公开(公告)号：US5026806A

公开(公告)日：1991-06-25

申请号：US417698

申请日：1989-10-05

申请人： Gerd Rehmer ,  Andreas Boettcher ,  Peter Pfoehler ,  Oral Aydin ,  Gerhard Nestler

发明人： Gerd Rehmer ,  Andreas Boettcher ,  Peter Pfoehler ,  Oral Aydin ,  Gerhard Nestler

IPC分类号： C08J5/18 ,  C08F220/18 ,  C08L23/00 ,  C08L33/04 ,  C08L33/06 ,  C09J133/06

CPC分类号： C09J133/062 ,  C08F220/18 ,  C09J2201/606

摘要： Materials which are cross-linkable by ultraviolet radiation under atmospheric oxygen and are based on (meth)acrylate copolymers having a K value of from 10 to 100 are obtained by free radical polymerization, in the presence or absence of a solvent, ofa) from 5% to 97.4% by weight of isoamyl acrylate and/or isoamyl methacrylate,b) from 9% to 89.9% by weight of (methacrylates whose homopolymers have a glass transition temperature below -30.degree. C.,c) from 2.5% to 30% by weight of .alpha.,.beta.-monoolefinically unsaturated compounds whose homopolymers have a glass transition temperature above -30.degree. C.,d) from 0% to 10% by weight of monoolefinically unsaturated acids and/or their anhydrides ande) from 0% to 20% by weight of further olefinically unsaturated monomers having one or more of the following functional groups: hydroxyl, amide, epoxide, ether, ester, urethane, urea, primary, secondary and tertiary amine and ether groups, andf) from 0.1% to 5% by weight of a copolymerizable benzophenone derivative or acetophenone derivative,the sum of the percentages by weight X (=a+b+c+d+f) being 100 in each case.

摘要翻译： 通过在大气氧下通过紫外线辐射可交联并且基于具有10至100的K值的（甲基）丙烯酸酯共聚物的材料通过自由基聚合在溶剂存在或不存在下通过a） 5％至97.4％的丙烯酸异戊酯和/或甲基丙烯酸异戊酯，b）9％至89.9％（重量）（甲基丙烯酸酯的均聚物的玻璃化转变温度低于-30℃，c）为2.5％至30％ 重量％的α，β-单烯烃不饱和化合物，其均聚物具有高于-30℃的玻璃化转变温度，d）0重量％至10重量％的单烯属不饱和酸和/或其酸酐，和e）0％ 至20重量％的具有一个或多个以下官能团的其它烯属不饱和单体：羟基，酰胺，环氧化物，醚，酯，氨基甲酸酯，脲，伯，仲和叔胺和醚基，以及f）0.1％ 至5重量％的可共聚的b 烯苯酯衍生物或苯乙酮衍生物，每种情况下，重量百分比X（= a + b + c + d + f）之和为100。

公开(公告)号：US4912147A

公开(公告)日：1990-03-27

申请号：US257877

申请日：1988-10-14

申请人： Peter Pfoehler ,  Maximilian Angel ,  Andreas Einwiller ,  Klaus Schagerer

发明人： Peter Pfoehler ,  Maximilian Angel ,  Andreas Einwiller ,  Klaus Schagerer

IPC分类号： C08F2/22 ,  C08F2/24 ,  C08F20/52 ,  C08F220/12 ,  C08F220/58 ,  C08F265/06 ,  C09J133/04 ,  D04H1/435 ,  D04H1/587 ,  D04H1/645 ,  D06M15/263

CPC分类号： D04H1/435 ,  C08F220/12 ,  C08F265/06 ,  D04H1/587 ,  D04H1/645 ,  D06M15/263

摘要： Aqueous (meth)acrylate copolymer dispersions can be prepared by polymerization of the monomers in two stages having different monomer compositions and with the concomitant use of crosslinking monomers in aqueous emulsion at the usual temperatures in the presence of the conventional emulsifiers and polymerization initiators, from 40 to 99.5% by weight of the total monomers being polymerized in the first stage and from 60 to 0.5% by weight of the total monomers being polymerized in the second stage, by a process in which from 0.5 to 10% by weight, based on the total monomers, of (meth)-acrylamidoglycollic acid and /or its methyl ester and/or its methyl ether are polymerized in the second stage and from 0 to 1.8% by weight, based on the total monomers, of the amidoglycollic acid compounds are polymerized in the first stage, and the resulting copolymer dispersions are used as binders for sheet-like textile fibrous structures.

摘要翻译： 水性（甲基）丙烯酸酯共聚物分散体可以通过在具有不同单体组成的两个阶段中聚合单体并在常规温度下在常规乳化剂和聚合引发剂存在下伴随使用交联单体在水性乳液中制备，从40 至99.5重量％的第一阶段中聚合的单体的总重量和在第二阶段中聚合的总单体的60至0.5重量％的方法，其中以0.5至10重量％ （甲基）丙烯酰胺聚糖和/或其甲基酯和/或其甲基醚的总单体在第二阶段中聚合，并且基于总单体为0至1.8重量％的酰胺聚糖酸化合物聚合 在第一阶段中，将所得的共聚物分散体用作片状纺织纤维结构体的粘合剂。

公开(公告)号：US5244950A

公开(公告)日：1993-09-14

申请号：US768764

申请日：1991-10-15

申请人： Bernhard Schlarb ,  Gerhard Auchter ,  Peter Pfoehler

发明人： Bernhard Schlarb ,  Gerhard Auchter ,  Peter Pfoehler

IPC分类号： C08F2/06 ,  C08K5/5435 ,  C09J133/06

CPC分类号： C08K5/5435 ,  C09J133/06

摘要： An aqueous synthetic resin dispersion consisting of (A) from 35 to 60% by weight of a synthetic resin prepared by free radical solution polymerization of a monomer mixture A1 and monomer mixture A2, wherein mixture A1 is (a) from 1.5 to 15% by weight of at least one C.sub.3-5 unsaturated monocarboxylic acid, maleic or itaconic acid or anhydride and half-esters of maleic acid or itaconic acid with a C.sub.1-8 ankanol or with glycol monoethers, (b) from 65 to 98.5% by weight of at least one C.sub.1-10 alkyl (meth)acrylate, and optionally at least one C.sub.11-20 alkyl (meth)acrylate (III), vinyl aromatic monomer (IV), mercaptosilane (V), and copolymerizable monomer (VI), and mixture A2 is (a) from 60 to 100% by weight of at least one monomer II, and optionally at least one monomer III, IV or VI and compound (V), with the proviso that more than 65% by weight of the sum total of A1 and A2 is accounted for by monomers II and an amount of compound V which differs from ) and is incorporated in the copolymer;(B) from 0.05 to 5% by weight of at least one epoxy group containing silane; and(C) at least one of ammonia and an organic amine; with the remainder being water and wherein the dispersion contains from 0 to 5% organic solvent.

摘要翻译： PCT No.PCT / EP90 / 00552 Sec。 371日期1991年10月15日 102（e）日期1991年10月15日PCT 1990年4月7日PCT PCT。 出版物WO90 / 12065 日本1990年10月18日。一种水性合成树脂分散体，其由（A）35〜60重量％的由单体混合物A1和单体混合物A2的自由基溶液聚合制备的合成树脂组成，其中混合物A1为（ ）1.5至15重量％的至少一种C3-5不饱和一元羧酸，马来酸或衣康酸或酸酐，以及马来酸或衣康酸与C 1-8烷醇或与二醇单醚的半酯，（b） 65〜98.5重量％的至少一种（甲基）丙烯酸C 1-10烷基酯和任选至少一种（甲基）丙烯酸C 11-20烷基酯（III），乙烯基芳族单体（Ⅳ），巯基硅烷（Ⅴ）和可共聚的 单体（VI）和混合物A2是（a）60至100重量％的至少一种单体II和任选的至少一种单体III，IV或VI和化合物（V），条件是超过65 A1和A2的总和的重量百分比由单体II和与之不同的化合物V的量占据而被并入 共聚物; （B）0.05至5重量％的至少一种含环氧基的硅烷; 和（C）氨和有机胺中的至少一种; 其余为水，并且其中分散体含有0至5％的有机溶剂。

公开(公告)号：US4898909A

公开(公告)日：1990-02-06

申请号：US139822

申请日：1987-12-30

申请人： Juergen Vietmeier ,  Peter Pfoehler ,  Gundo Brauch ,  Wolfgang Druschke ,  Albrecht Zosel

发明人： Juergen Vietmeier ,  Peter Pfoehler ,  Gundo Brauch ,  Wolfgang Druschke ,  Albrecht Zosel

IPC分类号： C08L33/08 ,  C08F20/10 ,  C08F220/18 ,  C08L33/04 ,  C09J7/02 ,  C09J133/04 ,  C09J133/08

CPC分类号： C08F220/18 ,  C09J133/08 ,  C09J7/0217 ,  C09J2201/606

摘要： Aqueous dispersions of copolymers having a glass transition temperature of not more than -45.degree. C. and a K value greater than 80 consist of not less than 80% by weight of acrylates of alkanols of 8 to 12 carbon atoms, from 1 to 4% by weight of .alpha.,.beta.- monoolefinically unsaturated carboxylic acids and/or their amide derivatives and from 0.1 to 3% by weight of .alpha.-methylstyrene, and are used for the production of self-adhesive structures having good tack at as low as -40.degree. C.

摘要翻译： 玻璃化转变温度不高于-45℃，K值大于80的共聚物的水分散体由不低于80重量％的8至12个碳原子的链烷醇的丙烯酸酯，1至4重量％ 的α，β-单烯属不饱和羧酸和/或其酰胺衍生物和0.1-3重量％的α-甲基苯乙烯，并且用于生产具有低至-40的良好粘性的自粘结构 DEG C.

公开(公告)号：US5405693A

公开(公告)日：1995-04-11

申请号：US113302

申请日：1993-08-30

申请人： Uwe Dittrich ,  Bernd Stanger ,  Josef Neutzner ,  Peter Pfoehler ,  Helmut Mueller ,  Johannes Tuerk

发明人： Uwe Dittrich ,  Bernd Stanger ,  Josef Neutzner ,  Peter Pfoehler ,  Helmut Mueller ,  Johannes Tuerk

IPC分类号： C08F220/18 ,  C08F2/24 ,  C08F20/10 ,  C08F20/26 ,  C08F220/28 ,  C08L33/04 ,  C08L33/06 ,  C09J7/02 ,  C09J133/04 ,  C09J133/06 ,  G09F3/10 ,  B32B7/12

CPC分类号： C09J133/06 ,  C09J2201/606 ,  Y10T428/2891 ,  Y10T428/31692 ,  Y10T428/31895 ,  Y10T428/31906 ,  Y10T428/31913 ,  Y10T428/31935

摘要： An aqueous dispersion containing a copolymer comprisinga) 60-95% by weight of a C.sub.2 -C.sub.10 -alkyl (meth)acrylateb) 5-40% by weight of methyl acrylatec) 0-30% by weight of methyl methacrylated) 0-30% by weight of a C.sub.8 -C.sub.12 -vinylaromatic compounde) 0-10% by weight of a C.sub.1 -C.sub.10 -hydroxyalkyl (meth)acrylatef) 0-5% by weight of an ethylenically unsaturated C.sub.3 -C.sub.5 -carboxylic acid or dicarboxylic acidg) 0-20% by weight of further ethylenically unsaturated compounds,vinyl acetate and chlorine-containing compounds being excluded, is used as an adhesive.

摘要翻译： 含有共聚物的水分散体，其包含a）60-95重量％的（甲基）丙烯酸C 2 -C 10烷基酯b）5-40重量％的丙烯酸甲酯c）0-30重量％的甲基丙烯酸甲酯d） 0〜30重量％的C 8 -C 12 - 乙烯基芳族化合物e）0-10重量％的（甲基）丙烯酸C 1 -C 10羟烷基酯f）0-5重量％的烯属不饱和C 3 -C 5 - 羧酸 酸或二羧酸g）0-20重量％的其它烯键式不饱和化合物，醋酸乙烯酯和不含氯的化合物被用作粘合剂。

公开(公告)号：US4937282A

公开(公告)日：1990-06-26

申请号：US359975

申请日：1989-06-01

申请人： Peter Pfoehler ,  Hermann Seyffer ,  Juergen Vietmeter ,  Johannes Tuerk ,  Wolfgang Druschke ,  Klaus Schagerer

发明人： Peter Pfoehler ,  Hermann Seyffer ,  Juergen Vietmeter ,  Johannes Tuerk ,  Wolfgang Druschke ,  Klaus Schagerer

IPC分类号： C08L33/06 ,  C08F220/00 ,  C08F220/10 ,  C08F220/12 ,  C08F220/18 ,  C08F220/26 ,  C08F220/28 ,  C08F220/44 ,  C08L33/04 ,  C09J7/02 ,  C09J133/00 ,  C09J133/04

CPC分类号： C08F220/18

摘要： Aqueous dispersions of copolymers of(a) from 70 to 85% by weight of nontertiary butyl (meth)acrylates,(b) from 8 to 27.2% by weight of (meth)acrylates (A) whose homopolymers have a glass transition temperature greater than that of the polybutyl (meth)acrylate up to 0.degree. C. and (meth)acrylates (B) whose homopolymers have a glass transition temperature below that of the polybutyl (meth)acrylate, the weight ratio of the (meth)acrylates (A) to the (meth)acrylates (B) being from 3:1 to 1:3,(c) from 2 to 15% by weight of methyl methacrylate, styrene and/or acrylonitrile and(d) 0.8 to 5% by weight of monoolefinically unsaturated mono- and/or dicarboxylic acids of 3 to 5 carbon atoms and/or their amides which are unsubstituted or substituted at the nitrogen atoms by alkyl and/or alkylol radicals of 1 to 4 carbon atoms and/or hydroxyalkyl (meth)acrylates where the alkyl groups are of 2 to 5 carbon atoms,are used for coating sheet-like substrates.

摘要翻译： （a）70至85重量％的（甲基）丙烯酸异丁酯，（b）8至27.2重量％的（甲基）丙烯酸酯（A）的共聚物的水分散体，其均聚物的玻璃化转变温度高于 （甲基）丙烯酸酯至0℃的聚丙烯酸酯和其均聚物的玻璃化转变温度低于（甲基）丙烯酸丁酯的（甲基）丙烯酸酯（B）的重量比为（甲基）丙烯酸酯 ）（甲基）丙烯酸酯（B）为3:1至1:3，（c）2至15重量％的甲基丙烯酸甲酯，苯乙烯和/或丙烯腈和（d）0.8至5重量％ 3至5个碳原子的单烯属不饱和单 - 和/或二羧酸和/或它们的酰胺，它们是未取代的或在氮原子上被1-4个碳原子的烷基和/或烷醇基取代，和/或（甲基）丙烯酸羟烷基酯 其中烷基为2至5个碳原子，用于涂覆片状基底。

公开(公告)号：US4931494A

公开(公告)日：1990-06-05

申请号：US210321

申请日：1988-06-23

申请人： Gerhard Auchter ,  Thomas Schwerzel ,  Rolf Osterloh ,  Gerhard Neubert ,  Peter Pfoehler ,  Wolfgang Druschke ,  Helmut Jaeger

发明人： Gerhard Auchter ,  Thomas Schwerzel ,  Rolf Osterloh ,  Gerhard Neubert ,  Peter Pfoehler ,  Wolfgang Druschke ,  Helmut Jaeger

IPC分类号： C08F2/16 ,  C08K5/25 ,  C08L33/04 ,  C08L33/06 ,  C09J133/04 ,  C09J133/06

CPC分类号： C08L33/064 ,  C08K5/25 ,  C09J133/06 ,  C08L33/06

摘要： Aqueous polymer dispersions which have a long shelf life are obtainable by dispersing a mixture of from 15 to 70% by weight of a copolymer (A) of(I) from 1.5 to 15% by weight of copolymerizable compounds of 3 to 10 carbon atoms which contain a carboxyl or carboxylic anhydride group,(II) from 65 to 98.5% by weight of C.sub.1 -C.sub.20 -alkyl acrylates or methacrylates,(III) from 0 to 20% by weight of vinylaromatics,(IV) from 0 to 20% by weight of copolymerizable carbonyl compounds and(V) from 0 to 10% by weight of further copolymerizable organic compounds not stated under (I) to (IV), and from 30to 85% by weight of a copolymer (B) of from 60 to 100% by weight of the monomers (II) and from 0 to 40% by weight of the monomers (III) to (V), with the proviso that the copolymers (A) and (B) together contain, as components, more than 65% by weight of alkyl (meth)acrylates (II) whose homopolymers have glass transition temperatures of less than 0.degree. C., and that one or more of the copolymers (A) and (B) contain the monomers (IV) as components, in water with the addition of ammonia and a polyhydrazide (C), and the said dispersions are used as pressure sensitive adhesives and as adhesives for laminated films.

摘要翻译： 通过将15〜70重量％的（I）共聚物（A）与1.5〜15重量％的3〜10个碳原子的可共聚的化合物分散而得到的具有长保存期限的聚合物水分散体可以得到， 含有羧基或羧酸酐基团，（II）65至98.5重量％的丙烯酸或甲基丙烯酸C 1 -C 20烷基酯，（III）0至20重量％的乙烯基芳烃，（Ⅳ）0至20重量％ 可共聚羰基化合物的重量和（V）0至10重量％的（I）至（IV）中未提及的另外可共聚的有机化合物，以及30至85重量％的共聚物（B）为60至100 单体（II）的重量％和单体（III）至（V）的0至40重量％，条件是共聚物（A）和（B）共同作为组分含有超过65 重量％的其均聚物具有小于0℃的玻璃化转变温度的（甲基）丙烯酸烷基酯（II），以及一种或多种共聚物（A）和（ B）在水中加入氨和聚酰肼（C）作为组分含有单体（Ⅳ），所述分散体用作压敏粘合剂和层压薄膜的粘合剂。