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    Chiral phosphorous compounds
    5.
    发明授权
    Chiral phosphorous compounds 失效
    手性磷化合物

    公开(公告)号：US08067642B2

    公开(公告)日：2011-11-29

    申请号：US12593292

    申请日：2008-03-28

    申请人： Graham R. Cumming ,  Declan Gilheany ,  Gary King ,  Matthias Voegler ,  Vladimir Larichev

    发明人： Graham R. Cumming ,  Declan Gilheany ,  Gary King ,  Matthias Voegler ,  Vladimir Larichev

    IPC分类号： C07F9/92

    CPC分类号： B01J31/2409 ,  B01J2231/645 ,  B01J2531/821 ,  B01J2531/822 ,  C07B2200/07 ,  C07C67/283 ,  C07C231/12 ,  C07F9/5027 ,  C07F15/0066 ,  C07C69/007 ,  C07C233/51 ,  C07C69/157

    摘要： The present invention provides P-chiral compounds of general formulae (II) and (III): in formula (II) at least one of R21, R25, R26 and R30 is independently selected from CM alkyl, CF3, C1-4 alkoxy, phenyl and benzyloxy and the remaining substituents selected from R21, R25, R26 and R30 are hydrogen; at least one of R22, R24, R27 and R29 are independently selected from C1-14 alkyl, CF3, C1-14 alkoxy, phenyl and benzyloxy and the remaining substituents selected, from R22, R24, R27 and R29 are hydrogen; and R23 and R28 are independently selected from hydrogen, CM alkyl, CF3, C1-14 alkoxy, phenyl and benzyloxy; in formula (III) at least one of R21, R25, R26 and R30 is independently selected from phenyl and benzyloxy and the remaining substituents selected from R21, R25, R−26 and R30 are hydrogen; and R22, R−23 R24, R27, R28 and R29 are independently selected from hydrogen, C1-14 alkyl, CF3, C1-14 alkoxy, phenyl and benzyloxy.

    摘要翻译： 本发明提供通式（II）和（III）的P-手性化合物：在式（II）中，R 21，R 25，R 26和R 30中的至少一个独立地选自CM烷基，CF 3，C 1-4烷氧基，苯基 和苄氧基，剩余的选自R 21，R 25，R 26和R 30的取代基是氢; R 22，R 24，R 27和R 29中的至少一个独立地选自C 1-14烷基，CF 3，C 1-14烷氧基，苯基和苄氧基，并且选自R 22，R 24，R 27和R 29的其余取代基是氢; R 23和R 28独立地选自氢，C 1-4烷基，CF 3，C 1-14烷氧基，苯基和苄氧基; 在式（III）中，R 21，R 25，R 26和R 30中的至少一个独立地选自苯基和苄氧基，其余的选自R 21，R 25，R 26和R 30的取代基是氢; R 22，R 23，R 24，R 27，R 28和R 29独立地选自氢，C 1-14烷基，CF 3，C 1-14烷氧基，苯基和苄氧基。

    Co-production of vinyl acetate and ethyl acetate
    7.
    发明授权
    Co-production of vinyl acetate and ethyl acetate 失效
    共同生产乙酸乙烯酯和乙酸乙酯

    公开(公告)号：US07700801B2

    公开(公告)日：2010-04-20

    申请号：US10988683

    申请日：2004-11-15

    申请人： R. Jay Warner ,  J. Alfonso Torres

    发明人： R. Jay Warner ,  J. Alfonso Torres

    IPC分类号： C07C67/00

    CPC分类号： C07C67/055 ,  B01J23/44 ,  B01J25/02 ,  C07C67/283 ,  C07C69/01 ,  C07C69/14 ,  C07C69/15

    摘要： A method of co-producing vinyl acetate and ethyl acetate includes: (a) reacting ethylene, acetic acid and oxygen to form vinyl acetate and at least a minor amount of ethyl acetate; (b) providing a crude product stream containing the vinyl acetate and ethyl acetate of step (a) and acetic acid to a distillation tower; (c) separating the crude product stream into: (i) a vinyl acetate product stream enriched in vinyl acetate with respect to the crude product stream; (ii) an acid recycle stream enriched in acetic acid with respect to the crude product stream; (iii) a mixed sidestream containing vinyl acetate and ethyl acetate, the mixed sidestream being enriched in ethyl acetate with respect to the vinyl acetate product stream; and (d) hydrogenating vinyl acetate in the mixed sidestream to provide an ethyl acetate product stream.

    摘要翻译： 共同生产乙酸乙烯酯和乙酸乙酯的方法包括：（a）使乙烯，乙酸和氧反应形成乙酸乙烯酯和至少少量的乙酸乙酯; （b）向蒸馏塔提供含有步骤（a）的乙酸乙烯酯和乙酸乙酯和乙酸的粗产物流; （c）将粗产物流分离成：（i）相对于粗产物流富含乙酸乙烯酯的乙酸乙烯酯产物流; （ii）相对于粗产物流富含乙酸的酸循环物流; （iii）含乙酸乙烯酯和乙酸乙酯的混合侧流，混合侧流相对于乙酸乙烯酯产物流富含乙酸乙酯; 和（d）在混合侧流中加氢乙酸乙烯酯以提供乙酸乙酯产物流。

    Co-production of vinyl acetate and ethyl acetate
    9.
    发明申请
    Co-production of vinyl acetate and ethyl acetate 失效
    共同生产乙酸乙烯酯和乙酸乙酯

    公开(公告)号：US20060106246A1

    公开(公告)日：2006-05-18

    申请号：US10988683

    申请日：2004-11-15

    申请人： R. Warner ,  J. Torres

    发明人： R. Warner ,  J. Torres

    IPC分类号： C07C67/05 ,  B01J19/00

    CPC分类号： C07C67/055 ,  B01J23/44 ,  B01J25/02 ,  C07C67/283 ,  C07C69/01 ,  C07C69/14 ,  C07C69/15

    摘要： A method of co-producing vinyl acetate and ethyl acetate includes: (a) reacting ethylene, acetic acid and oxygen to form vinyl acetate and at least a minor amount of ethyl acetate; (b) providing a crude product stream containing the vinyl acetate and ethyl acetate of step (a) and acetic acid to a distillation tower; (c) separating the crude product stream into: (i) a vinyl acetate product stream enriched in vinyl acetate with respect to the crude product stream; (ii) an acid recycle stream enriched in acetic acid with respect to the crude product stream; (iii) a mixed sidestream containing vinyl acetate and ethyl acetate, the mixed sidestream being enriched in ethyl acetate with respect to the vinyl acetate product stream; and (d) hydrogenating vinyl acetate in the mixed sidestream to provide an ethyl acetate product stream.

    摘要翻译： 共同生产乙酸乙烯酯和乙酸乙酯的方法包括：（a）使乙烯，乙酸和氧反应形成乙酸乙烯酯和至少少量的乙酸乙酯; （b）向蒸馏塔提供含有步骤（a）的乙酸乙烯酯和乙酸乙酯和乙酸的粗产物流; （c）将粗产物流分离成：（i）相对于粗产物流富含乙酸乙烯酯的乙酸乙烯酯产物流; （ii）相对于粗产物流富含乙酸的酸循环物流; （iii）含乙酸乙烯酯和乙酸乙酯的混合侧流，混合侧流相对于乙酸乙烯酯产物流富含乙酸乙酯; 和（d）在混合侧流中加氢乙酸乙烯酯以提供乙酸乙酯产物流。