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, or an --OR.sup.4 group, where R.sup.4 represents an alkyl group having 1 to 5 carbon atoms.
摘要翻译： 一种包含可加成聚合的烯属不饱和双键的化合物和光聚合引发剂的感光性组合物，其包含（1）选自由以下的化合物组成的组中的至少一种化合物：苯并蒽酮，取代的苯并蒽酮（其取代基包括卤素原子， 至5个碳原子和具有1至5个碳原子的烷氧基），1,2-苯并蒽醌和取代的苯并蒽醌（其取代基包括卤素原子，具有1至5个碳原子的烷基和具有1至5个碳原子的烷氧基）和 （2）选自由以下通式（a）表示的4,4'-二取代氨基 - 二苯甲酮，由以下通式（b）表示的对取代氨基 - 苯甲醛衍生物， ，由以下通式（c）表示的2-（对取代氨基 - 苯基）-1,3-二氧戊环，4,4'-双（取代氨基）-N-亚苄基苯胺r （d）和由下列通式（e）表示的2- [4-（取代氨基）肉桂酰基]萘表示：（a）图像（c）（c） （e）其中R和R'可以相同或不同，表示甲基或乙基，R 0表示氢原子，羟基，-CR 1 R 2 R 3 基团，其中可以相同或不同的R 1，R 2和R 3各自表示氢原子或具有1至3个碳原子的烷基或-OR 4基团，其中R 4表示具有1至5个碳原子的烷基 原子
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公开(公告)号：US4298679A
公开(公告)日：1981-11-03
申请号：US57149
申请日：1979-07-12
IPC分类号： C08F2/00 , C08F2/50 , G03F7/031 , H01L21/027 , G03C1/68
CPC分类号： G03F7/031 , Y10S430/12 , Y10S430/124
摘要： A light-sensitive composition comprising addition polymerizable ethylenically unsaturated double bond-containing compounds and a photopolymerization initiator comprising (1) at least one compound selected from the group consisting of benzanthrone, substituted benzanthrones (the substituents of which include halogen atoms, alkyl groups having 1 to 5 carbon atoms and alkoxy groups having 1 to 5 carbon atoms), 1,2-benzanthraquinone and substituted benzanthraquinones (substituents of which include halogen atoms, alkyl groups having 1 to 5 carbon atoms and alkoxy groups having 1 to 5 carbon atoms) and (2) at least one compound selected from the group consisting of 4,4'-di-substituted amino-benzophenones represented by the following general formula (a), p-substituted amino-benzaldehyde derivatives represented by the following general formula (b), 2-(p-substituted amino-phenyl)-1,3-dioxolanes represented by the following general formula (c), 4,4'-bis(substituted amino)-N-benzylideneanilines represented by the following general formula (d) and 2-[4-(substituted amino)cinnamoyl]naphthalenes represented by the following general formula (e): ##STR1## wherein R and R', which may be the same or different, each represents a methyl group or an ethyl group, and R.sup.0 represents a hydrogen atom, a hydroxy group, a --CR.sup.1 R.sup.2 R.sup.3 group, where R.sup.1, R.sup.2 and R.sup.3, which may be the same or different, each represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, or an --OR.sup.4 group, where R.sup.4 represents an alkyl group having 1 to 5 carbon atoms.
摘要翻译： 一种包含可加成聚合的烯属不饱和双键的化合物和光聚合引发剂的感光性组合物，其包含（1）选自由以下的化合物组成的组中的至少一种化合物：苯并蒽酮，取代的苯并蒽酮（其取代基包括卤素原子， 至5个碳原子和具有1至5个碳原子的烷氧基），1,2-苯并蒽醌和取代的苯并蒽醌（其取代基包括卤素原子，具有1至5个碳原子的烷基和具有1至5个碳原子的烷氧基）和 （2）选自由以下通式（a）表示的4,4'-二取代氨基 - 二苯甲酮，由以下通式（b）表示的对取代氨基 - 苯甲醛衍生物， ，由以下通式（c）表示的2-（对取代氨基 - 苯基）-1,3-二氧戊环，4,4'-双（取代氨基）-N-亚苄基苯胺r （d）和由下列通式（e）表示的2- [4-（取代氨基）肉桂酰基]萘表示：（a）图像（c）（c） （e）其中R和R'可以相同或不同，表示甲基或乙基，R 0表示氢原子，羟基，-CR 1 R 2 R 3 基团，其中可以相同或不同的R 1，R 2和R 3各自表示氢原子或具有1至3个碳原子的烷基或-OR 4基团，其中R 4表示具有1至5个碳原子的烷基 原子
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公开(公告)号：US4175971A
公开(公告)日：1979-11-27
申请号：US832864
申请日：1977-09-13
CPC分类号： G03F7/031 , Y10S430/12 , Y10S430/124
摘要： A light-sensitive composition comprising addition polymerizable ethylenically unsaturated double bond-containing compounds and a photopolymerization initiator comprising (1) at least one compound selected from the group consisting of benzanthrone, substituted benzanthrones (the substituents of which include halogen atoms, alkyl groups having 1 to 5 carbon atoms and alkoxy groups having 1 to 5 carbon atoms), 1,2-benzanthraquinone and substituted benzanthraquinones (substituents of which include halogen atoms, alkyl groups having 1 to 5 carbon atoms and alkoxy groups having 1 to 5 carbon atoms) and (2) at least one compound selected from the group consisting of 4,4'-di-substituted amino-benzophenones represented by the following general formula (a), p-substituted amino-benzaldehyde derivatives represented by the following general formula (b), 2-(p-substituted amino-phenyl)-1,3-dioxolanes represented by the following general formula (c), 4,4'-bis(substituted amino)-N-benzylideneanilines represented by the following general formula (d) and 2-[4-(substituted amino)cinnamoyl]naphthalenes represented by the following general formula (e): ##STR1## where R and R', which may be the same or different, each represents a methyl group or an ethyl group, and R.sup.0 represents a hydrogen atom, a hydroxy group, a --CR.sup.1 R.sup.2 R.sup.3 group, where R.sup.1, R.sup.2 and R.sup.3, which may be the same or different, each represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, or an --OR.sup.4 group, where R.sup.4 represents an alkyl group having 1 to 5 carbon atoms.
摘要翻译： 一种包含可加成聚合的烯属不饱和双键的化合物和光聚合引发剂的感光性组合物，其包含（1）选自由以下的化合物组成的组中的至少一种化合物：苯并蒽酮，取代的苯并蒽酮（其取代基包括卤素原子， 至5个碳原子和具有1至5个碳原子的烷氧基），1,2-苯并蒽醌和取代的苯并蒽醌（其取代基包括卤素原子，具有1至5个碳原子的烷基和具有1至5个碳原子的烷氧基）和 （2）选自由以下通式（a）表示的4,4'-二取代氨基 - 二苯甲酮，由以下通式（b）表示的对取代氨基 - 苯甲醛衍生物， ，由以下通式（c）表示的2-（对取代氨基 - 苯基）-1,3-二氧戊环，4,4'-双（取代氨基）-N-亚苄基苯胺r （d）和由下列通式（e）表示的2- [4-（取代氨基）肉桂酰基]萘表示：（a）图像（c）（c） （e）其中R和R'可相同或不同，表示甲基或乙基，R 0表示氢原子，羟基，-CR 1 R 2 R 3 基团，其中可以相同或不同的R 1，R 2和R 3各自表示氢原子或具有1至3个碳原子的烷基或-OR 4基团，其中R 4表示具有1至5个碳原子的烷基 原子
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公开(公告)号：US4124516A
公开(公告)日：1978-11-07
申请号：US817475
申请日：1977-07-20
申请人： Fumiaki Shinozaki , Tomoaki Ikeda , Yasuo Washizawa , Sho Nakao
发明人： Fumiaki Shinozaki , Tomoaki Ikeda , Yasuo Washizawa , Sho Nakao
摘要： A dot-etching solution for dot-etching a halftone image of a metal composed mainly of aluminum, the dot-etching solution comprising(1) water,(2) (a) phosphorous acid or (b) phosphorous acid and phosphoric acid,(3) at least one of a bismuth compound and an antimony compound, and(4) at least one compound selected from hydrogen chloride, an alkali metal chloride, calcium chloride and magnesium chloride.
摘要翻译： 用于对主要由铝构成的金属的半色调图像进行点蚀刻的点蚀刻溶液，所述点蚀刻溶液包含（1）水，（2）（A）磷酸或（B）磷酸和磷酸（ 3）至少一种双胺化合物和抗微生物化合物，和（4）至少一种选自氯化物，碱金属氯化物，氯化钙和氯化镁的化合物。
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公开(公告)号：US4411983A
公开(公告)日：1983-10-25
申请号：US357114
申请日：1982-03-11
申请人： Yasuo Washizawa , Fumiaki Shinozaki , Tomoaki Ikeda , Sho Nakao
发明人： Yasuo Washizawa , Fumiaki Shinozaki , Tomoaki Ikeda , Sho Nakao
CPC分类号： G03F7/32
摘要： By treating an imagewise exposed and developed image-forming material comprising a support and a light-sensitive resin composition layer with organic solvents miscible with water or with a mixture of water and organic solvents miscible with water, elimination of non-image areas is completed.
摘要翻译： 通过处理包含载体和感光树脂组合物层的成像曝光和显影图像形成材料，其中可与水混合的有机溶剂或与水可混溶的水和有机溶剂的混合物完成非图像区域的消除。
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公开(公告)号：US4197124A
公开(公告)日：1980-04-08
申请号：US875708
申请日：1978-02-06
申请人： Tomoaki Ikeda , Yuzo Mizobuchi , Fumiaki Shinozaki , Akira Nahara , Yoshihiro Ono , Yasuo Washizawa , Satoshi Yoshida , Takeshi Tomotsu
发明人： Tomoaki Ikeda , Yuzo Mizobuchi , Fumiaki Shinozaki , Akira Nahara , Yoshihiro Ono , Yasuo Washizawa , Satoshi Yoshida , Takeshi Tomotsu
CPC分类号： G03C1/705 , Y10S430/133
摘要： A planographic printing plate material comprising a support and a light sensitive layer provided on the support, the light-sensitive layer being composed of (A) an inorganic material; (B) at least one metal and/or metal compound [(A)/(B) are capable of reacting with each other upon application of electromagnetic radiation] and (C) an organic compound capable of affecting the reaction between the inorganic material (A) and the metal and/or metal compound (B), wherein the inorganic material (A), the metal or metal compound (B), and the organic compound (C) are in contact with each other. When the light-sensitive layer is exposed to electromagnetic radiation, a difference in the hydrophilic or oleophilic nature of the exposed areas and the unexposed areas results, whereby a planographic printing plate is obtained which can be mounted on a printing machine and printed without any other treatments.
摘要翻译： 平版印刷版材料，其包含支撑体和设置在所述载体上的感光层，所述感光层由（A）无机材料构成; （B）至少一种金属和/或金属化合物[（A）/（B））在施加电磁辐射时能够彼此反应]和（C）能够影响无机材料 A）和金属和/或金属化合物（B），其中无机材料（A），金属或金属化合物（B）和有机化合物（C）彼此接触。 当感光层暴露于电磁辐射时，导致曝光区域和未曝光区域的亲水或亲油性质的差异，由此得到平版印刷版，其可以安装在印刷机上并且没有任何其它印刷 治疗。
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8.发明授权Protective layer of fatty acid or nylon on photosensitive resin for metal-image forming element 失效用于金属成像元件的感光性树脂上的脂肪酸或尼龙的保护层
公开(公告)号：US4292392A
公开(公告)日：1981-09-29
申请号：US199122
申请日：1980-10-22
申请人： Tomoaki Ikeda , Fumiaki Shinozaki , Sho Nakao
发明人： Tomoaki Ikeda , Fumiaki Shinozaki , Sho Nakao
CPC分类号： G03F1/48 , Y10S430/162
摘要： A metal image-forming material comprising a support, a metal image-forming layer formed on the support and a photosensitive resin layer formed on the metal image-forming layer, with a protective layer of an organic compound (such as a higher fatty acid or an amide thereof or an alcohol-soluble nylon) further provided on the photosensitive layer resin. The photosensitive resin layer has improved scratch resistance, and good antiblocking property with respect to itself and to the surface of the support.
摘要翻译： 一种金属成像材料，包括载体，形成在载体上的金属图像形成层和形成在金属图像形成层上的感光性树脂层，具有有机化合物（例如高级脂肪酸或 其还设置在感光层树脂上的酰胺或醇溶性尼龙。 感光性树脂层具有改善的耐擦伤性，并且相对于其本身和支持体的表面具有良好的防粘连性。
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公开(公告)号：US4098712A
公开(公告)日：1978-07-04
申请号：US767875
申请日：1977-02-11
摘要： A processing solution useful for the development of or halftone dot reduction of a metal image-forming material comprising a support, a thin metallic layer composed mainly of aluminum on the support and a photosensitive resin layer on the metallic layer, with the processing solution comprising (1) an alkaline solution, such as an aqueous solution of sodium hydroxide or potassium hydroxide, and (2) at least one compound of the formula (I) or (II):m(brO.sub.3).sub.p (I)m.sub.m (IO.sub.n).sub.p (II)wherein M represents a hydrogen atom or a metal having a valence of 1 to 3, m represents 1, 2, 3, or 5, n represents 3, 4, or 6, and p represents 1, 2 or 3, which solution lends itself to safe storage and handling, and permits rapid and uniform etching of the metallic layer of the metal image-forming material without bubble formation occurring.
摘要翻译： 一种用于金属成像材料的开发或半色调点还原的处理溶液，其包括载体，在载体上主要由铝构成的薄金属层和金属层上的感光性树脂层，处理溶液包含 1）碱性溶液，例如氢氧化钠或氢氧化钾的水溶液，和（2）至少一种式（I）或（II）的化合物：
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公开(公告)号：US4115127A
公开(公告)日：1978-09-19
申请号：US776699
申请日：1977-03-11
申请人： Tomoaki Ikeda , Yuzo Mizobuchi , Akira Nahara , Yasuo Washizawa , Yoshihiro Ono , Takeshi Tomotsu
发明人： Tomoaki Ikeda , Yuzo Mizobuchi , Akira Nahara , Yasuo Washizawa , Yoshihiro Ono , Takeshi Tomotsu
CPC分类号： G03F7/0044 , G03C1/705 , Y10S430/136
摘要： A processing-free lithographic printing plate, which comprises a support having deposited thereon a composition containing germanium and sulfur and at least one of a metal or metal compound in a physically mixed state.
摘要翻译： 一种无加工的平版印刷版，其包括其上沉积有包含锗和硫的组合物以及处于物理混合状态的金属或金属化合物中的至少一种的载体。
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