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    Process for the production of urethanes
    1.
    发明授权
    Process for the production of urethanes 失效
    生产聚氨酯的工艺

    公开(公告)号：US4593116A

    公开(公告)日：1986-06-03

    申请号：US620207

    申请日：1984-06-13

    申请人： Gunter Stammann ,  Johann Grolig ,  Robert Becker ,  Helmut Waldmann

    发明人： Gunter Stammann ,  Johann Grolig ,  Robert Becker ,  Helmut Waldmann

    IPC分类号： C07B61/00 ,  B01J31/00 ,  B01J31/28 ,  C07C67/00 ,  C07C239/00 ,  C07C269/00 ,  C07C125/065 ,  C07C125/067 ,  C07C125/073 ,  C07C125/075

    CPC分类号： C07C269/00

    摘要： Urethanes are made by reacting an organic nitro compound with an organic compound containing at least one hydroxyl group in the presence of carbon monoxide, hydrogen and a catalyst system. The carbon monoxide and hydrogen are used in quantities such that the molar ratio of CO to H.sub.2 is from 0.3:1 to 3:1. The catalyst system is made up of at least one noble metal or compound of a noble metal from Group VIIIB of the Periodic System of Elements, at least one organic nitrogen base and a co-catalyst combination of iron or copper oxidic or hydroxidic compound and a chloride compound. The product urethanes are useful in the production of isocyanates and pesticides.

    摘要翻译： 聚氨酯是通过在一氧化碳，氢气和催化剂体系的存在下使有机硝基化合物与含有至少一个羟基的有机化合物反应来制备的。 一氧化碳和氢气的使用量使得CO与H 2的摩尔比为0.3:1至3:1。 该催化剂体系由至少一种元素周期表第VIIIB族的贵金属或贵金属的化合物，至少一种有机氮碱和铁或铜氧化物或氢氧化物的助催化剂组合和 氯化物。 产品氨基甲酸酯可用于生产异氰酸酯和农药。

    Process for the production of urethanes
    2.
    发明授权
    Process for the production of urethanes 失效
    生产聚氨酯的工艺

    公开(公告)号：US4582923A

    公开(公告)日：1986-04-15

    申请号：US735249

    申请日：1985-05-17

    申请人： Gunter Stammann ,  Robert Becker ,  Johann Grolig ,  Helmut Waldmann

    发明人： Gunter Stammann ,  Robert Becker ,  Johann Grolig ,  Helmut Waldmann

    IPC分类号： C07B61/00 ,  B01J31/00 ,  B01J31/26 ,  B01J31/28 ,  B01J31/32 ,  C07C269/04 ,  C07C271/06 ,  C07C271/20 ,  C07C271/26 ,  C07C271/38 ,  C07C125/067 ,  C07C125/065 ,  C07C125/073 ,  C07C125/075

    CPC分类号： C07C271/06

    摘要： Urethanes are made by reacting a primary amine with carbon monoxide and a compound containing at least one hydroxyl group in the presence of an oxidizing agent and a catalyst system. The catalyst system is made up of (i) a noble metal and/or a noble metal compound of a metal of the Eighth Secondary Group of the Periodic System of Elements and (ii) an oxidizing quinoid and/or a compound capable of being converted to an oxidizing quinoid compound under the reaction conditions. The catalyst system may optionally include (iii) metal compounds of elements of the Third to Fifth Main Groups and/or First to Eighth Secondary Groups of the Periodic System of Elements and/or (iv) a tertiary amine. This reaction is generally carried out at a temperature of from 100.degree. to 300.degree. C. and at a pressure of from 5 to 500 bars. The product urethanes are useful in the production of isocyanates and pesticides.

    摘要翻译： 聚氨酯通过在氧化剂和催化剂体系的存在下使伯胺与一氧化碳和含有至少一个羟基的化合物反应来制备。 催化剂体系由（i）贵金属和/或贵金属化合物的元素周期表第八族中的金属和/或氧化醌类和/或能够转化的化合物组成 在反应条件下与氧化喹啉化合物反应。 催化剂体系可以任选地包括（iii）元素周期表系统的第三至第五主族和/或第一至第八中间的元素的金属化合物和/或（ⅳ）叔胺。 该反应通常在100〜300℃的温度和5〜500巴的压力下进行。 产品氨基甲酸酯可用于生产异氰酸酯和农药。

    Process for the preparation of urethane
    5.
    发明授权
    Process for the preparation of urethane 失效
    氨基甲酸酯的制备方法

    公开(公告)号：US4304922A

    公开(公告)日：1981-12-08

    申请号：US125395

    申请日：1980-02-27

    申请人： Robert Becker ,  Johann Grolig ,  Christian Rasp ,  Gunter Stammann

    发明人： Robert Becker ,  Johann Grolig ,  Christian Rasp ,  Gunter Stammann

    IPC分类号： C07C239/00 ,  C07C67/00 ,  C07C271/06 ,  C07C125/065 ,  C07C125/073

    CPC分类号： C07C271/06

    摘要： Production of urethanes by the oxycarbonylation reaction of N,N'-disubstituted ureas and organic compounds containing at least one hydroxyl group with carbon monoxide in the presence of molecular oxygen and/or organic nitro compounds and a catalyst system comprising (a) a noble metal and/or noble metal compound of the eighth subgroup of the periodic system of elements and (b) a compound of an element and/or elements of the third to fifth main group and/or first to eighth subgroup of the periodic system of elements characterized in that said compounds are capable of undergoing Redox reactions under the reaction conditions.

    摘要翻译： 在分子氧和/或有机硝基化合物的存在下通过N，N'-二取代的脲和含有至少一个羟基的有机化合物与一氧化碳的羰基化反应制备氨基甲酸酯和包含（a）贵金属 和/或元素周期性系统的第八子群的贵金属化合物和（b）元素周期系统的元素和/或元素的第三至第五主族和/或第一至第八亚组的化合物，其特征在于 因为所述化合物能够在反应条件下进行氧化还原反应。

    Process for the production of urethanes
    6.
    发明授权
    Process for the production of urethanes 失效
    生产聚氨酯的工艺

    公开(公告)号：US4339592A

    公开(公告)日：1982-07-13

    申请号：US238518

    申请日：1981-02-26

    申请人： Robert Becker ,  Christian Rasp ,  Gunter Stammann ,  Johann Grolig

    发明人： Robert Becker ,  Christian Rasp ,  Gunter Stammann ,  Johann Grolig

    IPC分类号： C07C269/00 ,  B01J23/89 ,  B01J27/00 ,  B01J27/06 ,  B01J27/10 ,  B01J31/00 ,  B01J31/28 ,  B01J31/34 ,  C07B61/00 ,  C07C67/00 ,  C07C239/00 ,  C07C271/26 ,  C07C271/28 ,  C07C125/073

    CPC分类号： B01J27/06 ,  B01J23/8906

    摘要： A urethane is produced by reacting an organic nitro compound with carbon monoxide and an organic compound containing at least one hydroxyl group in the presence of a catalyst and a co-catalyst. This reaction is conducted in the liquid phase at elevated temperature and pressure. The catalyst employed is an element and/or compound of an element from the group of noble metals of the 8th Secondary Group of the Periodic Table. The co-catalyst used is formed from (1) a component taken from the group consisting of iron oxychloride, a mixture of iron compounds containing iron oxychloride and oxide-chloride combinations and (2) metallic iron or an iron alloy in finely divided or high surface form. The oxides which may be used in the oxide-chloride combinations of co-catalyst component (1) are the oxides and/or oxide hydrates of tetravalent tin, trivalent chromium, hexavalent molybdenum, hexavalent tungsten, pentavalent vanadium, divalent iron and trivalent iron. The chlorides which may be used in this oxide-chloride combination are chlorides of the elements of Groups IIIA, IVA, VA and IB to VIIIB of the Periodic Table and/or hydrochlorides of tertiary amines.

    摘要翻译： 氨基甲酸酯是通过有机硝基化合物与一氧化碳和含有至少一个羟基的有机化合物在催化剂和助催化剂的存在下反应生成的。 该反应在升高的温度和压力下在液相中进行。 所使用的催化剂是来自元素周期表第八族中的贵金属的元素和/或化合物。 所使用的助催化剂由（1）由三氯氧化铁组成的组分，含有氯氧化铁的铁化合物和氧化物 - 氯化物组合的混合物组成的组分和（2）细碎或高分的金属铁或铁合金 表面形式。 可用于助催化剂组分（1）的氧化物 - 氯化物组合的氧化物是四价锡，三价铬，六价钼，六价钨，五价钒，二价铁和三价铁的氧化物和/或氧化物水合物。 可用于该氧化物 - 氯化物组合中的氯化物是元素周期表IIIA，IVA，VA和IB至VIIIB族元素的氯化物和/或叔胺的盐酸盐。