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    Herbicidal cyclohexane-1,3-dione derivatives
    1.
    发明授权
    Herbicidal cyclohexane-1,3-dione derivatives 失效
    除草环己烷-1,3-二酮衍生物

    公开(公告)号：US4643763A

    公开(公告)日：1987-02-17

    申请号：US774527

    申请日：1985-09-10

    申请人： Graeme J. Farquharson ,  Keith G. Watson ,  Graham J. Bird

    发明人： Graeme J. Farquharson ,  Keith G. Watson ,  Graham J. Bird

    IPC分类号： A01N47/34 ,  A01N35/10 ,  A01N37/08 ,  A01N37/10 ,  A01N37/34 ,  A01N37/50 ,  A01N41/06 ,  A01N45/02 ,  A01N47/30 ,  C07C45/31 ,  C07C67/00 ,  C07C239/00 ,  C07C251/42 ,  C07C251/44 ,  C07C251/52 ,  C07C291/12 ,  C07C301/00 ,  C07C303/40 ,  C07C311/29 ,  C07C313/00 ,  C07C319/20 ,  C07C323/47 ,  C07C325/00 ,  C07C327/12 ,  C07C327/16 ,  C07C335/18 ,  C07C381/00 ,  A01N31/08 ,  A01N33/04 ,  C07C131/00

    CPC分类号： C07C251/52 ,  A01N35/10 ,  A01N37/08 ,  A01N37/10 ,  A01N41/06 ,  A01N45/02 ,  A01N47/30 ,  C07C251/42 ,  C07C45/31 ,  C07C2103/94

    摘要： The invention concerns novel compounds of the formula I ##STR1## wherein: m is an integer selected from 1 to 4;n is zero or an integer selected from 1 to 4;x are selected from halogen, nitro, cyano, alkyl, substituted alkyl, hydroxy, alkoxy, alkylthio, sulfamoyl, substituted sulfamoyl, amino, substituted amino, the group --(CH.sub.2).sub.p C(.dbd.A)Z in which p is zero or one A is oxygen or sulfur, and Z is hydrogen, hydroxy, alkoxy, alkylthio, alkyl, substituted alkyl, amino or substituted amino; the group --NHC(.dbd.B(NR.sup.7 R.sup.8 in which B is oxygen or sulfur and R.sup.7 and R.sup.8 are hydrogen or alkyl;R.sup.1 is selected from hydrogen, acyl and an inorganic or organic cation;R.sup.2 is selected from alkyl, substituted alkyl, alkenyl, haloalkenyl, alkynyl and haloalkynyl;R.sup.3 is selected from alkyl, fluoroalkyl, alkenyl, alkynyl, and phenyl; andR.sup.4 is selected from hydrogen, halogen, alkyl, cyano and alkoxycarbonyl.The compounds of the invention show herbicidal properties and plant growth regulating properties and in further embodiments the invention provides processes for the preparation of compounds of formula I, intermediates useful in the preparation of the compounds of formula I, compositions containing as active ingredient a compound of formula I, and herbicidal and plant growth regulating processes utilizing compounds of formula I.

    摘要翻译： 本发明涉及式I的新型化合物其中：m是选自1至4的整数; n为0或选自1至4的整数; x选自卤素，硝基，氰基，烷基，取代的烷基，羟基，烷氧基，烷硫基，氨磺酰基，取代的氨磺酰基，氨基，取代的氨基，其中p为0或1的 - （CH 2）pC（= A） A是氧或硫，Z是氢，羟基，烷氧基，烷硫基，烷基，取代的烷基，氨基或取代的氨基; 基团-NHC（= B（NR7R8，其中B是氧或硫，R7和R8是氢或烷基; R1选自氢，酰基和无机或有机阳离子; R2选自烷基，取代的烷基，烯基， 卤代烯基，炔基和卤代炔基; R3选自烷基，氟烷基，烯基，炔基和苯基; R4选自氢，卤素，烷基，氰基和烷氧基羰基，本发明化合物显示出除草性质和植物生长调节性质， 在进一步的实施方案中，本发明提供了制备式I化合物的方法，可用于制备式I化合物的中间体，含有式I化合物作为活性成分的组合物，以及利用式I化合物的除草和植物生长调节方法 一世。

    Herbicidal cyclohexane-1,3-dione derivatives
    3.
    发明授权
    Herbicidal cyclohexane-1,3-dione derivatives 失效
    除草环己烷-1,3-二酮衍生物

    公开(公告)号：US4631081A

    公开(公告)日：1986-12-23

    申请号：US536392

    申请日：1983-09-27

    申请人： Keith G. Watson ,  Graham J. Bird ,  Graeme J. Farquharson ,  Richard J. Conway ,  Peter G. Tucker

    发明人： Keith G. Watson ,  Graham J. Bird ,  Graeme J. Farquharson ,  Richard J. Conway ,  Peter G. Tucker

    IPC分类号： A01N43/40 ,  C07D213/48 ,  C07D213/50 ,  C07D213/53 ,  C07D213/55 ,  C07D213/61 ,  C07D213/64 ,  C07D213/69 ,  C07D213/70 ,  C07D213/80 ,  C07D213/82 ,  C07D213/85 ,  C07D213/89

    CPC分类号： C07D213/53 ,  A01N43/40 ,  C07D213/48 ,  C07D213/50 ,  C07D213/55 ,  C07D213/61 ,  C07D213/64 ,  C07D213/69 ,  C07D213/70 ,  C07D213/80 ,  C07D213/82 ,  C07D213/85 ,  C07D213/89

    摘要： The invention concerns novel compounds of the formula I ##STR1## wherein: Z is selected from oxygen and the group --YAn wherein Y is selected from C.sub.1 to C.sub.6 alkyl and benzyl and An is an anion;k is zero or the integer 1;n is an integer selected from 3 and 4;X is selected from halogen, nitro, cyano, alkyl, substituted alkyl, hydroxy, alkoxy, substituted alkoxy, alkenyl, alkenyloxy, alkynyl, alkynyloxy, acyloxy, alkoxycarbonyl, alkylthio, alkylsulfinyl, alkylsulfonyl, sulfamoyl, substituted sulfamoyl, alkanoyloxy, benzyloxy, substituted benzyloxy, amino, substituted amino and the groups formyl and alkanoyl and the oxime, imine and Schiff base derivatives thereof;R.sup.1 is selected from hydrogen, alkyl, alkenyl, alkynyl, substituted alkyl, alkylsulfonyl, arylsulfonyl, acyl and an inorganic or organic cation;R.sup.2 is selected from alkyl, substituted alkyl, alkenyl, haloalkenyl, alkynyl and haloalkynyl;R.sup.3 is selected from alkyl, fluoroalkyl, alkenyl, alkynyl, and phenyl; andR.sup.4 is selected from hydrogen, halogen, alkyl, cyano and alkoxycarbonyl.The compounds of the invention show herbicidal properties and plant growth regulating properties and in further embodiments the invention provides processes for the preparation of compounds of formula I, intermediates useful in the preparation of the compounds of formula I, compositions containing as active ingredient a compound of formula I, and herbicidal and plant growth regulating processes utilizing compounds of formula I.

    摘要翻译： 本发明涉及式I的新型化合物其中：Z选自氧和基团-YAn，其中Y选自C1至C6烷基和苄基，An为阴离子; k为零或整数1; n是选自3和4的整数; 卤素，硝基，氰基，烷基，取代的烷基，羟基，烷氧基，取代的烷氧基，烯基，烯氧基，炔基，炔氧基，酰氧基，烷氧基羰基， 苄氧基，氨基，取代氨基和甲酰基和烷酰基及其肟，亚胺和席夫碱衍生物; R 1选自氢，烷基，烯基，炔基，取代的烷基，烷基磺酰基，芳基磺酰基，酰基和无机或有机阳离子; R2选自烷基，取代的烷基，烯基，卤代烯基，炔基和卤代炔基; R3选自烷基，氟烷基，烯基，炔基和苯基; 并且R 4选自氢，卤素，烷基，氰基和烷氧基羰基。 本发明的化合物显示除草性质和植物生长调节性质，并且在进一步的实施方案中，本发明提供了制备式I化合物的方法，可用于制备式I化合物的中间体，作为活性成分的化合物 式I，以及利用式I化合物的除草和植物生长调节方法。

    Herbicidal compounds and compositions
    5.
    发明授权
    Herbicidal compounds and compositions 失效
    除草剂及组合物

    公开(公告)号：US5110989A

    公开(公告)日：1992-05-05

    申请号：US553413

    申请日：1990-07-17

    申请人： Alexander Serban ,  Keith G. Watson ,  Graham J. Bird ,  Graeme J. Farquharson ,  Linsay E. Cross

    发明人： Alexander Serban ,  Keith G. Watson ,  Graham J. Bird ,  Graeme J. Farquharson ,  Linsay E. Cross

    IPC分类号： C07C1/22 ,  C07C17/00 ,  C07C45/45 ,  C07C45/46 ,  C07C45/65 ,  C07C45/67 ,  C07C45/74 ,  C07C47/546 ,  C07C47/55 ,  C07C47/575 ,  C07C49/657 ,  C07C49/697 ,  C07C49/747 ,  C07C49/753 ,  C07C49/835

    CPC分类号： C07C1/22 ,  C07C17/35 ,  C07C45/455 ,  C07C45/46 ,  C07C45/65 ,  C07C45/673 ,  C07C45/74 ,  C07C47/546 ,  C07C47/55 ,  C07C47/575 ,  C07C49/657 ,  C07C49/697 ,  C07C49/747 ,  C07C49/753 ,  C07C49/835 ,  C07C2102/08

    摘要： The invention concerns novel compounds of the formula I ##STR1## wherein: W are selected from alkyl, alkenyl and alkynyl;X are selected from halogen, nitro, cyano, alkyl, substituted alkyl, hydroxy, alkoxy, substituted alkoxy, alkenyl, alkynyl, alkenyloxy, alkynyloxy, acyloxy, alkoxycarbonyl, alkylthio, alkylsulfinyl, alkylsulfonyl, sulfamoyl, substituted sulfamoyl, amino, substituted amino, and the groups formyl and alkanoyl and the oxime, imine and Schiff base derivatives thereof, and an alkylene group which bridges two adjacent carbon atoms of the benzene ring;R.sup.1 is selected from hydrogen, alkyl, alkenyl, alkynyl, substituted alkyl, alkylsulfonyl, arylsulfonyl, acyl and an inorganic or organic cation;R.sup.2 is selected from alkyl, substituted alkyl, alkenyl, haloalkenyl, alkynyl and haloalkynyl;R.sup.3 is selected from alkyl, fluoroalkyl, alkenyl, alkynyl, and phenyl;p is zero or an integer selected from 1 to 4;n is zero or an integer selected from 1 to 3; andm is zero or an integer selected from 1 to 3.The compounds of the invention show cereal selective herbicidal properties and plant growth regulating properties and in further embodiments the invention provides processes for the preparation of the compounds of formula I, intermediates useful in the preparation of the compounds of formula I, compositions containing as active ingredient a compound of formula I, and herbicidal and plant growth regulating processes utilizing compounds of formula I.

    摘要翻译： 本发明涉及式I的新型化合物其中：W选自烷基，烯基和炔基; X选自卤素，硝基，氰基，烷基，取代的烷基，羟基，烷氧基，取代的烷氧基，烯基，炔基，烯氧基，炔氧基，酰氧基，烷氧基羰基，烷硫基，烷基亚磺酰基，烷基磺酰基，氨磺酰基，取代氨磺酰基，氨基，取代的氨基， 和甲酰基和烷酰基以及其肟，亚胺和席夫碱衍生物和桥接苯环的两个相邻碳原子的亚烷基; R 1选自氢，烷基，烯基，炔基，取代的烷基，烷基磺酰基，芳基磺酰基，酰基和无机或有机阳离子; R2选自烷基，取代的烷基，烯基，卤代烯基，炔基和卤代炔基; R3选自烷基，氟烷基，烯基，炔基和苯基; p为零或选自1至4的整数; n为0或选自1至3的整数; 本发明的化合物显示谷物选择性除草性质和植物生长调节性质，并且在进一步的实施方案中，本发明提供了制备式I化合物的方法，可用于 式I化合物的制备，含有式I化合物作为活性成分的组合物，以及利用式I化合物的除草和植物生长调节方法。

    Cyclohexane-1,3-dione derivatives and their herbicidal compositions and methods
    8.
    发明授权
    Cyclohexane-1,3-dione derivatives and their herbicidal compositions and methods 失效
    环己烷-1,3-二酮衍生物及其除草组合物和方法

    公开(公告)号：US4511391A

    公开(公告)日：1985-04-16

    申请号：US497683

    申请日：1983-05-24

    申请人： Alexander Serban ,  Keith G. Watson ,  Graham J. Bird ,  Graeme J. Farquharson

    发明人： Alexander Serban ,  Keith G. Watson ,  Graham J. Bird ,  Graeme J. Farquharson

    IPC分类号： A01N43/12 ,  A01N43/30 ,  A01N43/32 ,  C07D307/79 ,  C07D317/54 ,  C07D317/58 ,  C07D317/62 ,  C07D319/18 ,  C07D307/78

    CPC分类号： C07D307/79 ,  A01N43/12 ,  A01N43/30 ,  A01N43/32 ,  C07D317/54 ,  C07D317/58 ,  C07D317/62 ,  C07D319/18

    摘要： The invention concerns novel compounds of the formula I ##STR1## wherein: X is selected from halogen, nitro, cyano, alkyl, substituted alkyl, alkenyl, alkynyl, hydroxy, alkoxy, substituted alkoxy, alkenyloxy, alkynyloxy, alkanoyloxy, alkoxycarbonyl, alkylthio, alkylsulfinyl, alkylsulfonyl, sulfamoyl, substituted sulfamoyl, benzyloxy, substituted benzyloxy, amino, substituted amino, and the groups formyl and alkanoyl and the oxime, imine and Schiff base derivatives thereof;Y and Z are independently selected from methylene, oxygen and sulfur provided that at least one of Y and Z is selected from oxygen and sulfur;R.sup.1 is selected from hydrogen, alkyl, alkenyl alkynyl, substituted alkyl, acyl, alkylsulfonyl, benzenesulfonyl, substituted benzenesulfonyl, and an inorganic or organic cation;R.sup.2 is selected from alkyl, alkenyl, alkynyl, substituted alkyl, haloalkenyl and haloalkynyl;R.sup.3 is selected from alkyl, fluoroalkyl, alkenyl, alkynyl and phenyl;R.sup.4 is selected from hydrogen, halogen, cyano, C.sub.1 to C.sub.6 alkyl and (C.sub.1 to C.sub.6 alkoxy)carbonyl;n is an integer selected from 1 to 3; andm is zero or an integer selected from 1 to 3.The compounds are cereal selective herbicides and in further embodiments the invention provides processes for the preparation of compounds of formula I, intermediates useful in the preparation of compounds of formula I, intermediates useful in the preparation of compounds of formula I, herbicidal compositions containing as active ingredient a compound of formula I, and processes for severely damaging or killing unwanted plants by applying to the plants or to the growth medium of the plants an effective amount of a compound of formula I.

    摘要翻译： 本发明涉及式I的新化合物其中：X选自卤素，硝基，氰基，烷基，取代的烷基，烯基，炔基，羟基，烷氧基，取代的烷氧基，烯氧基，炔氧基，烷酰氧基，烷氧基羰基，烷硫基 烷基亚磺酰基，烷基磺酰基，氨磺酰基，取代的氨磺酰基，苄氧基，取代的苄氧基，氨基，取代的氨基，以及甲酰基和烷酰基及其肟，亚胺和席夫碱衍生物; Y和Z独立地选自亚甲基，氧和硫，条件是Y和Z中的至少一个选自氧和硫; R 1选自氢，烷基，烯基炔基，取代的烷基，酰基，烷基磺酰基，苯磺酰基，取代的苯磺酰基和无机或有机阳离子; R2选自烷基，烯基，炔基，取代的烷基，卤代烯基和卤代炔基; R3选自烷基，氟烷基，烯基，炔基和苯基; R 4选自氢，卤素，氰基，C 1至C 6烷基和（C 1至C 6烷氧基）羰基; n是选自1至3的整数; 并且m为0或选自1至3的整数。化合物是谷物选择性除草剂，并且在进一步的实施方案中，本发明提供了制备式I化合物的方法，可用于制备式I化合物的中间体， 式I化合物的制备，含有作为活性成分的式I化合物的除草组合物，以及通过向植物或植物的生长培养基施用有效量的式（I）化合物而严重损害或杀死有害植物的方法， 一世。

    5-[Substituted bicyclic aryl or heteroaryl]cyclohexane-1,3-dione herbicides
    10.
    发明授权
    5-[Substituted bicyclic aryl or heteroaryl]cyclohexane-1,3-dione herbicides 失效
    5- [取代的双环芳基或杂芳基]环己烷-1,3-二酮除草剂

    公开(公告)号：US4664693A

    公开(公告)日：1987-05-12

    申请号：US600072

    申请日：1984-04-13

    申请人： Graham J. Bird ,  Graeme J. Farquharson ,  Keith G. Watson ,  Murray L. Whitelaw

    发明人： Graham J. Bird ,  Graeme J. Farquharson ,  Keith G. Watson ,  Murray L. Whitelaw

    IPC分类号： A01N35/10 ,  A01N43/12 ,  A01N43/38 ,  A01N43/52 ,  A01N43/74 ,  A01N43/78 ,  C07C45/51 ,  C07C47/453 ,  C07C67/00 ,  C07C239/00 ,  C07C251/44 ,  C07D209/14 ,  C07D263/54 ,  C07D277/62 ,  C07D277/66 ,  C07D307/79 ,  C07D307/80 ,  C07D307/81 ,  C07D333/54 ,  C07D333/58 ,  A01N43/00 ,  A01N43/02

    CPC分类号： C07D307/79 ,  A01N35/10 ,  A01N43/12 ,  A01N43/38 ,  A01N43/52 ,  A01N43/74 ,  C07C45/513 ,  C07C47/453 ,  C07D209/14 ,  C07D277/66 ,  C07D307/80 ,  C07D307/81 ,  C07D333/54

    摘要： The invention concerns novel compounds of the formula I ##STR1## wherein: A is selected from CH and N;B is selected from oxygen, sulfur, CH.sub.2 and the group N-Z wherein Z is selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, benzyl and substituted benzyl;X, which may be the same or different, and X.sup.1, which be the same or different, are selected from halogen, nitro, cyano, alkyl, substituted alkyl, hydroxy, alkoxy, substituted alkoxy, alkenyl, alkenyloxy, alkynyl, alkynyloxy, acyloxy, alkoxycarbonyl, alkylthio, alkylsulfinyl, alkylsulfonyl, sulfamoyl, substituted sulfamoyl, alkanoyloxy, benzyloxy, substituted benzyloxy, amino, substituted amino, and the groups formyl and alkanoyl and the oxime, imine and Schiff base derivatives thereof;R.sup.1 is selected from hydrogen, alkyl, alkenyl, alkynyl, substituted alkyl, alkylsulfonyl, arylsulfonyl, acyl and an inorganic or organic cation;R.sup.2 is selected from alkyl, substituted alkyl, alkenyl, haloalkenyl, alkynyl and haloalkynyl;R.sup.3 is selected from alkyl, fluoroalkyl, alkenyl, alkynyl, and phenyl;R.sup.4 is selected from hydrogen, halogen, alkyl, cyano and alkoxycarbonyl;n is 0 or an integer chosen from 1 to 4; andn.sup.1 is 0 or an integer chosen from 1 to 4.The compounds of the invention show herbicidal properties and plant growth regulating properties and in further embodiments the invention provides processes for the preparation of compounds of formula I, intermediates useful in the preparation of the compounds of formula I, compositions containing as active ingredient a compound of formula I, and herbicidal and plant growth regulating processes utilizing compounds of formula I.

    摘要翻译： 本发明涉及式I的新型化合物其中：A选自CH和N; B选自氧，硫，CH 2和基团N-Z，其中Z选自氢，烷基，烯基，炔基，环烷基，苄基和取代的苄基; X可以相同或不同，X 1相同或不同，选自卤素，硝基，氰基，烷基，取代的烷基，羟基，烷氧基，取代的烷氧基，烯基，烯氧基，炔基，炔氧基，酰氧基 烷氧基羰基，烷硫基，烷基亚磺酰基，烷基磺酰基，氨磺酰基，取代氨磺酰基，烷酰氧基，苄氧基，取代的苄氧基，氨基，取代的氨基，以及甲酰基和烷酰基及其肟，亚胺和席夫碱衍生物。 R 1选自氢，烷基，烯基，炔基，取代的烷基，烷基磺酰基，芳基磺酰基，酰基和无机或有机阳离子; R2选自烷基，取代的烷基，烯基，卤代烯基，炔基和卤代炔基; R3选自烷基，氟烷基，烯基，炔基和苯基; R4选自氢，卤素，烷基，氰基和烷氧基羰基; n为0或选自1至4的整数; 本发明的化合物显示出除草性质和植物生长调节性质，并且在进一步的实施方案中，本发明提供制备式I化合物的方法，可用于制备式I化合物的中间体 式I化合物，含有作为活性成分的式I化合物的组合物，以及利用式I化合物的除草和植物生长调节方法。