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    Aqueous fungicidal composition and use thereof for combating harmful microorganisms
    1.
    发明授权
    Aqueous fungicidal composition and use thereof for combating harmful microorganisms 有权
    杀真菌组合物及其用于防治有害微生物的用途

    公开(公告)号：US08741968B2

    公开(公告)日：2014-06-03

    申请号：US12831055

    申请日：2010-07-06

    申请人： Gunnar Kleist ,  Joerg Habicht ,  Holger Schöpke ,  Patrick Amrhein ,  Helga Göttsche

    发明人： Reimer Göttsche ,  Gunnar Kleist ,  Joerg Habicht ,  Holger Schöpke ,  Patrick Amrhein

    IPC分类号： A01N25/04 ,  A01N43/653 ,  A01N43/36 ,  A01N47/12 ,  A01P3/00 ,  C08L33/14 ,  C08L25/06

    CPC分类号： A01N25/02 ,  A01N25/04 ,  A01N43/36 ,  A01N43/653 ,  A01N47/12 ,  B27K3/007 ,  B27K3/15 ,  C08L25/06 ,  C08L33/14 ,  C08L97/02 ,  A01N25/30 ,  A01N2300/00

    摘要： The invention relates to aqueous fungicidal active substance compositions and to their use in the control of harmful microorganisms and in particular in the protection of cellulose-comprising materials, particularly wood, from infection by microorganisms, in particular those harmful fungi which can damage wood or cellulose.The active substance composition according to the invention comprises: a) at least one fungicidal organic active substance with a solubility in water of not more than 5 g/l at 25° C./1013 mbar, and b) a finely-divided polymer with an average particle size, determined by dynamic light scattering, of not more than 300 nm, in which the polymer particles comprise the active substance, the polymer being formed from ethylenically unsaturated monomers M comprising: at least 60% by weight, based on the total amount of the monomers M, of at least one neutral monoethylenically unsaturated monomer M1 with a solubility in water of not more than 30 g/l at 25° C., and up to 40% by weight, based on the total amount of the monomers M, of one or more ethylenically unsaturated monomers M2 other than the monomers M1.

    摘要翻译： 本发明涉及含水杀真菌活性物质组合物及其在控制有害微生物中的用途，特别是用于保护由微生物感染的纤维素材料特别是木材，特别是可损害木材或纤维素的那些有害真菌 。 根据本发明的活性物质组合物包含：a）至少一种在25℃，1013毫巴下在水中溶解度不超过5克/升的杀真菌有机活性物质，和b） 通过动态光散射确定的不大于300nm的平均粒度，其中聚合物颗粒包含活性物质，聚合物由烯键式不饱和单体M形成，包括：至少60重量％，基于总计 至少一种在25℃下在水中的溶解度不超过30g / l的至少一种中性单烯键式不饱和单体M1的单体量，和基于单体总量的至多40重量％ M，除了单体M1之外的一种或多种烯属不饱和单体M2。

    AQUEOUS FUNGICIDAL COMPOSITION AND USE THEREOF FOR COMBATING HARMFUL MICROORGANISMS
    2.
    发明申请
    AQUEOUS FUNGICIDAL COMPOSITION AND USE THEREOF FOR COMBATING HARMFUL MICROORGANISMS 有权
    水质防霉组合物及其用于组合有害微生物的用途

    公开(公告)号：US20100273897A1

    公开(公告)日：2010-10-28

    申请号：US12831055

    申请日：2010-07-06

    申请人： Reimer GÖTTSCHE ,  Heir Helga Göttsche ,  Gunnar Kleist ,  Joerg Habicht ,  Holger Schöpke ,  Patrick Amrhein

    发明人： Reimer GÖTTSCHE ,  Heir Helga Göttsche ,  Gunnar Kleist ,  Joerg Habicht ,  Holger Schöpke ,  Patrick Amrhein

    IPC分类号： A01N25/02

    CPC分类号： A01N25/02 ,  A01N25/04 ,  A01N43/36 ,  A01N43/653 ,  A01N47/12 ,  B27K3/007 ,  B27K3/15 ,  C08L25/06 ,  C08L33/14 ,  C08L97/02 ,  A01N25/30 ,  A01N2300/00

    摘要： The invention relates to aqueous fungicidal active substance compositions and to their use in the control of harmful microorganisms and in particular in the protection of cellulose-comprising materials, particularly wood, from infection by microorganisms, in particular those harmful fungi which can damage wood or cellulose.The active substance composition according to the invention comprises: a) at least one fungicidal organic active substance with a solubility in water of not more than 5 g/l at 25° C./1013 mbar, and b) a finely-divided polymer with an average particle size, determined by dynamic light scattering, of not more than 300 nm, in which the polymer particles comprise the active substance, the polymer being formed from ethylenically unsaturated monomers M comprising: at least 60% by weight, based on the total amount of the monomers M, of at least one neutral monoethylenically unsaturated monomer M1 with a solubility in water of not more than 30 g/l at 25° C., and up to 40% by weight, based on the total amount of the monomers M, of one or more ethylenically unsaturated monomers M2 other than the monomers M1.

    摘要翻译： 本发明涉及含水杀真菌活性物质组合物及其在控制有害微生物中的用途，特别是用于保护由微生物感染的纤维素材料特别是木材，特别是可损害木材或纤维素的那些有害真菌 。 根据本发明的活性物质组合物包含：a）至少一种在25℃，1013毫巴下在水中溶解度不超过5克/升的杀真菌有机活性物质，和b） 通过动态光散射确定的不大于300nm的平均粒度，其中聚合物颗粒包含活性物质，聚合物由烯键式不饱和单体M形成，包括：至少60重量％，基于总计 至少一种在25℃下在水中的溶解度不超过30g / l的至少一种中性单烯键式不饱和单体M1的单体量，和基于单体总量的至多40重量％ M，除了单体M1之外的一种或多种烯属不饱和单体M2。

    Aqueous insecticidal compositions and the use thereof for protecting lignocellulose-containing materials
    3.
    发明授权
    Aqueous insecticidal compositions and the use thereof for protecting lignocellulose-containing materials 有权
    水性杀虫组合物及其用于保护含木素纤维素的材料的用途

    公开(公告)号：US08999358B2

    公开(公告)日：2015-04-07

    申请号：US11885799

    申请日：2006-03-08

    申请人： Patrick Amrhein ,  Gunnar Kleist ,  Dirk Haentzschel ,  Joerg Habicht ,  Holger Schöpke

    发明人： Patrick Amrhein ,  Gunnar Kleist ,  Dirk Haentzschel ,  Joerg Habicht ,  Holger Schöpke

    IPC分类号： A01N25/04 ,  A01N53/02 ,  A01N47/10 ,  A01N57/10 ,  A01N43/36 ,  A01P7/04 ,  A01N25/26 ,  A01N25/28 ,  A01N53/00 ,  B27K3/00 ,  B27K3/15

    CPC分类号： A01N43/36 ,  A01N25/04 ,  A01N25/26 ,  A01N25/28 ,  A01N53/00 ,  B27K3/007 ,  B27K3/15 ,  A01N2300/00

    摘要： The present invention relates to aqueous insecticidal preparations in the form of an aqueous dispersion of finely divided polymer particles which comprise at least one insecticidal organic active ingredient with a solubility in water of not more than 5 g/l at 25° C. at 1013 mbar and which have a mean particle size, determined by dynamic light scattering, of not more than 300 nm, where the polymer particles which comprise the at least one insecticidal active ingredient of a cationic surface charge and where the aqueous dispersion of the active-ingredient-comprising polymer particles is obtainable by subjecting a monomer composition of ethylenically unsaturated monomers M, in which the ethylenically unsaturated monomers M comprise the at least one insecticidal active ingredient in dissolved form, to radical aqueous emulsion polymerization. The invention also related to the use of such aqueous insecticide compositions for protecting lignocellulosic materials, in particular timber, against attack by harmful insects.

    摘要翻译： 本发明涉及细分散的聚合物颗粒的水性分散体形式的含水杀虫剂，其含有至少一种在25℃，1013毫巴下在水中的溶解度不超过5克/升的杀虫有机活性成分 并且其具有不大于300nm的由动态光散射确定的平均粒度，其中包含至少一种阳离子表面活性成分的聚合物颗粒进料，并且其中活性成分 - 包含聚合物颗粒的方法可通过将烯键式不饱和单体M的单体组合物（其中烯键式不饱和单体M包含至少一种溶解形式的杀虫活性成分）进行自由基水性乳液聚合而获得。 本发明还涉及这种水性杀虫剂组合物用于保护木质纤维素材料，特别是木材，防止有害昆虫袭击的用途。

    Method for producing aqueous active substance compositions of active substances that are hardly soluble in water
    4.
    发明授权
    Method for producing aqueous active substance compositions of active substances that are hardly soluble in water 有权
    生成难溶于水的活性物质的水性活性物质组合物的制造方法

    公开(公告)号：US08974806B2

    公开(公告)日：2015-03-10

    申请号：US11658472

    申请日：2005-08-03

    申请人： Patrick Amrhein ,  Holger Schöpke ,  Gunnar Kleist ,  Michael Kluge

    发明人： Patrick Amrhein ,  Holger Schöpke ,  Gunnar Kleist ,  Michael Kluge

    IPC分类号： A01N25/12 ,  A01P15/00 ,  A01P3/00 ,  A01P13/00 ,  A01N43/36 ,  A01N25/04 ,  A01N25/26 ,  A01N25/28 ,  A01N43/653 ,  A01N53/00 ,  C08L97/02 ,  B27K3/00 ,  B27K3/15 ,  C08L33/08 ,  C08L35/02

    CPC分类号： A01N43/36 ,  A01N25/04 ,  A01N25/26 ,  A01N25/28 ,  A01N43/653 ,  A01N53/00 ,  B27K3/007 ,  B27K3/15 ,  C08L33/08 ,  C08L35/02 ,  C08L97/02 ,  A01N2300/00

    摘要： The present invention relates to a process for preparing aqueous active compound compositions of active compounds which are poorly soluble in water, in particular of active compounds for the protection of crops and materials. Moreover, the invention relates to the active compound compositions obtainable by the process and to their use for controlling harmful organisms in plants and in the protection of materials.The process comprises the following steps: a) provision of an aqueous suspension of solid active compound particles of at least one active compound having a solubility in water of not more than 5 g/l at 25° C./1013 mbar, comprising, for stabilizing the active compound particles, at least one surfactant, where the active compound particles in the suspension have a mean particle size, determined by dynamic light scattering, of not more than 1200 nm, b) emulsion polymerization of a first monomer composition M1 in the aqueous suspension of the active compound, where the monomer composition M1 comprises at least 95% by weight, based on its total weight, of at least one neutral, monoethylenically unsaturated monomer M1.1 having a solubility in water of not more than 30 g/l at 25° C./1013 mbar, giving an aqueous dispersion of polymer/active compound particles, and c) emulsion polymerization of a second monomer composition M2 in an aqueous dispersion of the polymer/active compound particles obtained in step b), where the monomer composition M2 comprises at least 60% by weight, based on its total weight, of at least one neutral, monoethylenically unsaturated monomer M2.1 having a solubility in water of not more than 30 g/l at 25° C./1013 mbar.

    摘要翻译： 本发明涉及一种制备水溶性较差的活性化合物的水性活性化合物组合物的方法，特别是用于保护作物和材料的活性化合物。 此外，本发明涉及通过该方法获得的活性化合物组合物及其用于控制​​植物中的有害生物和保护材料的用途。 该方法包括以下步骤：a）提供至少一种在25℃下在水中具有不超过5克/升溶解度的活性化合物的固体活性化合物颗粒的水性悬浮液。1013毫巴， 稳定活性化合物颗粒，至少一种表面活性剂，其中悬浮液中的活性化合物颗粒具有不超过1200nm的动态光散射测定的平均粒径，b）第一单体组合物M1在 活性化合物的水性悬浮液，其中单体组合物M1占总重量的至少95重量％至少一种在水中的溶解度不超过30g / m 2的中性单烯属不饱和单体M1.1， l在25℃/ 1013毫巴下，得到聚合物/活性化合物颗粒的水分散体，和c）第二单体组合物M2在聚合物/活性化合物颗粒的水分散体中的乳液聚合 其中单体组合物M2占其总重量至少为60重量％，至少一种在水中的溶解度不超过30g / l的至少一种中性单烯属不饱和单体M2.1 在25℃/ 1013毫巴。

    Aqueous Fungicidal Composition And Use Thereof For Combating Harmful Micro Organisms
    5.
    发明申请
    Aqueous Fungicidal Composition And Use Thereof For Combating Harmful Micro Organisms 审中-公开
    水性杀真菌组合物及其用于防治有害微生物

    公开(公告)号：US20080090886A1

    公开(公告)日：2008-04-17

    申请号：US11587052

    申请日：2005-04-25

    申请人： Reimer Gottsche ,  Helga Gottsche ,  Gunnar Kleist ,  Joerg Habicht ,  Holger Schopke ,  Patrick Amrhein

    发明人： Reimer Gottsche ,  Helga Gottsche ,  Gunnar Kleist ,  Joerg Habicht ,  Holger Schopke ,  Patrick Amrhein

    IPC分类号： A01N43/653 ,  A01N25/00 ,  A01P15/00 ,  A01P7/04 ,  A01N43/36

    摘要： The invention relates to aqueous fungicidal active substance compositions and to their use in the control of harmful microorganisms and in particular in the protection of cellulose-comprising materials, particularly wood, from infection by microorganisms, in particular those harmful fungi which can damage wood or cellulose. The active substance composition according to the invention comprises: a) at least one fungicidal organic active substance with a solubility in water of not more than 5 g/l at 25° C./1013 mbar, and b) a finely-divided polymer with an average particle size, determined by dynamic light scattering, of not more than 300 nm, in which the polymer particles comprise the active substance, the polymer being formed from ethylenically unsaturated monomers M comprising: at least 60% by weight, based on the total amount of the monomers M, of at least one neutral monoethylenically unsaturated monomer Ml with a solubility in water of not more than 30 g/l at 25° C., and up to 40% by weight, based on the total amount of the monomers M, of one or more ethylenically unsaturated monomers M2 other than the monomers M1.

    摘要翻译： 本发明涉及含水杀真菌活性物质组合物及其在控制有害微生物中的用途，特别是用于保护由微生物感染的纤维素材料特别是木材，特别是可损害木材或纤维素的那些有害真菌 。 根据本发明的活性物质组合物包含：a）至少一种在25℃，1013毫巴下在水中溶解度不超过5g / l的杀真菌有机活性物质，和b） 通过动态光散射确定的不大于300nm的平均粒度，其中聚合物颗粒包含活性物质，聚合物由烯键式不饱和单体M形成，包括：至少60重量％，基于总计 至少一种在25℃下在水中的溶解度不超过30g / l的至少一种中性单烯键式不饱和单体M 1和单体M的量基于单体的总量计至多40重量％ M，除了单体M1之外的一种或多种烯属不饱和单体M2。

    Aqueous Insecticidal Compositions and the Use Thereof for Protecting Lignocellulose-Containing Materials
    6.
    发明申请
    Aqueous Insecticidal Compositions and the Use Thereof for Protecting Lignocellulose-Containing Materials 有权
    水性杀虫组合物及其用途，用于保护含木质纤维素的材料

    公开(公告)号：US20080138371A1

    公开(公告)日：2008-06-12

    申请号：US11885799

    申请日：2006-03-08

    申请人： Patrick Amrhein ,  Gunnar Kleist ,  Dirk Haentzschel ,  Joerg Habicht ,  Holger Schopke

    发明人： Patrick Amrhein ,  Gunnar Kleist ,  Dirk Haentzschel ,  Joerg Habicht ,  Holger Schopke

    IPC分类号： A01N25/04 ,  A01N53/02 ,  A01N47/10 ,  A01N57/10 ,  A01N43/36 ,  A01P7/04

    CPC分类号： A01N43/36 ,  A01N25/04 ,  A01N25/26 ,  A01N25/28 ,  A01N53/00 ,  B27K3/007 ,  B27K3/15 ,  A01N2300/00

    摘要： The invention relates to aqueous insecticidal compositions embodied in the form of an aqueous polymer fine particle dispersion containing at least one type of organic insecticidal active substance whose water solubility is equal to or less than 5 g/l at 25° C./1013 mbar and a polymer particle average size, determined by dynamic light scattering, is equal to or less than 300 nm, wherein the polymer particles containing at least one insecticidal active substance exhibit a cationic surface charge and the aqueous dispersion of active substance containing polymer particles is obtained by radical aqueous emulsion polymerisation of an ethylenically unsaturated monomer composition M, in which said ethelenycally unsaturated monomer M contains at least one type of insecticidal active substance in a dissolved form. The use of the inventive aqueous insecticidal compositions for protecting lignocellulose-containing materials, in particular wood, against infest pest attacks is also disclosed.

    摘要翻译： 本发明涉及以含水聚合物细颗粒分散体的形式体现的含水杀虫组合物，其含有至少一种类型的有机杀虫活性物质，其水溶解度在25℃/ 1013毫巴下等于或小于5克/升， 通过动态光散射测定的聚合物粒子平均粒径为300nm以下，其中含有至少一种杀虫活性物质的聚合物粒子呈现阳离子表面电荷，含有活性物质的聚合物粒子的水分散体可以通过 烯键式不饱和单体组合物M的自由基水性乳液聚合，其中所述的乙烯基不饱和单体M含有至少一种溶解形式的杀虫活性物质。 还公开了本发明的水性杀虫组合物用于保护含木素纤维素的材料，特别是木材，防止虫害侵袭的用途。

    Method For Producing Aqueous Active Substance Compositions Of Active Substances That Are Hardly Soluble In Water
    7.
    发明申请
    Method For Producing Aqueous Active Substance Compositions Of Active Substances That Are Hardly Soluble In Water 有权
    用于生产在水中难溶于活性物质的水性活性物质组合物的方法

    公开(公告)号：US20080213326A1

    公开(公告)日：2008-09-04

    申请号：US11658472

    申请日：2005-08-03

    申请人： Patrick Amrhein ,  Holger Schopke ,  Gunnar Kleist ,  Michael Kluge

    发明人： Patrick Amrhein ,  Holger Schopke ,  Gunnar Kleist ,  Michael Kluge

    IPC分类号： A01N25/12 ,  A01P15/00 ,  A01P3/00 ,  A01P13/00

    CPC分类号： A01N43/36 ,  A01N25/04 ,  A01N25/26 ,  A01N25/28 ,  A01N43/653 ,  A01N53/00 ,  B27K3/007 ,  B27K3/15 ,  C08L33/08 ,  C08L35/02 ,  C08L97/02 ,  A01N2300/00

    摘要： The present invention relates to a process for preparing aqueous active compound compositions of active compounds which are poorly soluble in water, in particular of active compounds for the protection of crops and materials. Moreover, the invention relates to the active compound compositions obtainable by the process and to their use for controlling harmful organisms in plants and in the protection of materials.The process comprises the following steps: a) provision of an aqueous suspension of solid active compound particles of at least one active compound having a solubility in water of not more than 5 g/l at 25° C./1013 mbar, comprising, for stabilizing the active compound particles, at least one surfactant, where the active compound particles in the suspension have a mean particle size, determined by dynamic light scattering, of not more than 1200 nm, b) emulsion polymerization of a first monomer composition M1 in the aqueous suspension of the active compound, where the monomer composition M1 comprises at least 95% by weight, based on its total weight, of at least one neutral, monoethylenically unsaturated monomer M1.1 having a solubility in water of not more than 30 g/l at 25° C./1013 mbar, giving an aqueous dispersion of polymer/active compound particles, and c) emulsion polymerization of a second monomer composition M2 in an aqueous dispersion of the polymer/active compound particles obtained in step b), where the monomer composition M2 comprises at least 60% by weight, based on its total weight, of at least one neutral, monoethylenically unsaturated monomer M2.1 having a solubility in water of not more than 30 g/l at 25° C./1013 mbar.

    摘要翻译： 本发明涉及一种制备水溶性较差的活性化合物的水性活性化合物组合物的方法，特别是用于保护作物和材料的活性化合物。 此外，本发明涉及通过该方法获得的活性化合物组合物及其用于控制​​植物中的有害生物和保护材料的用途。 该方法包括以下步骤：a）提供至少一种在25℃下在水中具有不超过5克/升溶解度的活性化合物的固体活性化合物颗粒的水性悬浮液。1013毫巴， 稳定活性化合物颗粒，至少一种表面活性剂，其中悬浮液中的活性化合物颗粒具有不大于1200nm的动态光散射测定的平均粒径，b）第一单体组合物M 1的乳液聚合 活性化合物的水性悬浮液，其中单体组合物M 1基于其总重量包含至少95重量％的至少一种在水中的溶解度不超过30g的中性单烯属不饱和单体M 1.1 / l在25℃/ 1013毫巴下，得到聚合物/活性化合物颗粒的水分散体，和c）第二单体组合物M 2在聚合物/活性化合物颗粒的水分散体中的乳液聚合 其中单体组合物M 2基于其总重量包含至少60重量％的至少一种在水中的溶解度不超过30g / m 2的中性单烯键式不饱和单体M 2.1， l在25℃/ 1013毫巴。