公开(公告)号：US20140316066A1

公开(公告)日：2014-10-23

申请号：US14252988

申请日：2014-04-15

Applicant: Hitachi, Ltd.

Inventor： Masayuki KAMIKAWA ,  Takeyuki KONDO ,  Kenichiro OKA ,  Toshiaki MATSUO ,  Yasunari SASE

IPC: C08G63/78 ,  B01J19/00

CPC classification number: C08G63/785

Abstract: Provided are a polyester production apparatus and a method, which can rapidly exhaust water produced by the dehydration condensation reaction, from the reaction system.The polyester production apparatus includes: an esterification reactor producing polymer by the dehydration condensation reaction between 1,3-propanediol and dicarboxylic acid to volatilize a volatile component including eliminated water produced in said dehydration condensation reaction, a plurality of polymerization reactors increasing the polymerization degree by carrying out polycondensation reaction between polymers, and to volatilize the volatile component including the eliminated product generated by said polycondensation reaction, a wet-type condenser condensing said eliminated water and exhausting the condensed component and non-condensed component, and a decompression apparatus reducing a pressure in said esterification reactor. Said volatile component's outlet of said esterification reactor is connected to the volatile component's inlet of said wet-type condenser, and said decompression apparatus is connected next to the non-condensed component's outlet of said wet-type condenser.

Abstract translation: 提供一种可以从反应体系中快速排出由脱水缩合反应产生的水的聚酯制造装置和方法。 聚酯制造装置包括：通过1,3-丙二醇和二羧酸之间的脱水缩合反应生成聚合物的酯化反应器，使包含所述脱水缩合反应产生的除去水的挥发性成分挥发，将聚合度提高的多个聚合反应器 在聚合物之间进行缩聚反应，挥发挥发成分，包括由所述缩聚反应生成的被除去的产物，将冷凝所述被消除的水并排出冷凝成分和非冷凝成分的湿式冷凝器，以及减压装置 在所述酯化反应器中。 所述酯化反应器的所述挥发性组分的出口连接到所述湿式冷凝器的挥发性组分的入口，并且所述减压装置在所述湿式冷凝器的非冷凝组分的出口旁边连接。

公开(公告)号：US20130338382A1

公开(公告)日：2013-12-19

申请号：US13907060

申请日：2013-05-31

Applicant: Hitachi, Ltd.

Inventor： Takeyuki KONDO ,  Masayuki KAMIKAWA ,  Toshiaki MATSUO ,  Masashi TANTO ,  Yasunari SASE ,  Hiroyuki ITO

IPC: B01J8/10 ,  C13K1/02 ,  C07D307/46

CPC classification number: B01J8/10 ,  C07D307/46 ,  C07H3/02 ,  C13K1/02 ,  Y02P20/544

Abstract: In a method and apparatus for producing a useful substance by allowing a fluid containing a biomass raw material to act on a supercritical water and/or subcritical water, the fluid containing a biomass raw material in a high concentration is efficiently mixed with the supercritical water and/or subcritical water, whereby the amount of tar and carbon particles produced as by-products is decreased and blockage and abrasion of a pipe and an equipment is suppressed, or it is possible to easily remove the by-products.At least two inlet flow paths for flowing the raw material fluid and the supercritical water or subcritical water into the mixing flow path are provided, along with an agitation blade having a rotating shaft set on a center shaft of the mixing flow path and an agitation blade having a rotating shaft set on a center shaft of the mixing flow path.

Abstract translation: 在通过使含有生物质原料的流体作用在超临界水和/或亚临界水上而制造有用物质的方法和装置中，含有高浓度生物质原料的流体与超临界水有效地混合， /或亚临界水，从而减少作为副产物产生的焦油和碳颗粒的量，并抑制管道和设备的堵塞和磨损，或者可以容易地除去副产物。 提供用于将原料流体和超临界水或亚临界水流入混合流路的至少两个入口流动路径，以及具有设置在混合流动路径的中心轴上的旋转轴的搅拌叶片和搅拌叶片 具有设置在混合流路的中心轴上的旋转轴。

公开(公告)号：US20160136543A1

公开(公告)日：2016-05-19

申请号：US14897844

申请日：2014-06-19

Applicant: HITACHI, LTD.

Inventor： Keisuke SHIBUYA ,  Yasuhiko TADA ,  Takeyuki KONDO ,  Sei MURAKAMI

IPC: B01D15/22 ,  B01D15/18

CPC classification number: B01D15/22 ,  B01D15/08 ,  B01D15/1821 ,  B01D15/1885 ,  B01D15/20 ,  C07K1/22 ,  G01N2030/8813

Abstract: An object of the present invention is to separate a material to be separated at a low cost and constant accuracy when the material to be separated is separated from a mobile phase containing the material to be separated through the passing of the mobile phase through a stationary phase, even if the mobile phase has a large volume. A separation device characterized in that a separation column provided with a stationary phase having a volume capable of processing the entire volume of a mobile phase containing a material to be separated is provided, the separation column is replaceable, and the usage count of the stationary phase reaches a lifetime count through the processing of one batch.

Abstract translation: 本发明的目的是当待分离的材料通过流动相通过固定相与含有待分离材料的流动相分离时，以低成本和恒定的精度将待分离的材料分离 ，即使流动相具有较大的体积。 一种分离装置，其特征在于，设置有具有能够处理含有待分离材料的流动相的整个体积的体积的固定相的分离塔，所述分离塔是可更换的，并且所述固定相的使用计数 通过一批处理达到终身计数。

公开(公告)号：US20150299385A1

公开(公告)日：2015-10-22

申请号：US14441538

申请日：2013-11-07

Applicant: HITACHI, LTD.

Inventor： Masayuki KAMIKAWA ,  Toshiaki MATSUO ,  Takeyuki KONDO ,  Yasunari SASE ,  Masashi TANTO

IPC: C08G63/78 ,  B01J19/24 ,  C08G63/183

CPC classification number: C08G63/78 ,  B01J19/1862 ,  B01J19/20 ,  B01J19/245 ,  B01J2219/00006 ,  B01J2219/00083 ,  B01J2219/00103 ,  B01J2219/24 ,  C08G63/183 ,  C08G63/785 ,  Y02P20/582

Abstract: Provided are a device and a method for efficiently producing a polyester by using 1,4-butanediol as a starting material. The device for producing a polyester includes: a preparation tank (4) for starting material slurry; a storage tank (6) for starting material slurry; an esterification reactor (9); an initial polycondensation reactor (11); a middle polycondensation reactor (13); and a final polycondensation reactor (15). An exhaust system for each of the initial, middle, and final polycondensation reactors includes a wet condenser (17, 23, or 31) using a liquid containing 1,4-butanediol as a coolant; and a hot well (22, 30, or 38) connected to the corresponding wet condenser. Herein, process scattered substances scattering with exhaust are collected, and hydrolyzed in the hot well, so as to be returned to the esterification step. This allows the polyester to be efficiently produced.

Abstract translation: 提供了通过使用1,4-丁二醇作为起始材料来有效地制造聚酯的装置和方法。 用于制造聚酯的装置包括：用于起始材料浆料的制备罐（4）; 用于起始材料浆料的储罐（6）; 酯化反应器（9）; 初始缩聚反应器（11）; 中间缩聚反应器（13）; 和最终缩聚反应器（15）。 用于每个初始，中间和最终缩聚反应器的排气系统包括使用含有1,4-丁二醇作为冷却剂的液体的湿式冷凝器（17,23或31） 以及连接到相应的湿式冷凝器的热井（22,30或38）。 这里，收集与排气一起散射的散射物质，在热水中水解，回到酯化步骤。 这样可以有效地生产聚酯。

公开(公告)号：US20140024793A1

公开(公告)日：2014-01-23

申请号：US13946132

申请日：2013-07-19

Applicant: Hitachi, Ltd.

Inventor： Toshiaki MATSUO ,  Masayuki KAMIKAWA ,  Takeyuki KONDO ,  Norifumi MAEDA

IPC: C08G63/80

CPC classification number: C08G63/80 ,  C08G63/181 ,  C08G63/78 ,  C08G63/785

Abstract: Provided is a polyester production process which provides the polyester with a suitable molecular weight capable of enduring various mold processings and which can inhibit the polymer from being colored due to side reactions in synthesis.The above polyester production process comprises: an esterification step of carrying out an esterification reaction of ethylene glycol and 2,5-furandicarboxylic acid to form an oligomer and a condensation polymerization step of carrying out a condensation polymerization reaction of the oligomer to produce polyester, wherein the esterification reaction is carried out at 200 to 250° C.

Abstract translation: 提供一种聚酯制造方法，其为聚酯提供能够耐受各种成型加工的合适的分子量，并且可以抑制聚合物由于合成中的副反应而着色。 上述聚酯制造方法包括：进行乙二醇和2,5-呋喃二羧酸的酯化反应以形成低聚物的酯化步骤和进行低聚物的缩聚反应以制备聚酯的缩聚步骤，其中 酯化反应在200〜250℃下进行