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22 条记录 (耗时 0.03 秒)

    O-coordinated metal chelates and their use in optical recording media having high storage capacity
    4.
    发明申请
    O-coordinated metal chelates and their use in optical recording media having high storage capacity 审中-公开
    O-配位金属螯合物及其在存储容量高的光记录介质中的应用

    公开(公告)号：US20060177621A1

    公开(公告)日：2006-08-10

    申请号：US10565138

    申请日：2004-07-12

    申请人： Frank Bienewald ,  Jean-Luc Budry ,  Beat Schmidhalter ,  Annemarie Wolleb ,  Heinz Wolleb

    发明人： Frank Bienewald ,  Jean-Luc Budry ,  Beat Schmidhalter ,  Annemarie Wolleb ,  Heinz Wolleb

    IPC分类号： B32B3/02

    CPC分类号： G11B7/246 ,  C07C225/14 ,  C07D207/20 ,  C07D209/12 ,  C07D209/34 ,  C07D211/86 ,  C07D213/69 ,  C07D233/48 ,  C07D235/30 ,  C07D239/62 ,  C07D239/66 ,  C07D263/14 ,  C07D277/64 ,  C07D277/82 ,  C07D309/32 ,  C07D309/38 ,  C07D319/06 ,  C07D403/06 ,  G11B7/247 ,  G11B7/249 ,  G11B7/2534 ,  G11B7/259

    摘要： The invention relates to novel optical recording materials that comprise specific and in some cases novel diketone enamines or metal chelates thereof and that have excellent recording and playback quality especially at a wavelength of 350-500 nm. The invention accordingly relates to an optical recording medium comprising a substrate, a recording layer and optionally a reflecting layer, wherein the recording layer comprises a compound of formula (I), wherein M is hydrogen, aluminium or, preferably, a transition metal, which may in addition be coordinated with one or more further ligands and/or, for balancing out an excess charge, where applicable, may have an electrostatic interaction with one or more further ions inside or outside the coordination sphere, but M in formulae (Ib) and (Ic) is not hydrogen, Q is C—H, N or C—R6, it being possible for the stereochemistry of the C=Q double bond to be either E or Z. For the exact definitions of R1 to R6 reference should be made to the description. Also claimed are the novel compounds, especially tetracoordinated chelates, and a process for the preparation thereof.

    摘要翻译： 本发明涉及新颖的光学记录材料，其特别地包括新颖的二酮烯胺或其金属螯合物，并且具有优异的记录和回放质量，特别是在350-500nm的波长下。 因此，本发明涉及一种包括基底，记录层和任选地反射层的光学记录介质，其中记录层包含式（I）化合物，其中M是氢，铝或优选的过渡金属，其中 另外可以与一种或多种其它配位体配位和/或用于平衡过量电荷（如果适用的话）可能与配位球内部或外部的一种或多种其它离子具有静电相互作用，而式（Ib） 和（Ic）不是氢，Q是CH，N或CR 6，C = Q双键的立体化学可以是E或Z。对于R的确切定义 应当对说明书进行参考。 还要求保护的是新化合物，特别是四配位螯合物，以及其制备方法。

    Metallocenyl-phthalocyanines
    6.
    发明授权
    Metallocenyl-phthalocyanines 有权
    金属茂 - 酞菁

    公开(公告)号：US06399768B1

    公开(公告)日：2002-06-04

    申请号：US09365471

    申请日：1999-08-02

    申请人： Heinz Wolleb ,  Annemarie Wolleb ,  Beat Schmidhalter ,  Jean-Luc Budry

    发明人： Heinz Wolleb ,  Annemarie Wolleb ,  Beat Schmidhalter ,  Jean-Luc Budry

    IPC分类号： G11B724

    CPC分类号： C07F17/00 ,  C07F17/02 ,  C09B47/08 ,  C09B67/0035 ,  Y10S430/146 ,  Y10T428/12722 ,  Y10T428/21

    摘要： There was found a metallocenyl-phthalocyanine or its metal complex of a divalent metal, oxometal, halogenometal or hydroxymetal, in which at least one of the four phenyl rings of the phthalocyanine contains, bound via a bridge unit E, at least one metallocene radical as substituent, E being composed of a chain of at least two atoms or atom groups selected from the group consisting of —CH2—, —C(═O)—, —CH(C1-C4alkyl)—, —C(C1-C4alkyl)2—, —NH—, —S—, —O— and —CH═CH—, as well as mixtures of the novel compounds which comprise, inter alia, isomers, a process for the production, the use and recording media comprising the novel compounds.

    摘要翻译： 发现金属茂金属酞菁或其二价金属，氧化金属，卤素金属或羟基金属的金属络合物，其中酞菁的四个苯环中的至少一个含有通过桥单元E结合至少一个金属茂基团作为 取代基，E由至少两个原子的链或选自-CH 2 - ， - C（= O） - ， - CH（C 1 -C 4烷基） - ， - C（C 1 -C 4烷基） 2-，-NH-，-S-，-O-和-CH = CH-，以及包含异构体的新化合物的混合物，制备方法，使用和记录介质，其包含 新化合物。

    Metallocenyl-phthalocyanines
    9.
    发明授权
    Metallocenyl-phthalocyanines 失效
    金属茂 - 酞菁

    公开(公告)号：US06790593B2

    公开(公告)日：2004-09-14

    申请号：US10037106

    申请日：2001-10-22

    申请人： Heinz Wolleb ,  Annemarie Wolleb ,  Beat Schmidhalter ,  Jean-Luc Budry

    发明人： Heinz Wolleb ,  Annemarie Wolleb ,  Beat Schmidhalter ,  Jean-Luc Budry

    IPC分类号： G11B724

    CPC分类号： C07F17/00 ,  C07F17/02 ,  C09B47/08 ,  C09B67/0035 ,  Y10S430/146 ,  Y10T428/12722 ,  Y10T428/21

    摘要： There was found a metallocenyl-phthalocyanine or its metal complex of a divalent metal, oxometal, halogenometal or hydroxymetal, in which at least one of the four phenyl rings of the phthalocyanine contains, bound via a bridge unit E, at least one metallocene radical as substituent, E being composed of a chain of at least two atoms or atom groups selected from the group consisting of —CH2—, —C(═O)—, —CH(C1-C4alkyl)—, —C(C1-C4alkyl)2—, —NH—, —S—, —O— and —CH═CH—, as well as mixtures of the novel compounds which comprise, inter alia, isomers, a process for the production, the use and recording media comprising the novel compounds.

    摘要翻译： 发现金属茂金属酞菁或其二价金属，氧化金属，卤素金属或羟基金属的金属络合物，其中酞菁的四个苯环中的至少一个含有通过桥单元E结合至少一个金属茂基团作为 取代基，E由至少两个原子的链或选自-CH 2 - ， - C（= O） - ， - CH（C 1 -C 4烷基） - ， - C（C 1 -C 4烷基） 2-，-NH-，-S-，-O-和-CH = CH-，以及包含异构体的新化合物的混合物，制备方法，使用和记录介质，其包含 新化合物。

    Writable and erasable high-density optical storage media
    10.
    发明授权
    Writable and erasable high-density optical storage media 失效
    可写和可擦除的高密度光存储介质

    公开(公告)号：US06245403B1

    公开(公告)日：2001-06-12

    申请号：US09069266

    申请日：1998-04-29

    申请人： Heinz Spahni ,  Jin Mizuguchi ,  Beat Schmidhalter ,  Annemarie Wolleb ,  Jean-Luc Budry ,  Gérald Giller

    发明人： Heinz Spahni ,  Jin Mizuguchi ,  Beat Schmidhalter ,  Annemarie Wolleb ,  Jean-Luc Budry ,  Gérald Giller

    IPC分类号： B32B302

    CPC分类号： C07D471/06 ,  C09B5/62 ,  G11B7/00455 ,  G11B7/0052 ,  G11B7/00552 ,  G11B7/006 ,  G11B7/244 ,  Y10S428/913 ,  Y10S430/146 ,  Y10T428/21

    摘要： The invention relates to an optical storage medium comprising a substrate and a storage layer, wherein the storage layer comprises a compound of the formula (I) or (II) in which A and A′, independently of one another, are unsubstituted or mono- or di-halo-, -hydroxy-, —C1-C6alkyl-, —C1-C6alkoxy-, -cyano- or -nitro-substituted phenyl, pyridyl, pyrrolyl, imidazolyl, furyl or thienyl, which can, if desired, be fused to a benzene ring, are halide, tetrafluoroborate or unsubstituted or with one or more halogen substituted C1-C6alkane-sulfonate, benzenesulfonate, C1-C6alkylbenzenesulfonate, C1-C6alkylsulfate or di-C1-C6alkyl-phosphonate of N—C1-C6alkyl-pyridiniumyl, or are unsubstituted or mono- or di-hydroxy-substituted C2-C6alkyl or C2-C6alkenyl, whose chain may be uninterrupted or interrupted by one or two oxygen atoms, B and B′, independently of one another, are 2 H, S, S2 or SO2, and n and n′, independently of one another, are each a number from 1 to 4. The invention also relates to a process for the optical writing, storage, reading, modification or erasing of data at a wavelength of from 400 to 700 nm using a novel recording medium, to an optical recorder for the optical writing, modification or erasing of data using only continuous laser radiation or only modulated laser radiation, to a process for converting a compound of the formula (I) or (II) from a black form into a red form by mechanical force, and to new compounds of the formula (I) or (II).

    摘要翻译： 本发明涉及一种包括基材和存储层的光学存储介质，其中该储存层包含式（I）或（II）的化合物，其中A和A'彼此独立地为未取代的或单 - 或二卤代 - ， - 羟基 - ，-C 1 -C 6烷基 - ， - C 1 -C 6烷氧基 - ， - 氰基 - 或 - 硝基取代的苯基，吡啶基，吡咯基，咪唑基，呋喃基或噻吩基，如果需要， 苯基环，卤素取代的C 1 -C 6烷基磺酸酯，苯磺酸酯，C 1 -C 6烷基苯磺酸酯，C 1 -C 6烷基硫酸酯或N-C 1 -C 6烷基 - 吡啶鎓基的二-C 1 -C 6烷基 - 膦酸酯， 或未被取代的单或二羟基取代的C 2 -C 6烷基或C 2 -C 6烯基，其链可以不间断或被一个或两个氧原子间隔，B和B'彼此独立地为2 H，S， S2或SO2，n和n'彼此独立地为1至4的数。本发明还涉及一种pr 用于使用新颖的记录介质将波长为400至700nm的数据的光学写入，存储，读取，修改或擦除的光学记录到用于仅使用连续激光辐射的光学写入，修改或擦除数据的光学记录器， 通过机械力将式（I）或（II）的化合物从黑色形式转化成红色的方法，以及式（I）或（II）的新化合物的方法。