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公开(公告)号：US20120315397A1
公开(公告)日：2012-12-13
申请号：US13588555
申请日：2012-08-17
申请人： Gerardus Cornelis Overbeek , Alfred Jean Paul Bückmann , Michael Arnoldus Jacobus Schellekens , Jacobus Willem Griffioen
发明人： Gerardus Cornelis Overbeek , Alfred Jean Paul Bückmann , Michael Arnoldus Jacobus Schellekens , Jacobus Willem Griffioen
IPC分类号： C08L75/04 , C09D11/10 , B05D5/00 , C09J175/04
CPC分类号： C09D11/102 , C08L75/08 , C09D11/101 , C09D175/04 , C09D175/16 , C09J175/04 , C09J175/08 , C08L2666/20
摘要： A radiation curable composition comprising 15 to 85 wt % of at least one solvent comprising ≦20 wt % of water; 5 to 50 wt % of at least one radiation curable material having a Mn in the range of from 50 to 10,000 g/mol; and 10 to 70 wt % of at least one polyurethane having a Mw in the range of from 4,000 to 70,000 g/mol, the polyurethane having 0 to 5 wt % of isocyanate-reactive component(s) bearing ionic or potentially ionic water-dispersing groups and a free isocyanate group content ≦0.5 wt %.
摘要翻译： 一种可辐射固化组合物，其包含15至85重量％的至少一种溶剂，其包含20重量％的水; 5〜50重量％的至少一种Mn在50〜10,000g / mol范围内的可辐射固化材料; 和10至70重量％的至少一种Mw在4,000至70,000g / mol范围内的聚氨酯，所述聚氨酯具有0至5重量％的具有离子或潜在离子水分散体的异氰酸酯反应性组分 基团和游离异氰酸酯基含量＆nlE; 0.5wt％。
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公开(公告)号：US20130224382A1
公开(公告)日：2013-08-29
申请号：US13856696
申请日：2013-04-04
申请人： Gerardus Cornelis OVERBEEK , Alfred Jean Paul Bückmann , Michael Arnoldus Jacobus Schellekens , Jacobus Willem Griffioen
发明人： Gerardus Cornelis OVERBEEK , Alfred Jean Paul Bückmann , Michael Arnoldus Jacobus Schellekens , Jacobus Willem Griffioen
IPC分类号： C09D11/10 , C08L75/08 , C09J175/08
CPC分类号： C09D11/102 , C08L75/08 , C09D11/101 , C09D175/04 , C09D175/16 , C09J175/04 , C09J175/08 , C08L2666/20
摘要： A radiation curable composition comprising 15 to 85 wt % of at least one solvent comprising ≦20 wt % of water; 5 to 50 wt % of at least one radiation curable material having a Mn in the range of from 50 to 10,000 g/mol; and 10 to 70 wt % of at least one polyurethane having a Mw in the range of from 4,000 to 70,000 g/mol, the polyurethane having 0 to 5 wt % of isocyanate-reactive component(s) bearing ionic or potentially ionic water-dispersing groups and a free isocyanate group content ≦0.5 wt %.
摘要翻译： 一种可辐射固化组合物，其包含15至85重量％的至少一种包含20重量％水的溶剂; 5〜50重量％的至少一种Mn在50〜10,000g / mol范围内的可辐射固化材料; 和10至70重量％的至少一种Mw在4,000至70,000g / mol范围内的聚氨酯，所述聚氨酯具有0至5重量％的具有离子或潜在离子水分散体的异氰酸酯反应性组分 基团和0.5重量％的游离异氰酸酯基含量。
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公开(公告)号：US07968011B2
公开(公告)日：2011-06-28
申请号：US12281688
申请日：2007-03-06
CPC分类号： C09D11/101 , C09D11/52 , H01B1/22 , H05K1/095 , Y10T428/249948 , Y10T428/25 , Y10T428/265
摘要： A conductive ink comprising 10 to 75 wt % of at least one solvent comprising ≦20 wt % water; 0 to 50 wt % of at least one radiation curable material having a Mn in the range of from 50 to 10,000 g/mol; 5 to 70 wt % of at least one polyurethane having a Mw in the range of from 4,000 to 70,000 g/mol, 0 to 5 wt % of isocyanate-reactive component(s) bearing ionic or potentially ionic water-dispersing groups and a free isocyanate group content
摘要翻译： 导电油墨，其包含10至75重量％的至少一种溶剂，其包含20重量％的水; 0〜50重量％的至少一种Mn在50〜10,000g / mol范围内的可辐射固化材料; 5至70重量％的Mw为4,000至70,000g / mol的至少一种聚氨酯，0至5重量％的带有离子或潜在离子性水分散基团的异氰酸酯反应性组分， 异氰酸酯基含量<0.5重量％和20〜85重量％的导电材料。
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公开(公告)号：US20080317957A1
公开(公告)日：2008-12-25
申请号：US12097665
申请日：2006-12-07
申请人： Gerardus Cornelis Overbeek , Alfred Jean Paul Buckmann , Michael Arnoldus Jacobus Schellekens , Jacobus Willem Griffioen
发明人： Gerardus Cornelis Overbeek , Alfred Jean Paul Buckmann , Michael Arnoldus Jacobus Schellekens , Jacobus Willem Griffioen
IPC分类号： B05D5/00 , C09D175/04 , C09D11/10
CPC分类号： C09D11/102 , C08L75/08 , C09D11/101 , C09D175/04 , C09D175/16 , C09J175/04 , C09J175/08 , C08L2666/20
摘要： A radiation curable composition comprising 15 to 85 wt % of at least one solvent comprising ≦20 wt % of water; 5 to 50 wt % of at least one radiation curable material having a Mn in the range of from 50 to 10,000 g/mol; and 10 to 70 wt % of at least one polyurethane having a Mw in the range of from 4,000 to 70,000 g/mol, the polyurethane having 0 to 5 wt % of isocyanate-reactive component(s) bearing ionic or potentially ionic water-dispersing groups and a free isocyanate group content ≦0.5 wt %.
摘要翻译： 一种可辐射固化组合物，其包含15至85重量％的至少一种包含<= 20重量％的水的溶剂; 5〜50重量％的至少一种Mn在50〜10,000g / mol范围内的可辐射固化材料; 和10至70重量％的至少一种Mw在4,000至70,000g / mol范围内的聚氨酯，所述聚氨酯具有0至5重量％的具有离子或潜在离子水分散体的异氰酸酯反应性组分 基团和游离异氰酸酯基团含量<= 0.5wt％。
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5.发明申请PROCESS FOR OBTAINING LOW FREE MONOMER LEVELS IN A BLOCK COPOLYMER EMULSION PREPARED WITH (REVERSE) IODINE TRANSFER POLYMERISATION 审中-公开制备（反向）碘转移聚合的嵌段共聚物乳液中低自由基单体含量的方法公开(公告)号：US20100256299A1
公开(公告)日：2010-10-07
申请号：US12664922
申请日：2008-06-17
申请人： Tijs Nabuurs , Gerardus Cornelis Overbeek , Michael Arnoldus Jacobus Schellekens , Danny Visser , Frank Vaes
发明人： Tijs Nabuurs , Gerardus Cornelis Overbeek , Michael Arnoldus Jacobus Schellekens , Danny Visser , Frank Vaes
IPC分类号： C08L53/00
CPC分类号： C08L53/00 , C08F293/00 , C08F293/005 , C08F2438/00 , C08L2666/02 , C09D153/00 , C09J153/00
摘要： A process for obtaining an aqueous emulsion comprising a block copolymer by the solution polymerisation of vinyl monomers to obtain block [B] in the presence of a) a radical precursor; and b) an iodine atom containing block [A]; where block [A] and [B] together comprise 0 to 2 wt % of methacrylic acid; where block [A] and block [B] together comprise ≧2.5 wt % of vinyl monomers bearing ionic or potentially ionic water-dispersing groups not including methacrylic acid; and performing a post polymerisation reaction on the block copolymer emulsion obtained in step II; and wherein said aqueous emulsion has a free vinyl monomer level
摘要翻译： 一种通过乙烯基单体的溶液聚合获得嵌段共聚物以在a）自由基前体存在下获得嵌段[B]的方法; 和b）含有碘原子的嵌段[A]; 其中嵌段[A]和[B]一起包含0至2重量％的甲基丙烯酸; 其中嵌段[A]和嵌段[B]一起包含≥2.5wt％的具有不包括甲基丙烯酸的离子或潜在离子水分散基团的乙烯基单体; 并对在步骤II中获得的嵌段共聚物乳液进行后聚合反应; 并且其中当固体含量为≥20wt％时，所述水性乳液的游离乙烯基单体含量<1000ppm。
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公开(公告)号：US20110111244A1
公开(公告)日：2011-05-12
申请号：US12935991
申请日：2009-04-01
IPC分类号： B32B27/08 , C09D153/00 , B05D3/10
CPC分类号： C09D153/00 , C08F2/24 , C08F287/00 , C08F293/005 , C08L53/00 , C08L53/005 , Y10T428/31935 , Y10T428/31938 , C08L2666/02
摘要： An aqueous coating composition (which optionally can coat plastic substrates) the composition comprising a block copolymer and a polymer P; where the block copolymer comprises at least blocks [A]x[B]y; where at least block [A] is obtained by a controlled radical polymerisation of at least one ethylenically unsaturated monomer via a reversible addition-fragmentation chain transfer (RAFT) mechanism (optionally in solution in the presence of a control agent and a source of free radicals); and wherein block [A] comprises 20 to 100 mol % of ethylenically unsaturated monomer units bearing water-dispersing functional groups; wherein block [B] comprises 20 to 100 mol % of ethylenically unsaturated monomer units bearing plastic adhesion promoting functional groups; and wherein polymer P is prepared in the presence of blocks [A]x[B]y. The compositions may be used to coat plastic substrates, foam; surfaces having low surface energy, hydrophobic substrates and/or polyolefins.
摘要翻译： 包含嵌段共聚物和聚合物P的组合物的水性涂料组合物（其可任选地可以涂覆塑料基材）; 其中嵌段共聚物至少包含嵌段[A] x [B] y; 其中至少通过可逆加成 - 断裂链转移（RAFT）机理（任选在溶液中存在控制剂和自由基来源）通过至少一种烯属不饱和单体的受控自由基聚合获得嵌段[A] ）; 并且其中嵌段[A]包含20至100摩尔％的带有水分散官能团的烯属不饱和单体单元; 其中嵌段[B]包含20至100摩尔％的具有塑性粘合促进官能团的烯属不饱和单体单元; 并且其中聚合物P在嵌段[A] x [B] y的存在下制备。 组合物可用于涂覆塑料基材，泡沫; 具有低表面能的表面，疏水性基材和/或聚烯烃。
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公开(公告)号：US20110021689A1
公开(公告)日：2011-01-27
申请号：US12812659
申请日：2009-01-16
IPC分类号： C08L53/00
CPC分类号： C09D133/08 , C08F293/005 , C08F2438/03 , C08L53/00 , C08L53/005 , C09D153/00 , C08L2666/02
摘要： There is disclosed a process for obtaining a water-borne crosslinkable composition comprising a block copolymer comprising at least blocks [A]x[B]y (where x is an integer from 3 to 80 (inc.), where y is an integer ≧10 and where y>x) and a polymer P, the block copolymer-polymer having an acid value ≦150 mg KOH per g of block copolymer-polymer, where at least block [A] and [B] is obtained by a controlled radical polymerisation of at least one ethylenically unsaturated monomer via a reversible addition-fragmentation chain transfer (RAFT) mechanism in solution in the presence of a control agent and a source of free radicals; and where polymer P is obtained in the presence of blocks [A]x[B]y by an emulsion polymerisation process.
摘要翻译： 公开了一种获得水性交联组合物的方法，该组合物包含至少包含嵌段[A] x [B] y（其中x为3-80（inc。）的整数）的嵌段共聚物，其中y为整数≧ 10，并且其中y> x）和聚合物P，具有酸值＆nlE的嵌段共聚物 - 聚合物;每克嵌段共聚物 - 聚合物为150mg KOH，其中至少块[A]和[B]通过受控 在控制剂和自由基源的存在下，通过可逆加成 - 断裂链转移（RAFT）机理在溶液中自由基聚合至少一种烯属不饱和单体; 并且其中通过乳液聚合方法在嵌段[A] x [B] y存在下获得聚合物P。
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公开(公告)号：US20100136353A1
公开(公告)日：2010-06-03
申请号：US12594704
申请日：2008-04-03
IPC分类号： C09D153/00 , C08L39/00 , C08L53/00 , C09D5/14 , B32B27/00
CPC分类号： C09D151/003 , C08F293/005 , C08F2438/03 , C08L53/00 , C09D5/14 , C09D153/00 , C09D153/005 , Y10T428/31855 , Y10T428/31938 , C08L2666/02
摘要： An aqueous emulsion comprising at least a covalently bound vinyl oligomer and vinyl polymer, wherein said vinyl oligomer comprises 5 to 85 mol % of vinyl monomers bearing quaternary ammonium ion functional groups or quaternisable amine functional groups and is obtained by a controlled radical polymerisation of at least one vinyl monomer via a reversible addition-fragmentation chain transfer mechanism in solution in the presence of a control agent and a source of free radicals; wherein said vinyl polymer is obtained by emulsion polymerisation of vinyl monomers in the presence of the vinyl oligomer; wherein the weight % ratio of vinyl oligomer to vinyl polymer is in the range of from 0.5:99.5 to 65:35.
摘要翻译： 包含至少共价结合的乙烯基低聚物和乙烯基聚合物的水性乳液，其中所述乙烯基低聚物包含5-85摩尔％的带有季铵离子官能团或可季铵化胺官能团的乙烯基单体，并且通过至少一种受控自由基聚合获得 一种乙烯基单体通过在控制剂和自由基来源的溶液中的可逆加成 - 断裂链转移机理; 其中所述乙烯基聚合物通过乙烯基单体在乙烯基低聚物存在下的乳液聚合获得; 其中乙烯基低聚物与乙烯基聚合物的重量％比在0.5:99.5至65:35的范围内。
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公开(公告)号：US20110159306A1
公开(公告)日：2011-06-30
申请号：US13001940
申请日：2009-06-30
IPC分类号： B32B15/08 , B05D3/00 , C09D153/00
CPC分类号： B32B15/082 , C08F2/22 , C08F2/38 , C08F293/005 , C08L53/00 , C08L53/005 , C08L2666/02 , C09D153/00 , C09J153/00 , C23F11/00 , Y10T428/31692
摘要： An aqueous, metal, coating composition (and process for obtaining it) comprising a block copolymer and a polymer P; wherein the block copolymer comprises at least blocks [A]x[B]y, where at least block [A] is obtained by a controlled radical polymerisation of at least one ethylenically unsaturated monomer via a reversible addition-fragmentation chain transfer (RAFT) mechanism in solution in the presence of a control agent and a source of free radicals; and where (a) block [A] comprises (i) 0 to 80 mol % of metal adhering ethylenically unsaturated monomers; (ii) 0 to 100 mol % of water dispersible ethylenically unsaturated monomers; (iii) 0 to 70 mol % of C1 to C30 hydrocarbo (meth)acrylate and/or styrenic monomers; (iv) 0 to 35 mol % of ethylenically unsaturated monomer different from i), ii)+iii); where the amount of at least one of i), ii), iii)+iv) is >0 mol %; block [A] has a Hansch parameter x); and (c) polymer P is obtained by an emulsion polymerisation process in the presence of the block copolymer [A][B] and comprises: i) 0 to 5 wt % of metal adhering ethylenically unsaturated monomers; ii) 0 to 15 wt % of water dispersible ethylenically unsaturated monomers; iii) 50 to 100 wt % C1 to C30 hydrocarbo (meth)acrylate and/or styrenic monomers; and iv) 0 to 35% by weight of ethylenically unsaturated monomers units different from those from i), ii)+iii).
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公开(公告)号：US20110207871A1
公开(公告)日：2011-08-25
申请号：US12671887
申请日：2008-07-31
CPC分类号： C08F2/18 , C08F2/38 , C08F293/005 , C08F2438/03 , C08L53/00 , C09D153/00 , C08L2666/02
摘要： An aqueous dispersion comprising a crystallisable vinyl block copolymer-polymer which comprises: i) a vinyl block copolymer comprising at least blocks [A]x [B]y , wherein at least a crystallisable block [A] is obtained by a controlled radical polymerisation of at least one vinyl monomer via a reversible addition-fragmentation chain transfer (RAFT) mechanism in solution, in the presence of a control agent and a source of free radicals; and wherein the vinyl block copolymer comprises 2 to 50 wt % of vinyl monomers bearing at least a crystallisable side chain by weight of the vinyl block copolymer-polymer; wherein crystallisable block [A] has an average degree of polymerisation x, wherein x is an integer in the range of from 3 to 80; wherein block [B] has an average degree of polymerisation y, wherein y is an integer ≦3; and ii) a vinyl polymer [P] obtained by the free radical emulsion polymerisation of one or more vinyl monomers in the presence of the vinyl block copolymer; and wherein the block copolymer:polymer weight ratio is in the range of from 10:90 to 70:30.
摘要翻译： 包含可结晶乙烯基嵌段共聚物 - 聚合物的水分散体，其包含：i）至少包含嵌段[A] x [B] y的乙烯基嵌段共聚物，其中至少可结晶嵌段[A]通过受控自由基聚合 至少一种乙烯基单体通过溶解中的可逆加成 - 断裂链转移（RAFT）机理，在控制剂和自由基源的存在下进行; 并且其中所述乙烯基嵌段共聚物包含2-50重量％的至少具有乙烯基嵌段共聚物 - 聚合物重量的可结晶侧链的乙烯基单体; 其中可结晶嵌段[A]具有平均聚合度x，其中x是3至80的整数; 其中嵌段[B]具有平均聚合度y，其中y是整数nlE; 3; 和ii）在乙烯基嵌段共聚物存在下通过一种或多种乙烯基单体的自由基乳液聚合获得的乙烯基聚合物[P]; 并且其中所述嵌段共聚物：聚合物重量比在10:90至70:30的范围内。
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