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公开(公告)号:US09777436B2
公开(公告)日:2017-10-03
申请号:US14725384
申请日:2015-05-29
IPC分类号: D21H21/20 , D21H17/55 , D21H11/04 , C08G73/06 , D21H17/33 , D21H17/52 , D21H17/56 , D21H23/04
CPC分类号: D21H21/20 , C08G73/06 , D21H11/04 , D21H17/33 , D21H17/52 , D21H17/55 , D21H17/56 , D21H23/04
摘要: Compositions and methods related to new wet strength resins are provided. By using functionally-symmetrical cross-linkers and mono-functional modifiers, and separating the steps of reacting a prepolymer with the cross-linkers from the reaction of intermediate cross-linked prepolymer with epichlorohydrin, new wet strength resin products are provided having improved properties.
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公开(公告)号:US09506196B2
公开(公告)日:2016-11-29
申请号:US14679417
申请日:2015-04-06
发明人: Cornel Hagiopol , David F. Townsend , Clay E. Ringold , James W. Johnston , Robert McDonald , Metric M. Simpson , Frederick S. Potter
摘要: Resin systems and methods for making and using same are provided. The method for making a paper product can include contacting a plurality of pulp fibers with a resin system. The resin system can include a first polyamidoamine-epihalohydrin resin and a second resin that can include a second polyamidoamine-epihalohydrin resin, a urea-formaldehyde resin, or a mixture thereof to produce a paper product. The first resin and the second resin can be sequentially or simultaneously contacted with the plurality of pulp fibers. The period for sequential addition between the first resin and the second resin is about 1 second to about 1 hour.
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公开(公告)号:US09464193B2
公开(公告)日:2016-10-11
申请号:US14880726
申请日:2015-10-12
发明人: Cornel Hagiopol , Derek L. Atkinson
IPC分类号: C09J171/08 , C08L97/02 , C09J197/00 , C09J161/14 , C09J163/00 , C09J167/02 , C09J161/06 , C08G8/28 , C08G61/12 , C08G65/00 , C08L33/00 , C08L65/00
CPC分类号: C07D311/54 , C08G8/28 , C08G61/12 , C08G65/002 , C08L33/00 , C08L65/00 , C08L97/02 , C09J161/06 , C09J161/14 , C09J163/00 , C09J167/02 , C09J171/08 , C09J197/005 , C08L97/005
摘要: Modified polyphenol binder compositions and methods for making and using same are provided. In at least one specific embodiment, the binder composition can include at least one unsaturated monomer and at least one polyphenolic compound. The polyphenolic compound can include a lignin, a tannin, a novolac resin, a modified phenol formaldehyde resin, bis-phenol A, humic acid, or any mixture thereof.
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公开(公告)号:US09353483B2
公开(公告)日:2016-05-31
申请号:US14679442
申请日:2015-04-06
发明人: Cornel Hagiopol , David F. Townsend , Clay E. Ringold , James W. Johnston , Robert McDonald , Metric M. Simpson , Frederick S. Potter
摘要: Resin systems and methods for making and using same are provided. The method for making a paper product can include contacting a plurality of pulp fibers with a resin system. The resin system can include a first polyamidoamine-epihalohydrin resin and a second resin that can include a second polyamidoamine-epihalohydrin resin, a urea-formaldehyde resin, or a mixture thereof to produce a paper product. The first resin and the second resin can be sequentially or simultaneously contacted with the plurality of pulp fibers. The period for sequential addition between the first resin and the second resin is about 1 second to about 1 hour.
摘要翻译: 提供了树脂体系及其制造和使用方法。 制造纸制品的方法可以包括使多个纸浆纤维与树脂体系接触。 树脂体系可以包括第一聚酰胺胺 - 表卤醇树脂和第二树脂,其可以包括第二聚酰胺胺 - 表卤醇树脂,脲 - 甲醛树脂或其混合物以产生纸产品。 第一树脂和第二树脂可以与多个纸浆纤维顺序或同时地接触。 在第一树脂和第二树脂之间顺序加入的时间为约1秒至约1小时。
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公开(公告)号:US20160115315A1
公开(公告)日:2016-04-28
申请号:US14884723
申请日:2015-10-15
CPC分类号: C08L1/02 , C08G73/0286 , C08G73/0293 , C08L33/26 , C08L79/02 , C08L97/02 , C08L79/04
摘要: Resins compositions and methods for making and using same. The resin composition can include a glyoxalated polyacrylamide resin and a polyamide-epihalohydrin resin. The polyamide-epihalohydrin resin can include a polyamine partially crosslinked with a bridging moiety and having azetidinium ions. The bridging moiety can be derived from a functionally symmetric crosslinker. A fiber product can include a plurality of fibers and the resin composition, where the resin composition can be at least partially cured.
摘要翻译: 树脂组合物及其制备和使用方法。 树脂组合物可以包括乙二醛化聚丙烯酰胺树脂和聚酰胺 - 表卤醇树脂。 聚酰胺 - 表卤代醇树脂可以包括用桥连部分交联并具有氮杂环丁烷离子的多胺。 桥连部分可以衍生自功能对称的交联剂。 纤维制品可以包括多个纤维和树脂组合物,其中树脂组合物可以至少部分固化。
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公开(公告)号:US20150259858A1
公开(公告)日:2015-09-17
申请号:US14725384
申请日:2015-05-29
CPC分类号: D21H21/20 , C08G73/06 , D21H11/04 , D21H17/33 , D21H17/52 , D21H17/55 , D21H17/56 , D21H23/04
摘要: Compositions and methods related to new wet strength resins are provided. By using functionally-symmetrical cross-linkers and mono-functional modifiers, and separating the steps of reacting a prepolymer with the cross-linkers from the reaction of intermediate cross-linked prepolymer with epichlorohydrin, new wet strength resin products are provided having improved properties.
摘要翻译: 提供了与新型湿强度树脂有关的组合物和方法。 通过使用功能对称的交联剂和单官能改性剂,并且分离使预聚物与交联剂与中间交联预聚物与表氯醇反应的反应步骤,提供了具有改进性能的新的湿强度树脂产品。
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公开(公告)号:US20140090577A1
公开(公告)日:2014-04-03
申请号:US14040791
申请日:2013-09-30
CPC分类号: B27N3/002 , B27N3/02 , B29D7/01 , C08H6/00 , C08H8/00 , C08J5/18 , C08L97/02 , C09J197/005 , C08L97/005
摘要: Methods for making composite products are provided. In at least one specific embodiment, the method can include combining a plurality of lignocellulose substrates and one or more free radical precursors to produce a mixture of the lignocellulose substrates and the one or more free radical precursors. The method can also include maintaining the mixture at a temperature less than 60° C. for at least 10 minutes while retaining at least 11 wt % of the one or more free radical precursors charged to the mixture. The method can then include heating the mixture comprising at least 11 wt % of the one or more free radical precursors charged to the mixture to a temperature of at least 60° C. to about 300° C. to produce a composite product. The composite product can have a density less than 1 g/cm3 and an internal bond strength of at least 0.35 MPa.
摘要翻译: 提供复合制品的制造方法。 在至少一个具体实施方案中,该方法可以包括组合多个木质纤维素基质和一种或多种自由基前体以产生木质纤维素基质和一种或多种自由基前体的混合物。 该方法还可以包括将混合物保持在低于60℃的温度下至少10分钟,同时保留装入混合物中的至少11重量%的一种或多种游离基前体。 该方法然后可以包括将包含至少11重量%的加入到混合物中的一种或多种自由基前体的混合物加热至至少60℃至约300℃的温度以产生复合产物。 复合产品的密度可以小于1g / cm3,内部粘合强度至少为0.35MPa。
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公开(公告)号:US10738025B2
公开(公告)日:2020-08-11
申请号:US15289521
申请日:2016-10-10
发明人: Cornel Hagiopol , Derek L. Atkinson
IPC分类号: C07D311/54 , C08G8/28 , C08G61/12 , C08L33/00 , C08L65/00 , C08L97/02 , C09J161/06 , C09J161/14 , C09J163/00 , C09J167/02 , C09J171/08 , C09J197/00 , C08G65/00
摘要: Modified polyphenol binder compositions and methods for making and using same are provided. In at least one specific embodiment, the binder composition can include at least one unsaturated monomer and at least one polyphenolic compound. The polyphenolic compound can include a lignin, a tannin, a novolac resin, a modified phenol formaldehyde resin, bis-phenol A, humic acid, or any mixture thereof.
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公开(公告)号:US10227431B2
公开(公告)日:2019-03-12
申请号:US16131278
申请日:2018-09-14
发明人: Bobby L. Williamson , Adam K. Sniady , Brian L. Swift , Ramji Srinivasan , Feng Jing , Cornel Hagiopol
IPC分类号: C09J167/06 , C08F222/10 , C08F283/00 , C09J197/00 , C09J161/06 , C09J161/14 , C08F222/12 , C09D135/02 , C08F122/38 , B27N3/00
摘要: Binder compositions and methods for making and using same are provided. In at least one specific embodiment, the binder composition can include at least one unsaturated compound having two or more unsaturated carbon-carbon bonds and at least one free radical precursor. At least one of the unsaturated carbon-carbon bonds can be a pi-bond that is not conjugated with an aromatic moiety and can be capable of free radical addition. The free radical precursor can be present in an amount of about 7 wt % to about 99 wt %, based on the weight of the one or more unsaturated compounds.
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公开(公告)号:US20170292223A1
公开(公告)日:2017-10-12
申请号:US15634615
申请日:2017-06-27
CPC分类号: D21H21/20 , C08G73/0286 , C08L25/08 , C08L77/00 , C09D125/08 , D21H17/40 , D21H17/44 , D21H17/45 , D21H17/455 , D21H17/55 , D21H17/72
摘要: Wet strengthened fiber products, wet strengthening resins, and methods for making such wet strengthened fiber products and wet strengthening resins. The wet strengthened fiber product can include a fiber web and an at least partially cured wet strengthening resin, which prior to at least partially curing, the wet strengthening resin can include a polyamide-epihalohydrin (PAE) resin and a cationic styrene maleimide (SMI) resin. The PAE resin can include a reaction product of a polyamidoamine and an epihalohydrin and the cationic SMI resin can include a reaction product of a styrene maleic anhydride (SMA) copolymer and an amine. The wet strengthened fiber product can include the wet strengthening resin in an amount of about 0.05 wt % to about 5 wt %, based on a dried weight of the wet strengthened fiber product.
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