公开(公告)号：US07115774B2

公开(公告)日：2006-10-03

申请号：US10443116

申请日：2003-05-22

申请人： Lionel Magna ,  Helene Olivier-Bourbigou ,  Stephane Harry ,  Dominique Commereuc

发明人： Lionel Magna ,  Helene Olivier-Bourbigou ,  Stephane Harry ,  Dominique Commereuc

IPC分类号： C07C51/12

CPC分类号： B01J31/0292 ,  B01D3/009 ,  B01J8/005 ,  B01J8/025 ,  B01J31/0231 ,  B01J31/0239 ,  B01J31/0268 ,  B01J31/0278 ,  B01J31/0288 ,  B01J31/20 ,  B01J31/2234 ,  B01J31/26 ,  B01J31/30 ,  B01J31/4038 ,  B01J31/4046 ,  B01J2219/00006 ,  B01J2219/00047 ,  B01J2231/321 ,  B01J2231/34 ,  B01J2531/822 ,  B01J2531/827 ,  C07C51/12 ,  Y02P20/127 ,  Y02P20/584 ,  C07C53/08

摘要： In a process for liquid phase carbonylation of alcohols by carbon monoxide, the carbonylation reaction is carried out in a reaction zone at a temperature of 50° C. to 150° C. at a pressure in the range 0.5 MPa to 20 MPa in the presence of at least one catalyst comprising at least one rhodium and/or iridium complex and a halogenated promoter in at least one non-aqueous ionic liquid comprising at least one salt with general formula Q+A−, in which Q+ represents a quaternary ammonium and/or a quaternary phosphonium cation, said salt having a melting point of less than 90° C.; the non-aqueous ionic liquid containing at least the major portion of the catalyst is separated; and the separated non-aqueous ionic liquid containing at least the major portion of the catalyst is returned to the reaction zone.

摘要翻译： 在通过一氧化碳液相羰基化醇的方法中，羰基化反应在50℃至150℃的温度下在反应区中在0.5MPa至20MPa的压力下进行， 至少一种包含至少一种铑和/或铱络合物的催化剂和至少一种非水离子液体中的卤化促进剂，其包含至少一种具有通式Q +的盐， 其中Q +表示季铵和/或季鏻阳离子，所述盐的熔点低于90℃; 分离至少含有催化剂主要部分的非水性离子液体; 并且至少含有主要部分催化剂的分离的非水性离子液体返回到反应区。

公开(公告)号：US06667269B2

公开(公告)日：2003-12-23

申请号：US09815332

申请日：2001-03-23

申请人： Helene Olivier-Bourbigou ,  Dominique Commereuc ,  Stephane Harry

发明人： Helene Olivier-Bourbigou ,  Dominique Commereuc ,  Stephane Harry

IPC分类号： B01J3100

CPC分类号： C07F15/04 ,  B01J31/143 ,  B01J31/2273 ,  B01J2231/20 ,  B01J2531/0297 ,  B01J2531/847 ,  C07C2/32 ,  C07C2531/14 ,  C07C2531/22

摘要： A catalytic composition for the dimerization, the codimerization or the oligomerization of olefins is obtained by bringing into contact at least one nickel compound that contains a heterocyclic carbene with at least one hydrocarbylaluminum halide and optionally at least one organic solvent. It is used in a process of dimerization, codimerization or oligomerization of olefins.

摘要翻译： 通过使包含至少一种烃基卤化铝和任选的至少一种有机溶剂的至少一种含有杂环卡宾的镍化合物接触来进行二烯化，烯丙基的二聚化或低聚反应的催化组合物。 它用于烯烃二聚，共聚或低聚的过程。

公开(公告)号：US06576724B2

公开(公告)日：2003-06-10

申请号：US09815347

申请日：2001-03-23

申请人： Helene Olivier-Bourbigou ,  Dominique Commereuc ,  Stephane Harry

发明人： Helene Olivier-Bourbigou ,  Dominique Commereuc ,  Stephane Harry

IPC分类号： C08F460

CPC分类号： C07C2/32 ,  B01J31/0284 ,  B01J31/0288 ,  B01J31/143 ,  B01J31/2273 ,  B01J2231/20 ,  B01J2531/847 ,  C07C2527/125 ,  C07C2531/22 ,  C07C2531/26

摘要： A catalytic composition for the dimerization, the codimerization or the oligomerization of olefins results from the dissolution of at least one nickel complex that contains a heterocyclic carbene in a liquid mixture that comprises at least one ammonium halide or quaternary phosphonium halide, at least one aluminum halide and optionally at least one organometallic aluminum compound. It is used in a process of dimerization, codimerization or oligomerization of olefins.

摘要翻译： 用于二聚，共聚或低聚烯烃的催化组合物是由至少一种含有杂环卡宾的镍络合物在包含至少一种卤化铵或季鏻卤化物的液体混合物中溶解，至少一种卤化铝 和任选的至少一种有机金属铝化合物。 它用于烯烃二聚，共聚或低聚的过程。

公开(公告)号：US08957270B2

公开(公告)日：2015-02-17

申请号：US13102593

申请日：2011-05-06

申请人： Sandrine Berard ,  Stephane Harry ,  Natacha Touchais ,  Lionel Magna ,  Helene Olivier-Bourbigou ,  Cedrik Popelin ,  David Proriol ,  Lucien Saussine

发明人： Sandrine Berard ,  Stephane Harry ,  Natacha Touchais ,  Lionel Magna ,  Helene Olivier-Bourbigou ,  Cedrik Popelin ,  David Proriol ,  Lucien Saussine

IPC分类号： C07C2/22 ,  C10G50/00

CPC分类号： C10G50/00 ,  C10G2300/1011 ,  C10G2300/703 ,  C10G2400/04 ,  C10G2400/08 ,  Y02P30/20

摘要： A process for producing a base for a fuel from a C2 ethanol feedstock, by a first stage for oligomerization of the feedstock into a hydrocarbon effluent that contains a mixture of olefins for the most part having between 4 and 30 carbons, and contains a C10-C24 fraction that has a mean linearity that is greater than 60%, in the presence of a homogeneous catalytic system that contains a metal precursor of titanium, zirconium, hafnium, nickel and/or iron, a second stage for oligomerization of a portion of the effluent that is obtained from stage a), into a hydrocarbon effluent that contains a mixture of olefins for the most part having between 4 and 30 carbon atoms, and containing a C10-C24 fraction that has a mean linearity that is less than 50%, in the presence of a homogeneous catalytic system.

摘要翻译： 一种用于从C2乙醇原料生产燃料的碱的方法，其通过第一阶段将原料低聚成含有大部分具有4-30个碳原子的烯烃混合物的烃流出物，并含有C10- 在含有钛，锆，铪，镍和/或铁的金属前体的均相催化体系的存在下，平均线性大于60％的C24级分，用于低聚物的一部分的第二阶段 从阶段a）获得的流出物包含含有大部分具有4-30个碳原子的烯烃混合物并含有平均线性小于50％的C 10 -C 24级分的烃流出物， 在均相催化体系的存在下。

公开(公告)号：US20110282119A1

公开(公告)日：2011-11-17

申请号：US13102593

申请日：2011-05-06

申请人： Sandrine BERARD ,  Stephane Harry ,  Natacha Touchais ,  Lionel Magna ,  Helene Olivier-Bourbigou ,  Cedrik Popelin ,  David Proriol ,  Lucien Saussine

发明人： Sandrine BERARD ,  Stephane Harry ,  Natacha Touchais ,  Lionel Magna ,  Helene Olivier-Bourbigou ,  Cedrik Popelin ,  David Proriol ,  Lucien Saussine

IPC分类号： C07C2/04

CPC分类号： C10G50/00 ,  C10G2300/1011 ,  C10G2300/703 ,  C10G2400/04 ,  C10G2400/08 ,  Y02P30/20

摘要： This invention describes a process for the production of bases for fuels (such as diesel and/or kerosene) from a C2 ethanol feedstock, whereby said process comprises at least a first stage for oligomerization of said feedstock into at least one hydrocarbon effluent that comprises a mixture of olefins that for the most part have between 4 and 30 carbons, whereby said olefin mixture comprises a C10-C24 fraction that has a mean linearity that is greater than 60%, in the presence of a homogeneous catalytic system that comprises at least one metal precursor that is selected from among the group that is formed by titanium, zirconium, hafnium, nickel and iron, taken by themselves or in a mixture, a second stage for oligomerization of at least a portion of the effluent that is obtained from stage a), into at least one hydrocarbon effluent that comprises a mixture of olefins that for the most part have between 4 and 30 carbon atoms, with said olefin mixture comprising a C10-C24 fraction that has a mean linearity that is less than 50%, in the presence of a homogeneous catalytic system that is identical to or different from the one that is used in stage a).

摘要翻译： 本发明描述了一种从C2乙醇原料生产燃料（例如柴油和/或煤油）的碱的方法，其中所述方法至少包括将所述原料低聚至至少一种碳氢化合物流出物的第一阶段，其包括 大部分具有4至30个碳原子的烯烃混合物，其中所述烯烃混合物包含平均线性大于60％的C10-C24级分，在均相催化体系存在下，其包含至少一种 选自由钛，锆，铪，镍和铁形成的组中的金属前体，它们本身或混合物中，第二阶段用于将至少一部分从阶段a获得的流出物 ）至少一种烃流出物，其包含大部分具有4至30个碳原子的烯烃混合物，所述烯烃混合物包含C10-C24部分，其中ha 在与a）阶段中使用的相同或不同的均相催化体系的存在下，其平均线性小于50％。