Pressure sensitive adhesive composition, articles made therewith and method of use
    2.
    发明授权
    Pressure sensitive adhesive composition, articles made therewith and method of use 有权
    压敏粘合剂组合物,制成的制品及其使用方法

    公开(公告)号:US06893718B2

    公开(公告)日:2005-05-17

    申请号:US10151785

    申请日:2002-05-20

    摘要: A pressure sensitive adhesive composition is described, comprising the reaction product of a copolymer and a bisamide crosslinking agent, (A) the copolymer comprising the reaction product of (i) a (meth)acrylate ester of a non-tertiary alcohol in which the alkyl group contains between 1 and 4 carbon atoms, inclusive, and (ii) a carboxylic acid-functional, ethylenically unsaturated co-monomer, and (B) a bisamide crosslinking agent having the formula: where, R1 and R3 independently, are selected from the group consisting of H and CnH2n+1, n is an integer ranging from 1 to 5, R2 is a divalent radical selected from the group consisting of benzeno (—C6H4—), substituted benzeno, triazine, CmH2m, and combinations thereof, m is an integer ranging from 1 to 10, and the relative amounts of the carboxylic acid-functional, ethylenically unsaturated co-monomer and the bisamide crosslinking agent providing a ratio of the number of equivalents of amide groups to the number of equivalents of carboxylic acid groups of less than about 0.1. Articles made with the pressure sensitive adhesive composition and methods for its use are also described.

    摘要翻译: 描述了包含共聚物和双酰胺交联剂的反应产物的压敏粘合剂组合物,(A)包含(i)非叔醇的(甲基)丙烯酸酯的反应产物的共聚物,其中烷基 基团含有1至4个碳原子,包括端基和(ii)羧酸官能的烯属不饱和共聚单体,和(B)具有下式的双酰胺交联剂:其中R 1, 和R 3独立地选自H和C n H 2n + 1,n是1至 5,R 2是选自苯并(C 6 -C 15 - ),取代的苯并,三嗪, C m 2 H 2 m及其组合,m为1至10的整数,并且羧酸官能的烯键式不饱和共聚单体和 双酰胺交联剂提供 将酰胺基的当量数与羧酸基的当量数之比小于约0.1。 还描述了用压敏粘合剂组合物制成的制品及其使用方法。

    Tackified polydiorganosiloxane polyurea segmented copolymers and a process for making same
    7.
    发明授权
    Tackified polydiorganosiloxane polyurea segmented copolymers and a process for making same 失效
    增粘的聚二有机硅氧烷聚脲分段共聚物及其制备方法

    公开(公告)号:US06664359B1

    公开(公告)日:2003-12-16

    申请号:US08930771

    申请日:1997-10-02

    IPC分类号: C08L8310

    摘要: A tackified composition comprising (a) a polydiorgannosiloxane polyurea segmented copolymer comprising the reaction product of (i) at least one polyaminie, wherein the polyamine comprises at least one polydiorganosiloxane diamine, or a mixture of at least one polydiorganosiloxane diamine and at least one organic polyamine, and (ii) at least one polyisocyanate, wherein the mol ratio of isocyanate to amined is between 0.9:1 and 0.95:1 or between 1.05:1 and about 1.3:1, and (b) silicate resins. The tackified compositions are useful as pressure sensitive adhesives, particularly for foamed backing tapes, medical tapes and the like, hot melt adhesives, vibration dampers, anti-corrosive materials.

    摘要翻译: 一种增粘组合物,其包含(a)聚二氢甘油硅氧烷聚脲分段共聚物,其包含(i)至少一种多胺的反应产物,其中所述多胺包含至少一种聚二有机硅氧烷二胺,或至少一种聚二有机硅氧烷二胺和至少一种有机多胺 ,和(ii)至少一种多异氰酸酯,其中异氰酸酯与胺化物的摩尔比在0.9:1至0.95:1之间或1.05:1至约1.3:1之间,和(b)硅酸酯树脂。 增粘组合物可用作压敏粘合剂,特别是用于发泡背胶带,医用胶带等,热熔粘合剂,减震器,防腐蚀材料。

    Tackified polydiorganosiloxane oligourea segmented copolymers and a process for making same
    8.
    发明授权
    Tackified polydiorganosiloxane oligourea segmented copolymers and a process for making same 失效
    增粘的聚二有机硅氧烷低聚脲分段共聚物及其制备方法

    公开(公告)号:US06407195B2

    公开(公告)日:2002-06-18

    申请号:US08930020

    申请日:1997-09-26

    IPC分类号: C08G7704

    CPC分类号: C09J183/10 C08G77/458

    摘要: Tackified compositions comprise a curable polydiorganosiloxane oligourea segmented copolymer which has alternating soft polydiorganosiloxane units and hard diisocyanate residues, the diisocyanate residue being the diisocyanate minus the —NCO groups. The units are connected together by urea linkages and the copolymer has end groups that are reactive under free radical or moisture cure conditions, and silicate resin. Also provided are pressure-sensitive adhesives, hot melt adhesives, and vibration damping composites, vibration damping constrained layer constructions, a bi-directional vibration damping constrained layer constructions, vibration damping shaped articles as well as a method of vibrationally damping an article and processes for producing curable vibration damping material.

    摘要翻译: 增粘组合物包含可固化的聚二有机硅氧烷低聚脲分段共聚物,其具有交替的软的聚二有机硅氧烷单元和硬质二异氰酸酯残基,二异氰酸酯残基是二异氰酸酯减去-NCO基团。 这些单元通过尿素键连接在一起,共聚物具有在自由基或湿气固化条件下反应的端基和硅酸盐树脂。 还提供了压敏粘合剂,热熔粘合剂和减振复合材料,减振约束层结构,双向振动阻尼约束层结构,振动阻尼成形制品以及振动阻尼制品的方法和方法 生产可固化振动阻尼材料。

    Polydiorganosiloxane polyurea segmented copolymers and a process for making same
    10.
    发明授权
    Polydiorganosiloxane polyurea segmented copolymers and a process for making same 失效
    聚二有机硅氧烷聚脲分段共聚物及其制备方法

    公开(公告)号:US06355759B1

    公开(公告)日:2002-03-12

    申请号:US08930324

    申请日:1997-09-26

    IPC分类号: C08G7724

    CPC分类号: C08G77/452 C08L83/10

    摘要: Melt-processable polydiorganosiloxane polyurea segmented copolymer compositions are provided. The compositions comprise alternating soft polydiorganosiloxane units and hard diisocyanate residue units, the diisocyanate residue being the diisocyanate minus the —NCO groups, the units being connected together by urea linkages which also provide hard units. The compositions are prepared by continuously providing at least one diisocyanate and at least one polydiorganosiloxane diamine to a reactor, mixing the diisocyanate and the polydiorganosiloxane diamine in the reactor under substantially solvent-free conditions, allowing the diisocyanate and polydiorganosiloxane diamine to react to form a polydiorganosiloxane polyurea copolymer, and conveying the copolymer from the reactor.

    摘要翻译: 提供可熔融加工的聚二有机硅氧烷聚脲分段共聚物组合物。 组合物包含交替的软的聚二有机硅氧烷单元和硬二异氰酸酯残基单元,二异氰酸酯残基是二异氰酸酯减去-NCO基团,该单元通过还提供硬单元的脲键连接在一起。 通过向反应器中连续提供至少一种二异氰酸酯和至少一种聚二有机硅氧烷二胺制备组合物,在基本无溶剂的条件下将二异氰酸酯和聚二有机硅氧烷二胺混合在反应器中,使二异氰酸酯和聚二有机硅氧烷二胺反应形成聚二有机基硅氧烷 聚脲共聚物,并从反应器输送共聚物。