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公开(公告)号:US11342545B2
公开(公告)日:2022-05-24
申请号:US16706331
申请日:2019-12-06
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Jeffrey D. Cain , Andrew C. Bobel , Nicholas P. Pieczonka , Robert D. Schmidt , Anil K. Sachdev , Mark W. Verbrugge
IPC: H01M4/04 , H01M4/1391 , H01M10/0525
Abstract: The present disclosure relates to electroactive materials for use in electrodes of lithium-ion electrochemical cells and methods of making the same, for example, methods for lithiating electroactive materials. A method of lithiating an electroactive material may include dispersing an electroactive material precursor within a room-temperature electrolyte that includes a lithium-based salt and contacting the electrolyte mixture and a lithium source so as to cause the lithium source to ionize and form lithium ions. The lithium ions may react with the electroactive material precursor to form a fully lithiated electroactive material (e.g., greater than 70% of total lithiation). The method further includes, in certain aspects, electrochemically discharging the fully lithiated electroactive material to form a lithiated electroactive material having an optimized lithiation state (e.g., less than or equal to about 40% of a first lithiation state of the fully lithiated electroactive material).
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公开(公告)号:US20220020974A1
公开(公告)日:2022-01-20
申请号:US16928052
申请日:2020-07-14
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Thomas A. Yersak , Fan Xu , Robert D. Schmidt , Biqiong Wang
Abstract: A separator includes a porous polymeric separator having an anode side and a cathode side, a cathode-compatible material applied to the cathode side, wherein the cathode-compatible material comprises a polymeric binder and one or more of lithium aluminum titanium phosphate (LATP) particles, lithium lanthanum titanate (LLTO) particles, lithium aluminum germanium phosphate (LAGP) particles, and lithium superionic conductor (LISICON) particles, and an anode-compatible material applied to the anode side, wherein the anode-compatible material comprises lithium lanthanum zirconium oxide (LLZO) particles and a polymeric binder. The polymeric binder of the cathode-compatible material can be polyvinylidene fluoride and the polymeric binder of the anode-compatible material can be polyvinylidene. The polymeric binder of the cathode-compatible material the anode-compatible material can be the polymeric separator. The LLZO particles and the one or more of LATP, LLTO, LAGP, and LISICON particles can have an average particle size of 10 nm to 10 μm.
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公开(公告)号:US11094996B2
公开(公告)日:2021-08-17
申请号:US16575143
申请日:2019-09-18
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Xingcheng Xiao , Robert D. Schmidt
IPC: H01M50/403 , H01M4/1393 , H01M4/36 , H01M4/04 , H01M50/449
Abstract: A method of modifying a carbonate layer formed on a surface of an electrochemical cell component is provided. The surface includes a ceramic oxide. The carbonate layer includes a carbonate and is substantially non-conductive to lithium ions and sodium ions. The method includes contacting the carbonate layer with a modifying agent to form a mixture and causing the modifying agent to incorporate into the carbonate layer and form a modified hybrid layer including a eutectic mixture of the modifying agent and the carbonate. The modified hybrid layer is conductive to lithium ions and sodium ions.
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公开(公告)号:US12148897B2
公开(公告)日:2024-11-19
申请号:US17160553
申请日:2021-01-28
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Jing Gao , Brian J. Koch , Gayatri V. Dadheech , Mark W. Verbrugge , Alok Warey , James R. Salvador , Robert D. Schmidt
IPC: H01M10/48 , G01R31/389 , G01R31/392 , H01M10/0525 , H01M10/0585 , H01M10/42
Abstract: A monitoring assembly for an electrochemical cell of a secondary lithium battery includes a porous sensory structure and a transducer. The porous sensory structure includes a sensory layer disposed on a major surface of a porous separator and a buffer layer disposed between the sensory layer and a facing surface of a negative electrode layer. The buffer layer electrically isolates the sensory layer from the facing surface of the negative electrode layer. The sensory layer includes an electrically conductive material and is configured to produce a response to an input signal or to a physical stimulus received within the electrochemical cell. The transducer is configured to process the response produced by the sensory layer to generate an output signal indicative of a diagnostic condition within the electrochemical cell.
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公开(公告)号:US20220238932A1
公开(公告)日:2022-07-28
申请号:US17160553
申请日:2021-01-28
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Jing Gao , Brian J. Koch , Gayatri V. Dadheech , Mark W. Verbrugge , Alok Warey , James R. Salvador , Robert D. Schmidt
IPC: H01M10/48 , H01M10/0525 , H01M10/42
Abstract: A monitoring assembly for an electrochemical cell of a secondary lithium battery includes a porous sensory structure and a transducer. The porous sensory structure includes a sensory layer disposed on a major surface of a porous separator and a buffer layer disposed between the sensory layer and a facing surface of a negative electrode layer. The buffer layer electrically isolates the sensory layer from the facing surface of the negative electrode layer. The sensory layer includes an electrically conductive material and is configured to produce a response to an input signal or to a physical stimulus received within the electrochemical cell. The transducer is configured to process the response produced by the sensory layer to generate an output signal indicative of a diagnostic condition within the electrochemical cell.
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公开(公告)号:US20240413386A1
公开(公告)日:2024-12-12
申请号:US18330649
申请日:2023-06-07
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Xingcheng Xiao , Robert D. Schmidt , Yifan Zhao
IPC: H01M10/0562
Abstract: A method to create a garnet-based solid electrolyte separator for a battery cell is provided. The method includes coating a garnet-based material powder, initially including a lithium carbonate layer upon an outer surface of the garnet-based material powder, with aluminum fluoride to create a fluoride-treated garnet-based material powder. The method further includes operating a solid-state reaction upon the fluoride-treated garnet-based material powder, such that the aluminum fluoride reacts with the lithium carbonate layer to create aluminum oxide, carbon dioxide, and lithium fluoride. The solid-state reaction creates a fluoride-treated and solid-state reacted garnet-based material powder including the aluminum oxide and the lithium fluoride. The method further includes sintering the fluoride-treated and solid-state reacted garnet-based material powder including the aluminum oxide and the lithium fluoride. The sintering includes applying pressure upon the fluoride-treated and solid-state reacted garnet-based material powder to densify the powder and create the separator.
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公开(公告)号:US20240204284A1
公开(公告)日:2024-06-20
申请号:US18085050
申请日:2022-12-20
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Shuonan Xu , Neeraj S. Shidore , Robert D. Schmidt , Steven Earl Muldoon , Chandra S. Namuduri , Robert D. Drexler , Antonio Duaine Ulisse
IPC: H01M10/615 , G01R31/389 , H01M10/48 , H01M10/63 , H01M10/657
CPC classification number: H01M10/615 , G01R31/389 , H01M10/486 , H01M10/63 , H01M10/657
Abstract: A device for thermal control of a battery system includes a heating control module configured to generate an alternating current (AC) heating current and heat the battery system to a desired temperature by applying the AC heating current to the battery system over a selected heating time duration. The heating control module is configured to monitor a rate of increase of a temperature of the battery system during the applying, during the heating time duration, perform a periodic impedance measurement, the periodic impedance measurement including application of a measurement signal having a selected frequency range to the battery system for a measurement period, a length of the measurement period select to minimize a difference between a desired rate of increase and the monitored rate of increase, and adjust the AC heating current during the applying based on the temperature and the impedance measurement.
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公开(公告)号:US11728490B2
公开(公告)日:2023-08-15
申请号:US17237418
申请日:2021-04-22
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Robert D. Schmidt , Gayatri V. Dadheech
IPC: H01M4/66 , H01M10/0562 , H01M10/0525
CPC classification number: H01M4/667 , H01M10/0525 , H01M10/0562 , H01M2220/20 , H01M2300/008 , H01M2300/0071
Abstract: The present disclosure provides an electrochemical cell that includes an electrically conductive material layer, a precursor material disposed on or adjacent to a first surface of the electrically conductive material layer, and an electroactive material layer disposed on or adjacent to the precursor material. In certain variations, the precursor material forms a continuous layer and a solid-electrolyte interface layer is disposed on or adjacent to an exposed surface of the electroactive material layer. In other variations, the precursor material forms a plurality of distinct precursor structures disposed on the first surface of the electrically conductive material layer in a predetermined pattern, such that at least a portion of each distinct precursor structure is unobstructed by the electroactive material layer. The distinct precursor structures are configured to form surface structures that chemically attach the solid-electrolyte interface layer and the electrically conductive material layer.
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