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公开(公告)号：US07678361B2
公开(公告)日：2010-03-16
申请号：US10553312
申请日：2004-03-31
申请人： Georg Markowz , Johannes Albrecht , Johannes Ehrlich , Michael Jucys , Elias Klemm , Armin Lange De Oliveira , Reinhard Machnik , Juergen Rapp , Ruediger Schuette , Steffen Schirrmeister , Olaf Von Morstein , Hartmut Hederer , Martin Schmitz-Niederau
发明人： Georg Markowz , Johannes Albrecht , Johannes Ehrlich , Michael Jucys , Elias Klemm , Armin Lange De Oliveira , Reinhard Machnik , Juergen Rapp , Ruediger Schuette , Steffen Schirrmeister , Olaf Von Morstein , Hartmut Hederer , Martin Schmitz-Niederau
IPC分类号： B01J19/24 , C01B15/029 , C07C27/00 , C07C27/12 , C07C39/04 , C07C27/06 , C07D301/12
CPC分类号： B01F5/0471 , B01F13/0059 , B01F2005/0034 , B01J19/0093 , B01J2219/00783 , B01J2219/00835 , B01J2219/0086 , B01J2219/00889
摘要： The present invention discloses a microreactor for performing heterogeneous catalytic reactions, being of plate or stack construction for industrial use, with provision made for chambers between the plates for the chemical reaction and for the heat removal. Inside the reaction chambers, catalyst material is applied to the internal walls or filled into recesses, and in all chambers there are spacers. In particular the slot-shaped reaction chambers have channels with a hydraulic diameter smaller than 1500 μm and a ratio of free slot width to free slot height in the range of 10 to 450.
摘要翻译： 本发明公开了一种用于进行非均相催化反应的微反应器，它是用于工业应用的板或堆叠结构，为用于化学反应和排热的板之间的室提供。 在反应室内部，将催化剂材料施加到内壁或填充到凹部中，并且在所有室中都存在间隔物。 特别地，槽形反应室具有水力直径小于1500μm的通道，并且自由槽宽度与自由槽高度的比率在10至450的范围内。
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公开(公告)号：US20070053808A1
公开(公告)日：2007-03-08
申请号：US10553312
申请日：2004-03-31
申请人： Georg Markowz , Johannes Albrecht , Johannes Ehrlich , Michael Jucys , Elias Klemm , Armin Oliveira , Reinhard Machnik , Juergen Rapp , Ruediger Schuette , Steffen Schirrmeister , Olaf Morstein , Hartmut Hederer , Martin Schmitz-Niederau
发明人： Georg Markowz , Johannes Albrecht , Johannes Ehrlich , Michael Jucys , Elias Klemm , Armin Oliveira , Reinhard Machnik , Juergen Rapp , Ruediger Schuette , Steffen Schirrmeister , Olaf Morstein , Hartmut Hederer , Martin Schmitz-Niederau
CPC分类号： B01F5/0471 , B01F13/0059 , B01F2005/0034 , B01J19/0093 , B01J2219/00783 , B01J2219/00835 , B01J2219/0086 , B01J2219/00889
摘要： The present invention discloses a microreactor for performing heterogeneous catalytic reactions, being of plate or stack construction for industrial use, with provision made for chambers between the plates for the chemical reaction and for the heat removal. Inside the reaction chambers, catalyst material is applied to the internal walls or filled into recesses, and in all chambers there are spacers. In particular the slot-shaped reaction chambers have channels with a hydraulic diameter smaller than 1500 μm and a ratio of free slot width to free slot height in the range of 10 to 450.
摘要翻译： 本发明公开了一种用于进行非均相催化反应的微反应器，它是用于工业应用的板或堆叠结构，为用于化学反应和排热的板之间的室提供。 在反应室内部，将催化剂材料施加到内壁或填充到凹部中，并且在所有室中都存在间隔物。 特别地，槽形反应室具有液压直径小于1500μm的通道，并且自由槽宽度与自由槽高度的比率在10至450的范围内。
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3.发明申请Catalyst-Coated Support, Method For Producing The Same, Reactor Comprising The Same And Use Thereof 有权催化剂涂层支撑，其生产方法，反应器包括它和使用它公开(公告)号：US20080286176A1
公开(公告)日：2008-11-20
申请号：US11912031
申请日：2006-04-18
申请人： Steffen Schirmeister , Karsten Bueker , Martin Schmitz-Niederau , Bernd Langanke , Andreas Geisselmann , Georg Markowz , Klaus Thomas Schwarz , Elias Johannes Klemm , Frank Becker , Reinhard Machnik
发明人： Steffen Schirmeister , Karsten Bueker , Martin Schmitz-Niederau , Bernd Langanke , Andreas Geisselmann , Georg Markowz , Klaus Thomas Schwarz , Elias Johannes Klemm , Frank Becker , Reinhard Machnik
IPC分类号： B01J19/00 , B01J27/198 , B01J23/54 , B01J23/28 , B01J23/30 , B01J23/745 , B01J23/75 , B01J23/72 , B01J23/50 , B01J21/00
CPC分类号： B01J15/005 , B01J19/0093 , B01J19/249 , B01J23/002 , B01J23/52 , B01J29/89 , B01J35/1066 , B01J35/108 , B01J37/0215 , B01J37/0217 , B01J37/0226 , B01J2219/00783 , B01J2219/00835 , B01J2219/00873 , B01J2219/2453 , B01J2219/2458 , B01J2219/2462 , B01J2219/2479 , B01J2219/2497 , B01J2523/00 , C07C51/265 , C07C51/313 , Y10T428/249953 , C07C63/16 , B01J2523/19 , B01J2523/41 , B01J2523/824
摘要： Supports having a catalytic coating comprising at least one porous and cavity-containing catalyst layer are described, cavities being irregular spaces having dimensions greater than 5 μm in at least two dimensions or having cross-sectional areas of at least 10 μm2.The catalytic coatings are distinguished by a high adhesive strength and can preferably be used in microreactors.
摘要翻译： 描述了具有包含至少一个多孔和含空腔的催化剂层的催化涂层的载体，空腔是在至少两个维度上具有大于5um的尺寸的不规则空间或具有至少10mum 2的横截面积< / SUP>。 催化涂层的特征在于高粘合强度，并且可优选用于微反应器。
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4.发明申请CATALYST-COATED SUPPORT, METHOD FOR PRODUCING THE SAME, REACTOR COMPRISING THE SAME AND USE THEREOF 有权催化涂层支持物，其制造方法，包含该催化剂的反应器及其用途公开(公告)号：US20120039775A1
公开(公告)日：2012-02-16
申请号：US13156814
申请日：2011-06-09
申请人： Steffen Schirmeister , Karsten Büker , Martin Schmitz-Niederau , Bernd Langanke , Andreas Geisselmann , Georg Markowz , Klaus Thomas Schwarz , Elias Johannes Klemm , Frank Becker , Reinhard Machnik
发明人： Steffen Schirmeister , Karsten Büker , Martin Schmitz-Niederau , Bernd Langanke , Andreas Geisselmann , Georg Markowz , Klaus Thomas Schwarz , Elias Johannes Klemm , Frank Becker , Reinhard Machnik
CPC分类号： B01J15/005 , B01J19/0093 , B01J19/249 , B01J23/002 , B01J23/52 , B01J29/89 , B01J35/1066 , B01J35/108 , B01J37/0215 , B01J37/0217 , B01J37/0226 , B01J2219/00783 , B01J2219/00835 , B01J2219/00873 , B01J2219/2453 , B01J2219/2458 , B01J2219/2462 , B01J2219/2479 , B01J2219/2497 , B01J2523/00 , C07C51/265 , C07C51/313 , Y10T428/249953 , C07C63/16 , B01J2523/19 , B01J2523/41 , B01J2523/824
摘要： Supports having a catalytic coating comprising at least one porous and cavity-containing catalyst layer are described, cavities being irregular spaces having dimensions greater than 5 μm in at least two dimensions or having cross-sectional areas of at least 10 μm2.The catalytic coatings are distinguished by a high adhesive strength and can preferably be used in microreactors.
摘要翻译： 描述了具有包含至少一个多孔和含空腔的催化剂层的催化涂层的载体，空腔是具有至少两个维度的尺寸大于5μm或具有至少10μm的横截面积的尺寸的不规则空间。 催化涂层的特征在于高粘合强度，并且可优选用于微反应器。
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5.发明授权Catalyst-coated support, method for producing the same, reactor comprising the same and use thereof 有权催化剂涂覆的载体，其制备方法，包含该载体的反应器及其用途公开(公告)号：US08227034B2
公开(公告)日：2012-07-24
申请号：US13156814
申请日：2011-06-09
申请人： Steffen Schirmeister , Karsten Bueker , Martin Schmitz-Niederau , Bernd Langanke , Andreas Geisselmann , Georg Markowz , Klaus Thomas Schwarz , Elias Johannes Klemm , Frank Becker , Reinhard Machnik
发明人： Steffen Schirmeister , Karsten Bueker , Martin Schmitz-Niederau , Bernd Langanke , Andreas Geisselmann , Georg Markowz , Klaus Thomas Schwarz , Elias Johannes Klemm , Frank Becker , Reinhard Machnik
CPC分类号： B01J15/005 , B01J19/0093 , B01J19/249 , B01J23/002 , B01J23/52 , B01J29/89 , B01J35/1066 , B01J35/108 , B01J37/0215 , B01J37/0217 , B01J37/0226 , B01J2219/00783 , B01J2219/00835 , B01J2219/00873 , B01J2219/2453 , B01J2219/2458 , B01J2219/2462 , B01J2219/2479 , B01J2219/2497 , B01J2523/00 , C07C51/265 , C07C51/313 , Y10T428/249953 , C07C63/16 , B01J2523/19 , B01J2523/41 , B01J2523/824
摘要： Catalyst-coated support, method for producing the same, reactor comprising the same and use thereof. Supports having a catalytic coating comprising at least one porous and cavity-containing catalyst layer are described, cavities being irregular spaces having dimensions greater than 5 μm in at least two dimensions or having cross-sectional areas of at least 10 μm2. The catalytic coatings are distinguished by a high adhesive strength and can preferably be used in microreactors.
摘要翻译： 催化剂涂覆的载体，其制备方法，包含该载体的反应器及其用途。 描述了具有包含至少一个多孔和含空腔的催化剂层的催化涂层的载体，空腔是具有至少两个维度的尺寸大于5μm或具有至少10μm的横截面积的尺寸的不规则空间。 催化涂层的特征在于高粘合强度，并且可优选用于微反应器。
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6.发明授权Catalyst-coated support, method for producing the same, reactor comprising the same and use thereof 有权催化剂涂覆的载体，其制备方法，包含该载体的反应器及其用途公开(公告)号：US07981830B2
公开(公告)日：2011-07-19
申请号：US11912031
申请日：2006-04-18
申请人： Steffen Schirmeister , Karsten Büker , Martin Schmitz-Niederau , Bernd Langanke , Andreas Geisselmann , Georg Markowz , Klaus Thomas Schwarz , Elias Johannes Klemm , Frank Becker , Reinhard Machnik
发明人： Steffen Schirmeister , Karsten Büker , Martin Schmitz-Niederau , Bernd Langanke , Andreas Geisselmann , Georg Markowz , Klaus Thomas Schwarz , Elias Johannes Klemm , Frank Becker , Reinhard Machnik
CPC分类号： B01J15/005 , B01J19/0093 , B01J19/249 , B01J23/002 , B01J23/52 , B01J29/89 , B01J35/1066 , B01J35/108 , B01J37/0215 , B01J37/0217 , B01J37/0226 , B01J2219/00783 , B01J2219/00835 , B01J2219/00873 , B01J2219/2453 , B01J2219/2458 , B01J2219/2462 , B01J2219/2479 , B01J2219/2497 , B01J2523/00 , C07C51/265 , C07C51/313 , Y10T428/249953 , C07C63/16 , B01J2523/19 , B01J2523/41 , B01J2523/824
摘要： Supports having a catalytic coating comprising at least one porous and cavity-containing catalyst layer are described, cavities being irregular spaces having dimensions greater than 5 μm in at least two dimensions or having cross-sectional areas of at least 10 μm2. The catalytic coatings are distinguished by a high adhesive strength and can preferably be used in microreactors.
摘要翻译： 描述了具有包含至少一个多孔和含空腔的催化剂层的催化涂层的载体，空腔是具有至少两个维度的尺寸大于5μm或具有至少10μm的横截面积的尺寸的不规则空间。 催化涂层的特征在于高粘合强度，并且可优选用于微反应器。
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7.发明申请CATALYST-COATED SUPPORT, METHOD FOR THE PRODUCTION THEREOF, A REACTOR EQUIPPED THEREWITH, AND USE THEREOF 有权催化涂层支持，其生产方法，其设备的反应器及其使用公开(公告)号：US20120198769A1
公开(公告)日：2012-08-09
申请号：US13380142
申请日：2010-06-23
IPC分类号： B01J21/06 , B01J29/06 , B01J21/18 , B01J21/08 , B01J19/00 , C07D301/03 , C07C45/28 , C07C51/16 , C01B3/38 , C01B3/40 , C07C5/48 , C10J3/72 , B01J27/224 , B82Y40/00 , B82Y30/00
CPC分类号： B01J19/249 , B01D53/86 , B01D2257/7022 , B01J12/007 , B01J19/0093 , B01J21/08 , B01J23/52 , B01J23/66 , B01J35/006 , B01J35/10 , B01J35/1066 , B01J37/0045 , B01J37/0217 , B01J37/0225 , B01J37/0232 , B01J37/0244 , B01J37/349 , B01J2219/00783 , B01J2219/00788 , B01J2219/00822 , B01J2219/00824 , B01J2219/00835 , B01J2219/00837 , B01J2219/00846 , B01J2219/0086 , B01J2219/2453 , B01J2219/2458 , B01J2219/2459 , B01J2219/2479 , C07C45/35 , C07C51/215 , C07C67/05 , C07C47/22 , C07C53/08 , C07C69/15
摘要： A catalyst-coated support including a sheetlike support, a primer layer applied thereto and composed of nanoparticles composed of silicon oxide-comprising material, and at least one catalyst layer applied to the primer layer. The layers applied are notable for a particularly good adhesive bond strength and can be used particularly efficiently in heterogeneously catalyzed gas phase reactions, especially in microreactors.
摘要翻译： 一种催化剂涂覆的载体，包括片状载体，施加到其上的底漆层，由含有氧化硅的材料构成的纳米颗粒构成，以及至少一个施加到底漆层的催化剂层。 施加的层是特别好的粘合剂粘合强度的特征，并且可以特别有效地用于非均相催化的气相反应中，特别是在微反应器中。
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8.发明授权Catalyst-coated support, method for the production thereof, a reactor equipped therewith, and use thereof 有权催化剂涂覆的载体，其制备方法，装备有反应器的反应器及其用途公开(公告)号：US09421513B2
公开(公告)日：2016-08-23
申请号：US13380142
申请日：2010-06-23
IPC分类号： B01J12/00 , B01J19/00 , B01J21/08 , B01J19/24 , B01J23/52 , B01J35/10 , B01J37/02 , B01J37/34 , C07C45/35 , C07C51/215 , C07C67/05 , B01D53/86 , B01J23/66 , B01J35/00 , B01J37/00
CPC分类号： B01J19/249 , B01D53/86 , B01D2257/7022 , B01J12/007 , B01J19/0093 , B01J21/08 , B01J23/52 , B01J23/66 , B01J35/006 , B01J35/10 , B01J35/1066 , B01J37/0045 , B01J37/0217 , B01J37/0225 , B01J37/0232 , B01J37/0244 , B01J37/349 , B01J2219/00783 , B01J2219/00788 , B01J2219/00822 , B01J2219/00824 , B01J2219/00835 , B01J2219/00837 , B01J2219/00846 , B01J2219/0086 , B01J2219/2453 , B01J2219/2458 , B01J2219/2459 , B01J2219/2479 , C07C45/35 , C07C51/215 , C07C67/05 , C07C47/22 , C07C53/08 , C07C69/15
摘要： A catalyst-coated support including a sheetlike support, a primer layer applied thereto and composed of nanoparticles composed of silicon oxide-comprising material, and at least one catalyst layer applied to the primer layer. The layers applied are notable for a particularly good adhesive bond strength and can be used particularly efficiently in heterogeneously catalyzed gas phase reactions, especially in microreactors.
摘要翻译： 一种催化剂涂覆的载体，包括片状载体，施加到其上的底漆层，由含有氧化硅的材料构成的纳米颗粒构成，以及至少一个施加到底漆层的催化剂层。 施加的层是特别好的粘合剂粘合强度的特征，并且可以特别有效地用于非均相催化的气相反应中，特别是在微反应器中。
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