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公开(公告)号：US3959408A
公开(公告)日：1976-05-25
申请号：US459360
申请日：1974-04-09
IPC分类号： C08L27/00 , C08F259/00 , C08F285/00 , C08L1/00 , C08L27/06 , C08L51/00 , C08L51/02 , C08L51/04 , C08L9/04 , C08L9/08
CPC分类号： C08F285/00 , C08L27/06 , C08L51/00 , Y10S525/902
摘要： Vinyl chloride resin composition having excellent impact resistance, weather resistance and processability which comprises a vinyl chloride resin and a multicomponent resin blended therewith, said multicomponent resin being prepared by (1) graft polymerizing acrylonitrile, and a vinyl monomer which is methyl methacrylate and/or styrene, and a cross-linking agent onto cross-linked copolymer rubber obtained by emulsion-polymerizing an alkyl acrylate, butadiene and a cross-linking agent or onto a cross-linked terpolymer rubber obtained by emulsion-polymerizing an alkyl acrylate, butadiene, methyl methacrylate and a cross-linking agent and (2) further graft polymerizing thereonto an alkyl methacrylate and a cross-linking agent. Quantitative limitations are included.
摘要翻译： 所述多组分树脂通过（1）丙烯腈的接枝聚合和作为甲基丙烯酸甲酯的乙烯基单体和/或（甲基）丙烯酸酯的乙烯基单体制备，所述氯化乙烯树脂组合物具有优异的耐冲击性，耐候性和加工性，其包含氯乙烯树脂和与其混合的多组分树脂， 苯乙烯和交联剂在通过将丙烯酸烷基酯，丁二烯和交联剂乳化聚合得到的交联共聚物橡胶上或通过乳液聚合丙烯酸烷基酯，丁二烯，甲基 甲基丙烯酸酯和交联剂，和（2）其上接枝聚合到甲基丙烯酸烷基酯和交联剂上。 包括定量限制。
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公开(公告)号：US4206290A
公开(公告)日：1980-06-03
申请号：US933040
申请日：1978-08-11
申请人： Haruhiko Yusa , Masanori Oota , Kazuo Takahashi , Humio Akutsu
发明人： Haruhiko Yusa , Masanori Oota , Kazuo Takahashi , Humio Akutsu
CPC分类号： C08L27/06 , C08L55/02 , C08L2205/02 , C08L51/04 , Y10S260/24
摘要： A resinous composition having fire retardance, impact resistance and easy workability is obtained by blending (1) about 80 to 30 parts by weight of an ABS resin with (2) about 20 to 70 parts by weight of (i) a vinyl chloride resin compound comprising 100 to 5 parts by weight of a copolymer resin consisting essentially of 0.5 to 40% by weight of a higher alkyl vinyl ether and 99.5 to 60% by weight of vinyl chloride and (ii) 0 to 95 parts by weight of a polyvinyl chloride resin.
摘要翻译： 通过将（1）约80〜30重量份的ABS树脂与（2）约20〜70重量份的（i）氯乙烯树脂化合物（I）混合，得到具有阻燃性，耐冲击性和易加工性的树脂组合物 包含100至5重量份的基本上由0.5至40重量％的较高级烷基乙烯基醚和99.5至60重量％的氯乙烯组成的共聚物树脂，和（ii）0至95重量份的聚氯乙烯 树脂。
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公开(公告)号：US4607080A
公开(公告)日：1986-08-19
申请号：US821878
申请日：1986-01-27
申请人： Haruhiko Yusa , Masanori Oota , Kazuo Takahashi
发明人： Haruhiko Yusa , Masanori Oota , Kazuo Takahashi
IPC分类号： C08L25/08 , C08F265/06 , C08L25/00 , C08L25/14 , C08L33/04 , C08L33/12 , C08L51/00 , C08L51/04 , C09D201/02 , C08L33/08
摘要： An impact-resistant thermoplastic resin composition having excellent transparency and appearance properties which comprises (A) a butadiene-styrenemethyl methacrylate-alkyl acrylate graft copolymer obtained by postpolymerization of styrene, methyl methacrylate and an alkyl acrylate to a latex comprising a butadiene homopolymer rubber or a butadiene-styrene copolymer rubber comprising mainly butadiene and having an average particle diameter of 0.1 to 0.5 .mu., and (B) a methyl methacrylate-styrene copolymer. This composition has quantitative limitation.
摘要翻译： 一种具有优异的透明性和外观性能的耐冲击热塑性树脂组合物，其包含（A）通过苯乙烯，甲基丙烯酸甲酯和丙烯酸烷基酯的后聚合得到的甲基丙烯酸丁二烯 - 苯乙烯甲酯 - 丙烯酸烷基酯接枝共聚物，其包含丁二烯均聚物橡胶或 丁二烯 - 苯乙烯共聚物橡胶，（B）甲基丙烯酸甲酯 - 苯乙烯共聚物主要由丁二烯组成，平均粒径为0.1〜0.5μm。 这种成分具有数量上的限制。
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公开(公告)号：US4345043A
公开(公告)日：1982-08-17
申请号：US183833
申请日：1980-09-03
申请人： Haruhiko Yusa , Masanori Oota , Haruki Isaka
发明人： Haruhiko Yusa , Masanori Oota , Haruki Isaka
IPC分类号： C08L27/00 , C08F2/00 , C08F2/44 , C08K3/22 , C08K9/00 , C08K9/04 , C08K9/08 , C08L1/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02
摘要： Modified titanium oxide is prepared by polymerizing a mixture of vinyl chloride and a carboxylic monomer such as 10-undecenoic acid in the presence of titanium oxide. The thus obtained, modified titanium oxide is mixed with a vinyl chloride resin, typically, polyvinyl chloride to give a vinyl chloride resin composition having an improved weatherability and being substantially free of serious drawbacks accompanying the addition of conventional titanium oxide such as plating out during extrusion and decrease in extrusion throughput.
摘要翻译： 通过在二氧化钛的存在下聚合氯乙烯和羧酸单体如10-十一碳烯酸的混合物来制备改性氧化钛。 将如此获得的改性氧化钛与氯乙烯树脂（通常为聚氯乙烯）混合，得到具有改善的耐候性的氯乙烯树脂组合物，并且基本上没有伴随常规氧化钛的添加的严重缺点，例如在挤出期间电镀 并降低挤出产量。
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公开(公告)号：US4275178A
公开(公告)日：1981-06-23
申请号：US108278
申请日：1979-12-28
申请人： Haruhiko Yusa , Masanori Oota , Katsumi Suzuki
发明人： Haruhiko Yusa , Masanori Oota , Katsumi Suzuki
IPC分类号： C08F2/00 , C08F2/22 , C08F291/00 , C08L7/00 , C08L21/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L51/04 , C08L55/02
CPC分类号： C08L51/003 , C08L51/04
摘要： Graft-copolymers for improving impact strength comprising a relatively large quantity of an elastomeric trunk polymer, such as acrylonitrile/styrene/butadiene resins and methyl methacrylate/styrene/butadiene resins, have some undesirable powder characteristics, for example, poor fluidity and an easily blocking property.However, by blending a graft-copolymer of this type with a graft-copolymer comprising a relatively small quantity of an elastomeric trunk polymer in slurry form or dry state, it is possible to obtain a graft-copolymer blend with improved powder characteristics without significantly lowering the effect of improving the impact strength of the former graft-copolymer.The graft-copolymer blend thus obtained, when blended with a hard resin such as polyvinyl chloride, provides a resin composition with high impact strength.
摘要翻译： 用于改善冲击强度的接枝共聚物包括相对大量的弹性体树脂聚合物，例如丙烯腈/苯乙烯/丁二烯树脂和甲基丙烯酸甲酯/苯乙烯/丁二烯树脂，具有一些不期望的粉末特性，例如流动性差和容易堵塞 属性。 然而，通过将这种类型的接枝共聚物与包含相对少量的浆料形式或干燥状态的弹性体树脂聚合物的接枝共聚物共混，可以获得具有改进的粉末特性而不显着降低的接枝共聚物共混物 改善前接枝共聚物冲击强度的效果。 由此获得的接枝共聚物共混物当与诸如聚氯乙烯的硬树脂共混时，提供了具有高冲击强度的树脂组合物。
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公开(公告)号：US4287312A
公开(公告)日：1981-09-01
申请号：US28798
申请日：1979-04-10
申请人： Haruhiko Yusa , Masanori Oota , Katumi Suzuki
发明人： Haruhiko Yusa , Masanori Oota , Katumi Suzuki
IPC分类号： C08F279/00 , C08F279/02 , C08L51/04
CPC分类号： C08F279/02
摘要： A process for producing a graft-polymer comprises adding an aqueous solution of a salt of a strong acid and a monovalent strong base, which solution has been adjusted to a pH value of 8 to 13, to a rubber latex containing diene rubber particles and a fatty acid soap as an emulsifying agent to coagulate the above mentioned rubber particles, and thereafter adding a vinyl monomer to the latex containing the coagulated rubber particles to graft-polymerize the vinyl monomer.According to this process, the formation of rubber masses and macroparticles during the coagulation is reduced and a rubber latex containing rubber particles having a narrow range of particle size distribution is obtained. When a graft-copolymer obtained by using the latex is blended with thermoplastic resins such as vinyl chloride resins, the impact resistance of the thermoplastic resins can be remarkably improved without impairing their transparency and gloss.
摘要翻译： 制备接枝聚合物的方法包括将含有二烯橡胶颗粒的橡胶胶乳和强酸的一价强碱的水溶液和已经调节至pH值为8至13的pH值的一价强碱 脂肪酸皂作为乳化剂凝结上述橡胶颗粒，然后在含有凝固的橡胶颗粒的胶乳中加入乙烯基单体以使乙烯基单体接枝聚合。 根据该方法，凝结时的橡胶质量和大颗粒的形成减少，得到含有窄粒径分布范围的橡胶粒子的橡胶胶乳。 当通过使用胶乳获得的接枝共聚物与诸如氯乙烯树脂的热塑性树脂共混时，热塑性树脂的耐冲击性可以显着提高而不损害其透明度和光泽。
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公开(公告)号：US4442262A
公开(公告)日：1984-04-10
申请号：US322152
申请日：1981-11-17
CPC分类号： C08L51/04 , C08L67/025
摘要： Disclosed herein is a composition of a polyester-block copolymer, comprising 5 to 80% by weight of at least one kind of graft-copolymer obtained by graft-copolymerizing 50 to 25 parts by weight of a monomeric mixture predominantly consisting essentially of styrene and methyl methacrylate and containing 0.01 to 3.0% by weight of a cross-linking agent with 50 to 75 parts by weight of a cross-linked elastomeric trunk polymer containing not less than 50% by weight of rubber like segment selected from the group consisting of butadiene unit and C.sub.4 to C.sub.10 -alkyl acrylate units, and 0.01 to 3.0% by weight of a cross-linking agent, and 95 to 20% by weight of a polyester-block copolymer, the composition giving shaped articles of favorable superficial appearance even when processed by shape-forming under conditions of mixing and kneading of a relatively low degree.
摘要翻译： 本文公开了一种聚酯嵌段共聚物的组合物，其包含5-80重量％的至少一种接枝共聚物，所述接枝共聚物通过接枝共聚50至25重量份主要由苯乙烯和甲基 含有0.01〜3.0重量％的交联剂和50〜75重量份的交联弹性体树脂聚合物，其含有不小于50重量％的橡胶状链段，所述橡胶状链段选自丁二烯单元 丙烯酸C4〜C10烷基酯单元，交联剂为0.01〜3.0重量％，聚酯嵌段共聚物为95〜20重量％，即使在加工成型制品时， 在相对较低程度的混合和捏合条件下成形。
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公开(公告)号：US4897462A
公开(公告)日：1990-01-30
申请号：US364496
申请日：1989-06-09
申请人： Haruhiko Yusa , Mitsuru Hoshino , Haruki Isaka
发明人： Haruhiko Yusa , Mitsuru Hoshino , Haruki Isaka
IPC分类号： C08F291/00 , C08F6/22 , C08F279/02 , C08F291/02 , C08J3/16
CPC分类号： C08J3/16 , C08F279/02 , C08F6/22
摘要： In a process for producing a rubber-containing graft copolymer, which comprises bringing a latex of a graft copolymer comprising 60% to 90% by weight of a rubbery polymer and 40% to 10% by weight of a hard polymer, said graft copolymer latex being obtained by emulsion polymerizing a hard polymer-forming monomer in a latex of said rubbery polymer and having a minimum film-forming temperature of 75.degree. C. or less, into contact with an aqueous electrolyte solution under stirring, thereby to coagulate the latex, and recovering the precipitated graft copolymer, the improvement is disclosed such that the graft copolymer latex is subjected to slow coagulation so as to allow the graft copolymer to precipitate as substantially spherical particles, wherein the term "slow coagulation" refers to coagulation which proceeds at a milder rate than that of coagulation in which the aqueous electrolyte solution is hydrochloric acid and the pH of the latex during coagulation is 1.8 or less.
摘要翻译： 在制备含橡胶接枝共聚物的方法中，其包括将包含60重量％至90重量％的橡胶状聚合物和40重量％至10重量％的硬质聚合物的接枝共聚物的胶乳，所述接枝共聚物胶乳 通过将所述橡胶状聚合物的胶乳中的硬聚合物形成性单体乳液聚合并且最低成膜温度为75℃以下，在搅拌下与含水电解质溶液接触而使胶乳凝聚而得到， 回收沉淀的接枝共聚物时，公开了使接枝共聚物胶乳缓慢凝固以使接枝共聚物沉淀为基本上球形的颗粒的改进，其中术语“缓慢凝固”是指在 其中电解质溶液为盐酸，凝固时的胶乳pH为1.8以下。
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公开(公告)号：US4268636A
公开(公告)日：1981-05-19
申请号：US105743
申请日：1979-12-19
IPC分类号： C08L27/00 , C08L1/00 , C08L27/06 , C08L33/00 , C08L33/02 , C08L33/04 , C08L33/10 , C08L51/00 , C08L51/02 , C08L9/00
摘要： A composition comprising polyvinyl chloride and a novel polymer processing aid is provided. The polymer processing aid can be obtained either by blending in latex form an alkyl methacrylate copolymer (A) and a copolymer (B) comprising as its essential constituents an alkyl methacrylate, a dialkyl itaconate or an alkyl acrylate, and a diolefin, or by copolymerizing one of the copolymers in the presence of the other copolymer.The polymer processing aid thus obtained improves the processability of the vinyl chloride resin composition with less reduction in impact strength.
摘要翻译： 提供了包含聚氯乙烯和新型聚合物加工助剂的组合物。 聚合物加工助剂可以通过将乳液形式的甲基丙烯酸烷基酯共聚物（A）和包含作为其主要组分的基本组分的共聚物（B）与甲基丙烯酸烷基酯，衣康酸二烷基酯或丙烯酸烷基酯和二烯烃共聚，或通过共聚 在其他共聚物存在下的共聚物之一。 由此获得的聚合物加工助剂改善了氯乙烯树脂组合物的冲击强度降低较少的加工性能。
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公开(公告)号：US4857592A
公开(公告)日：1989-08-15
申请号：US159407
申请日：1988-02-11
申请人： Mitsuru Hoshino , Haruhiko Yusa , Katsumi Suzuki
发明人： Mitsuru Hoshino , Haruhiko Yusa , Katsumi Suzuki
IPC分类号： C08F285/00 , C08L27/06 , C08L51/00 , C08L51/04 , C08L53/00
CPC分类号： C08F285/00 , C08L27/06 , C08L51/00
摘要： A polyvinyl chloride resin composition comprises 3-30 wt. % of a graft copolymer and 97-70 wt. % of a polyvinyl chloride resin and has highly-balanced properties between impact resistance, transparency and stress-whitening resistance and excellent processing characteristics. The graft copolymer is obtained by graft-polymerizing, in the presence of a latex containing greater than 75 but not exceeding 85 parts by weight of a rubbery butadiene-styrene copolymer formed of 65-85 wt. % of butadiene, 15-35 wt. % of styrene and 0-3 wt. % of crosslinkable monomer, (i) 5-24 parts by weight of a first monomer mixture as a first-stage component, said first monomer mixture being composed of 70-97 wt. % of methyl methacrylate and 30-3 wt. % of an alkyl acrylate whose alkyl group has 1-8 carbon atoms; and then (ii) 3-21 parts by weight of a second monomer mixture as a second-stage component, said second monomer mixture being composed of 97-100 wt % of styrene and 0-3 wt. % of crosslinkable monomer. The sum of the first and second monomer mixtures and the rubbery butadiene-styrene copolymer is 100 parts by weight. The monomers grafted in the first stage amount to 30-80 wt. % of the sum of the grafted monomers.
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