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    ADHESION TO PLASTIC WITH BLOCK COPOLYMERS OBTAINED USING RAFT
    5.
    发明申请
    ADHESION TO PLASTIC WITH BLOCK COPOLYMERS OBTAINED USING RAFT 审中-公开
    使用RAFT获得的具有嵌段共聚物的塑料粘合剂

    公开(公告)号：US20110111244A1

    公开(公告)日：2011-05-12

    申请号：US12935991

    申请日：2009-04-01

    申请人： Michael Arnoldus Jacobus Schellekens ,  Gerardus Cornelis Overbeek ,  Tijs Nabuurs ,  John Geurts

    发明人： Michael Arnoldus Jacobus Schellekens ,  Gerardus Cornelis Overbeek ,  Tijs Nabuurs ,  John Geurts

    IPC分类号： B32B27/08 ,  C09D153/00 ,  B05D3/10

    CPC分类号： C09D153/00 ,  C08F2/24 ,  C08F287/00 ,  C08F293/005 ,  C08L53/00 ,  C08L53/005 ,  Y10T428/31935 ,  Y10T428/31938 ,  C08L2666/02

    摘要： An aqueous coating composition (which optionally can coat plastic substrates) the composition comprising a block copolymer and a polymer P; where the block copolymer comprises at least blocks [A]x[B]y; where at least block [A] is obtained by a controlled radical polymerisation of at least one ethylenically unsaturated monomer via a reversible addition-fragmentation chain transfer (RAFT) mechanism (optionally in solution in the presence of a control agent and a source of free radicals); and wherein block [A] comprises 20 to 100 mol % of ethylenically unsaturated monomer units bearing water-dispersing functional groups; wherein block [B] comprises 20 to 100 mol % of ethylenically unsaturated monomer units bearing plastic adhesion promoting functional groups; and wherein polymer P is prepared in the presence of blocks [A]x[B]y. The compositions may be used to coat plastic substrates, foam; surfaces having low surface energy, hydrophobic substrates and/or polyolefins.

    摘要翻译： 包含嵌段共聚物和聚合物P的组合物的水性涂料组合物（其可任选地可以涂覆塑料基材）; 其中嵌段共聚物至少包含嵌段[A] x [B] y; 其中至少通过可逆加成 - 断裂链转移（RAFT）机理（任选在溶液中存在控制剂和自由基来源）通过至少一种烯属不饱和单体的受控自由基聚合获得嵌段[A] ）; 并且其中嵌段[A]包含20至100摩尔％的带有水分散官能团的烯属不饱和单体单元; 其中嵌段[B]包含20至100摩尔％的具有塑性粘合促进官能团的烯属不饱和单体单元; 并且其中聚合物P在嵌段[A] x [B] y的存在下制备。 组合物可用于涂覆塑料基材，泡沫; 具有低表面能的表面，疏水性基材和/或聚烯烃。

    WATER BORNE CROSSLINKABLE BLOCK COPOLYMERS OBTAINED USING RAFT
    6.
    发明申请
    WATER BORNE CROSSLINKABLE BLOCK COPOLYMERS OBTAINED USING RAFT 审中-公开
    使用RAFT获得的水性可交换嵌段共聚物

    公开(公告)号：US20110021689A1

    公开(公告)日：2011-01-27

    申请号：US12812659

    申请日：2009-01-16

    申请人： Michael Arnoldus Jacobus Schellekens ,  Tijs Nabuurs ,  John Geurts ,  Gerardus Cornelis Overbeek

    发明人： Michael Arnoldus Jacobus Schellekens ,  Tijs Nabuurs ,  John Geurts ,  Gerardus Cornelis Overbeek

    IPC分类号： C08L53/00

    CPC分类号： C09D133/08 ,  C08F293/005 ,  C08F2438/03 ,  C08L53/00 ,  C08L53/005 ,  C09D153/00 ,  C08L2666/02

    摘要： There is disclosed a process for obtaining a water-borne crosslinkable composition comprising a block copolymer comprising at least blocks [A]x[B]y (where x is an integer from 3 to 80 (inc.), where y is an integer ≧10 and where y>x) and a polymer P, the block copolymer-polymer having an acid value ≦150 mg KOH per g of block copolymer-polymer, where at least block [A] and [B] is obtained by a controlled radical polymerisation of at least one ethylenically unsaturated monomer via a reversible addition-fragmentation chain transfer (RAFT) mechanism in solution in the presence of a control agent and a source of free radicals; and where polymer P is obtained in the presence of blocks [A]x[B]y by an emulsion polymerisation process.

    摘要翻译： 公开了一种获得水性交联组合物的方法，该组合物包含至少包含嵌段[A] x [B] y（其中x为3-80（inc。）的整数）的嵌段共聚物，其中y为整数≧ 10，并且其中y> x）和聚合物P，具有酸值＆nlE的嵌段共聚物 - 聚合物;每克嵌段共聚物 - 聚合物为150mg KOH，其中至少块[A]和[B]通过受控 在控制剂和自由基源的存在下，通过可逆加成 - 断裂链转移（RAFT）机理在溶液中自由基聚合至少一种烯属不饱和单体; 并且其中通过乳液聚合方法在嵌段[A] x [B] y存在下获得聚合物P。

    ADHESION TO PLASTIC WITH BLOCK COPOLYMERS OBTAINED USING RAFT
    7.
    发明申请
    ADHESION TO PLASTIC WITH BLOCK COPOLYMERS OBTAINED USING RAFT 审中-公开
    使用RAFT获得的具有嵌段共聚物的塑料粘合剂

    公开(公告)号：US20120196143A1

    公开(公告)日：2012-08-02

    申请号：US13439278

    申请日：2012-04-04

    申请人： Michael Arnoldus Jacobus SCHELLEKENS ,  Gerardus Cornelis Overbeek ,  Tijs Nabuurs ,  John Geurts

    发明人： Michael Arnoldus Jacobus SCHELLEKENS ,  Gerardus Cornelis Overbeek ,  Tijs Nabuurs ,  John Geurts

    IPC分类号： C09D153/00 ,  B05D7/02 ,  B32B27/30 ,  B05D5/00 ,  C08F2/22 ,  B05D3/00 ,  B05D7/24

    CPC分类号： C09D153/00 ,  C08F2/24 ,  C08F287/00 ,  C08F293/005 ,  C08L53/00 ,  C08L53/005 ,  Y10T428/31935 ,  Y10T428/31938 ,  C08L2666/02

    摘要： An aqueous coating composition (which optionally can coat plastic substrates) the composition comprising a block copolymer and a polymer P; where the block copolymer comprises at least blocks [A]x[B]y; where at least block [A] is obtained by a controlled radical polymerisation of at least one ethylenically unsaturated monomer via a reversible addition-fragmentation chain transfer (RAFT) mechanism (optionally in solution in the presence of a control agent and a source of free radicals); and wherein block [A] comprises 20 to 100 mol % of ethylenically unsaturated monomer units bearing water-dispersing functional groups; wherein block [B] comprises 20 to 100 mol % of ethylenically unsaturated monomer units bearing plastic adhesion promoting functional groups; and wherein polymer P is prepared in the presence of blocks [A]x[B]y. The compositions may be used to coat plastic substrates, foam; surfaces having low surface energy, hydrophobic substrates and/or polyolefins.

    摘要翻译： 包含嵌段共聚物和聚合物P的组合物的水性涂料组合物（其可任选地可以涂覆塑料基材）; 其中嵌段共聚物至少包含嵌段[A] x [B] y; 其中至少通过可逆加成 - 断裂链转移（RAFT）机理（任选在溶液中存在控制剂和自由基来源）通过至少一种烯属不饱和单体的受控自由基聚合获得嵌段[A] ）; 并且其中嵌段[A]包含20至100摩尔％的带有水分散官能团的烯属不饱和单体单元; 其中嵌段[B]包含20至100摩尔％的具有塑性粘合促进官能团的烯属不饱和单体单元; 并且其中聚合物P在嵌段[A] x [B] y的存在下制备。 组合物可用于涂覆塑料基材，泡沫; 具有低表面能的表面，疏水性基材和/或聚烯烃。