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公开(公告)号：US4296045A
公开(公告)日：1981-10-20
申请号：US770228
申请日：1977-02-18
摘要： A poly(-N-alkyliminoalane) having the composition (HAlNR).sub.n, wherein R represents an aliphatic, cycloaliphatic, aromatic or alkyl-aromatic group, and n is a number in the range of 3 to 50, is prepared by directly reacting metallic aluminum with a primary amine having the formula H.sub.2 NR, wherein R has the meaning given above, in the presence of hydrogen at a pressure in the range of from 1 to 1000 kg/cm.sup.2 and at least a stoichiometric quantity of aluminum, at a temperature in the range of from room temperature to the dissociation temperature of the end product, and in the presence of a promoter such as a small quantity of the poly(-N-alkyliminoalane) constituting the end product of said reaction.
摘要翻译： 具有组成（HA1NR）n的聚（N-烷基亚氨基亚氨烷），其中R表示脂族，脂环族，芳族或烷基 - 芳族基团，n为3〜50的数，是通过使金属 铝，其具有式H2NR的伯胺，其中R具有上述含义，在氢气存在下，在1至1000kg / cm 2的压力和至少化学计量的铝的存在下，在 在最终产物的室温至解离温度的范围内，以及在构成所述反应的最终产物的少量聚（N-烷基亚氨基亚氨烷）等促进剂存在下进行。
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公开(公告)号：US4258226A
公开(公告)日：1981-03-24
申请号：US103489
申请日：1979-12-14
IPC分类号： B01J31/12 , B01J31/22 , B01J31/30 , C07B61/00 , C07C1/00 , C07C5/10 , C07C13/18 , C07C67/00 , C07C5/02
CPC分类号： B01J31/0237 , B01J31/0238 , B01J31/121 , B01J31/122 , B01J31/143 , B01J31/26 , B01J31/30 , C07C5/10 , B01J21/02 , B01J2231/641 , B01J2231/646 , B01J23/02 , C07C2521/02 , C07C2521/10 , C07C2523/04 , C07C2527/128 , C07C2531/02 , C07C2531/12 , C07C2531/14 , C07C2531/30
摘要： For hydrogenating unsaturated compounds, and especially those containing aromatic rings, a catalytic system of novel conception is suggested. This is a quaternary heterogeneous system which comprises an elemental metal of Groups IIA or IIIA, a primary or a secondary amine, a Ni or a Co halide, and an activator such as Na, NaH, NaAlH.sub.4 or AlEt.sub.3.Very satisfactory results as to yields and smoothness of reaction are obtained in the conversion of benzene to cyclohexane and of toluene to methylcyclohexane.
摘要翻译： 为了氢化不饱和化合物，特别是含有芳香环的化合物，提出了一种新颖的概念催化体系。 这是一种四元非均相体系，其包括IIA族或IIIA族的元素金属，伯胺或仲胺，Ni或Co卤化物，和活化剂如Na，NaH，NaAlH4或AlEt3。 在苯转化为环己烷和甲苯转化成甲基环己烷时，得到的产率和反应平滑度得到非常令人满意的结果。
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3.发明授权Oligomeric iminic derivatives of aluminum hydride and method for their preparation 失效氢化铝的低聚亚胺衍生物及其制备方法
公开(公告)号：US4239692A
公开(公告)日：1980-12-16
申请号：US020837
申请日：1979-03-15
IPC分类号： C07F5/06
CPC分类号： C07F5/069
摘要： There are disclosed oligomeric aluminum hydride iminic derivatives to be employed as catalysts in polymerization processes and, which are prepared by causing alkali-metal or alkaline-earth-metal alanates to react with a primary amine which contains a group of the type --X--R".sub.m, wherein X is a nitrogen atom or an oxygen atom and m is equal to the valence of X minus one. The compounds have a trimeric or a tetrameric "open cage" spatial configuration.
摘要翻译： 公开了在聚合过程中用作催化剂的低聚物氢化铝亚胺衍生物，其通过使碱金属或碱土金属的丙烯酸酯与含有-X-R型基团的伯胺反应来制备 其中X是氮原子或氧原子，m等于X的化合价减去1。 这些化合物具有三聚体或四聚体“开放笼”的空间结构。
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公开(公告)号：US4022809A
公开(公告)日：1977-05-10
申请号：US524312
申请日：1974-11-15
CPC分类号： C07F5/069
摘要： A poly-N-alkyliminoalane containing repeated imine units of the type ##STR1## wherein R is an aliphatic radical, is prepared by reacting an alane of an alkali or alkali-earth metal with a primary amine in the presence of a hydrocarbon solvent.
摘要翻译： 通过在烃溶剂存在下使碱金属或碱土金属的烷烃与伯胺反应制备含有重复亚胺单元的类型“IMAGE”的聚-N-烷基亚氨基亚胺，其中R是脂族基团。
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公开(公告)号：US4710531A
公开(公告)日：1987-12-01
申请号：US524788
申请日：1983-08-19
CPC分类号： C08K5/00 , C08K13/02 , C08K3/00 , C08K3/04 , C08K3/16 , C08K3/22 , C08K5/06 , C08K5/09 , C08K5/41
摘要： Self-extinguishing polycarbonates are disclosed, which consist of mixtures of polycarbonates with at least one salt of metals of the I and/or the II A and B Groups of the Periodic Table, and/or ammonium salts of organic carboxylic compounds having the general formula (I) ##STR1## and, as an adjuvant, at least one compound which is a member selected from the group consisting of the following classes of compounds:(i) a halogenated phenyl ether;(ii) a phthalimide or naphthalimide;(iii) an organic sulphone or a derivative thereof;(iv) an inorganic compound selected from the group consisting of halides of alkali metals or of alkaline earth metals, oxides of metals of the Groups IB,VIB,VIIB,IIIA,IVA and VIII of the Periodic Table, of the lanthanide group, carbon black and the residues of the pyrolysis of the organic acid salts of formula (I).
摘要翻译： 公开了自熄性聚碳酸酯，其由聚碳酸酯与至少一种I和/或IIA和B族元素周期金属的盐的混合物和/或具有通式（I）的有机羧酸化合物的铵盐组成） （I）和（I）化合物，作为佐剂，至少一种选自以下类别化合物的化合物：（i）卤代苯基醚; （ii）邻苯二甲酰亚胺或萘二甲酰亚胺; （iii）有机砜或其衍生物; （iv）选自碱金属或碱土金属的卤化物，元素周期表IB，VIB，VIIB，IIIA，IVA和VIII族金属的氧化物，无机化合物，镧系元素，碳 黑色和式（I）的有机酸盐的热解残留物。
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6.发明授权Process for the synthesis of mixed polyimino derivatives of aluminum and alkaline earth metals 失效合成铝和碱土金属的混合聚亚氨基衍生物的方法
公开(公告)号：US4193939A
公开(公告)日：1980-03-18
申请号：US678
申请日：1979-01-03
摘要： A single stage process is provided for the direct synthesis of mixed polyimino derivatives of aluminum and alkaline earth metals consisting of reacting aluminum, an amine, the alkaline earth metal or hydride or amide derivative thereof, in the presence of hydrogen, the reaction being promoted by an activator in either hydrocarbon or ether solvents.
摘要翻译： 提供了一种单级方法，用于直接合成铝和碱土金属的混合聚亚氨基衍生物，其由铝，胺，碱土金属或其氢化物或酰胺衍生物在氢的存在下反应，反应由 烃或醚溶剂中的活化剂。
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7.发明授权Process for the synthesis of mixed polyimino derivatives of aluminium and alkaline earth metals 失效合成铝和碱土金属的混合聚亚氨基衍生物的方法
公开(公告)号：US4179459A
公开(公告)日：1979-12-18
申请号：US831240
申请日：1977-09-07
摘要： A single stage process is provided for the direct synthesis of mixed polyimino derivatives of aluminium and alkaline earth metals consisting of reacting aluminium, an amine, the alkaline earth metal or hydride or amide derivative thereof, in the presence of hydrogen, the reaction being promoted by an activator in either hydrocarbon or ether solvents.
摘要翻译： 提供了一种单级方法，用于直接合成铝和碱土金属的混合聚亚氨基衍生物，其由铝，胺，碱土金属或其氢化物或酰胺衍生物在氢的存在下反应，反应由 烃或醚溶剂中的活化剂。
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公开(公告)号：US4757103A
公开(公告)日：1988-07-12
申请号：US921847
申请日：1986-10-23
摘要： Self-extinguishing polycarbonates consisting of mixtures of polycarbonates with at least one salt of particular carboxylic organic compounds, said salt being of metals of Group I A and/or B, and/or Group II A and/or B of the Periodic Table of elements, and/or of ammonium.
摘要翻译： 由聚碳酸酯与至少一种特定羧酸有机化合物的盐的混合物组成的自熄性聚碳酸酯，所述盐为元素周期表第IA和/或B族金属和/或IIA族和/或B族元素， 和/或铵。
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公开(公告)号：US4325885A
公开(公告)日：1982-04-20
申请号：US149896
申请日：1980-05-15
IPC分类号： C07F5/06
CPC分类号： C07F5/069
摘要： There are disclosed oligomeric aluminum hydride iminic derivatives, to be employed as catalysts in polymerization processes and which are prepared by causing alkali-metal or alkaline-earth-metal alanates to react with a primary amine which contains a group of the type --X--R".sub.m, wherein X is a nitrogen atom or an oxygen atom and m is equal to the valence of X minus one. The compounds have a trimeric or a tetrameric "open cage" spatial configuration.
摘要翻译： 公开了低聚氢化铝亚胺衍生物，用作聚合方法中的催化剂，其通过使碱金属或碱土金属的丙烯酸酯与含有-X-R型基团的伯胺反应来制备 其中X是氮原子或氧原子，m等于X的化合价减去1。 这些化合物具有三聚体或四聚体“开放笼”的空间结构。
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10.发明授权Process for synthesizing mixed alkoxy hydride derivatives of aluminium and alkaline earth metals 失效合成铝和碱土金属的混合烷氧基氢化物衍生物的方法
公开(公告)号：US4313891A
公开(公告)日：1982-02-02
申请号：US88581
申请日：1979-10-26
IPC分类号： C07C1/26 , C07C29/14 , C07C29/143 , C07C29/147 , C07C29/68 , C07C29/70 , C07C31/32 , C07F5/06
CPC分类号： C07F5/069 , C07C1/26 , C07C29/14 , C07C29/143 , C07C29/147 , C07C29/68 , C07C29/70 , C07C31/32 , C07C2101/14
摘要： This invention relates to a process for synthesizing compounds of aluminium and alkaline earth metals containing hydride hydrogens and alkoxy radicals, of compositionM[A1H.sub.4-n (OR).sub.n ].sub.2.xBin which 0.5.ltoreq.n.ltoreq.3.5; OR is an alkoxy radical derived from a primary, secondary or tertiary alcohol; R is an aliphatic, cycloaliphatic or aromatic hydrocarbon radical; M is an alkaline earth metal; B is a Lewis base; x can vary between 0 and 4; and R can also contain functional groups OR', SR', NR'.sub.2 ect., consisting of reacting together:(a) a halide of an alkaline earth metal;(b) an alanate of an alkaline earth metal of formula M' A1H.sub.4 (M'.apprxeq.alkaline metal);(c) an alcohol chosen from primary, secondary or tertiary aliphatic, cycloaliphatic or aromatic alcohols containing 1 to 20 carbon atoms.
摘要翻译： 本发明涉及合成含有氢化物氢和烷氧基的铝和碱土金属化合物的方法，组合物M [AlH4-n（OR）n] 2.xB，其中0.5≤n≤3.5; OR是衍生自伯，仲或叔醇的烷氧基; R是脂族，脂环族或芳族烃基; M是碱土金属; B是路易斯基地 x可以在0和4之间变化; 并且R还可以含有官能团OR'，SR'，NR'2等，它们一起反应：（a）碱土金属的卤化物; （b）式M'A1H4的碱土金属的铝酸盐（M'APPROX碱金属）; （c）选自含有1至20个碳原子的伯，仲或叔脂族，脂环族或芳族醇的醇。
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