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公开(公告)号：US4355093A
公开(公告)日：1982-10-19
申请号：US249707
申请日：1981-03-31
CPC分类号： G03F7/11
摘要： A laminate suitable for the production of printing plates and relief plates, and possessing a photosensitive layer, which is soluble in water or in an aqueous solution, and contains a hydrophilic polymeric binder, applied to a base, contains, between the base and the photosensitive layer, an intermediate layer which consists of a mixture of a polymeric binder which is compatible with the polymeric binder of the photosensitive layer and contains at least 30% by weight of a reaction product of a polyvinyl alcohol with acrylic anhydride and/or methacrylic anhydride, with at least one monomer which is compatible therewith and selected from the group consisting of the hydroxyalkyl acrylates and methacrylates and the diacrylates and dimethacrylates containing urethane groups. After application to the base, the intermediate layer is cured at 110.degree.-220.degree. C. before the photosensitive layer is applied.
摘要翻译： 适用于生产印版和浮雕板并且具有可溶于水或在水溶液中并含有施加到基底上的亲水性聚合物粘合剂的光敏层的层压体在基底和感光体之间包含 层，中间层，其由与感光层的聚合物粘合剂相容并且含有至少30重量％的聚乙烯醇与丙烯酸酐和/或甲基丙烯酸酐的反应产物的聚合物粘合剂的混合物组成， 与至少一种与之相容的单体，选自丙烯酸羟烷基酯和甲基丙烯酸羟烷基酯，以及含有氨基甲酸酯基团的二丙烯酸酯和二甲基丙烯酸酯。 施加到基底后，中间层在施加感光层之前在110℃-220℃下固化。
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2.发明授权
公开(公告)号：US4517277A
公开(公告)日：1985-05-14
申请号：US437699
申请日：1982-10-29
申请人： John Lynch , Herbert Naarmann , Gunther Schulz , Rudolf Vyvial , Gunter Wallbillich , Manfred Zurger
发明人： John Lynch , Herbert Naarmann , Gunther Schulz , Rudolf Vyvial , Gunter Wallbillich , Manfred Zurger
IPC分类号： G03F7/09 , C08F8/14 , G03F7/00 , G03F7/027 , G03F7/032 , G03F7/033 , G03F7/038 , G03C1/68 , C08F8/02
CPC分类号： G03F7/0388 , C08F8/14 , G03F7/033 , G03F7/038 , C08F2810/30 , Y10S430/11
摘要： Photosensitive recording materials which are suitable for the production of printing plates and relief plates and possess a photopolymerizable relief-forming layer which can be developed with water and is based on a polyvinylalcohol/monomer mixture contain, as a binder in the said layer, a polyvinylalcohol derivative which is obtained by reacting polyvinylalcohol with an acylating agent which has groups which are polymerizable by free radicals, the reaction being carried out in the heterogeneous phase, in an aprotic dispersant, using the acylating agent in an amount which corresponds to not less than twice the molar amount required to achieve the desired degree of acylation.
摘要翻译： 适用于生产印版和浮雕板的光敏记录材料，并具有可用水显影并基于聚乙烯醇/单体混合物的可光聚合的浮雕形成层，在所述层中含有作为粘合剂的聚乙烯醇 衍生物，其通过使聚乙烯醇与具有可自由基聚合的基团的酰化剂反应获得，该反应在非质子分散剂中在非均相中进行，使用酰化剂，其量相当于不少于两倍 达到所需酰化度所需的摩尔量。
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公开(公告)号：US06197872B1
公开(公告)日：2001-03-06
申请号：US09230348
申请日：1999-12-17
申请人： Herbert Naarmann , Graham Edmund McKee , Alfred Pirker , Hans-Josef Sterzel , Franz Brandstetter , Bernd-Steffen von Bernstorff , Bernhard Rosenau , Ulrich Endemann , Burkhard Straube
发明人： Herbert Naarmann , Graham Edmund McKee , Alfred Pirker , Hans-Josef Sterzel , Franz Brandstetter , Bernd-Steffen von Bernstorff , Bernhard Rosenau , Ulrich Endemann , Burkhard Straube
IPC分类号： C08L5100
CPC分类号： E04C2/20 , C08F255/02 , C08F265/04 , C08F283/12 , C08L25/12 , C08L51/003 , C08L51/04 , C08L2666/24 , C08L2666/02
摘要： The use of a thermoplastic molding composition differing from ABS and comprising, based on a total of 100% by weight of amounts of components A and B, and, if desired, C and/or D, a: as component A, from 1 to 99% by weight, preferably from 15 to 60% by weight, in particular from 25 to 50% by weight, of a particulate emulsion polymer with a glass transition temperature of below 0° C. and with a median particle size of from 50 to 1000 nm, preferably from 50 to 500 nm b: as component B, from 1 to 99% by weight, preferably from 40 to 85% by weight, in particular from 50 to 75% by weight, of at least one amorphous or partly crystalline polymer, c: as component C, from 0 to 50% by weight of polycarbonates, and d: as component D, from 0 to 50% by weight of fibrous or particulate fillers or mixtures of these for producing sheet-like wall elements and fastening parts therefor.
摘要翻译： 使用不同于ABS的热塑性模塑组合物，并且基于总量为100重量％的组分A和B的量，以及如果需要，包括C和/或D，a：作为组分A，从1至 99重量％，优选15至60重量％，特别是25至50重量％的玻璃化转变温度低于0℃的颗粒状乳液聚合物，中值粒度为50至 1000nm，优选50-500nmb：作为组分B，1-99重量％，优选40-85重量％，特别是50-75重量％的至少一种无定形或部分结晶聚合物 ，c：作为组分C，0至50重量％的聚碳酸酯，和d：作为组分D，0至50重量％的纤维或颗粒填料或它们的混合物用于生产片状壁元件及其紧固部件。
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公开(公告)号：US06103813A
公开(公告)日：2000-08-15
申请号：US230349
申请日：1999-01-25
申请人： Herbert Naarmann , Graham Edmund Mc Kee , Alfred Pirker , Hans-Josef Sterzel , Franz Brandstetter , Bernd-Steffen von Bernstorff , Bernhard Rosenau , Ulrich Endemann , Burkhard Straube
发明人： Herbert Naarmann , Graham Edmund Mc Kee , Alfred Pirker , Hans-Josef Sterzel , Franz Brandstetter , Bernd-Steffen von Bernstorff , Bernhard Rosenau , Ulrich Endemann , Burkhard Straube
IPC分类号： C08L101/00 , C08F255/02 , C08F265/00 , C08F265/04 , C08F283/12 , C08L25/12 , C08L51/00 , C08L81/04 , F04D29/70 , F24F13/08 , C08L51/04
CPC分类号： F04D29/703 , C08F255/02 , C08F265/04 , C08F283/12 , C08L25/12 , C08L81/04 , C08L51/003 , F24F13/082
摘要： The use of a thermoplastic molding composition differing from ABS and comprising, based on a total of 100% by weight of amounts of components A and B, and, if desired, C and/or D,a: as component A, from 1 to 99% by weight, preferably from 15 to 60% by weight, in particular from 25 to 50% by weight, of a particulate emulsion polymer with a glass transition temperature of below 0.degree. C. and with a median particle size of from 50 to 1000 nm, preferably from 50 to 500 nm,b: as component B, from 1 to 99% by weight, preferably from 40 to 85% by weight, in particular from 50 to 75% by weight, of at least one amorphous or partly crystalline polymer,c: as component C, from 0 to 50% by weight of polycarbonates, andd: as component D, from 0 to 50% by weight of fibrous or particulate fillers or mixtures of thesefor producing covering grid plates for ventilator openings.
摘要翻译： PCT No.PCT / EP97 / 04032 Sec。 371日期1999年1月25日 102（e）日期1999年1月25日PCT提交1997年7月24日PCT公布。 出版物WO98 / 04632 日期1998年2月5日使用不同于ABS的热塑性模塑组合物，其包含基于总量100重量份的组分A和B的量，以及如果需要，包括C和/或D，a：作为组分 A，1至99重量％，优选15至60重量％，特别是25至50重量％的玻璃化转变温度低于0℃的颗粒状乳液聚合物和中值粒子 尺寸为50至1000nm，优选50至500nm，b：作为组分B，1至99重量％，优选40至85重量％，特别是50至75重量％的 至少一种无定形或部分结晶聚合物，c：作为组分C，0至50重量％的聚碳酸酯，d：作为组分D，0至50重量％的纤维或颗粒填料或这些的混合物用于生产覆盖物 格栅板用于呼吸机开口。
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公开(公告)号：US5530087A
公开(公告)日：1996-06-25
申请号：US347367
申请日：1994-12-02
申请人： Herbert Naarmann , Rudolf Gompper , Thomas Mueller
发明人： Herbert Naarmann , Rudolf Gompper , Thomas Mueller
IPC分类号： G02F1/35 , C08G73/00 , C08G73/02 , C08L101/00 , C09D179/02 , C09K3/00 , C09K9/02 , G02F1/355 , G02F1/361 , H01B1/12
CPC分类号： C08G73/00 , G02F1/3616
摘要： Polyanils of the general formula ##STR1## where R.sup.1 is C.sub.1 -C.sub.24 -alkyl, C.sub.1 -C.sub.24 -alkoxy, Cl, Br, CF.sub.3 or NO.sub.2,R.sup.2 is para-phenylene, a fused aromatic ring system of 10 to 30 carbon atoms or ##STR2## R.sup.3 is a chemical bond, S, O, NH, CH.sub.2, CH.dbd.CH, CO, SO or SS andn is an integer from 5 to 100,and their acid addition salts of the general formula II ##STR3## where X.sup.- is ClO.sub.4.sup.-, BF.sub.4.sup.-, AsF.sub.6.sup.- or ##STR4## and R.sub.4 is C.sub.1 --C.sub.8 -alkyl are disclosed. The polyanils are useful as electrically conductive materials and for nonlinear optical purposes.
摘要翻译： PCT No.PCT / EP93 / 01303 Sec。 371日期1994年12月2日第 102（e）日期1994年12月2日PCT提交1993年5月25日PCT公布。 公开号WO93 / 25603 日本公报1993年12月23日。通式“IMAGE”I的聚苯胺，其中R 1为C 1 -C 24 - 烷基，C 1 -C 24 - 烷氧基，Cl，Br，CF 3或NO 2，R 2为对 - 亚苯基，稠合芳环系 10到30个碳原子或者是一个化学键，S，O，NH，CH 2，CH = CH，CO，SO或SS，n是5到100的整数，它们的一般酸加成盐 公开了II式，其中X是ClO 4 - ，BF 4 - ，AsF 6 - 或者“IMA”，R 4是C 1 -C 8烷基。 聚酰胺可用作导电材料和非线性光学目的。
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公开(公告)号：US4927578A
公开(公告)日：1990-05-22
申请号：US195663
申请日：1988-05-18
摘要： Virtually uncrosslinked polyacetylenes in film form are prepared by polymerization of acetylene using a liquid catalyst system consisting of an organicaluminum compound and a titanate in the form of a solution in a viscous inert liquid on a substrate to which the catalyst solution is applied, by a process in which, after the polymerization, the polymer is treated with a strong reducing agent which is inert to the organoaluminum catalyst component, the polymer is, if desired, oriented and is freed from residual catalyst and reducing agent by washing with a liquid, doped with a strong electron acceptor or electron donor in a conventional manner to increase the conductivity and dried, and the materials thus obtained are, if desired, covered with a layer or sheath of nonconductive material.
摘要翻译： 膜形式的几乎未交联的聚乙炔通过使用由有机铝化合物和钛酸盐形成的液体催化剂体系的乙炔聚合制备，所述液体催化剂体系为溶液形式的溶液，所述液体催化剂体系是在施加有催化剂溶液的基材上的粘性惰性液体中， 其中聚合后聚合物用对有机铝催化剂组分是惰性的强还原剂处理，如果需要，聚合物是取向的，并通过用液体洗涤而被除去残余的催化剂和还原剂，掺杂 强电子受体或电子给体以常规方式增加导电性并干燥，如果需要，由此获得的材料被非导电材料层或鞘覆盖。
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公开(公告)号：US4566955A
公开(公告)日：1986-01-28
申请号：US631946
申请日：1984-07-18
申请人： Herbert Naarmann
发明人： Herbert Naarmann
CPC分类号： C08G61/124 , C08G73/06 , H01B1/127 , H01M4/60
摘要： Finely divided electrically conductive pyrrole polymers are prepared by a process in which a finely divided pyrrole polymer, obtained by polymerization of pyrroles in solution with an oxygen-containing oxidizing agent, is electrochemically charged in the presence of a conductive salt. The finely divided electrically conductive pyrrole polymers can be used for the production of moldings.
摘要翻译： 精细分散的导电吡咯聚合物通过以下方法制备，其中通过在含有氧的氧化剂溶液中聚合吡咯而获得的细碎的吡咯聚合物在导电盐存在下进行电化学充电。 精细分散的导电吡咯聚合物可用于制造模制品。
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公开(公告)号：US4532188A
公开(公告)日：1985-07-30
申请号：US504723
申请日：1983-06-16
IPC分类号： H01M4/60 , C08F38/00 , C08G61/00 , C08G61/10 , C08G61/12 , C08J7/02 , C08L65/00 , H01B1/12 , H01L21/331 , H01L29/73 , H01L51/05 , H01L51/30 , H01L51/40 , B32B27/00 , C25B11/00
CPC分类号： H01B1/127 , C08G61/124 , Y10T428/31855 , Y10T428/8305
摘要： Highly electrically conductive copolymers of pyrroles and alkynes and/or aromatics, which possess good mechanical properties coupled with a well-balanced spectrum of properties, are prepared by anodic polymerization of the pyrroles and alkynes and/or aromatics in a polar solvent in the presence of a suitable conductive salt.
摘要翻译： 通过吡咯和炔和/或芳族化合物在极性溶剂中的存在下阳极聚合，制备具有良好机械性能与良好平衡的性质光谱的吡咯和炔和/或芳族化合物的高度导电的共聚物 合适的导电盐。
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公开(公告)号：US4436854A
公开(公告)日：1984-03-13
申请号：US344015
申请日：1982-01-29
IPC分类号： C08L25/00 , C08K5/00 , C08L7/00 , C08L21/00 , C08L51/00 , C08L51/02 , C08L51/04 , C08L71/00 , C08L71/12 , C08K5/52 , C08K5/53 , C08L71/04
CPC分类号： C08L51/04 , C08K5/0066 , C08L71/123
摘要： Self-extinguishing molding materials, comprising (A) a polymer of a vinyl-aromatic compound, especially a styrene polymer, which has been made impact-resistant (B) a polyphenylene ether and (C) a flameproofing additive, with or without (D) conventional additives, wherein one part of the soft component of the impact-resistant polymer of the vinyl-aromatic compound has a mean particle size of .ltoreq.1.5 .mu.m and the other part has a mean particle size of .ltoreq.3 .mu.m. Such molding materials not only have good self-extinguishing properties but also give moldings having a particularly uniform matt surface.
摘要翻译： 自动灭火成型材料，包括（A）已经制成抗冲击性的乙烯基芳族化合物，特别是苯乙烯聚合物的聚合物（B）聚苯醚和（C）具有或不具有（D）的（C）阻燃添加剂 ）常规添加剂，其中乙烯基芳族化合物的耐冲击聚合物的一部分软组分的平均粒度为<1.5μm，另一部分的平均粒度为<3μm m。 这种成型材料不仅具有良好的自熄性，而且还具有特别均匀的无光泽表面的模制品。
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公开(公告)号：US4412037A
公开(公告)日：1983-10-25
申请号：US302040
申请日：1981-09-14
IPC分类号： C08L25/00 , C08L7/00 , C08L21/00 , C08L51/00 , C08L51/02 , C08L51/04 , C08L71/00 , C08L71/12 , C08L61/04
CPC分类号： C08L51/04 , C08L71/123
摘要： Thermoplastic molding materials based on styrene polymers which have been made impact-resistant and on polyphenylene ethers, wherein the particles of the soft component of the styrene polymer which has been made impact-resistant have a mean diameter of more than 1 micron, and wherein the proportion of particles which have a diameter of less than 0.6 micron is not less than 40% by weight and the proportion of particles which have a diameter of from 0.6 to 3 microns is less than 3% by weight.
摘要翻译： 基于已经制成抗冲击性的苯乙烯聚合物和聚苯醚的热塑性成型材料，其中已经制成抗冲击性的苯乙烯聚合物的软组分的颗粒具有大于1微米的平均直径，并且其中 直径小于0.6微米的颗粒的比例不小于40重量％，直径为0.6至3微米的颗粒的比例小于3重量％。
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