摘要:
The novel compounds of the general formula ##STR1## where R.sup.1 and R.sup.2 are identical or different aliphatic, cycloaliphatic, aromatic or heterocyclic radicals which are free of groups which impart water solubility,X, Y and Z are each chlorine, bromine or a radical OR.sup.3 andR.sup.3 is unsubstituted or substituted phenyl, naphthyl or anthryl,are very useful as fluorescent dyes in organic material.
摘要:
An isothiazolylazo dye of the formula I ##STR1## wherein R is an alkyl group or unsubstituted aryl or substituted aryl group selected from the group consisting of ##STR2## and K is a radical of the formula ##STR3## where B is C.sub.1 -C.sub.4 alkyl or a substituted amino radical selected from the group consisting of ##STR4## R.sup.1 is hydrogen, methyl, methoxy or ethoxy, R.sup.2 and R.sup.3 independently of one another are each unsubstituted C.sub.1 -C.sub.4 alkyl or substituted alkyl groups selected from the group of C.sub.1 -C.sub.4 alkyls which are substituted by chlorine, bromine, cyano, hydroxyl, C.sub.1 -C.sub.4 -alkoxy, benzyloxy, phenoxy, phenyl, C.sub.1 -C.sub.4 -alkylcarbonyloxy which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkoxy, phenoxy or phenyl, phenycarbonyloxy which is unsubstituted or substituted by chlorine, bromine, methoxy, ethoxy, methyl or ethyl, oxycarbonyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.1 -C.sub.4 -alkoxycarbonyloxy, carbamyl, phenalkyloxycarbonyloxy, phenoxyalkyloxycarbonyloxy, C.sub.1 -C.sub.4 -alkoxyalkoxycarbonyloxy, phenylaminocarbonyloxy which is unsubstituted or substituted by chlorine, methoxy or methyl, C.sub.1 -C.sub.4 -alkoxyalkoxycarbonyl, phenylalkyloxycarbonyl or C.sub.1 -C.sub.4 -alkylaminocarbonyloxy which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, chlorine or bromine; or R.sup.3 is hydrogen, R.sup.4 is a radical of the formula --A--OCO--Y--R, Z is hydrogen or methyl, X is hydrogen, methyl, methoxy, chlorine or an acylamino radical selected from the group consisting of A is C.sub.2 - or C.sub.3 -alkylene and Y is --O-- or --NH--. The dyes are very useful for dyeing cellulose esters and synthetic polyesters; the dyeings obtained are from yellow to blue, and very fast.
摘要:
An organic compound of the general formula ##STR1## where R.sup.1 and R.sup.2 are cyano, formyl, substituted or unsubstituted alkanoyl or aroyl, a carboxylic acid ester group, substituted or unsubstituted carbamoyl or sulfamoyl, alkylsulfonyl, arylsulfonyl or alkylsulfinyl, orR.sup.1 and R.sup.2 together may be a cyclic radical,R.sup.2 may also be alkyl, aryl or hetaryl,R.sup.3 is hydrogen, substituted or unsubstituted alkyl, aryl or hetaryl,X is CH, CR.sup.5 or N,R.sup.4 is a radical of the formula ##STR2## R.sup.5 to R.sup.10 are substituents conventionally present in dyes. The compounds may be used as dyes for synthetic and natural fibers and give very fast dyeings.
摘要:
A molding based on supercritically dried silica aerogel parts in the form of spherical particles having a diameter of from 0.1 to 10 mm or sheet-like pieces having a thickness of from 2 to 30 mm and a diameter of from 1 to 5 cm, wherein the molding is produced by pressing at from 500.degree. to 1000.degree. C. and at from 0.5 to 10 bar, if necessary under a protective gas, such as nitrogen, without addition of binders.
摘要:
An electrostatic toner consists of a polymer a charge controlling component and an optional color-giving component, wherein the charge controlling agent component comprises one or more compounds of the formula `(I)`, ##STR1## ps where R.sup.1 is chlorine or methyl, R.sup.2 is C.sub.4 -C.sub.22 -alkyl, benzyl or 2-phenylethyl, A.THETA. is an anion, n is 0, 1 or 2, m is 1 or 2 and r is 1 or 2.
摘要:
Compounds of the general formula I ##STR1## where R is unsubstituted or substituted alkyl, alkenyl, aryl or hetaryl and R.sup.1 and R.sup.2 independently of one another are each unsubstituted or substituted alkyl or aryl, or, together with the nitrogen, form a heterocyclic ring, are prepared by a process wherein a compound of the general formula II ##STR2## is reacted with a water-soluble monohaloacetate in an aqueous alkaline medium. They are very useful coupling components for the preparation of azo dyes.
摘要:
Dyes of the thiazole series, having the general formula I ##STR1## where D is the radical of an aromatic diazo component,R is a heterocyclic radical andR.sup.1 and R.sup.2 are hydrogen or unsubstituted or substituted hydrocarbon radicals, which may also together form a ring, which may or may not be heterocyclic.The dyes according to the invention are particularly suitable for dyeing synthetic polyesters.
摘要:
4,5-Disubstituted thiazoles are manufactured by reacting 4-amino-5-cyano-thiazoles with hydrogen sulfide in the presence of basic compounds, followed by dehydrogenating cyclization. The new 3-amino-thiazolo-(4,5-c)-isothiazoles I, 4-amino-5-thiocarbamidothiazoles III and 4,5-disubstituted thiazoles IV obtainable by the process of the invention are valuable intermediates for the manufacture of azo dyes and of crop protection agents.
摘要:
Fluorescent pigments have a mean particle size of from 8 to 16 lm and contain apolar polymer matrices based on polymethyl methacrylate, polystyrene, polybutadiene-modified polystyrene, polycarbonate, polyvinyl chloride or polyamide and one or more apolar fluorescent dyes of the coumarin or perylene series.
摘要:
Compounds which, in the form of the free acid, are of the general formula I ##STR1## where D is phenyl which unsubstituted or substituted by fluorine, chlorine, bromine, nitro, cyano, C.sub.1 -C.sub.4 -alkylsulfonyl, C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.4 -alkoxy, carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl or hydroxysulfonyl or by unsubstituted or substituted carbamyl or sulfamyl, andK is a radical of a heterocyclic coupling component, and the rings A and E may furthermore be substituted by methyl, methoxy, chlorine or hydroxysulfonyl.