摘要:
A laminate suitable for the production of printing plates and relief plates, and possessing a photosensitive layer, which is soluble in water or in an aqueous solution, and contains a hydrophilic polymeric binder, applied to a base, contains, between the base and the photosensitive layer, an intermediate layer which consists of a mixture of a polymeric binder compatible with the polymeric binder of the photosensitive layer, and a diacrylate or dimethacrylate monomer which contains urethane groups and is obtained by reacting a hydroxyalkyl acrylate or hydroxyalkyl methacrylate with a diisocyanate. After application to the base, the intermediate layer is cured at 110.degree.-220.degree. C. before the photosensitive layer is applied.
摘要:
A laminate suitable for the production of printing plates and relief plates, and possessing a photosensitive layer, which is soluble in water or in an aqueous solution, and contains a hydrophilic polymeric binder, applied to a base, contains, between the base and the photosensitive layer, an intermediate layer which consists of a mixture of a polymeric binder which is compatible with the polymeric binder of the photosensitive layer and contains at least 30% by weight of a reaction product of a polyvinyl alcohol with acrylic anhydride and/or methacrylic anhydride, with at least one monomer which is compatible therewith and selected from the group consisting of the hydroxyalkyl acrylates and methacrylates and the diacrylates and dimethacrylates containing urethane groups. After application to the base, the intermediate layer is cured at 110.degree.-220.degree. C. before the photosensitive layer is applied.
摘要:
Fluid photo-crosslinkable composition consisting essentially of a photo-initiator and a mixture ofA. a polyurethane obtained by reacting a hydroxyl-containing saturated aliphatic polyester with a polyisocyanate and a monoacrylate or monomethacrylate of a diol, andB. an N-vinyl lactam optionally in admixture with other monomers.These compositions are suitable for the production of high-quality relief printing plates and have a short processing time.
摘要:
Magnetic recording media comprise a non-magnetic base which is provided with a magnetic layer which consists of a dispersion of an anisotropic magnetic material in an organic binder which consists essentially of an OH-containing polyurea-urethane binder crosslinked with polyisocyanate. The OH-containing polyurea-urethane is obtained by reacting a polydiol, a diol and a primary or secondary aminoalcohol, and if appropriate a triol, with a diisocyanate.
摘要:
Photopolymerizable compositions for the manufacture of relief printing plates, especially relief plates for making mats, comprising an alcohol-soluble linear polyamide, a photoinitiator and a mixture of (a) a diether or triether obtained from 1 mole of an aliphatic diol or triol and from 2 to 3 moles of N-hydroxymethylacrylamide or N-hydroxymethylmethacrylamide and (b) an unsaturated ester-urethane obtained from 1 mole of toluylene diisocyanate and 2 moles of a hydroxyalkyl acrylate or methacrylate, (a) and (b) being mixed in specific ratios.
摘要:
A process for the preparation of polymerizable, primarily linear thermoplastic polyurethane elastomers with acrylate side groups comprising reacting an organic polyisocyanate with a mixture of(a) an acrylate diol having a molecular weight of 146 to 3000,(b) an organic polyhydroxyl compound other than those of paragraph (a) having a molecular weight between 400 and 5000, and(c) a chain extender selected from the group consisting of diols, diamines, aminoalcohols, and triols, having molecular weights between 61 and 400, water, and mixtures thereofwherein the ratio of isocyanate to active hydrogen containing groups is from 0.8:1 to 1.2:1 and wherein 1.4 to 1.8 moles of organic polyisocyante, 0 to 15 moles of component (c) and 0.3 to 6 moles of component (a) are used per mole of component (b). The polymerizable polyurethane elastomers may be used for the manufacture of molded parts, laminates, adhesives, coatings, magnetic tapes, and other articles.
摘要:
A photosensitive multi-layer material comprising a base and a photosensitive layer which has a polyamide binder and is soluble or dispersible in an alcoholic solvent contains two layers between the base and the photosensitive layer, namely (a) an adhesion-promoting layer, adjacent to the base, which is derived from a polyurethane binder, prepared by reacting a hydroxyl-containing epoxy resin and a polyisocyanate, and a pigment combination in which a white zinc sulfide pigment is the essential constituent, and (b) an adhesive layer, adjacent to the photosensitive layer, which consists of a baked mixture of an alcohol-soluble copolyamide and a melamine-formaldehyde resin.
摘要:
Photopolymer relief plates are produced by applying a photopolymerizable relief-forming layer R, which contains a thermal polymerization inhibitor liberating nitrosyl free radicals on ultraviolet irradiation, to a dimensionally stable base which bears an adhesive layer A for the layer R, the layer A containing 0.01 to 10 percent by weight of a compound ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are identical or different and each is alkyl or R.sup.5 --(O-alkylene).sub.x --, R.sup.5 being H or alkyl and x being 1, 2, 3, 4 or 5, and then exposing, and developing, the layer R in a conventional manner.
摘要:
A process and apparatus for the production of exposed printing plates consisting of a resin layer and a support, said resin layer being prepared from a fluid photopolymerizable material which is introduced into a mold having at least one transparent wall which is covered with an image-bearing transparency, and being exposed through said image-bearing transparency, which causes photopolymerization of the exposed areas of the resin layer and bonds these areas to the support which is provided with an adhesive layer. The improved process comprises introducing a predetermined amount of fluid photopolymerizable material, said amount corresponding substantially to the volume of the resin layer of the exposed printing plate; adjusting said support and said transparent wall of the mold so that they are equidistant from one another, adjustment being advantageously effected by bending or doming the support relative to the transparent wall after the latter has been bent or domed by the fluid material introduced into the mold under pressure. Further embodiments of the invention serve to minimize the loss of photopolymerizable material and to avoid the formation of foam when the fluid material is introduced into the mold. The apparatus of the invention can be manufactured and operated easily and economically.
摘要:
Magnetic recording media contain a nonmagnetic substrate and a magnetizable layer, the magnetizable layer containing ferromagnetic pigments and a system of polymeric materials, wherein the system of polymeric materials containsa) from 3 to 35% by weight of a polymer containing ionic or ionogenic groupsb) from 5 to 97% by weight of a polymer XIV which contains basic groups, and has a molecular weight of from 30000 to 2000000.