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    Process for preparing protective-colloid-stabilized vinyl ester or vinyl ester-ethylene polymers in the form of their aqueous dispersions
    1.
    发明授权
    Process for preparing protective-colloid-stabilized vinyl ester or vinyl ester-ethylene polymers in the form of their aqueous dispersions 有权
    制备保护胶体稳定的乙烯基酯或其水分散体形式的乙烯基酯 - 乙烯聚合物的方法

    公开(公告)号：US06262163B1

    公开(公告)日：2001-07-17

    申请号：US09280923

    申请日：1999-03-29

    申请人： Hans-Peter Weitzel ,  Udo Kotschi ,  Manfred Hannebaum

    发明人： Hans-Peter Weitzel ,  Udo Kotschi ,  Manfred Hannebaum

    IPC分类号： C08L3106

    CPC分类号： C08F18/04 ,  C08F2/24

    摘要： The invention relates to a process for preparing protective-colloid-stabilized vinyl ester or vinyl ester-ethylene polymers in the form of their aqueous dispersions by emulsion polymerization in the presence of one or more protective colloids, which comprises carrying out the polymerization in the presence of a hydrophobic but silane-free protective colloid based on (meth)acrylate polymers with from 80 to 95% by weight, based on the total weight of the copolymer, of acrylic or methacrylic esters of aliphatic alcohols having from 1 to 12 carbon atoms, and from 5 to 20% by weight, based on the total weight of the copolymer, of ethylenically unsaturated mono- or dicarboxylic acids, and with a glass transition temperature Tg of the copolymer of from 60 to 120° C., and with a Fikentscher K value of the copolymer of from 20 to 50.

    摘要翻译： 本发明涉及一种在一种或多种保护胶体存在下通过乳液聚合制备其水分散体形式的保护胶体稳定的乙烯基酯或乙烯基酯 - 乙烯聚合物的方法，其包括在存在下进行聚合 的基于（甲基）丙烯酸酯聚合物的疏水但不含硅烷的保护胶体，其基于共聚物的总重量为80至95重量％，具有1至12个碳原子的脂族醇的丙烯酸或甲基丙烯酸酯， 和5至20重量％，基于共聚物的总重量，烯键式不饱和单羧酸或二羧酸，并且共聚物的玻璃化转变温度Tg为60至120℃，以及Fikentscher 共聚物的K值为20〜50。

    Process for continuous emulsion polymerization
    2.
    发明授权
    Process for continuous emulsion polymerization 有权
    连续乳液聚合方法

    公开(公告)号：US08822572B2

    公开(公告)日：2014-09-02

    申请号：US13505921

    申请日：2011-07-07

    申请人： Jessica Hain ,  Udo Kotschi ,  Hans-Peter Weitzel

    发明人： Jessica Hain ,  Udo Kotschi ,  Hans-Peter Weitzel

    IPC分类号： C08F2/22

    CPC分类号： C08F2/22 ,  B01J19/1862 ,  B01J2219/00162 ,  C08F2/30 ,  C08F6/001 ,  C08F6/003 ,  C08F210/02 ,  C08F218/08 ,  C09D131/04 ,  C08L23/02 ,  C08L31/00 ,  C08F228/02 ,  C08F2220/325

    摘要： A process for aqueous, free-radically initiated, continuous emulsion polymerization of A) at least one vinyl ester and optionally at least one (meth)acrylic ester, B) ethylene, and C) 0 to 10% by weight of one or more ethylenically unsaturated, functionalized comonomers, in the presence of 3.0 to 12.5% by weight of one or more emulsifiers, where at least 50% by weight are nonionic emulsifiers, and 0 to 10% by weight of one or more protective colloids, in a stirred tank cascade with at least two pressure reactors connected in series and with at least one low-pressure reactor connected downstream.

    摘要翻译： A）至少一种乙烯基酯和任选的至少一种（甲基）丙烯酸酯B）乙烯和C）0至10重量％的一种或多种烯属的（甲基）丙烯酸酯的水，自由基引发，连续乳液聚合的方法 在3.0至12.5重量％的一种或多种乳化剂（其中至少50重量％为非离子乳化剂）和0至10重量％的一种或多种保护性胶体的存在下，在搅拌槽中存在不饱和官能化共聚单体 与至少两个串联的压力反应器与连接在下游的至少一个低压反应器串联连接。

    Process for Continuous Emulsion Polymerization
    3.
    发明申请
    Process for Continuous Emulsion Polymerization 有权
    连续乳液聚合方法

    公开(公告)号：US20130102702A1

    公开(公告)日：2013-04-25

    申请号：US13505921

    申请日：2011-07-07

    申请人： Jessica Hain ,  Udo Kotschi ,  Hans-Peter Weitzel

    发明人： Jessica Hain ,  Udo Kotschi ,  Hans-Peter Weitzel

    IPC分类号： C08F2/22

    CPC分类号： C08F2/22 ,  B01J19/1862 ,  B01J2219/00162 ,  C08F2/30 ,  C08F6/001 ,  C08F6/003 ,  C08F210/02 ,  C08F218/08 ,  C09D131/04 ,  C08L23/02 ,  C08L31/00 ,  C08F228/02 ,  C08F2220/325

    摘要： A process for aqueous, free-radically initiated, continuous emulsion polymerization of A) at least one vinyl ester and optionally at least one (meth)acrylic ester, B) ethylene, and C) 0 to 10% by weight of one or more ethylenically unsaturated, functionalized comonomers, in the presence of 3.0 to 12.5% by weight of one or more emulsifiers, where at least 50% by weight are nonionic emulsifiers, and 0 to 10% by weight of one or more protective colloids, in a stirred tank cascade with at least two pressure reactors connected in series and with at least one low-pressure reactor connected downstream.

    摘要翻译： A）至少一种乙烯基酯和任选的至少一种（甲基）丙烯酸酯B）乙烯和C）0至10重量％的一种或多种烯属的（甲基）丙烯酸酯的水，自由基引发，连续乳液聚合的方法 在3.0至12.5重量％的一种或多种乳化剂（其中至少50重量％为非离子乳化剂）和0至10重量％的一种或多种保护性胶体的存在下，在搅拌槽中存在不饱和官能化共聚单体 与至少两个串联的压力反应器与连接在下游的至少一个低压反应器串联连接。

    Semi-Continuous Method for Emulsion Polymerisation
    6.
    发明申请
    Semi-Continuous Method for Emulsion Polymerisation 有权
    乳液聚合的半连续方法

    公开(公告)号：US20120316287A1

    公开(公告)日：2012-12-13

    申请号：US13512150

    申请日：2011-07-07

    申请人： Hans-Peter Weitzel ,  Robert Braunsperger

    发明人： Hans-Peter Weitzel ,  Robert Braunsperger

    IPC分类号： C08L33/04 ,  C08F2/01

    CPC分类号： C08F2/22 ,  B01J19/0066 ,  B01J19/18 ,  B01J2219/0004 ,  C08F210/02 ,  C08F218/08

    摘要： A method for producing aqueous polymer dispersions by means of radically initiated emulsion polymerisation, in an aqueous medium, of vinyl ester and ethylene, in series-connected polymerisation reactors, wherein in a first discontinuous polymerisation phase at least some of the reactants are introduced into the first polymerisation reactor and the remainder is added in a metered fashion. The reactor is filled up to more than 90% by volume, and at least 90 wt % of the monomers are reacted; in a second continuous polymerisation phase, the reactants are continuously supplied to the first polymerisation reactor and product is continuously withdrawn, and the product is continuously transferred into a second polymerisation reactor, and in the second polymerisation reactor the polymerisation is continued until at least 98 wt % of the monomers used have reacted.

    摘要翻译： 在串联连接的聚合反应器中通过自由基引发的乳液聚合在乙烯基酯和乙烯的水性介质中制备聚合物水分散体的方法，其中在第一不连续聚合相中，将至少一些反应物引入 第一聚合反应器，其余部分以计量方式加入。 反应器填充至超过90体积％，并且至少90重量％的单体反应; 在第二连续聚合阶段中，将反应物连续地供应到第一聚合反应器，并连续抽出产物，并将产物连续转移到第二聚合反应器中，并且在第二聚合反应器中，继续聚合直至至少98wt 所用单体的百分比已经反应。

    Method for the production of protective colloid-stabilized polymer products and device for carrying out the method
    7.
    发明授权
    Method for the production of protective colloid-stabilized polymer products and device for carrying out the method 有权
    用于生产保护胶体稳定的聚合物产品的方法和用于实施该方法的装置

    公开(公告)号：US08119708B2

    公开(公告)日：2012-02-21

    申请号：US12675052

    申请日：2008-08-11

    申请人： Hans-Peter Weitzel ,  Mehmet Gunaltay ,  Manfred Selig

    发明人： Hans-Peter Weitzel ,  Mehmet Gunaltay ,  Manfred Selig

    IPC分类号： C08G18/08

    CPC分类号： C08F6/00 ,  B01F5/0602 ,  B01F15/06 ,  C08F2/002 ,  C08F2/20 ,  C08F2/22 ,  C08F218/04 ,  F28D2021/0052 ,  F28F13/06 ,  Y02P20/123 ,  Y02P20/124 ,  C08F210/02

    摘要： The invention relates to a method for the production of protective colloid-stabilized polymer products by means of emulsion polymerization in a reactor having an external cooling circuit, which is equipped with a pump and a heat exchanger, characterized in that the reaction mixture present in the reactor is delivered to a cooled static mixer-heat exchanger having stationary fixtures and is subsequently returned to the reactor. The invention further relates to a device for the production of protective colloid-stabilized polymer products by means of emulsion polymerization, comprising a reactor and an external cooling circuit, characterized in that the external cooling circuit is equipped with a pump and a cooled static mixer-heat exchanger having stationary fixtures.

    摘要翻译： 本发明涉及一种通过在具有外部冷却回路的反应器中通过乳液聚合制备保护胶体稳定的聚合物产物的方法，所述反应器具有泵和热交换器，其特征在于，所述反应混合物存在于 反应器被输送到具有固定固定装置的冷却的静态混合器 - 热交换器，随后返回到反应器。 本发明还涉及一种用于通过乳液聚合制备保护胶体稳定的聚合物产品的装置，其包括反应器和外部冷却回路，其特征在于，所述外部冷却回路装备有泵和冷却的静态混合器 - 具有固定固定装置的热交换器。

    Redispersible powders comprising pozzolanic components
    8.
    发明授权
    Redispersible powders comprising pozzolanic components 有权
    包含火山灰组分的可再分散粉末

    公开(公告)号：US07388047B2

    公开(公告)日：2008-06-17

    申请号：US10873874

    申请日：2004-06-22

    申请人： Hans-Peter Weitzel ,  Hermann Lutz ,  Peter Fritze ,  Stefan Killat

    发明人： Hans-Peter Weitzel ,  Hermann Lutz ,  Peter Fritze ,  Stefan Killat

    IPC分类号： C08K3/34

    CPC分类号： C08K3/34 ,  C04B28/04 ,  C04B40/0042 ,  C04B2103/0057 ,  C04B2111/00637 ,  C04B24/26 ,  C04B2103/0088 ,  C04B14/106 ,  C04B24/2623 ,  C04B14/28 ,  C04B14/06 ,  C04B24/383

    摘要： Water-redispersible polymer powder compositions based on homopolymers or copolymers of one or more monomers from the group consisting of vinyl esters of unbranched or branched alkylcarboxylic acids having from 1 to 15 carbon atoms, methacrylic esters and acrylic esters of alcohols having from 1 to 15 carbon atoms, vinylaromatics, olefins, dienes and vinyl halides, one or more protective colloids, if desired antiblocking agents, contain one or more compounds from the group of pozzolanas. The pozzolanic compounds preferably take the place of anti-blocking agents conventionally used.

    摘要翻译： 基于来自具有1至15个碳原子的未支化或支化烷基羧酸的乙烯基酯的一种或多种单体的均聚物或共聚物的水可再分散性聚合物粉末组合物，具有1至15个碳原子的醇的甲基丙烯酸酯和丙烯酸酯 原子，乙烯基芳烃，烯烃，二烯和乙烯基卤化物，一种或多种保护胶体，如果需要，防粘连剂包含一种或多种火山灰组合物。 火山灰化合物优选代替常规使用的防粘连剂。