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公开(公告)号：US06187061B1
公开(公告)日：2001-02-13
申请号：US09315434
申请日：1999-05-20
IPC分类号： H01G900
CPC分类号： H01G9/155 , H01G4/30 , H01G11/72 , H01M6/181 , H01M10/4264 , H01M16/00 , Y02E60/13 , Y10T29/417
摘要： Supercapacitor cell electrode and separator elements formulated as membranes of plasticized polymers matrix compositions are laminated with electrically conductive current collector elements to form flexible, unitary supercapacitor structures. The matrix plasticizer component is extracted from the laminate with polymer-inert solvent and replaced with electrolyte solution to activate the supercapacitor. Various arrangements of cell structure elements provide parallel and series cell structures which yield improved specific energy capacity and increased voltage output for utilization demands. The supercapacitor elements may also be laminated with similar polymeric rechargeable battery cell structures to provide hybrid devices capable of delivering both high energy and high power as needed in electronic systems.
摘要翻译： 配制为增塑聚合物基体组合物的膜的超级电容器电极和隔离元件与导电集电器元件层叠以形成柔性的单一超级电容器结构。 用聚合物惰性溶剂从层压体中提取基质增塑剂组分，并用电解质溶液代替以激活超级电容器。 电池结构元件的各种布置提供并联和串联电池结构，其产生改进的比能量容量和增加的电压输出用于利用需求。 超级电容器元件也可以与类似的聚合物可再充电电池单元结构层压，以提供能够在电子系统中根据需要传送高能量和高功率的混合设备。
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公开(公告)号：US5635138A
公开(公告)日：1997-06-03
申请号：US373830
申请日：1995-01-17
CPC分类号： G01N23/20008 , H01M10/48 , H01M6/181
摘要： An apparatus and method for monitoring structural changes of an electrode in a rechargeable battery include an in situ x-ray study electrochemical cell holder (30) comprising top and bottom cell holder members (32, 34) including at least one beryllium window element (36) for transmission of diffractometer x-radiation. A rechargeable battery cell (43) mounted within the x-ray cell holder enclosure comprises an electrolyte/separator element (68) interposed between positive and negative electrodes (64, 66). A current collector element (70) formed of an electrically-conductive open-mesh grid is disposed between the positive electrode and the separator to enable ion-conducting contact of the electrode and separator while maintaining electrical continuity between the electrode and an external x-ray cell holder terminal (54). As a result of this arrangement, the positive electrode need not contact the window element to establish an electrical battery circuit, but may be sufficiently spaced from the window to avoid electrolytic corrosion of the beryllium element. The in situ x-ray electrochemical cell holder and battery cell structure allow for continuous monitoring of the structural changes in electrode materials during charge/discharge cycling.
摘要翻译： 用于监测可再充电电池中的电极的结构变化的装置和方法包括原位x射线研究电化学电池座（30），其包括顶部和底部电池保持器构件（32,34），其包括至少一个铍窗口元件（36） ）用于传播衍射仪x辐射。 安装在x射线电池保持器外壳内的可再充电电池单元（43）包括插在正极和负极（64,66）之间的电解质/分离元件（68）。 由导电开口网格形成的集电器元件（70）设置在正电极和隔板之间，以使电极和隔板之间能够进行离子导电接触，同时保持电极与外部x射线之间的电连续性 电池座端子（54）。 作为这种布置的结果，正极不需要接触窗口元件以建立电池电路，而是可以与窗口充分间隔开以避免铍元件的电解腐蚀。 原位X射线电化学电池座和电池单元结构允许连续监测充电/放电循环期间电极材料的结构变化。
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3.发明授权Rechargeable battery cell having surface-treated lithiated intercalation positive electrode 失效具有表面处理的锂化插层正极的可充电电池
公开(公告)号：US5705291A
公开(公告)日：1998-01-06
申请号：US630807
申请日：1996-04-10
CPC分类号： H01M4/505 , H01M4/134 , H01M4/62 , Y02P70/54 , Y10T29/49115
摘要： A rechargeable lithiated intercalation battery cell having reduced self-discharge comprises a negative electrode, a nonaqueous electrolyte, and a positive electrode wherein the surfaces of the aggregate lithiated intercalation composition particulates comprising the positive cell electrode have been coated with a passivating layer of a composition comprising a borate, lithiated borate, aluminate, lithiated aluminate, silicate, lithiated silicate, or mixtures thereof.
摘要翻译： 具有减少的自放电的可充电锂化插层电池单元包括负极，非水电解质和正电极，其中包含阳极电池电极的聚集体锂化插层组合物颗粒的表面已经涂覆有组合物的钝化层， 硼酸盐，锂化硼酸盐，铝酸盐，锂化铝酸盐，硅酸盐，锂化硅酸盐或其混合物。
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公开(公告)号：US06181545B2
公开(公告)日：2001-01-30
申请号：US09159557
申请日：1998-09-24
IPC分类号： H01G900
CPC分类号： H01G9/155 , H01G4/30 , H01G11/72 , H01M6/181 , H01M10/4264 , H01M16/00 , Y02E60/13 , Y10T29/417
摘要： Supercapacitor cell electrode and separator elements formulated as membranes of plasticized polymeric matrix compositions are laminated with electrically conductive current collector elements to form flexible, unitary supercapacitor structures. The matrix plasticizer component is extracted from the laminate with polymer-inert solvent and replaced with electrolyte solution to activate the supercapacitor. Various arrangements of cell structure elements provide parallel and series cell structures which yield improved specific energy capacity and increased voltage output for utilization demands. The supercapacitor elements may also be laminated with similar polymeric rechargeable battery cell structures to provide hybrid devices capable of delivering both high energy and high power as needed in electronic systems.
摘要翻译： 配制为增塑聚合物基质组合物的膜的超级电容器电极和隔离元件与导电集电器元件层叠以形成柔性的单一超级电容器结构。 用聚合物惰性溶剂从层压体中提取基质增塑剂组分，并用电解质溶液代替以激活超级电容器。 电池结构元件的各种布置提供并联和串联电池结构，其产生改进的比能量容量和增加的电压输出用于利用需求。 超级电容器元件也可以与类似的聚合物可再充电电池单元结构层压，以提供能够在电子系统中根据需要传送高能量和高功率的混合设备。
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公开(公告)号：US5695887A
公开(公告)日：1997-12-09
申请号：US645018
申请日：1996-05-09
IPC分类号： H01M2/16 , H01M4/131 , H01M4/133 , H01M4/1391 , H01M4/50 , H01M4/505 , H01M4/62 , H01M10/0525 , H01M10/058 , H01M10/36 , H01M2/14
CPC分类号： H01M4/131 , H01M10/0525 , H01M4/505 , H01M4/623 , H01M10/058 , H01M2/166 , H01M4/133 , H01M4/1391 , Y02P70/54 , Y10T29/49115
摘要： The extent of self-discharge of rechargeable Li-ion secondary batteries is significantly reduced by treatment of LiMn.sub.2 O.sub.4 intercalation compound electrode material with a chelating agent, such as acetylacetone. This treatment decreases the incidence of non-coordinated Mn-ion sites which can lead to battery electrolyte decomposition and resulting loss of battery capacity. The treatment, which also includes annealing at about 400.degree. C. to 800.degree. C., further prevents such decomposition by varying the surface area and topography of the potentially catalytic electrode material.
摘要翻译： 通过用螯合剂如乙酰丙酮处理LiMn2O4插层复合电极材料，可充电锂离子二次电池的自放电程度显着降低。 这种处理降低了不协调的Mn离子位点的发生，这可能导致电池电解质分解并导致电池容量的损失。 还包括在约400℃至800℃退火的处理，通过改变潜在催化电极材料的表面积和形貌进一步防止这种分解。
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公开(公告)号：US06432581B1
公开(公告)日：2002-08-13
申请号：US09568970
申请日：2000-05-11
IPC分类号： H01M450
CPC分类号： H01M10/052 , H01M4/382 , H01M4/405 , H01M4/505 , H01M4/58 , H01M4/581 , H01M4/582 , H01M2004/027 , H01M2004/028
摘要： The present invention relates to secondary lithium batteries which include inorganic compound for the negative electrode and a cathode compound for the positive electrode which comprises Li2Mn2−xMexO4−zFz wherein 0≦X≦0.5 and can be optimized to match the irreversible capacity loss associated with a chosen inorganic negative electrode; 0≦Z≦0.5; and Me is selected from the group consisting of Al, Cr, Zn, Co, Ni, Li, Mg, Fe, Cu, Ti, Si or combinations thereof. In addition, the present invention relates to rechargeable plastic lithium ion batteries having a positive electrode, a negative electrode, and a separator element arranged between the electrodes, wherein the positive electrode includes an intercalation compound of Li2Mn2−xMexO4−zFz as set forth above and the negative electrode includes an active inorganic compound.
摘要翻译： 本发明涉及二次锂电池，其包括用于负极的无机化合物和用于正电极的阴极化合物，其包含Li 2 Mn 2+ -xMexO 4-z F z，其中0 <= X <= 0.5并且可以被优化以匹配相关的不可逆容量损失 与选择的无机负极; 0 <= Z <= 0.5; Me选自Al，Cr，Zn，Co，Ni，Li，Mg，Fe，Cu，Ti，Si或其组合。 此外，本发明涉及具有设置在电极之间的正极，负极和隔板元件的可再充电塑料锂离子电池，其中正电极包括如上所述的Li 2 Mn 2-x MexO 4-zF z的插层化合物和 负极包括活性无机化合物。
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7.发明授权Li.sub.x CoO.sub.2 electrode for high-capacity cycle-stable secondary lithium battery 失效LixCoO2电极用于大容量循环稳定二次锂电池
公开(公告)号：US5693435A
公开(公告)日：1997-12-02
申请号：US515777
申请日：1995-08-16
CPC分类号： H01M4/525 , C01G51/42 , H01M10/052 , C01P2002/08 , C01P2002/77 , C01P2002/88 , C01P2006/40 , Y02P70/54 , Y10T29/49108
摘要： Li.sub.x CoO.sub.2 wherein x is about 1.00 to 1.15 is annealed at about 950.degree. C. to 1000.degree. C. for about 0.25 to 10 hours to yield a lithium intercalation material which is used in an electrode to provide a rechargeable battery having high specific capacity and the capability of maintaining such capacity over numerous operating charge/discharge cycles.
摘要翻译： 其中x为约1.00至1.15的LixCoO 2在约950℃至1000℃下退火约0.25至10小时以产生锂嵌入材料，其用于电极中以提供具有高比容量的可再充电电池，并且 在许多操作充电/放电循环中保持这种容量的能力。
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8.发明授权
公开(公告)号：US5674645A
公开(公告)日：1997-10-07
申请号：US706546
申请日：1996-09-06
CPC分类号： H01M4/505 , C01G45/1242 , C01G49/009 , C01G51/54 , H01M4/582 , C01P2002/52 , C01P2002/54 , C01P2002/72 , C01P2002/77 , C01P2006/40 , H01M2004/028
摘要： The cycling stability and capacity of li-ion rechargeable batteries are improved by the use of lithium manganese oxy-fluoride electrode component intercalation materials having the general formula, Li.sub.1+x M.sub.y Mn.sub.2-x-y O.sub.4-z F.sub.z, where M is a transition metal, e.g., Co, Cr, or Fe, and x.ltoreq.0.4, y.ltoreq.0.3, and 0.05.ltoreq.z.ltoreq.1.0.
摘要翻译： 锂离子可充电电池的循环稳定性和容量通过使用具有通式Li1 + xMyMn2-x-yO4-zFz的锰酸锰氟化物电极组分插层材料得到改善，其中M是过渡金属， Co，Cr或Fe，x <= 0.4，y <0.3，和0.05
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公开(公告)号：US5630993A
公开(公告)日：1997-05-20
申请号：US498315
申请日：1995-07-05
IPC分类号： C01G51/00 , C01G51/04 , C01G53/00 , C01G53/04 , H01M4/48 , H01M4/485 , H01M4/52 , H01M4/525 , H01M10/052 , H01M10/36
CPC分类号： H01M4/525 , C01G51/42 , C01G53/42 , H01M4/485 , C01P2002/20 , C01P2002/54 , C01P2002/72 , C01P2002/77 , C01P2006/40 , H01M10/052
摘要： A method of making a single phase, layered lithiated transition metal oxide material which comprises reacting a transition metal hydroxide with a lithium source in a basic solution in the presence of water at a pressure greater than atmospheric and at a temperature of from about 50.degree. C. to 150.degree. C.
摘要翻译： 一种制备单相层状锂化过渡金属氧化物材料的方法，其包括使过渡金属氢氧化物与碱性溶液中的锂源在水的存在下在大气压和大约50℃的温度下反应 至150℃
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10.发明授权
公开(公告)号：US5587133A
公开(公告)日：1996-12-24
申请号：US383401
申请日：1995-02-03
IPC分类号： C01G51/00 , C01G51/04 , C01G53/00 , H01M4/52 , H01M4/525 , H01M10/0525 , H01M10/0568 , H01M10/0569 , H01M10/36 , C01D1/02 , C01G49/02
CPC分类号： H01M10/0525 , C01G51/42 , C01G53/42 , H01M4/525 , C01P2002/72 , C01P2006/32 , C01P2006/40 , H01M10/0568 , H01M10/0569
摘要： LiCoO.sub.2 and LiNiO.sub.2 are fully delithiated electrochemically using solid state electrolytic cells and oxidation resistant electrolytes to yield new phases of CoO.sub.2 and NiO.sub.2.
摘要翻译： LiCoO2和LiNiO2在电化学上使用固态电解槽和抗氧化电解质完全脱锂以产生CoO2和NiO2的新相。
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