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1.发明授权公开(公告)号：US09051229B2
公开(公告)日：2015-06-09
申请号：US13725595
申请日：2012-12-21
IPC分类号： C07C1/22 , B01J31/18 , C07C1/20 , C07C1/247 , C07B31/00 , C07C37/055 , C07C41/26 , C07C41/18
CPC分类号： C07C1/22 , B01J31/188 , B01J2231/64 , B01J2531/0216 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07B31/00 , C07C1/20 , C07C1/247 , C07C37/055 , C07C41/18 , C07C41/26 , C07C2531/12 , C07C2531/14 , C07C2531/18 , C07C2601/10 , C07C2601/20 , Y02P20/52 , C07C39/04 , C07C43/23 , C07C43/205 , C07C43/275 , C07C15/46 , C07C13/275 , C07C15/04 , C07C15/14 , C07C15/24 , C07C15/16 , C07C13/21 , C07C15/02 , C07C13/12 , C07C13/15
摘要： Phosphoranimide-metal catalysts and their role in C—O bond hydrogenolysis and hydrodeoxygenation (HDO) are disclosed. The catalysts comprise of first row transition metals such as nickel, cobalt and iron. The catalysts have a metal to anionic phosphoranimide ratio of 1:1 and catalyze C—O bond hydrogenolyses of a range of oxygen-containing organic compounds under lower temperature and pressure conditions than those commonly used in industrial hydrodeoxygenation.
摘要翻译： 公开了磷酰亚胺 - 金属催化剂及其在C-O键氢解和加氢脱氧（HDO）中的作用。 催化剂由第一排过渡金属如镍，钴和铁组成。 催化剂的金属对阴离子磷酰亚胺的比例为1:1，并且在较低温度和压力条件下催化一系列含氧有机化合物的C-O键氢解比通常用于工业加氢脱氧。
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公开(公告)号：US09120984B2
公开(公告)日：2015-09-01
申请号：US13725547
申请日：2012-12-21
CPC分类号： C10G45/06 , B01J31/189 , C10G45/04 , C10G49/04
摘要： Phosphoranimide-metal catalysts and their role in hydrodesulfurization are disclosed. The catalysts comprise of first row transition metals such as nickel, cobalt and iron. The catalysts have a metal to anionic phosphoranimide ratio of 1:1 and catalyze hydrodesulfurization of a range of sulfur-containing organic compounds under lower temperature and pressure conditions than those commonly used in industrial hydrodesulfurization.
摘要翻译： 公开了磷酰亚胺金属催化剂及其在加氢脱硫中的作用。 催化剂由第一排过渡金属如镍，钴和铁组成。 催化剂的金属对阴离子磷酰亚胺比为1:1，催化剂在较低温度和压力条件下的一系列含硫有机化合物的加氢脱硫比工业加氢脱硫常用的那些。
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公开(公告)号：US08901334B2
公开(公告)日：2014-12-02
申请号：US13725676
申请日：2012-12-21
CPC分类号： C07F15/065 , B01J31/188 , B01J31/189 , B01J2231/641 , B01J2231/645 , B01J2531/0216 , B01J2531/0222 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C1/322 , C07C5/08 , C07C2531/28 , C07F15/025 , C07F15/045 , C07C15/18 , C07C15/14
摘要： Phosphoranimide-metal catalysts are disclosed. The catalysts comprise first row transition metals such as nickel, cobalt or iron. The hydrocarbon-soluble catalysts have a metal to anionic phosphoranimide ratio of 1:1, have no inactive bulk phase and no dative ancillary ligands, and are active for a range of commercially important reductive transformations. A method of synthesis of these catalysts by reduction of a precursor of these catalysts is also disclosed.
摘要翻译： 公开了磷酰亚胺金属催化剂。 催化剂包括第一排过渡金属如镍，钴或铁。 烃溶性催化剂的金属对阴离子磷酰亚胺的比例为1:1，没有非活性的本体相，没有配位辅助配体，并且在一系列商业上重要的还原转化中是有活性的。 还公开了通过还原这些催化剂的前体合成这些催化剂的方法。
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公开(公告)号：US09120741B2
公开(公告)日：2015-09-01
申请号：US13725735
申请日：2012-12-21
IPC分类号： C07F9/44 , C07C67/283 , C07C29/17 , C07C5/03 , C07C5/08 , C07B31/00 , C07B35/02 , C07C29/143 , C07F7/08 , C07C5/09
CPC分类号： C07C67/283 , B01J31/188 , B01J2231/323 , B01J2231/643 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07B31/00 , C07B35/02 , C07C5/03 , C07C5/08 , C07C5/09 , C07C29/143 , C07C29/17 , C07C29/172 , C07C2531/18 , C07C2531/28 , C07C2601/18 , C07F7/0829 , C07C69/78 , C07C35/20 , C07C33/20 , C07C15/02 , C07C15/18 , C07C15/52
摘要： Phosphoranimide-metal catalysts and their role in hydrogenation and hydrosilylation are disclosed. The catalysts comprise first row transition metals such as nickel, cobalt or iron. The catalysts have a metal to anionic phosphoranimide ratio of 1:1. This disclosure presents a process for catalytic hydrogenation and hydrosilylation of a range of unsaturated organic compounds under lower temperature and pressure conditions than conditions associated with industrial hydrogenation and hydrosilylation.
摘要翻译： 公开了磷酰亚胺 - 金属催化剂及其在氢化和氢化硅烷化中的作用。 催化剂包括第一排过渡金属如镍，钴或铁。 催化剂的金属对阴离子磷酰亚胺的比例为1:1。 本公开内容提供了在较低温度和压力条件下，与工业氢化和氢化硅烷化相关的条件下一系列不饱和有机化合物的催化氢化和氢化硅烷化的方法。
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5.发明申请公开(公告)号：US20140179954A1
公开(公告)日：2014-06-26
申请号：US13725595
申请日：2012-12-21
CPC分类号： C07C1/22 , B01J31/188 , B01J2231/64 , B01J2531/0216 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07B31/00 , C07C1/20 , C07C1/247 , C07C37/055 , C07C41/18 , C07C41/26 , C07C2531/12 , C07C2531/14 , C07C2531/18 , C07C2601/10 , C07C2601/20 , Y02P20/52 , C07C39/04 , C07C43/23 , C07C43/205 , C07C43/275 , C07C15/46 , C07C13/275 , C07C15/04 , C07C15/14 , C07C15/24 , C07C15/16 , C07C13/21 , C07C15/02 , C07C13/12 , C07C13/15
摘要： Phosphoranimide-metal catalysts and their role in C—O bond hydrogenolysis and hydrodeoxygenation (HDO) are disclosed. The catalysts comprise of first row transition metals such as nickel, cobalt and iron. The catalysts have a metal to anionic phosphoranimide ratio of 1:1 and catalyze C—O bond hydrogenolyses of a range of oxygen-containing organic compounds under lower temperature and pressure conditions than those commonly used in industrial hydrodeoxygenation.
摘要翻译： 公开了磷酰亚胺 - 金属催化剂及其在C-O键氢解和加氢脱氧（HDO）中的作用。 催化剂由第一排过渡金属如镍，钴和铁组成。 催化剂的金属对阴离子磷酰亚胺的比例为1:1，并且在较低温度和压力条件下催化一系列含氧有机化合物的C-O键氢解比通常用于工业加氢脱氧。
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公开(公告)号：US20140174989A1
公开(公告)日：2014-06-26
申请号：US13725547
申请日：2012-12-21
IPC分类号： C10G45/06
CPC分类号： C10G45/06 , B01J31/189 , C10G45/04 , C10G49/04
摘要： Phosphoranimide-metal catalysts and their role in hydrodesulfurization are disclosed. The catalysts comprise of first row transition metals such as nickel, cobalt and iron. The catalysts have a metal to anionic phosphoranimide ratio of 1:1 and catalyze hydrodesulfurization of a range of sulfur-containing organic compounds under lower temperature and pressure conditions than those commonly used in industrial hydrodesulfurization.
摘要翻译： 公开了磷酰亚胺金属催化剂及其在加氢脱硫中的作用。 催化剂由第一排过渡金属如镍，钴和铁组成。 催化剂的金属对阴离子磷酰亚胺比为1:1，催化剂在较低温度和压力条件下的一系列含硫有机化合物的加氢脱硫比工业加氢脱硫常用的那些。
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