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    Organic fuel cell methods and apparatus
    2.
    发明授权
    Organic fuel cell methods and apparatus 失效
    有机燃料电池的方法和装置

    公开(公告)号：US06248460B1

    公开(公告)日：2001-06-19

    申请号：US08478801

    申请日：1995-06-07

    申请人： Subbarao Surampudi ,  Sekharipuram R. Narayanan ,  Eugene Vamos ,  Harvey A. Frank ,  Gerald Halpert ,  George A. Olah ,  G. K. Surya Prakash

    发明人： Subbarao Surampudi ,  Sekharipuram R. Narayanan ,  Eugene Vamos ,  Harvey A. Frank ,  Gerald Halpert ,  George A. Olah ,  G. K. Surya Prakash

    IPC分类号： H01M810

    CPC分类号： H01M4/8605 ,  H01M4/8807 ,  H01M4/8853 ,  H01M4/921 ,  H01M4/926 ,  H01M8/0234 ,  H01M8/0239 ,  H01M8/0243 ,  H01M8/04186 ,  H01M8/1004 ,  H01M8/1009 ,  H01M8/1011 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1053 ,  H01M8/22 ,  H01M8/2455 ,  H01M2300/0082 ,  Y02E60/523

    摘要： A liquid organic fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol/water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion™. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle/Teflon™-binder structure is immersed within a Nafion™/methanol bath to impregnate the electrode with Nafion™. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electro-deposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed. New organic fuels, namely, trimethoxymethane, dimethoxymethane, and trioxane are also described for use with either conventional or improved fuel cells.

    摘要翻译： 提供一种采用固体电解质膜的液体有机燃料电池。 诸如甲醇/水混合物的有机燃料循环通过电池的阳极，同时氧气或空气循环通过电池的阴极。 电池固体电解质膜优选由Nafion TM制造。 另外，提供了一种用于改善用于有机燃料电池的碳电极结构的性能的方法，其中将高表面积碳颗粒/ Teflon TM粘合剂结构浸入Nafion TM /甲醇浴中以浸渍 电极与Nafion TM。 其中描述了一种用于制造用于有机燃料电池的阳极的方法，其中金属合金沉积在含有全氟辛烷磺酸的电沉积溶液中的电极上。 还公开了一种用于与使用硫酸电解质的燃料电池一起使用的全氟辛烷磺酸的燃料添加剂。 还描述了新的有机燃料，即三甲氧基甲烷，二甲氧基甲烷和三恶烷，用于常规或改进的燃料电池。

    Organic fuel cell methods and apparatus
    4.
    发明授权
    Organic fuel cell methods and apparatus 失效
    有机燃料电池的方法和装置

    公开(公告)号：US07445859B2

    公开(公告)日：2008-11-04

    申请号：US10857587

    申请日：2004-05-27

    申请人： Eugene Vamos ,  Subbarao Surampudi ,  Sekharipuram R. Narayanan ,  Harvey A. Frank ,  Gerald Halpert ,  George A. Olah ,  G. K. Surya Prakash

    发明人： Eugene Vamos ,  Subbarao Surampudi ,  Sekharipuram R. Narayanan ,  Harvey A. Frank ,  Gerald Halpert ,  George A. Olah ,  G. K. Surya Prakash

    IPC分类号： H01M8/08 ,  H01M8/10

    CPC分类号： H01M4/8605 ,  H01M4/8807 ,  H01M4/8853 ,  H01M4/921 ,  H01M4/926 ,  H01M8/0234 ,  H01M8/0239 ,  H01M8/0243 ,  H01M8/04186 ,  H01M8/1004 ,  H01M8/1009 ,  H01M8/1011 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1053 ,  H01M8/22 ,  H01M8/2455 ,  H01M2300/0082 ,  Y02E60/523

    摘要： A liquid organic, fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol/water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion™. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle/Teflon™-binder structure is immersed within a Nafion™/methanol bath to impregnate the electrode with Nafion™. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electro-deposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed. New organic fuels, namely, trimethoxymethane, dimethoxymethane, and trioxane are also described for use with either conventional or improved fuel cells.

    摘要翻译： 提供一种使用固体电解质膜的液体有机燃料电池。 诸如甲醇/水混合物的有机燃料循环通过电池的阳极，同时氧气或空气循环通过电池的阴极。 电池固体电解质膜优选由Nafion TM制造。 另外，提供了一种用于改善用于有机燃料电池的碳电极结构的性能的方法，其中将高表面积碳颗粒/ Teflon TM粘合剂结构浸入Nafion TM /甲醇浴中以浸渍 电极与Nafion TM。 其中描述了一种用于制造用于有机燃料电池的阳极的方法，其中金属合金沉积在含有全氟辛烷磺酸的电沉积溶液中的电极上。 还公开了一种用于与使用硫酸电解质的燃料电池一起使用的全氟辛烷磺酸的燃料添加剂。 还描述了新的有机燃料，即三甲氧基甲烷，二甲氧基甲烷和三恶烷，用于常规或改进的燃料电池。

    Organic fuel cell methods and apparatus
    5.
    发明授权
    Organic fuel cell methods and apparatus 有权
    有机燃料电池的方法和装置

    公开(公告)号：US06821659B2

    公开(公告)日：2004-11-23

    申请号：US09881309

    申请日：2001-06-13

    申请人： Subbarao Surampudi ,  Sekharipuram R. Narayanan ,  Eugene Vamos ,  Harvey A. Frank ,  Gerald Halpert ,  George A. Olah ,  G. K. Surya Prakash

    发明人： Subbarao Surampudi ,  Sekharipuram R. Narayanan ,  Eugene Vamos ,  Harvey A. Frank ,  Gerald Halpert ,  George A. Olah ,  G. K. Surya Prakash

    IPC分类号： H01M810

    CPC分类号： H01M4/8605 ,  H01M4/8807 ,  H01M4/8853 ,  H01M4/921 ,  H01M4/926 ,  H01M8/0234 ,  H01M8/0239 ,  H01M8/0243 ,  H01M8/04186 ,  H01M8/1004 ,  H01M8/1009 ,  H01M8/1011 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1053 ,  H01M8/22 ,  H01M8/2455 ,  H01M2300/0082 ,  Y02E60/523

    摘要： A liquid organic, fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol/water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion™. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle/Teflon™ binder structure is immersed within a Nafion™/methanol bath to impregnate the electrode with Nafion™. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electro-deposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed. New organic fuels, namely, trimethoxymethane, dimethoxymethane, and trioxane are also described for use with either conventional or improved fuel cells.

    摘要翻译： 提供一种使用固体电解质膜的液体有机燃料电池。 诸如甲醇/水混合物的有机燃料循环通过电池的阳极，同时氧气或空气循环通过电池的阴极。 电池固体电解质膜优选由Nafion TM制造。 此外，提供了一种用于改善用于有机燃料电池的碳电极结构的性能的方法，其中将高表面积碳颗粒/ Teflon TM粘合剂结构浸入Nafion TM /甲醇浴中以浸渍电极 与Nafion（TM）。 其中描述了一种用于制造用于有机燃料电池的阳极的方法，其中金属合金沉积在含有全氟辛烷磺酸的电沉积溶液中的电极上。 还公开了一种用于与使用硫酸电解质的燃料电池一起使用的全氟辛烷磺酸的燃料添加剂。 还描述了新的有机燃料，即三甲氧基甲烷，二甲氧基甲烷和三恶烷，用于常规或改进的燃料电池。

    Producing methanol and its products exclusively from geothermal sources and their energy
    7.
    发明授权
    Producing methanol and its products exclusively from geothermal sources and their energy 有权
    生产甲醇及其产品完全来自地热源及其能源

    公开(公告)号：US08791166B2

    公开(公告)日：2014-07-29

    申请号：US12501157

    申请日：2009-07-10

    申请人： George A. Olah ,  G. K. Surya Prakash

    发明人： George A. Olah ,  G. K. Surya Prakash

    IPC分类号： C07C27/06 ,  C25B3/00 ,  C07C4/06

    CPC分类号： C07C1/20 ,  C07C29/1518 ,  C07C41/09 ,  Y02P30/42 ,  C07C11/04 ,  C07C11/06 ,  C07C43/043 ,  C07C31/04

    摘要： The invention provides a method for producing methanol and its products exclusively from a geothermal source as the sole source material also using the needed energy from the geothermal energy source. The method includes separating or isolating carbon dioxide accompanying hot water or steam of the source, generating hydrogen from the water and subsequently preparing methanol from the carbon dioxide and hydrogen. The methanol can be further converted into dimethyl ether or other products.

    摘要翻译： 本发明提供了一种仅从地热源生产甲醇及其产品的方法，作为唯一的源材料，也使用来自地热能​​源的所需能量。 该方法包括分离或分离伴随热水或源自蒸汽的二氧化碳，从水中产生氢气，随后从二氧化碳和氢气中制备甲醇。 甲醇可进一步转化为二甲醚或其他产品。

    Electrolysis of carbon dioxide in aqueous media to carbon monoxide and hydrogen for production of methanol
    8.
    发明授权
    Electrolysis of carbon dioxide in aqueous media to carbon monoxide and hydrogen for production of methanol 有权
    将水性介质中的二氧化碳电解为一氧化碳和氢气用于生产甲醇

    公开(公告)号：US08138380B2

    公开(公告)日：2012-03-20

    申请号：US12754952

    申请日：2010-04-06

    申请人： George A. Olah ,  G. K. Surya Prakash

    发明人： George A. Olah ,  G. K. Surya Prakash

    IPC分类号： C07C27/10 ,  C07C29/00 ,  C25B1/00 ,  C25B1/02 ,  C25B3/00 ,  C25C1/02

    CPC分类号： C07C29/1518 ,  C25B1/00 ,  C25B1/04 ,  C25B3/04 ,  Y02E60/366 ,  Y02P20/134 ,  C07C31/04

    摘要： An environmentally beneficial method of producing methanol from varied sources of carbon dioxide including flue gases of fossil fuel burning power plants, industrial exhaust gases or the atmosphere itself. Converting carbon dioxide by an electrochemical reduction of carbon dioxide in a divided electrochemical cell that includes an anode in one compartment and a metal cathode electrode in a compartment that also contains an aqueous solution comprising methanol and an electrolyte. An anion-conducting membrane can be provided between the anode and cathode to produce at the cathode therein a reaction mixture containing carbon monoxide and hydrogen, which can be subsequently used to produce methanol while also producing oxygen in the cell at the anode. The oxygen produced at the anode can be recycled for efficient combustion of fossil fuels in power plants to exclusively produce CO2 exhausts for capture and recycling as the source of CO2 for the cell.

    摘要翻译： 一种从不同来源的二氧化碳生产甲醇的环境有益的方法，包括燃烧发电厂的废气，工业废气或大气本身。 通过在分隔的电化学电池中电化学还原二氧化碳来转化二氧化碳，该电化学电池包括一个隔室中的阳极和室中还包含含有甲醇和电解质的水溶液的金属阴极电极。 可以在阳极和阴极之间提供阴离子导电膜，以在其阴极处产生含有一氧化碳和氢气的反应混合物，其随后用于产生甲醇，同时在阳极中的电池中产生氧气。 在阳极产生的氧气可以再循环，以便在发电厂中有效地燃烧化石燃料，专门生产用于捕获和再循环的二氧化碳排放物，作为电池的二氧化碳源。