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    Highly durable first surface silver based optical coatings and method of making the same
    2.
    发明授权
    Highly durable first surface silver based optical coatings and method of making the same 有权
    高耐用的第一表面银基光学涂料及其制造方法

    公开(公告)号：US08394502B2

    公开(公告)日：2013-03-12

    申请号：US12807026

    申请日：2010-08-26

    申请人： Grzegorz Stachowiak

    发明人： Grzegorz Stachowiak

    IPC分类号： B32B15/04 ,  B32B15/08

    CPC分类号： G02B5/0808 ,  C03C17/36 ,  C03C17/3621 ,  C03C17/3652 ,  C03C17/3663 ,  C03C2217/78 ,  C23C28/00 ,  Y10T428/12549 ,  Y10T428/31678

    摘要： A highly durable, environmentally and thermally stable Silver coating for mirrors, Infrared thin-film filters, or other optical coatings having very high reflection values over a large spectral and angular range where the enhanced durability and thermal stability are achieved through the selection and layer sequence of materials, which provide good chemical and environmental protection to Silver. Of particular importance are the layers directly below the Silver, and directly above the Silver (nucleation layer and barrier layer). It is important that the materials of those two layers provide diffusion barriers for Oxygen, water vapour and other corrosive gases, and are compatible in such a way that the layer below the Silver provides a good nucleation bed for Silver assuring that Silver will grow dense and highly reflective, and in some cases, when deposited in very thin layers, highly transparent in the visible spectrum, and the material of the layer directly above the Silver layer has to be compatible with Silver in a sense that it grows dense on the top of Silver, does not reduce the reflectivity of Silver, and also provides a good nucleation layer for the next layer being deposited.

    摘要翻译： 高度耐用，环保和热稳定的银涂层，用于镜子，红外薄膜滤光片或其他光学涂层，在大的光谱和角度范围内具有非常高的反射值，通过选择和层序来实现增强的耐久性和热稳定性 的材料，为银提供良好的化学和环保。 特别重要的是银之下的层，直接在银（成核层和阻挡层）之上。 重要的是，这两层的材料为氧气，水蒸气和其他腐蚀性气体提供了扩散阻挡层，并且以这样的方式相容，使得Silver下面的层为银提供了良好的成核床，从而确保Silver将生长密集， 高反射性，并且在某些情况下，当沉积在非常薄的层中时，在可见光谱中高度透明，并且银层正上方的层的材料必须与银相容，因为它在银的顶部生长密集 银，不会降低银的反射率，并且还为下一层沉积提供了良好的成核层。

    Heat treatable coated article with niobium nitride IR reflecting layer and method of making same
    5.
    发明申请
    Heat treatable coated article with niobium nitride IR reflecting layer and method of making same 审中-公开
    具有氮化铌红外反射层的可热处理涂层制品及其制造方法

    公开(公告)号：US20050205416A1

    公开(公告)日：2005-09-22

    申请号：US11049959

    申请日：2005-02-04

    申请人： Grzegorz Stachowiak

    发明人： Grzegorz Stachowiak

    IPC分类号： C03C17/34 ,  C23C14/34

    CPC分类号： C03C17/3435

    摘要： A coated article is provided so as to include a solar control coating having an infrared (IR) reflecting layer sandwiched between at least a pair of dielectric layers. The IR reflecting layer includes niobium nitride (NbxNy). The use of niobium nitride enables the coated article to have good corrosion resistance to acid(s), good mechanical performance such as scratch resistance, and/or good color stability (i.e., a low ΔE* value(s)) upon heat treatment (HT). The coated article may be heat treated (e.g., thermally tempered) in certain example embodiments of the invention.

    摘要翻译： 提供一种涂覆制品，以便包括具有夹在至少一对电介质层之间的红外线（IR）反射层的太阳能控制涂层。 IR反射层包括氮化铌（Nb x N y N y）。 使用氮化铌使得涂层制品在热处理时对酸具有良好的耐腐蚀性，良好的机械性能如耐刮擦性和/或良好的颜色稳定性（即，较低的DeltaE *值） HT）。 在本发明的某些示例性实施例中，涂覆的制品可以被热处理（例如热回火）。

    Heat treatable coated articles with metal nitride layer and methods of making same
    6.
    发明授权
    Heat treatable coated articles with metal nitride layer and methods of making same 有权
    具有金属氮化物层的可热处理涂层制品及其制造方法

    公开(公告)号：US06926967B2

    公开(公告)日：2005-08-09

    申请号：US10777191

    申请日：2004-02-13

    申请人： George Neuman ,  Grzegorz Stachowiak ,  Hong Wang

    发明人： George Neuman ,  Grzegorz Stachowiak ,  Hong Wang

    IPC分类号： C03C17/34 ,  B32B9/00

    CPC分类号： C03C17/3435 ,  Y10T428/12847 ,  Y10T428/12944

    摘要： A heat treatable coated article including a solar management layer for reflecting infrared (IR) or the like, is provided between a substrate and an overlying dielectric layer. An underlying dielectric layer between the substrate and solar management layer is optional. In certain embodiments, the solar management layer may include NiCrNx while the dielectric layer(s) may include a nitride such as silicon nitride. By nitriding the solar management layer, it has been found that the resulting coated article is more color stable upon heat treatment (HT). For example, the coated article may have a ΔE* value (transmissive and/or glass side reflective) of no greater than 5.0, more preferably no greater than 4.0, and most preferably no greater than 3.0. Coated articles herein may be used in the context of insulating glass (IG) window units, vehicle windows, or the like.

    摘要翻译： 包括用于反射红外（IR）等的太阳能管理层的可热处理涂层制品设置在基板和上覆介电层之间。 衬底和太阳能管理层之间的底层电介质层是可选的。 在某些实施例中，太阳能管理层可以包括NiCrN x x，而介电层可以包括诸如氮化硅的氮化物。 通过氮化太阳能管理层，已经发现所得涂层制品在热处理（HT）时更加稳定。 例如，涂覆制品可以具有不大于5.0，更优选不大于4.0，最优选不大于3.0的DeltaE *值（透射和/或玻璃侧反射）。 本文中的涂覆制品可用于中空玻璃（IG）窗单元，车窗等的上下文中。

    Low-E matchable coated articles, and methods
    8.
    发明授权
    Low-E matchable coated articles, and methods 有权
    Low-E匹配涂层制品及方法

    公开(公告)号：US06730352B2

    公开(公告)日：2004-05-04

    申请号：US10439169

    申请日：2003-05-16

    申请人： Grzegorz Stachowiak

    发明人： Grzegorz Stachowiak

    IPC分类号： B05D506

    CPC分类号： C03C17/3618 ,  C03C17/36 ,  C03C17/3626 ,  C03C17/3644 ,  C03C17/3652 ,  C03C17/366 ,  C03C17/3681 ,  C03C2217/78 ,  Y10T428/12896 ,  Y10T428/265

    摘要： A heat treatable coated article including an infrared (IR) reflecting layer (e.g., of or including Ag), the coated article being able to attain a &Dgr;E* (glass side) no greater than about 3.5, more preferably no greater than 3.0, and even more preferably no greater than 2.6, following or due to heat treatment (e.g., thermal tempering). Accordingly, low-E (i.e., low emissivity) coated articles of certain embodiments of this invention appear from the glass side thereof visually similar to the naked eye both before and after heat treatment. Good matchability characteristics (i.e., low &Dgr;E* values) combined with good durability can be achieved by controlling to what extent barrier layer(s) in contact with the IR reflecting layer are nitrided and to what thickness(es) they are sputtered. Optionally, certain embodiments of this invention relate to coated articles that also have high visible transmission and/or good durability. Coated articles herein may be used in the context of insulating glass (IG) window units, vehicle windows, or any other suitable applications. In certain embodiments of this invention, an exemplary layer stack includes: glass/Si3N4/NiCrNx/Ag/NiCrNx/Si3N4. Other materials may instead be used without departing from the scope and/or spirit of the instant invention which is a low-E matchable and/or durable product.

    摘要翻译： 包括红外（IR）反射层（例如，包括或包含Ag）的可热处理涂层制品，涂覆制品能够获得不大于约3.5，更优选不大于3.0的ΔE*（玻璃面），以及 甚至更优选不大于2.6，随后或由于热处理（例如，热回火）。 因此，在热处理之前和之后，本发明的某些实施方案的低-E（即低发射率）涂层制品在肉眼看起来与肉眼相似。 可以通过控制与IR反射层接触的屏障层在多大程度上被溅射以及它们被溅射的厚度来实现与良好的耐久性相结合的良好匹配性（即，低ΔE*值）。 任选地，本发明的某些实施方案涉及也具有高可见透射率和/或良好耐久性的涂覆制品。 本文中的涂覆制品可用于中空玻璃（IG）窗单元，车窗或任何其它合适应用的上下文中。 在本发明的某些实施例中，示例性层堆叠包括：玻璃/ Si 3 N 4 / NiCrN x / Ag / NiCrN x / Si 3 N 4。 在不脱离本发明的范围和/或精神的情况下可以使用其它材料，所述范围和/或精神是低E可匹配和/或耐用的产品。

    Coated article with anti-reflective layer(s) system
    9.
    发明授权
    Coated article with anti-reflective layer(s) system 有权
    具有抗反射层系统的涂层制品

    公开(公告)号：US06589658B1

    公开(公告)日：2003-07-08

    申请号：US09995800

    申请日：2001-11-29

    申请人： Grzegorz Stachowiak

    发明人： Grzegorz Stachowiak

    IPC分类号： B32B1706

    CPC分类号： C03C17/3618 ,  C03C17/36 ,  C03C17/3626 ,  C03C17/3644 ,  C03C17/3652 ,  C03C17/366 ,  C03C2217/734 ,  Y10T428/12896 ,  Y10T428/31678

    摘要： Coated articles are provided with an anti-reflective (AR) layer(s) system which enables reduced reflection, increased visible transmission, and/or neutral color. In certain embodiments, the AR layer(s) system includes a titanium oxide layer, a silicon oxynitride layer, and/or a silicon oxide layer on the substrate over an infrared (IR) reflecting layer(s) such as silver. Silicon nitride layer(s) may optionally be provided below and/or over the IR reflecting layer in certain example embodiments.

    摘要翻译： 涂层制品设置有抗反射（AR）层系统，其能够减少反射，增加可见透射和/或中性色。 在某些实施方案中，AR层系统在红外（IR）反射层（例如银）上的衬底上包括氧化钛层，氧氮化硅层和/或氧化硅层。 在某些示例性实施例中，氮化硅层可任选地设置在IR反射层的下方和/或上方。