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    Polyurethanes made from hydroxy-methyl containing fatty acids or alkyl esters of such fatty acids
    2.
    发明授权
    Polyurethanes made from hydroxy-methyl containing fatty acids or alkyl esters of such fatty acids 有权
    由含羟基甲基的脂肪酸或这种脂肪酸的烷基酯制成的聚氨酯

    公开(公告)号：US08686057B2

    公开(公告)日：2014-04-01

    申请号：US11663466

    申请日：2005-10-24

    申请人： Hanno R. Van der Wal ,  Camiel F. Bartelink

    发明人： Hanno R. Van der Wal ,  Camiel F. Bartelink

    IPC分类号： C08G18/28

    CPC分类号： C08G18/36 ,  C08G18/4288 ,  C08G2101/0083

    摘要： Polyurethane polymers are made from a reaction mixture that contains a polyisocyanate, a hydroxylmethyl-containing fatty acid or ester, and another polyol, polyamine or aminoalcohol. The carboxylic acid or ester group on the hydroxymethyl-containing fatty acid or ester are capable of engaging in a variety of reactions with the polyisocyanate and/or amine or hydroxyl groups present in the reaction mixture. This allows for good quality, high molecular weight polymers to be produced even though the hydroxymethyl-containing fatty acid or ester tends to be a low functionality material.

    摘要翻译： 聚氨酯聚合物由含有多异氰酸酯，含羟甲基脂肪酸或酯的反应混合物和另一种多元醇，多胺或氨基醇制成。 含有羟甲基的脂肪酸或酯上的羧酸或酯基能够与存在于反应混合物中的多异氰酸酯和/或胺或羟基发生各种反应。 即使含有羟甲基的脂肪酸或酯倾向于低官能度材料，也可以生产高质量的高分子量聚合物。

    Polyurethanes made from hydroxy-methyl containing fatty acids or alkyl esters of such fatty acids
    4.
    发明申请
    Polyurethanes made from hydroxy-methyl containing fatty acids or alkyl esters of such fatty acids 有权
    由含羟基甲基的脂肪酸或这种脂肪酸的烷基酯制成的聚氨酯

    公开(公告)号：US20090264548A1

    公开(公告)日：2009-10-22

    申请号：US11663466

    申请日：2005-10-24

    申请人： Hanno R. Van der Wal ,  Camiel F. Bartelink

    发明人： Hanno R. Van der Wal ,  Camiel F. Bartelink

    IPC分类号： C08G18/36 ,  C08J9/00

    CPC分类号： C08G18/36 ,  C08G18/4288 ,  C08G2101/0083

    摘要： Polyurethane polymers are made from a reaction mixture that contains a polyisocyanate, a hydroxylmethyl-containing fatty acid or ester, and another polyol, polyamine or aminoalcohol. The carboxylic acid or ester group on the hydroxymethyl-containing fatty acid or ester are capable of engaging in a variety of reactions with the polyisocyanate and/or amine or hydroxyl groups present in the reaction mixture. This allows for good quality, high molecular weight polymers to be produced even though the hydroxymethyl-containing fatty acid or ester tends to be a low functionality material.

    摘要翻译： 聚氨酯聚合物由含有多异氰酸酯，含羟甲基脂肪酸或酯的反应混合物和另一种多元醇，多胺或氨基醇制成。 含有羟甲基的脂肪酸或酯上的羧酸或酯基能够与存在于反应混合物中的多异氰酸酯和/或胺或羟基发生各种反应。 即使含有羟甲基的脂肪酸或酯倾向于低官能度材料，也可以生产高质量的高分子量聚合物。

    Thermoplastic Polyurethane Containing Structural Units of Polyester and Polyether Diols
    6.
    发明申请
    Thermoplastic Polyurethane Containing Structural Units of Polyester and Polyether Diols 有权
    含聚酯和聚醚二醇结构单元的热塑性聚氨酯

    公开(公告)号：US20090149622A1

    公开(公告)日：2009-06-11

    申请号：US11991832

    申请日：2006-09-22

    申请人： Mark F. Sonnenschein ,  J. Mark Cox ,  Hanno R. Van der Wal ,  Benjamin L. Wendt

    发明人： Mark F. Sonnenschein ,  J. Mark Cox ,  Hanno R. Van der Wal ,  Benjamin L. Wendt

    IPC分类号： C08G18/32

    CPC分类号： C08G18/4837 ,  C08G18/10 ,  C08G18/4018 ,  C08G18/664 ,  C08G18/6674 ,  C08G18/3206

    摘要： The present invention is a transparent thermoplastic polyurethane (TPU) comprising structural units of: a.) a diisocyanate; b.1) a polyester diol and b.2) a specific polyether diol and c.) a chain extender. The TPU has good combinations of light transmission and clarity, tensile strength, low temperature flexibility, and high moisture vapor transition rates compared to other commercial or known TPUs. A preferred example composition is a TPU that is based on MDI as the diisocyanate monomer, polycaprolactone as a polyester diol, an EO capped EO/PO polyether diol containing less than 20% EO, and butanediol as chain extender. These composition have good combinations of clarity, tensile strength, hydrolytic stability and processability compared to TPUs prepared using either polyester or polyether diols alone or the combination with a higher EO polyether diol.

    摘要翻译： 本发明是一种透明热塑性聚氨酯（TPU），其包含以下结构单元：a。）二异氰酸酯; b.1）聚酯二醇和b.2）特定的聚醚二醇和c。）扩链剂。 与其他商业或已知的TPU相比，TPU具有良好的透光性和透明度，拉伸强度，低温柔韧性和高水蒸汽转变速率的组合。 优选的实施例组合物是基于MDI作为二异氰酸酯单体的TPU，作为聚酯二醇的聚己内酯，含有少于20％EO的EO封端的EO / PO聚醚二醇和作为扩链剂的丁二醇。 与单独使用聚酯或聚醚二醇或与较高EO聚醚二醇的组合制备的TPU相比，这些组合物具有良好的透明度，拉伸强度，水解稳定性和加工性能的组合。

    HYBRID POLYESTER-POLYETHER POLYOLS
    7.
    发明申请
    HYBRID POLYESTER-POLYETHER POLYOLS 有权
    混合聚酯聚醚多元醇

    公开(公告)号：US20130035467A1

    公开(公告)日：2013-02-07

    申请号：US13640429

    申请日：2011-04-21

    申请人： Pavel L. Shutov ,  Jorge Jimenez ,  Hanno R. Van der Wal ,  Francois M. Casati

    发明人： Pavel L. Shutov ,  Jorge Jimenez ,  Hanno R. Van der Wal ,  Francois M. Casati

    IPC分类号： C07C69/80 ,  C08G18/32

    CPC分类号： C08G18/4261 ,  C08G18/4866 ,  C08G63/42 ,  C08G63/672 ,  C08G63/914 ,  C08G65/2603 ,  C08G65/2663 ,  C08G65/2672 ,  C08G65/2678 ,  C08G2101/0025 ,  C08J9/141 ,  C08J2375/06

    摘要： A process for preparing a hybrid polyester-polyether polyol comprises contacting a carboxyl group-containing component and an epoxide, optionally in the presence of one or more of a double metal cyanide catalyst, a superacid catalyst, a metal salt of a superacid catalyst and/or a tertiary amine catalyst, under conditions such that a hybrid polyester-polyether polyol is formed. The hybrid polyester-polyether polyol offers the advantages of both ester and ether functionalities when used in a polyurethane formulation, thus enhancing physical properties. The process results in products having narrow polydispersity, a low acid number and unsaturation, and reduced byproduct formation, particularly when the double metal cyanide catalyst is employed.

    摘要翻译： 制备混合聚酯 - 聚醚多元醇的方法包括任选地在一种或多种双金属氰化物催化剂，超酸催化剂，超酸催化剂的金属盐和/或其中的一种或多种的存在下使含羧基的组分和环氧化物接触， 或叔胺催化剂，在形成混合聚酯 - 聚醚多元醇的条件下进行。 当用于聚氨酯配方时，混合聚酯 - 聚醚多元醇具有酯和醚官能团的优点，从而提高物理性能。 该方法产生具有窄多分散性，低酸值和不饱和度的产物，以及减少的副产物形成，特别是当使用双金属氰化物催化剂时。

    Thermoplastic polyurethane containing structural units of polyester and polyether diols
    8.
    发明授权
    Thermoplastic polyurethane containing structural units of polyester and polyether diols 有权
    含聚酯和聚醚二醇结构单元的热塑性聚氨酯

    公开(公告)号：US08296974B2

    公开(公告)日：2012-10-30

    申请号：US11991832

    申请日：2006-09-22

    申请人： Mark F. Sonnenschein ,  J. Mark Cox ,  Hanno R. Van der Wal ,  Benjamin L. Wendt

    发明人： Mark F. Sonnenschein ,  J. Mark Cox ,  Hanno R. Van der Wal ,  Benjamin L. Wendt

    IPC分类号： A43B5/04 ,  C08G18/00

    CPC分类号： C08G18/4837 ,  C08G18/10 ,  C08G18/4018 ,  C08G18/664 ,  C08G18/6674 ,  C08G18/3206

    摘要： The present invention is a transparent thermoplastic polyurethane (TPU) comprising structural units of: a.) a diisocyanate; b.1) a polyester diol and b.2) a specific polyether diol and c.) a chain extender. The TPU has good combinations of light transmission and clarity, tensile strength, low temperature flexibility, and high moisture vapor transition rates compared to other commercial or known TPUs. A preferred example composition is a TPU that is based on MDI as the diisocyanate monomer, polycaprolactone as a polyester diol, an EO capped EO/PO polyether diol containing less than 20% EO, and butanediol as chain extender. These composition have good combinations of clarity, tensile strength, hydrolytic stability and processability compared to TPUs prepared using either polyester or polyether diols alone or the combination with a higher EO polyether diol.

    摘要翻译： 本发明是一种透明热塑性聚氨酯（TPU），其包含以下结构单元：a。）二异氰酸酯; b.1）聚酯二醇和b.2）特定的聚醚二醇和c。）扩链剂。 与其他商业或已知的TPU相比，TPU具有良好的透光性和透明度，拉伸强度，低温柔韧性和高水蒸汽转变速率的组合。 优选的实施例组合物是基于MDI作为二异氰酸酯单体的TPU，作为聚酯二醇的聚己内酯，含有少于20％EO的EO封端的EO / PO聚醚二醇和作为扩链剂的丁二醇。 与单独使用聚酯或聚醚二醇或与较高EO聚醚二醇的组合制备的TPU相比，这些组合物具有良好的透明度，拉伸强度，水解稳定性和加工性能的组合。