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1.发明申请Preparation of LLDPE having controlled xylene solubles or hexane extractables 审中-公开制备具有受控二甲苯可溶物或己烷可萃取物的LLDPE公开(公告)号：US20120053305A1
公开(公告)日：2012-03-01
申请号：US12806894
申请日：2010-08-24
IPC分类号： C08F10/02
CPC分类号： C08F210/16 , C08J5/18 , C08J2323/06 , C08F210/08 , C08F2500/12 , C08F2500/26 , C08F210/14 , C08F4/6494 , C08F4/6543 , C08F4/651
摘要： Disclosed is a method for making LLDPE grades having different xylene solubles or hexane extractables with the same Ziegler-Natta catalyst by varying the amount of alkylaluminum used for polymerization. The method comprises copolymerizing ethylene with a C3-10 α-olefin in the presence of a Ziegler-Natta catalyst, an alkylaluminum, and an electron donor; determining the dependency of the xylene solubles or hexane extractables on the alkylaluminum/electron donor ratio; and adjusting the alkylaluminum/electron donor ratio to achieve a desired xylene solubles or hexane extractables.
摘要翻译： 公开了通过改变用于聚合的烷基铝的量，通过相同的齐格勒 - 纳塔催化剂制备具有不同的二甲苯可溶物或己烷可萃取物的LLDPE级别的方法。 该方法包括在齐格勒 - 纳塔催化剂，烷基铝和电子给体存在下使乙烯与C3-10α-烯烃共聚合; 确定二甲苯可溶物或己烷可萃取物对烷基铝/电子给体比的依赖性; 并调节烷基铝/电子给体比以获得所需的二甲苯可溶物或己烷可萃取物。
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公开(公告)号：US20120053307A1
公开(公告)日：2012-03-01
申请号：US12806893
申请日：2010-08-24
IPC分类号： C08F4/50 , C08F210/00
CPC分类号： C08F210/16 , C08F210/08 , C08F2500/12 , C08F2500/26 , C08F4/651 , C08F4/6543 , C08F4/6545
摘要： Disclosed is a process for making a linear low density polyethylene (LLDPE) having low gels. The process comprises copolymerizing ethylene with one or more C3-10 α-olefins to produce an LLDPE resin which has a gel defect area less than 25 ppm. The copolymerization is performed in the presence of a Ziegler-Natta catalyst which comprises an MgCl2 support, a Ti(IV) complex, and a cyclic ether as an internal electron donor. The Ziegler-Natta catalyst has an Mg/Ti molar ratio greater than or equal to 7.
摘要翻译： 公开了制备具有低凝胶的线性低密度聚乙烯（LLDPE）的方法。 该方法包括使乙烯与一种或多种C 3-10α-烯烃共聚以制备凝胶缺陷面积小于25ppm的LLDPE树脂。 共聚合在齐格勒 - 纳塔催化剂存在下进行，该催化剂包含MgCl 2载体，Ti（IV）络合物和环醚作为内电子给体。 齐格勒 - 纳塔催化剂的Mg / Ti摩尔比大于或等于7。
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3.发明申请PROCESS FOR THE PREPARATION OF ETHYLENE POLYMERS WITH NARROW MOLECULAR WEIGHT DISTRIBUTION 审中-公开制备具有窄分子量分布的乙烯聚合物的方法公开(公告)号：US20120130031A1
公开(公告)日：2012-05-24
申请号：US13387106
申请日：2010-08-02
申请人： Masaki Fushimi , Dario Liguori , Tiziano Dall'Occo , Giampiero Morini , Joachim T.M. Pater , Gianni Vitale
发明人： Masaki Fushimi , Dario Liguori , Tiziano Dall'Occo , Giampiero Morini , Joachim T.M. Pater , Gianni Vitale
IPC分类号： C08F4/76
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F4/6494 , C08F2500/12 , C08F2500/04 , C08F210/06
摘要： Process for the preparation of ethylene polymers having narrow MWD characterized by a F/E ratio lower than 35 carried out in the presence of a catalyst system comprising (a) a solid catalyst component comprising Ti atoms that are substantially in the +4 oxidation state, Mg, Cl, and optionally OR groups and internal donors in which R is a C1-C20 hydrocarbon group, in which the OR/Ti molar ratio is equal to or lower than 0.35 and the internal donor/Ti ratio is lower than 1, (b) an aluminum alkyl compound and (c) a compound selected from alkoxybenzenes of specified formula.
摘要翻译： 制备具有窄MWD的乙烯聚合物的方法，其特征在于在催化剂体系存在下进行F / E比低于35的乙烯聚合物，其包含（a）包含基本上处于+4氧化态的Ti原子的固体催化剂组分， Mg，Cl和任选的OR基团和其中R是C1-C20烃基的内给体，其中OR / Ti摩尔比等于或低于0.35，内给体/ Ti比低于1（ b）烷基铝化合物和（c）选自具有规定式的烷氧基苯的化合物。
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公开(公告)号：US20130217844A1
公开(公告)日：2013-08-22
申请号：US13878712
申请日：2011-10-17
IPC分类号： C08F4/646
CPC分类号： C08F4/646 , C08F10/06 , C08F110/06 , C08F4/651 , C08F4/6543 , C08F2500/12
摘要： A process for the (co)polymerization of propylene carried out at a temperature ranging from 77 to 95° C. in the presence of a catalyst comprising the product obtained by reacting: —an organo-aluminium compound, with—-a solid catalyst component comprising Mg, Ti and electron donor compound selected from specific diolesters.
摘要翻译： 在丙烯存在下，在77至95℃的温度下进行丙烯（共）聚合的方法，该催化剂包括通过以下步骤获得的产物： - 有机铝化合物与 - 固体催化剂组分 包括选自特定二极体的Mg，Ti和电子给体化合物。
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公开(公告)号：US20140094576A1
公开(公告)日：2014-04-03
申请号：US14123794
申请日：2012-06-01
IPC分类号： C08F10/02
CPC分类号： C08F10/02 , C08F10/00 , C08F110/02 , C08F110/06 , C08F4/6492 , C08F2500/24
摘要： A pre-polymerized catalyst component for the polymerization of olefins CH2═CHR, wherein R is hydrogen or a C1-C12 hydrocarbon group, characterized by comprising a non-stereospecific solid catalyst component, comprising Ti, Mg and a halogen, said pre-polymerized catalyst component containing an amount of a (co)polymer of a monomer having formula CH2═CHA, where A is a C6 aliphatic or aromatic ring, optionally substituted, up to 5 g per g of said solid catalyst component. Said prepolymerized catalyst shows an excellent balance in terms of activity, morphological stability, reduced tendency to agglomeration and hydrogen response.
摘要翻译： 用于烯烃CH 2 = CHR聚合的预聚合催化剂组分，其中R是氢或C1-C12烃基，其特征在于包含非立体特异性固体催化剂组分，其包含Ti，Mg和卤素，所述预聚合 催化剂组分含有一定量的具有式CH 2 = CAB的单体（（共））聚合物，其中A是任选取代的C 6脂族或芳环，每克所述固体催化剂组分最多达5克。 所述预聚合催化剂在活性，形态稳定性，凝聚趋势和氢反应方面表现出极好的平衡。
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公开(公告)号：US20140046010A1
公开(公告)日：2014-02-13
申请号：US14111144
申请日：2012-03-29
申请人： Simona Guidotti , Giampiero Morini , Simona Esposito , Alessandro Mignogna , Joachim T.M. Pater , Fabrizio Piemontesi , Diego Brita
发明人： Simona Guidotti , Giampiero Morini , Simona Esposito , Alessandro Mignogna , Joachim T.M. Pater , Fabrizio Piemontesi , Diego Brita
IPC分类号： C08F4/16
CPC分类号： C08F4/16 , C08F10/06 , C08F4/651 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F2500/02 , C08F210/06 , C08F2/001
摘要： A porous solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor to the succinate donor is higher than, or equal to, 0.60.
摘要翻译： 一种多孔固体催化剂组分，其包含卤化镁，至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种选自1,3-二醚，另一种选自琥珀酸盐，其特征在于 事实上，ID / Ti的摩尔比为0.30〜0.90，其中ID是琥珀酸盐和1,3-二醚的总摩尔量，1,3-二醚供体与琥珀酸盐供体的摩尔比高于或 等于0.60。
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7.发明申请Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom 失效二氯化镁 - 醇加合物和由其获得的催化剂组分公开(公告)号：US20120165483A1
公开(公告)日：2012-06-28
申请号：US13394042
申请日：2010-09-03
IPC分类号： C08F4/654 , C08F110/06
CPC分类号： C08F110/06 , C08F10/06 , C08F4/022 , C08F4/651 , C08F4/6545
摘要： Solid adducts comprising a MgCl2, ethanol and a compound (A), said compounds being present in molar ratios defined by the following formula MgCl2.(EtOH)n(A)p in which n is from 0.1 to 6, p ranges from 0.001 to 0.5 and A is a compound selected from cyclic hydrocarbon structures which are substituted with at least two hydroxy groups.
摘要翻译： 包含MgCl 2，乙醇和化合物（A）的固体加合物，所述化合物以下式MgCl 2（EtOH）n（A）p定义的摩尔比存在，其中n为0.1至6，p为0.001至 0.5和A是选自被至少两个羟基取代的环状烃结构的化合物。
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公开(公告)号：US20110082270A1
公开(公告)日：2011-04-07
申请号：US12587187
申请日：2009-10-02
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6555 , C08F4/6495 , C08F4/651 , C08F210/08 , C08F2500/12 , C08F2500/04 , C08F2500/21
摘要： A modified Ziegler-Natta catalyst system, a method for preparing the catalyst system, and a process for polymerizing an olefin in the presence of the catalyst system are disclosed. The catalyst system comprises a titanium or vanadium compound, an aluminum compound, and a pyridazine. Improved properties such as increased molecular weight and narrowed molecular weight distribution are obtained.
摘要翻译： 公开了改进的齐格勒 - 纳塔催化剂体系，制备催化剂体系的方法和在催化剂体系存在下使烯烃聚合的方法。 催化剂体系包括钛或钒化合物，铝化合物和哒嗪。 获得了改进的性能，例如分子量增加和分子量分布变窄。
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公开(公告)号：US20110082268A1
公开(公告)日：2011-04-07
申请号：US12587148
申请日：2009-10-02
CPC分类号： C08F10/00 , C08F210/16 , C08F4/651 , C08F4/6495 , C08F4/6555 , C08F210/08 , C08F2500/12 , C08F2500/04 , C08F2500/21
摘要： A modified Ziegler-Natta catalyst system, a method for preparing the catalyst system, and a process for polymerizing an olefin in the presence of the catalyst system are disclosed. The catalyst system comprises a titanium or vanadium compound, an aluminum compound, and an indazole. Improved comonomer incorporation and the ability to regulate molecular weight are achieved in the manufacture of polyolefins.
摘要翻译： 公开了改进的齐格勒 - 纳塔催化剂体系，制备催化剂体系的方法和在催化剂体系存在下使烯烃聚合的方法。 催化剂体系包括钛或钒化合物，铝化合物和吲唑。 在聚烯烃的制造中实现改进的共聚单体掺入和调节分子量的能力。
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公开(公告)号：US20130197173A1
公开(公告)日：2013-08-01
申请号：US13879333
申请日：2011-10-17
IPC分类号： C08F4/16
CPC分类号： C08F4/16 , C08F10/06 , C08F110/06 , C08F4/6543 , C08F4/6494 , C08F4/651 , C08F2/14 , C08F2500/03 , C08F2500/12
摘要： A catalyst system comprising the product obtained by contacting (a) a solid catalyst component containing Mg, Ti, halogen and at least an electron donor compound selected from diolesters of a specific formula (b) an alkylaluminum cocatalyst and (c) an ester of formula R′OOC—(CR″2)m—COOR′ in which m is an integer from 2 to 8, the R′ groups, equal to or different from each other, are C1-C10 alkyl groups and the R″ groups, independently, are hydrogen or C1-C15 hydrocarbon groups.
摘要翻译： 一种催化剂体系，其包括通过使（a）含有Mg，Ti，卤素和至少一种选自特定式（b）的二极体的电子给体化合物的（a）固体催化剂组分与烷基铝助催化剂和（c）式 R'OOC-（CR''2）m-COOR'，其中m为2至8的整数，R'基彼此相同或不同，为C 1 -C 10烷基和R“基团 独立地是氢或C 1 -C 15烃基。
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