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    O-coordinated metal chelates and their use in optical recording media having high storage capacity
    7.
    发明申请
    O-coordinated metal chelates and their use in optical recording media having high storage capacity 审中-公开
    O-配位金属螯合物及其在存储容量高的光记录介质中的应用

    公开(公告)号：US20060177621A1

    公开(公告)日：2006-08-10

    申请号：US10565138

    申请日：2004-07-12

    申请人： Frank Bienewald ,  Jean-Luc Budry ,  Beat Schmidhalter ,  Annemarie Wolleb ,  Heinz Wolleb

    发明人： Frank Bienewald ,  Jean-Luc Budry ,  Beat Schmidhalter ,  Annemarie Wolleb ,  Heinz Wolleb

    IPC分类号： B32B3/02

    CPC分类号： G11B7/246 ,  C07C225/14 ,  C07D207/20 ,  C07D209/12 ,  C07D209/34 ,  C07D211/86 ,  C07D213/69 ,  C07D233/48 ,  C07D235/30 ,  C07D239/62 ,  C07D239/66 ,  C07D263/14 ,  C07D277/64 ,  C07D277/82 ,  C07D309/32 ,  C07D309/38 ,  C07D319/06 ,  C07D403/06 ,  G11B7/247 ,  G11B7/249 ,  G11B7/2534 ,  G11B7/259

    摘要： The invention relates to novel optical recording materials that comprise specific and in some cases novel diketone enamines or metal chelates thereof and that have excellent recording and playback quality especially at a wavelength of 350-500 nm. The invention accordingly relates to an optical recording medium comprising a substrate, a recording layer and optionally a reflecting layer, wherein the recording layer comprises a compound of formula (I), wherein M is hydrogen, aluminium or, preferably, a transition metal, which may in addition be coordinated with one or more further ligands and/or, for balancing out an excess charge, where applicable, may have an electrostatic interaction with one or more further ions inside or outside the coordination sphere, but M in formulae (Ib) and (Ic) is not hydrogen, Q is C—H, N or C—R6, it being possible for the stereochemistry of the C=Q double bond to be either E or Z. For the exact definitions of R1 to R6 reference should be made to the description. Also claimed are the novel compounds, especially tetracoordinated chelates, and a process for the preparation thereof.

    摘要翻译： 本发明涉及新颖的光学记录材料，其特别地包括新颖的二酮烯胺或其金属螯合物，并且具有优异的记录和回放质量，特别是在350-500nm的波长下。 因此，本发明涉及一种包括基底，记录层和任选地反射层的光学记录介质，其中记录层包含式（I）化合物，其中M是氢，铝或优选的过渡金属，其中 另外可以与一种或多种其它配位体配位和/或用于平衡过量电荷（如果适用的话）可能与配位球内部或外部的一种或多种其它离子具有静电相互作用，而式（Ib） 和（Ic）不是氢，Q是CH，N或CR 6，C = Q双键的立体化学可以是E或Z。对于R的确切定义 应当对说明书进行参考。 还要求保护的是新化合物，特别是四配位螯合物，以及其制备方法。

    Metallocenyl-phthalocyanines
    8.
    发明授权
    Metallocenyl-phthalocyanines 有权
    金属茂 - 酞菁

    公开(公告)号：US06399768B1

    公开(公告)日：2002-06-04

    申请号：US09365471

    申请日：1999-08-02

    申请人： Heinz Wolleb ,  Annemarie Wolleb ,  Beat Schmidhalter ,  Jean-Luc Budry

    发明人： Heinz Wolleb ,  Annemarie Wolleb ,  Beat Schmidhalter ,  Jean-Luc Budry

    IPC分类号： G11B724

    CPC分类号： C07F17/00 ,  C07F17/02 ,  C09B47/08 ,  C09B67/0035 ,  Y10S430/146 ,  Y10T428/12722 ,  Y10T428/21

    摘要： There was found a metallocenyl-phthalocyanine or its metal complex of a divalent metal, oxometal, halogenometal or hydroxymetal, in which at least one of the four phenyl rings of the phthalocyanine contains, bound via a bridge unit E, at least one metallocene radical as substituent, E being composed of a chain of at least two atoms or atom groups selected from the group consisting of —CH2—, —C(═O)—, —CH(C1-C4alkyl)—, —C(C1-C4alkyl)2—, —NH—, —S—, —O— and —CH═CH—, as well as mixtures of the novel compounds which comprise, inter alia, isomers, a process for the production, the use and recording media comprising the novel compounds.

    摘要翻译： 发现金属茂金属酞菁或其二价金属，氧化金属，卤素金属或羟基金属的金属络合物，其中酞菁的四个苯环中的至少一个含有通过桥单元E结合至少一个金属茂基团作为 取代基，E由至少两个原子的链或选自-CH 2 - ， - C（= O） - ， - CH（C 1 -C 4烷基） - ， - C（C 1 -C 4烷基） 2-，-NH-，-S-，-O-和-CH = CH-，以及包含异构体的新化合物的混合物，制备方法，使用和记录介质，其包含 新化合物。

    Metallocenyl-phthalocyanines
    9.
    发明授权
    Metallocenyl-phthalocyanines 失效
    金属茂 - 酞菁

    公开(公告)号：US06790593B2

    公开(公告)日：2004-09-14

    申请号：US10037106

    申请日：2001-10-22

    申请人： Heinz Wolleb ,  Annemarie Wolleb ,  Beat Schmidhalter ,  Jean-Luc Budry

    发明人： Heinz Wolleb ,  Annemarie Wolleb ,  Beat Schmidhalter ,  Jean-Luc Budry

    IPC分类号： G11B724

    CPC分类号： C07F17/00 ,  C07F17/02 ,  C09B47/08 ,  C09B67/0035 ,  Y10S430/146 ,  Y10T428/12722 ,  Y10T428/21

    摘要： There was found a metallocenyl-phthalocyanine or its metal complex of a divalent metal, oxometal, halogenometal or hydroxymetal, in which at least one of the four phenyl rings of the phthalocyanine contains, bound via a bridge unit E, at least one metallocene radical as substituent, E being composed of a chain of at least two atoms or atom groups selected from the group consisting of —CH2—, —C(═O)—, —CH(C1-C4alkyl)—, —C(C1-C4alkyl)2—, —NH—, —S—, —O— and —CH═CH—, as well as mixtures of the novel compounds which comprise, inter alia, isomers, a process for the production, the use and recording media comprising the novel compounds.

    摘要翻译： 发现金属茂金属酞菁或其二价金属，氧化金属，卤素金属或羟基金属的金属络合物，其中酞菁的四个苯环中的至少一个含有通过桥单元E结合至少一个金属茂基团作为 取代基，E由至少两个原子的链或选自-CH 2 - ， - C（= O） - ， - CH（C 1 -C 4烷基） - ， - C（C 1 -C 4烷基） 2-，-NH-，-S-，-O-和-CH = CH-，以及包含异构体的新化合物的混合物，制备方法，使用和记录介质，其包含 新化合物。

    High-capacity storage media
    10.
    发明授权
    High-capacity storage media 失效
    大容量存储介质

    公开(公告)号：US5851621A

    公开(公告)日：1998-12-22

    申请号：US842292

    申请日：1997-04-23

    申请人： Heinz Wolleb ,  Beat Schmidhalter ,  Jean-Luc Budry

    发明人： Heinz Wolleb ,  Beat Schmidhalter ,  Jean-Luc Budry

    IPC分类号： B41M5/26 ,  C07D311/82 ,  C07D491/16 ,  C09B11/28 ,  G11B7/244 ,  G11B7/246 ,  G11B7/249 ,  G11B7/253 ,  G11B7/2534 ,  G11B7/258 ,  B32B3/00

    CPC分类号： G11B7/246 ,  C09B11/28 ,  G11B7/249 ,  G11B7/253 ,  G11B7/258 ,  G11B7/2534 ,  Y10S428/913 ,  Y10S430/146 ,  Y10T428/21 ,  Y10T428/31678

    摘要： The invention relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, which recording layer consists essentially of a dye of the formula (I), ##STR1## in which R.sub.1 and R.sub.6 are hydrogen or unsubstituted or substituted alkyl, alkenyl, alkynyl, aralkyl or aryl, R.sub.6 and R.sub.7 are unsubstituted or substituted alkyl, alkenyl, alkynyl, aralky or aryl, R.sub.3, R.sub.4, R.sub.8 and R.sub.9 are hydrogen, halogen, OR.sub.17, SR.sub.17, NR.sub.18 R.sub.19, NO.sub.2, alkyl, alkenyl or Alkynyl, R.sub.5 and R.sub.10 are hydrogen, halogen, OR.sub.17, SR.sub.17, NO.sub.2, NR.sub.18 R.sub.19 or unsubstituted or substituted alkyl, alkenyl, alkynyl or aralkyl, and R.sub.11 is hydrogen, (CH.sub.2).sub.1-10 COO.sup.-, (CH.sub.2).sub.1-10 COOR.sub.24, alkyl, alkenyl, alkynyl or unsubstituted or substituted aralkyl or aryl; Y is the anion of an inorganic, organic or organometallic acid, Z is a metal cation, ammonium cation or phosphonium cation, m, n and o are from 1 to 3, and p and q are from 0 to 4; and the stoichiometry of o, p and q is such as not to result in any excess positive or negative charge in the formula (I). The substituents can, if desired, be connected to one another in such a way, via a direct bond or via a bridge --O-- or --NR.sub.12 --, as to form additional five- or six-membered rings. The novel recording media are of high sensitivity and have good reproduction characteristics.

    摘要翻译： 本发明涉及一种光记录介质，其包括基板，反射层和记录层，该记录层基本上由式（I）的染料，其中R 1和R 6为氢或未取代的 或取代的烷基，烯基，炔基，芳烷基或芳基，R6和R7是未取代的或取代的烷基，烯基，炔基，芳基或芳基，R3，R4，R8和R9分别是氢，卤素，OR17，SR17，NR18R19， ，烯基或炔基，R 5和R 10是氢，卤素，OR 17，SR 17，NO 2，NR 18 R 19或未取代或取代的烷基，烯基，炔基或芳烷基，R 11是氢，（CH 2）1-10 COO-，（CH 2） 烷基，烯基，炔基或未取代或取代的芳烷基或芳基; Y是无机，有机或有机金属酸的阴离子，Z是金属阳离子，铵阳离子或鏻阳离子，m，n和o为1至3，p和q为0至4; 并且o，p和q的化学计量比如在式（I）中不会导致任何过量的正电荷或负电荷。 如果需要，取代基可以以这样的方式通过直接键或通过桥-O-或-NR 12 - 彼此连接，形成另外的五元或六元环。 该新颖的记录介质具有高灵敏度和良好的再生特性。