公开(公告)号：US20120315397A1

公开(公告)日：2012-12-13

申请号：US13588555

申请日：2012-08-17

申请人： Gerardus Cornelis Overbeek ,  Alfred Jean Paul Bückmann ,  Michael Arnoldus Jacobus Schellekens ,  Jacobus Willem Griffioen

发明人： Gerardus Cornelis Overbeek ,  Alfred Jean Paul Bückmann ,  Michael Arnoldus Jacobus Schellekens ,  Jacobus Willem Griffioen

IPC分类号： C08L75/04 ,  C09D11/10 ,  B05D5/00 ,  C09J175/04

CPC分类号： C09D11/102 ,  C08L75/08 ,  C09D11/101 ,  C09D175/04 ,  C09D175/16 ,  C09J175/04 ,  C09J175/08 ,  C08L2666/20

摘要： A radiation curable composition comprising 15 to 85 wt % of at least one solvent comprising ≦20 wt % of water; 5 to 50 wt % of at least one radiation curable material having a Mn in the range of from 50 to 10,000 g/mol; and 10 to 70 wt % of at least one polyurethane having a Mw in the range of from 4,000 to 70,000 g/mol, the polyurethane having 0 to 5 wt % of isocyanate-reactive component(s) bearing ionic or potentially ionic water-dispersing groups and a free isocyanate group content ≦0.5 wt %.

摘要翻译： 一种可辐射固化组合物，其包含15至85重量％的至少一种溶剂，其包含20重量％的水; 5〜50重量％的至少一种Mn在50〜10,000g / mol范围内的可辐射固化材料; 和10至70重量％的至少一种Mw在4,000至70,000g / mol范围内的聚氨酯，所述聚氨酯具有0至5重量％的具有离子或潜在离子水分散体的异氰酸酯反应性组分 基团和游离异氰酸酯基含量＆nlE; 0.5wt％。

公开(公告)号：US07968011B2

公开(公告)日：2011-06-28

申请号：US12281688

申请日：2007-03-06

申请人： Gerardus Cornelis Overbeek ,  Michael Arnoldus Jacobus Schellekens ,  Alfred Jean Paul Bückmann

发明人： Gerardus Cornelis Overbeek ,  Michael Arnoldus Jacobus Schellekens ,  Alfred Jean Paul Bückmann

IPC分类号： H01B1/04 ,  H01B1/02 ,  H01B1/22 ,  C08K3/04 ,  C08K3/08

CPC分类号： C09D11/101 ,  C09D11/52 ,  H01B1/22 ,  H05K1/095 ,  Y10T428/249948 ,  Y10T428/25 ,  Y10T428/265

摘要： A conductive ink comprising 10 to 75 wt % of at least one solvent comprising ≦20 wt % water; 0 to 50 wt % of at least one radiation curable material having a Mn in the range of from 50 to 10,000 g/mol; 5 to 70 wt % of at least one polyurethane having a Mw in the range of from 4,000 to 70,000 g/mol, 0 to 5 wt % of isocyanate-reactive component(s) bearing ionic or potentially ionic water-dispersing groups and a free isocyanate group content

摘要翻译： 导电油墨，其包含10至75重量％的至少一种溶剂，其包含20重量％的水; 0〜50重量％的至少一种Mn在50〜10,000g / mol范围内的可辐射固化材料; 5至70重量％的Mw为4,000至70,000g / mol的至少一种聚氨酯，0至5重量％的带有离子或潜在离子性水分散基团的异氰酸酯反应性组分， 异氰酸酯基含量<0.5重量％和20〜85重量％的导电材料。

公开(公告)号：US20130172439A1

公开(公告)日：2013-07-04

申请号：US13515951

申请日：2010-12-17

申请人： Rajasingham Satgurunathan ,  Emilio Martin ,  Adrianus Antonius Johannes Van Geel ,  Franciscus Adrianus Johannes Suykerbuyk ,  Daniela Senatore ,  Alfred Jean Paul Bückmann

发明人： Rajasingham Satgurunathan ,  Emilio Martin ,  Adrianus Antonius Johannes Van Geel ,  Franciscus Adrianus Johannes Suykerbuyk ,  Daniela Senatore ,  Alfred Jean Paul Bückmann

IPC分类号： C08F2/50

CPC分类号： C09D11/107 ,  B05D3/06 ,  C09D11/101

摘要： There is described a substantially solid, solvent free, radiation curable composition comprising a) optionally from 0.1% to 99.9% by weight of a colorant; and b) from 0.1% to 99.9% of radiation curable polymer obtained and/or obtainable from at least one mono-(terminal functional forming) monomer of formula I: R1(R2)C═CR3(C═O)(X1)nR4 Formula 1, where n is 0 or 1, X1 is oxy or —NR5— (where R5 represents H or optionally substituted organo), R1 independently represents optionally substituted C1-10hydrocarbo, hydroxyl, optionally substituted C2-10hydrocarbo-oxy comprising a ring moiety, and/or carboxy; and R2, R3 and R4 each independently represent H, an optional substituent and/or optionally substituted organo groups and where n is 0, R3 may also represent oxy or —NR5—; and c) optionally from 0.1% to 90% of a radiation curable high molecular weight reactive diluent; and d) optionally from 0.01 to 10% of at least one photo-initiator; and where the radiation curable polymer (b) is i) obtained and/or obtainable in a suspension polymerisation process using a cobalt catalyst as a chain transfer agent; ii) is solid under standard conditions; and iii) is mono-(terminal functional) comprising one terminally located activated unsaturated moiety (such as of Formula 1 herein). where the composition has at least one of the properties (A) to (F): A) is substantially free of volatile organic compounds (VOCs); B) has a residual concentration of initiator (such as peroxide) of less than 0.025 g per g of polymer; C) comprises a polymer having a total ethylenic unsaturation (for example from moiet(ies) of Formula 1, such as C═C and/or (meth)acrylate) greater than 0.1 milli-equivalents C═C per g polymer; D) is substantially-free of sulphur comprising species; E) is substantially free of cobalt (II) species; and/or F) has a weight average molecular weight (Mw) of less then 25 kDa.

公开(公告)号：US20130131268A1

公开(公告)日：2013-05-23

申请号：US13578040

申请日：2011-02-10

申请人： Alfred Jean Paul Bückmann ,  Danny Visser ,  Johannes Jacobus Julius Van Den Biggelaar

发明人： Alfred Jean Paul Bückmann ,  Danny Visser ,  Johannes Jacobus Julius Van Den Biggelaar

IPC分类号： C09D4/00

CPC分类号： C09D4/00 ,  C08L33/04 ,  C08L75/16 ,  C09D7/65 ,  C09D151/003 ,  C09D167/07 ,  C09D175/14 ,  C09D175/16

摘要： A radiation curable liquid coating composition comprising 1 to 90 wt % of at least one multifunctional (meth)acrylated oligomer; 10 to 80 wt % of at least one C8 to C20 monofunctional aliphatic alkyl (meth)acrylate; 0 to 40 wt % of at least one monomeric reactive diluent wherein (a)+(b)+(c)=100%; and additionally comprising 0.1 to 15 wt % of matting agent by weight of the coating composition.

摘要翻译： 一种可辐射固化的液体涂料组合物，其包含1-90wt％的至少一种多官能（甲基）丙烯酸酯化的低聚物; 10〜80重量％的至少一种C8〜C20单官能脂肪族烷基（甲基）丙烯酸酯; 0至40重量％的至少一种单体反应性稀释剂，其中（a）+（b）+（c）= 100％; 并且还包含0.1至15重量％的涂料组合物重量的消光剂。

公开(公告)号：US09512322B2

公开(公告)日：2016-12-06

申请号：US13578040

申请日：2011-02-10

申请人： Alfred Jean Paul Bückmann ,  Danny Visser ,  Johannes Jacobus Julius Van Den Biggelaar

发明人： Alfred Jean Paul Bückmann ,  Danny Visser ,  Johannes Jacobus Julius Van Den Biggelaar

IPC分类号： C09D175/16 ,  C09D4/00 ,  C09D151/00 ,  C09D7/12 ,  C09D167/07 ,  C09D175/14 ,  C08L33/04 ,  C08L75/16

CPC分类号： C09D4/00 ,  C08L33/04 ,  C08L75/16 ,  C09D7/65 ,  C09D151/003 ,  C09D167/07 ,  C09D175/14 ,  C09D175/16

摘要： A radiation curable liquid coating composition comprising 1 to 90 wt % of at least one multifunctional (meth)acrylated oligomer; 10 to 80 wt % of at least one C8 to C20 monofunctional aliphatic alkyl (meth)acrylate; 0 to 40 wt % of at least one monomeric reactive diluent wherein (a)+(b)+(c)=100%; and additionally comprising 0.1 to 15 wt % of matting agent by weight of the coating composition.

摘要翻译： 一种可辐射固化的液体涂料组合物，其包含1-90wt％的至少一种多官能（甲基）丙烯酸酯化的低聚物; 10〜80重量％的至少一种C8〜C20单官能脂肪族烷基（甲基）丙烯酸酯; 0至40重量％的至少一种单体反应性稀释剂，其中（a）+（b）+（c）= 100％; 并且还包含0.1至15重量％的涂料组合物重量的消光剂。

公开(公告)号：US20130224382A1

公开(公告)日：2013-08-29

申请号：US13856696

申请日：2013-04-04

申请人： Gerardus Cornelis OVERBEEK ,  Alfred Jean Paul Bückmann ,  Michael Arnoldus Jacobus Schellekens ,  Jacobus Willem Griffioen

发明人： Gerardus Cornelis OVERBEEK ,  Alfred Jean Paul Bückmann ,  Michael Arnoldus Jacobus Schellekens ,  Jacobus Willem Griffioen

IPC分类号： C09D11/10 ,  C08L75/08 ,  C09J175/08

CPC分类号： C09D11/102 ,  C08L75/08 ,  C09D11/101 ,  C09D175/04 ,  C09D175/16 ,  C09J175/04 ,  C09J175/08 ,  C08L2666/20

摘要： A radiation curable composition comprising 15 to 85 wt % of at least one solvent comprising ≦20 wt % of water; 5 to 50 wt % of at least one radiation curable material having a Mn in the range of from 50 to 10,000 g/mol; and 10 to 70 wt % of at least one polyurethane having a Mw in the range of from 4,000 to 70,000 g/mol, the polyurethane having 0 to 5 wt % of isocyanate-reactive component(s) bearing ionic or potentially ionic water-dispersing groups and a free isocyanate group content ≦0.5 wt %.

摘要翻译： 一种可辐射固化组合物，其包含15至85重量％的至少一种包含20重量％水的溶剂; 5〜50重量％的至少一种Mn在50〜10,000g / mol范围内的可辐射固化材料; 和10至70重量％的至少一种Mw在4,000至70,000g / mol范围内的聚氨酯，所述聚氨酯具有0至5重量％的具有离子或潜在离子水分散体的异氰酸酯反应性组分 基团和0.5重量％的游离异氰酸酯基含量。

公开(公告)号：US20120035316A1

公开(公告)日：2012-02-09

申请号：US13276196

申请日：2011-10-18

申请人： Saskia Carolien VAN DER SLOT ,  Tijs Nabuurs ,  Alfred Jean Paul BÜCKMANN ,  Gerardus Cornelis Overbeek

发明人： Saskia Carolien VAN DER SLOT ,  Tijs Nabuurs ,  Alfred Jean Paul BÜCKMANN ,  Gerardus Cornelis Overbeek

IPC分类号： C09D133/24 ,  C08F216/04 ,  C08F222/20 ,  C08F216/14 ,  C09D133/14 ,  C09D135/02 ,  C09J133/24 ,  C09J133/14 ,  C09J135/02 ,  C08F216/36 ,  C08F293/00 ,  B82Y30/00

CPC分类号： C08F4/26 ,  C08F2/22 ,  C08F2/38 ,  C08F220/14 ,  C08F265/06 ,  C08F290/062 ,  C09D151/00 ,  C09J151/00 ,  C08F2220/1825 ,  C08F220/06 ,  C08F220/58

摘要： Process for preparing a macromonomer using free radical-initiated aqueous emulsion polymerisation in a polymerisation reactor of at least one olefinically unsaturated monomer, which process employs a hydrophobic Co chelate complex as a CTA, a stabilising substance(s) for the emulsion polymerisation process and a monomer feed stage MF;wherein an aqueous pre-emulsified mixture A, comprising at least part of the Co chelate(s) employed, at least part of the stabilising substance(s) employed, and (i) a non-polymerisable organic solvent(s) and/or (ii) a polymerisable monomer(s) in unpolymerised or at least partially polymerised form, is contacted in the reactor with monomer(s) of feed stage MF at the beginning of and/or during the course of feed stage MF; and wherein in mixture A the weight ratio of (i) and/or (ii) to the stabilising substance(s) is in the range of from 10/1 to 1/10.

摘要翻译： 在至少一种烯属不饱和单体的聚合反应器中使用自由基引发的水性乳液聚合制备大分子单体的方法，该方法使用疏水性Co螯合物络合物作为CTA，用于乳液聚合方法的稳定物质和 单体进料级MF; 其中包含至少部分所述Co螯合物的至少一部分所用稳定物质的水性预乳化混合物A和（i）不可聚合的有机溶剂和/或 （ii）未聚合或至少部分聚合形式的可聚合单体在反应器中在进料阶段MF的开始和/或期间在进料阶段MF的单体接触; 并且其中在混合物A中，（i）和/或（ii）与稳定物质的重量比在10/1至1/10的范围内。